Molecular and laser spectroscopy advances and applications

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Weitere Verfasser: Gupta, V. P. 1942- (HerausgeberIn)
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Veröffentlicht: Amsterdam Elsevier [2018]
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Datensatz im Suchindex

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adam_text Contents List of Contributors xi 4 Advantages of Near-Infrared Spectroscopy 19 Biography xiii 5 Spectral Analysis in the Near-Infrared Preface XV Region 5 1 Conventional Spectral Analysis 19 Method 20 5 2 Chemometrics 22 1 Introduction and Overview 1 6 Quantum Mechanical Methods in V P Gupta Near-Infrared Spectroscopy 23 6 1 Introduction 23 1 Introduction 162 Differences Between Quantum 2 Overview 5 Mechanical Approaches to Infrared and 2 1 Near-Infrared Spectroscopy 5 Near-Infrared Modes 23 2 2 Mid-Infrared Spectroscopy 563 General Overview of Anharmonic 2 3 Terahertz Spectroscopy (0 2 to 30 THz) 6 Approaches 23 2 4 Linear and Nonlinear Raman and 6 4 The Applications of Quantum Chemical Infrared Spectroscopy and Microscopy 6 Methods to Near-Infrared Spectroscopy 24 2 5 Resonance Raman Spectroscopy 7 7 Instrumentation 27 2 6 Two-Photon Absorption Spectroscopy 771 Basic Technologies 27 2 7 Femtosecond Raman Spectroscopy 772 Advanced Technologies 28 2 8 Two-Dimensional Correlation 7 3 Imaging Spectrometry 29 Spectroscopy 8 8 Selected Applications 31 2 9 Laser Spectroscopy of Nanomaterials 881 Medicinal Plants 32 2 10 Laser-Induced Breakdown Spectroscopy 882 Foods 33 2 11 Photoacoustic Spectroscopy 983 Pharmaceutical 34 2 12 Matrix Isolation Spectroscopy 984 Polymers 35 Reference 985 Biomedical Applications Combined With Imaging Studies 35 2 Near-IR Spectroscopy and Its 8 6 Advanced Imaging Technology 36 Applications 11 References 37 Yukihiro Ozaki, Christian W Huck, 3 Recent Advances in Sensor Krzysztof B Bee Developments Based on Silver 1 Introduction 11 Halide Fibers for Mid-Infrared 2 Principles and Advantages of Near-Infrared Spectroscopy 2 1 Principles of Near-Infrared Spectroscopy 12 Spectrometric Analysis 39 12 H Michael Heise, Sven Delbeck, Lukas Küpper 3 Examples of Near-Infrared Spectra 13 1 Introduction 39 3 1 Water 13 1 1 Recent Spectrometer Developments 40 3 2 Methanol 14 2 Fundamentals of Infrared Fibers 41 3 3 High Reflective Green-Black Pigments 14 2 1 Experimental Details 41 3 4 Phenol and 2,6-Dihalogenated Phenols 14 2 2 Polycrystalline Fibers and Water 3 5 Comparison of a Near-Infrared Spectrum Adsorption 44 With an Infrared Spectrum 15 3 Mid-Infrared Fiber-Optic Probes 45 VII viii Contents 4 General and Special Applications of Fiber-Optic Probes 53 5 Conclusions 61 Acknowledgments 61 References 61 4 Terahertz Spectroscopy: Advances and Applications 65 Shriganesh S Prabhu 1 Introduction 65 2 Terahertz Instrumentation 66 2 1 Terahertz Sources 66 2 2 Terahertz Detectors 69 3 Experimental Setups 70 3 1 Setup for Terahertz Time-Domain Spectroscopy and Terahertz Emission Spectroscopy 70 3 2 Extraction of n and k for Samples 71 3 3 Terahertz Imaging 72 4 Comparison of Terahertz Spectroscopy With Other Spectroscopy Techniques 73 4 1 Advantages: Additional Information Over Other Spectroscopy Techniques 74 4 2 Disadvantages: Limitations of the Terahertz Spectroscopy 74 5 Application of Terahertz Spectroscopy 74 5 1 Pharmaceuticals 74 5 2 Bacteria Detection 76 5 3 Agriculture 80 6 Future Outlook 82 References 82 5 Coherent Optical Spectroscopy/ Microscopy and Applications 87 Vikas Kumar, Nicola Coluccelli, Dario Polli 1 Introduction 87 2 Coherent Optical Spectroscopy/Microscopy 88 3 Importance of Lasers in Optical Spectroscopy/Microscopy 88 4 Linear and Nonlinear Spectroscopy/ Microscopy 89 5 Linear Spectroscopy/Microscopy Techniques 90 5 1 Infrared (Absorption) Spectroscopy 90 5 2 Confocal Microscopy 91 5 3 Laser-Induced Fluorescence Microscopy 92 5 4 Spontaneous Raman Spectroscopy/ Microscopy 93 6 Nonlinear Spectroscopy/Microscopy Techniques 94 6 1 Coherent Raman Spectroscopy/ Microscopy 94 6 2 Second Harmonic Generation Microscopy 108 6 3 Third Harmonic Generation Microscopy 110 6 4 Two-Photon Excitation Fluorescence Microscopy 112 7 Conclusions 113 References 113 6 Applications of Raman and Infrared Microscopy to Materials and Biology 117 Sanchita S/7, Rekha Gautam, Siva Umapathy 1 Introduction 117 2 Principles and Instrumentation of Infrared Spectroscopy 118 2 1 Fourier Transform Infrared Microspectrometer 118 2 2 Advancement in Infrared Spectroscopy 121 2 3 Applications of Infrared Spectroscopy 121 3 Principles and Instrumentation of Raman Spectroscopy 122 3 1 Raman Microspectrometer 122 3 2 Raman Imaging 127 3 3 Methods to Improve Signal-to-Noise Ratio of Raman Signals 128 3 4 Applications of Raman Spectroscopy 129 4 Conclusion 141 Acknowledgments 142 References 142 7 Resonance Raman Spectroscopy: Principles and Applications 147 Joydeep Chowdhury 1 Introduction 147 2 Raman and Resonance Raman Effect 148 3 Experimental Setup 149 3 1 Excitation Source 149 3 2 Collection Optics and Detectors 150 4 Applications of Resonance Raman Spectroscopy 151 4 1 Application of Resonance Raman in Agriculture: Carotenoids Detection 151 4 2 RR of Chlorophyll and Bacteriochlorophylls 151 4 3 Raman Resonance in Art and Archaeology 152 4 4 Resonance Raman Spectroscopy in Life Sciences 152 4 5 Explosive Detection 154 Contents ix 5 Recent Applications of Resonance Raman Spectroscopy 158 5 1 Carbon Nanotubes 158 5 2 Other Applications 160 6 Conclusions 160 Acknowledgments 161 References 161 8 Two-Photon Spectroscopy of Organic Materials 165 Marcelo G Vivas, Leonardo De Boni Cleber R Mendonqa 1 Introduction 165 2 Theoretical Background for Two-Photon Absorption Process in Organic Materials 166 2 1 Sum-Over-Essential States Approach 167 3 Two-Photon Absorption Spectroscopy Techniques 171 3 1 Femtosecond Z-Scan Technique 171 3 2 Fluorescence Technique 172 4 Molecular Structure—Two-Photon Absorption Properties Relationship 172 4 1 Dipolar Structures 173 4 2 Quadrupolar Structures 175 4 3 Octupolar Structures 175 4 4 Dendrimers 177 4 5 Unstable Species 178 5 Polarization Effect on the Two-Photon Absorption Spectroscopy 180 5 1 Nonchiral Molecules 180 5 2 Chiral Molecules 185 6 Summary and Future Scope 187 Acknowledgments 188 References 188 9 Femtosecond Stimulated Raman Spectroscopy 193 Palas Roy, Shreetama Karmakar, Jyotishman Dasgupta 1 Introduction 193 1 1 Chemical Reactions and Reaction Coordinates 194 1 2 Femtosecond Spectroscopic Methods 195 2 Theoretical Background on Femtosecond Stimulated Raman Spectroscopy 196 3 Conventional Optical Layout for Femtosecond Stimulated Raman Spectroscopy Signal Detection 197 3 1 Broadband Probe 198 3 2 Raman Pump 198 3 3 Actinic Pump 199 3 4 Sample Preparation 201 3 5 Alternate Detection Strategies for Femtosecond Stimulated Raman Signals 201 4 Applications of Femtosecond Stimulated Raman Spectroscopy to Chemistry and Biology 203 4 1 Excited-State Dynamics in Conjugated Polymers 204 4 2 Excited Chromophores in Protein Pockets 206 4 3 Reaction Dynamics in Small Molecules 210 5 Summary and Future Scope 211 Acknowledgments 211 References 213 10 2D Correlation Spectroscopy and Its Application in Vibrational and Optical Spectroscopy 217 Yizhuang Xu, Yukihiro Ozaki, Isao Noda, Young M Jung 1 Introduction 217 2 Background of Two-Dimensional Correlation Spectroscopy 218 3 New Developments on Two-Dimensional Correlation Spectroscopy 219 3 1 Chemometrics-Combined Two-Dimensional Correlation Spectroscopy 219 3 2 Moving-Window Two-Dimensional Analysis and Two-Dimensional Waterfall Maps 220 3 3 Orthogonal Sample Design and Related Techniques 221 3 4 Projection 2D 223 3 5 Two-Dimensional Codistribution Spectroscopy 225 4 Applications of Two-Dimensional Correlation Spectroscopy 225 5 Concluding Remarks 230 References 231 11 Laser Spectroscopy and Lasing Actions in Nanomaterials 241 Yashashchandra Dwivedi 1 Introduction 241 2 Laser Spectroscopy of Nanomaterials 243 3 Time-Resolved Spectroscopy of Nanomaterials 245 4 Lasing Action in Nanomaterials 250 x Contents 5 Ultrafast Pump—Probe Spectroscopy of Nanomaterials 256 Acknowledgment 260 References 260 12 Laser-Induced Breakdown Spectroscopy: Advanced Analytical Technique 265 Chet R Bhatt, Charles T Chany, Fang Y Yueh, Jagdish P Singh, Dustin L McIntyre 1 Introduction 265 2 Theoretical Details 266 2 1 Plasma Characterization 267 3 Calibration Models 268 4 Experimental Details 268 4 1 Spectral Detection System 269 5 Applications 269 5 1 Application to Solid Samples 269 5 2 Application to Food Science 272 References 280 13 Photoacoustic Spectroscopy: Applications in Security and Biology 283 Surya N Thakur 1 Introduction 283 1 1 Hie Photophone 284 1 2 The Spectrophone 284 2 Radiative and Nonradiative Transitions in Molecules 285 2 1 Production of Photoacoustic Signal in Gases 286 2 2 Production of Photoacoustic Signal in Solids 288 3 Experimental Methods in Photoacoustic Spectroscopy 289 3 1 Photoacoustic Cells for Static Gas Samples 290 3 2 Photoacoustic Cell for Flowing Gaseous Samples 291 3 3 Photoacoustic Cells for Solid Samples 293 3 4 Piezoelectric Transducers for Photo- acoustic Detection 294 3 5 Quartz Tuning Fork for Photoacoustic Detection 295 4 Photoacoustic Detection of Harmful Chemicals 297 4 1 Photoacoustic Detection of Gaseous Molecules 298 4 2 Photoacoustic Detection of Condensed Matter 303 5 Hyperspectral Imaging and Photoacoustic Spectroscopy 308 5 1 Photoacoustic Imaging 310 5 2 Photoacoustic Tomography 311 5 3 Combined Photoacoustic Tomography—Optical Coherence Tomography Imaging 314 6 Conclusion 314 Acknowledgments 314 References 314 14 Matrix Isolation Spectroscopy—A Window to Molecular Processes 317 Pankaj Dubey, Jyoti Saini, Kanupriya Verma, Ginny Karir, Anamika Mukhopadhyay, K S Viswanathan 1 Introduction 317 2 Matrix Isolation Infrared Setup 318 2 1 Effusive and Supersonic Sources 319 3 Conformational Studies 319 4 Weak Intermolecular Interactions 323 4 1 Hydrogen-Bonding Interactions 323 4 2 Other Types of Noncovalent Interactions 328 5 Photochemical Processes in the Matrix 329 5 1 Study of Reactive Species 329 5 2 Insertion of Metal Atoms Into Covalent Bonds 329 6 Ions and Neutral Metal Clusters 330 6 1 Cations in the Matrix 331 6 2 Anions in the Matrix 331 6 3 Neutral Metal Clusters in Matrix 333 7 Laser Ablation Matrix Isolation 333 8 Species With Unusual Oxidation States 335 9 Role of Computational Chemistry 335 10 Other Experimental Techniques to Probe Matrix-Isolated Species 336 References 337 Index
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physical xvi, 346 Seiten Illustrationen, Diagramme
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spellingShingle Molecular and laser spectroscopy advances and applications
Laserspektroskopie (DE-588)4034620-1 gnd
Molekülspektroskopie (DE-588)4128850-6 gnd
subject_GND (DE-588)4034620-1
(DE-588)4128850-6
title Molecular and laser spectroscopy advances and applications
title_auth Molecular and laser spectroscopy advances and applications
title_exact_search Molecular and laser spectroscopy advances and applications
title_full Molecular and laser spectroscopy advances and applications V.P. Gupta, University of Lucknow, Lucknow, India
title_fullStr Molecular and laser spectroscopy advances and applications V.P. Gupta, University of Lucknow, Lucknow, India
title_full_unstemmed Molecular and laser spectroscopy advances and applications V.P. Gupta, University of Lucknow, Lucknow, India
title_short Molecular and laser spectroscopy
title_sort molecular and laser spectroscopy advances and applications
title_sub advances and applications
topic Laserspektroskopie (DE-588)4034620-1 gnd
Molekülspektroskopie (DE-588)4128850-6 gnd
topic_facet Laserspektroskopie
Molekülspektroskopie
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