The properties of energetic materials sensitivity, physical and thermodynamic properties
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Berlin
De Gruyter
[2018]
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Schriftenreihe: | De Gruyter graduate
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LEADER | 00000nam a2200000 c 4500 | ||
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005 | 20190718 | ||
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020 | |a 3110521873 |9 3-11-052187-3 | ||
024 | 3 | |a 9783110521870 | |
035 | |a (OCoLC)1059290178 | ||
035 | |a (DE-599)DNB1136433252 | ||
040 | |a DE-604 |b ger |e rda | ||
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245 | 1 | 0 | |a The properties of energetic materials |b sensitivity, physical and thermodynamic properties |c Mohammad H. Keshavarz, Thomas M. Klapötke |
264 | 1 | |a Berlin |b De Gruyter |c [2018] | |
264 | 4 | |c © 2018 | |
300 | |a xii, 193 Seiten |b Illustrationen |c 24 cm | ||
336 | |b txt |2 rdacontent | ||
337 | |b n |2 rdamedia | ||
338 | |b nc |2 rdacarrier | ||
490 | 0 | |a De Gruyter graduate | |
650 | 0 | 7 | |a Thermodynamische Eigenschaft |0 (DE-588)4126056-9 |2 gnd |9 rswk-swf |
650 | 0 | 7 | |a Thermophysikalische Eigenschaft |0 (DE-588)4193167-1 |2 gnd |9 rswk-swf |
650 | 0 | 7 | |a Energetisches Material |0 (DE-588)7643045-5 |2 gnd |9 rswk-swf |
689 | 0 | 0 | |a Energetisches Material |0 (DE-588)7643045-5 |D s |
689 | 0 | 1 | |a Thermophysikalische Eigenschaft |0 (DE-588)4193167-1 |D s |
689 | 0 | 2 | |a Thermodynamische Eigenschaft |0 (DE-588)4126056-9 |D s |
689 | 0 | |5 DE-604 | |
700 | 1 | |a Klapötke, Thomas M. |d 1961- |e Verfasser |0 (DE-588)120550377 |4 aut | |
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999 | |a oai:aleph.bib-bvb.de:BVB01-030569281 |
Datensatz im Suchindex
_version_ | 1804178871925342208 |
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adam_text | Contents
Preface—v
About the authors — vii
1 Crystal density — 1
1 1 Quantum mechanical approach — 2
1 2 Empirical methods for the calculation of the crystal density
of different classes of energetic materials — 3
121 Nitroaromatic energetic compounds — 3
122 Acyclic and cyclic nitramines, nitrate esters and nitroaliphatic
compounds — 5
123 Improved method for the prediction of the crystal densities
of nitroaliphatics, nitrate esters and nitramines — 6
124 Reliable correlation for the prediction of the crystal densities
of polynitro arenes and polynitro heteroarenes — 8
125 The extended correlation for the prediction of the crystal density
of energetic compounds — 9
126 Energetic azido compounds —11
1 3 Empirical methods for the assessment of the crystal density
of hazardous ionic molecular energetic materials using the
molecular structures —13
131 Two general empirical methods —13
132 The effects of various substituents on the density of tetrazollum nitrate
salts —14
2 Heat of formation —17
2 1 Condensed and gas phase heats of formation
of energetic compounds —17
211 QM, MM and GA approaches—17
212 Empirical approaches or QSPR methods on the basis
of structural parameters —19
2 2 Energetic compounds with high nitrogen contents — 31
221 Using the molecular structure — 31
222 Gas phase information — 32
3 Melting point — 35
3 1 GAV, QSPR and quantum mechanical methods — 35
3 2 Simple empirical methods on the basis of molecular structure — 36
321 Nitroaromatic compounds — 37
X
Contents
3 2 2
3 2 3
3 2 4
3 2 5
3 2 6
3 2 7
3 2 8
4
4 1
4 1 1
4 1 2
4 1 3
4 1 4
4 1 5
4 2
5
5 1
5 2
5 2 1
5 2 2
5 2 3
5 2 4
6
6 1
6 2
6 2 1
6 2 2
Polynitro arene and polynitro heteroarene compounds — 37
Nitramines, nitrate esters, nitrate salts and nitroaliphatics — 39
Nonaromatic energetic compounds — 40
Improved method for predicting the melting points of energetic
compounds — 41
Organic molecules containing hazardous peroxide groups — 46
Organic azides — 47
General method for the prediction of melting points of energetic
compounds including organic peroxides, organic azides, organic
nitrates, polynitro arenes, polynitro heteroarenes, acyclic and cyclic
nitramines, nitrate esters and nitroaliphatic compounds — 48
Enthalpy and entropy of fusion — 65
Different approaches for the prediction of the enthalpy of fusion — 65
Nitroaromatic carbocyclic energetic compounds — 66
Nitroaromatic energetic compounds — 67
Nonaromatic energetic compounds containing nitramine, nitrate
and nitro functional groups — 68
improved method for the reliable prediction of the enthalpy of fusion
oil energetic compounds — 69
A reliable method to predict the enthalpy of fusion in energetic
materials — 72
Different methods to predict the entropy of fusion — 74
Heat of sublimation — 83
Quantum mechanical and complex approaches for predicting
the heat of sublimation — 83
The use of structural parameters — 84
Nitroaromatic compounds — 84
Nitramines — 85
Nitroaromatics, nitramines, nitroaliphatics and nitrate esters — 86
General method for polynitro arenes, polynitro heteroarenes, acyclic
and cyclic nitramines, nitrate esters, nitroaliphatics, cyclic and acyclic
peroxides, as well as nitrogen-rich compounds — 87
Impact sensitivity—91
Complex methods — 92
Simple methods on the basis of molecular structure — 94
Oxygen balance correlations — 94
Elemental composition and molecular moieties — 94
Contents — xi
7 Electric spark sensitivity—107
7 1 Measurement of electric spark sensitivity —107
7 2 Different methods for predicting electric spark sensitivity —108
7 3 Simple methods for predicting electrostatic spark sensitivity —108
731 Polynitroaromatic compounds—109
732 Cyclic and acyclic nitramines —109
733 General correlation for polynitroaromatics as well as cyclic
and acyclic nitramines —110
7 4 Some aspects of predictive methods — 111
8 Shock sensitivity —113
8 1 Small-scale gap test —113
8 2 Large-scale gap test--115
9 Friction sensitivity —119
10 Heat sensitivity —121
10 1 Thermal kinetics correlations —121
10 1 1 Nitroparrafins —122
10 1 2 Nitramines —123
10 1 3 Polynitro arenes —123
10 1 4 Organic energetic compounds-----125
10 2 Heat of decomposition and temperature
of thermal decomposition —126
10 2 1 Heat of decomposition of nitroaromatics —127
10 2 2 Heats of decomposition of organic peroxides —128
10 2 3 Onset and maximum loss temperatures —129
10 3 Deflagration temperature —135
W-3-1 fn+onadd—«5
iO-S-2 ^onadd—1136
10 3 3 Energetic compounds containing both F^onadd and Fnonadd —136
11 Relationships between different sensitivities —139
11 1 Relationship between impact sensitivity of energetic compounds
and activation energies of thermal decomposition —139
11 1 1 Nitroaromatics---140
11 1 2 Nitramines —140
11 2 Relationship between electric spark sensitivity and impact sensitivity
of nitroaromatics —141
11 3 Relationship between electric spark sensitivity and activation energy
of the thermal decomposition of nitramines —141
xii
Contents
11 4 Correlation of the electrostatic sensitivity and activation energies
for the thermal decomposition of nitroaromatics —142
11 5 Relationship between the activation energy of thermolysis
and friction sensitivity of cyclic and acyclic nitramines —143
Problems —145
Answers to Problems —155
List of symbols —159
A Glossary of compound names and heats of formation for pure as well as
composite explosives —165
B Calculation of the gas phase standard enthalpies of formation —169
References —177
|
any_adam_object | 1 |
author | Keshavarz, Mohammad Hossein 1966- Klapötke, Thomas M. 1961- |
author_GND | (DE-588)1139275755 (DE-588)120550377 |
author_facet | Keshavarz, Mohammad Hossein 1966- Klapötke, Thomas M. 1961- |
author_role | aut aut |
author_sort | Keshavarz, Mohammad Hossein 1966- |
author_variant | m h k mh mhk t m k tm tmk |
building | Verbundindex |
bvnumber | BV045180053 |
classification_rvk | VN 5480 |
ctrlnum | (OCoLC)1059290178 (DE-599)DNB1136433252 |
dewey-full | 662.2 |
dewey-hundreds | 600 - Technology (Applied sciences) |
dewey-ones | 662 - Explosives, fuels & related products |
dewey-raw | 662.2 |
dewey-search | 662.2 |
dewey-sort | 3662.2 |
dewey-tens | 660 - Chemical engineering |
discipline | Chemie / Pharmazie |
format | Book |
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id | DE-604.BV045180053 |
illustrated | Illustrated |
indexdate | 2024-07-10T08:10:52Z |
institution | BVB |
isbn | 9783110521870 3110521873 |
language | English |
oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-030569281 |
oclc_num | 1059290178 |
open_access_boolean | |
owner | DE-83 DE-19 DE-BY-UBM |
owner_facet | DE-83 DE-19 DE-BY-UBM |
physical | xii, 193 Seiten Illustrationen 24 cm |
publishDate | 2018 |
publishDateSearch | 2018 |
publishDateSort | 2018 |
publisher | De Gruyter |
record_format | marc |
series2 | De Gruyter graduate |
spelling | Keshavarz, Mohammad Hossein 1966- Verfasser (DE-588)1139275755 aut The properties of energetic materials sensitivity, physical and thermodynamic properties Mohammad H. Keshavarz, Thomas M. Klapötke Berlin De Gruyter [2018] © 2018 xii, 193 Seiten Illustrationen 24 cm txt rdacontent n rdamedia nc rdacarrier De Gruyter graduate Thermodynamische Eigenschaft (DE-588)4126056-9 gnd rswk-swf Thermophysikalische Eigenschaft (DE-588)4193167-1 gnd rswk-swf Energetisches Material (DE-588)7643045-5 gnd rswk-swf Energetisches Material (DE-588)7643045-5 s Thermophysikalische Eigenschaft (DE-588)4193167-1 s Thermodynamische Eigenschaft (DE-588)4126056-9 s DE-604 Klapötke, Thomas M. 1961- Verfasser (DE-588)120550377 aut Erscheint auch als Online-Ausgabe, PDF 978-3-11-052188-7 Erscheint auch als Online-Ausgabe, EPUB 978-3-11-052195-5 B:DE-101 application/pdf http://d-nb.info/1136433252/04 Inhaltsverzeichnis X:MVB https://www.degruyter.com/viewbooktoc/product/481100?format=B&rskey=xdRsTg HEBIS Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=030569281&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
spellingShingle | Keshavarz, Mohammad Hossein 1966- Klapötke, Thomas M. 1961- The properties of energetic materials sensitivity, physical and thermodynamic properties Thermodynamische Eigenschaft (DE-588)4126056-9 gnd Thermophysikalische Eigenschaft (DE-588)4193167-1 gnd Energetisches Material (DE-588)7643045-5 gnd |
subject_GND | (DE-588)4126056-9 (DE-588)4193167-1 (DE-588)7643045-5 |
title | The properties of energetic materials sensitivity, physical and thermodynamic properties |
title_auth | The properties of energetic materials sensitivity, physical and thermodynamic properties |
title_exact_search | The properties of energetic materials sensitivity, physical and thermodynamic properties |
title_full | The properties of energetic materials sensitivity, physical and thermodynamic properties Mohammad H. Keshavarz, Thomas M. Klapötke |
title_fullStr | The properties of energetic materials sensitivity, physical and thermodynamic properties Mohammad H. Keshavarz, Thomas M. Klapötke |
title_full_unstemmed | The properties of energetic materials sensitivity, physical and thermodynamic properties Mohammad H. Keshavarz, Thomas M. Klapötke |
title_short | The properties of energetic materials |
title_sort | the properties of energetic materials sensitivity physical and thermodynamic properties |
title_sub | sensitivity, physical and thermodynamic properties |
topic | Thermodynamische Eigenschaft (DE-588)4126056-9 gnd Thermophysikalische Eigenschaft (DE-588)4193167-1 gnd Energetisches Material (DE-588)7643045-5 gnd |
topic_facet | Thermodynamische Eigenschaft Thermophysikalische Eigenschaft Energetisches Material |
url | http://d-nb.info/1136433252/04 https://www.degruyter.com/viewbooktoc/product/481100?format=B&rskey=xdRsTg http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=030569281&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
work_keys_str_mv | AT keshavarzmohammadhossein thepropertiesofenergeticmaterialssensitivityphysicalandthermodynamicproperties AT klapotkethomasm thepropertiesofenergeticmaterialssensitivityphysicalandthermodynamicproperties |