Liquid phase aerobic oxidation catalysis industrial applications and academic perspectives
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[2016]
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| 020 | |a 9783527690121 |c oBook |9 978-3-527-69012-1 | ||
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| 245 | 1 | 0 | |a Liquid phase aerobic oxidation catalysis |b industrial applications and academic perspectives |c edited by Shannon S. Stahl and Paul L. Alsters |
| 264 | 1 | |a Weinheim |b Wiley-VCH Verlag GmbH & Co. KGaA |c [2016] | |
| 264 | 4 | |c © 2016 | |
| 300 | |a XXII, 429 Seiten |b Illustrationen, Diagramme | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 650 | 0 | 7 | |a Aerobe Behandlung |0 (DE-588)4429879-1 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Flüssigphasenoxidation |0 (DE-588)4154733-0 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Katalytische Oxidation |0 (DE-588)4163425-1 |2 gnd |9 rswk-swf |
| 653 | |a Catalysis | ||
| 653 | |a Chemie | ||
| 653 | |a Chemistry | ||
| 653 | |a Industrial Chemistry | ||
| 653 | |a Katalyse | ||
| 653 | |a Nachhaltige u. Grüne Chemie | ||
| 653 | |a Pharmaceutical & Medicinal Chemistry | ||
| 653 | |a Pharmazeutische u. Medizinische Chemie | ||
| 653 | |a Sustainable Chemistry & Green Chemistry | ||
| 653 | |a Technische u. Industrielle Chemie | ||
| 689 | 0 | 0 | |a Flüssigphasenoxidation |0 (DE-588)4154733-0 |D s |
| 689 | 0 | 1 | |a Katalytische Oxidation |0 (DE-588)4163425-1 |D s |
| 689 | 0 | 2 | |a Aerobe Behandlung |0 (DE-588)4429879-1 |D s |
| 689 | 0 | |5 DE-604 | |
| 700 | 1 | |a Stahl, Shannon S. |d 1970- |0 (DE-588)111408445X |4 edt | |
| 700 | 1 | |a Alsters, Paul L. |d 1965- |0 (DE-588)1067830901 |4 edt | |
| 710 | 2 | |a Wiley-VCH |0 (DE-588)16179388-5 |4 pbl | |
| 776 | 0 | 8 | |i Erscheint auch als |n Online-Ausgabe, EPUB |z 978-3-527-69014-5 |
| 776 | 0 | 8 | |i Erscheint auch als |n Online-Ausgabe, MOBI |z 978-3-527-69013-8 |
| 776 | 0 | 8 | |i Erscheint auch als |n Online-Ausgabe, PDF |z 978-3-527-69015-2 |
| 856 | 4 | 2 | |m DNB Datenaustausch |q application/pdf |u http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=029179712&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |3 Inhaltsverzeichnis |
| 943 | 1 | |a oai:aleph.bib-bvb.de:BVB01-029179712 | |
Datensatz im Suchindex
| _version_ | 1819688000695566336 |
|---|---|
| adam_text | 1
1.1
1.2
1.3
1.4
1.5
1.6
2
2.1
2.2
2
.
2.1
2
.
2.2
2.2.3
2.3
2.3.1
2.3.2
2.3.3
2.3.4
2.4
2.4.1
2.4.2
CONTENTS
PREFACE X V
LIST OF CONTRIBUTORS XVII
PART I RADICAL CHAIN AEROBIC OXIDATION
1
OVERVIEW OF RADICAL CHAIN OXIDATION CHEMISTRY 3
IVE HERMANS
INTRODUCTION 3
CHAIN INITIATION 6
CHAIN PROPAGATION 7
FORMATION OF RING-OPENED BY-PRODUCTS IN THE CASE OF CYCLOHEXANE
OXIDATION 11
COMPLICATIONS IN THE CASE OF OLEFIN AUTOXIDATION 12
SUMMARY AND CONCLUSIONS 13
REFERENCES 14
NONCATALYZED RADICAL CHAIN OXIDATION: CUMENE HYDROPEROXIDE 15
MANFRED WEBER, JAN-BERND GROSSE DALDRUP, AND MARKUS WEBER
INTRODUCTION 15
CHEMISTRY AND CATALYSIS 15
CUMENE ROUTE TO PHENOL AND ACETONE: CHEMISTRY OVERVIEW 16
THERMAL DECOMPOSITION OF CUMENE HYDROPEROXIDE 17
OXIDATION OF CUMENE 19
PROCESS TECHNOLOGY 21
PROCESS OVERVIEW 21
REACTORS FOR THE CUMENE OXIDATION 22
REACTOR MODELING 23
PROCESS SAFETY ASPECTS 26
NEW DEVELOPMENTS 27
PROCESS INTENSIFICATION BY MODIFICATION OF THE OXIDATION
REACTION 27
IMPROVEMENTS OF REACTOR AND PROCESS DESIGN 29
REFERENCES 30
3
3.1
3.2
3.3
3.3.1
3.3.2
3.4
4
4.1
4.2
4.2.1
4.2.2
4.2.3
4.2.4
4.2.5
4.2.6
4.2.7
4.2.8
4.3
4.3.1
4.3.2
4.4
4.4.1
4.4.2
4.4.3
4.5
5
5.1
5.2
CYCLOHEXANE OXIDATION: HISTORY OF TRANSITION FROM CATALYZED
TO NONCATALYZED 33
JOHAN THOMAS TINGE
INTRODUCTION 33
CHEMISTRY AND CATALYSIS 34
PROCESS TECHNOLOGY 35
THE TRADITIONAL CATALYZED CYCLOHEXANE OXIDATION PROCESS 35
THE NONCATALYZED DSM OXANONE CYCLOHEXANE OXIDATION
PROCESS 37
NEW DEVELOPMENTS 38
EPILOGUE 39
REFERENCES 39
CHEMISTRY AND MECHANISM OF OXIDATION OF PORO-XYLENE TO TEREPHTHALIC
ACID USING CO-MN-BR CATALYST 41
VICTOR A. ADAMIAN AND WILLIAM H. GONG
INTRODUCTION 41
CHEMISTRY AND CATALYSIS 42
CO - BR CATALYSIS 43
COBALT - MANGANESE - BROMIDE CATALYSIS (MC OXIDATION): THE NATURE
OF SYNERGY BETWEEN CO AND MN 48
THE ROLE AND NATURE OF BROMINE SPECIES IN MC OXIDATION 50
NATURE OF COBALT(III) AND MN(III) SPECIES 52
REACTIONS OF COBALT(II) WITH PEROXY RADICALS AND THE EFFECT OF SOLVENT
ON OXIDATION RATE 52
PHENOMENON OF MANGANESE PRECIPITATION 54
CONSOLIDATED VIEW OF MC OXIDATION MECHANISM 54
OXIDATION BY-PRODUCTS 56
PROCESS TECHNOLOGY 58
OXIDATION 58
PURIFICATION 58
NEW DEVELOPMENTS 61
HOMOGENEOUS BROMINELESS CATALYSIS 61
HETEROGENEOUS BROMINELESS OXIDATION CATALYSIS 62
ALTERNATIVE SOLVENTS 62
CONCLUSIONS 62
REFERENCES
63
PART II CU-CATALYZED AEROBIC OXIDATION 67
CU-CATALYZED AEROBIC OXIDATION: OVERVIEW AND NEW
DEVELOPMENTS 69
DAMIAN HRUSZKEWYCZ, SCOTT MCCANN, AND SHANNON STAHL
INTRODUCTION 69
CHEMISTRY AND CATALYSIS 70
5.2.1
5.2.2
5.3
5.3.1
5.3.2
5.4
6
6.1
6.2
6.3
6.4
7
7.1
7.1.1
7.1.2
7.1.3
7.1.4
7.2
8
8.1
8.2
8
.
2.1
8
.
2.2
8.2.3
8.3
8.3.1
CU-CATALYZED OXYDECARBOXYLATIVE PHENOL SYNTHESIS 70
CU-CATALYZED OXIDATIVE CARBONYLATION OF METHANOL FOR THE SYNTHESIS
OF DIMETHYL CARBONATE 72
PROCESS TECHNOLOGY 74
CU-CATALYZED OXYDECARBOXYLATIVE PHENOL SYNTHESIS 74
CU-CATALYZED OXIDATIVE CARBONYLATION OF METHANOL FOR THE SYNTHESIS
OF DIMETHYL CARBONATE 75
NEW DEVELOPMENTS: PHARMACEUTICAL APPLICATIONS OF CU-CATALYZED
AEROBIC OXIDATION REACTIONS 76
REFERENCES 82
COPPER-CATALYZED AEROBIC ALCOHOL OXIDATION 85
JANELLE E. STEVES AND SHANNON 5.
STAHL
INTRODUCTION 85
CHEMISTRY AND CATALYSIS 86
PROSPECTS FOR SCALE-UP 91
CONCLUSIONS 93
REFERENCES 94
PHENOL OXIDATIONS 97
POLYPHENYLENE OXIDES BY OXIDATIVE POLYMERIZATION OF PHENOLS 97
PATRICK GAMEZ
INTRODUCTION 97
CHEMISTRY AND CATALYSIS 99
PROCESS TECHNOLOGY 102
NEW DEVELOPMENTS 104
2,3,5-TRIMETHYLHYDROQUINONE AS A VITAMIN E INTERMEDIATE VIA
OXIDATION OF METHYL-SUBSTITUTED PHENOLS 106
JAN SCHUETZ AND THOMAS NETSCHER
REFERENCES 109
PART III PD-CATALYZED AEROBIC OXIDATION 113
PD-CATALYZED AEROBIC OXIDATION REACTIONS: INDUSTRIAL APPLICATIONS
AND NEW DEVELOPMENTS 115
DIAN WANG, JONATHAN N. JAWORSKI, AND SHANNON 5.
STAHL
INTRODUCTION 115
CHEMISTRY AND CATALYSIS: INDUSTRIAL APPLICATIONS 117
ACETOXYLATION OF ALKENES TO VINYL OR ALLYL ACETATES 117
OXIDATIVE CARBONYLATION OF ALCOHOLS TO CARBONATES, OXALATES,
AND CARBAMATES 118
OXIDATIVE COUPLING OF ARENES TO BIARYL COMPOUNDS 121
CHEMISTRY AND CATALYSIS: APPLICATIONS OF POTENTIAL INDUSTRIAL
INTEREST 122
OXIDATION OF ALCOHOLS TO ALDEHYDES 122
8.3.2 OXIDATION OF ARENES TO PHENOLS AND PHENYL ESTERS 123
8.3.3 BENZYLIC ACETOXYLATION 125
8.3.4 ARENE OLEFINATION (OXIDATIVE HECK REACTION) 126
8.4 CHEMISTRY AND CATALYSIS: NEW DEVELOPMENTS AND
OPPORTUNITIES 128
8.4.1 LIGAND-MODULATED AEROBIC OXIDATION CATALYSIS 128
8.4.2 USE OF NO* AS COCATALYST 130
8.4.3 METHANE OXIDATION 132
8.5 CONCLUSION 133
REFERENCES 133
9 ACETALDEHYDE FROM ETHYLENE AND RELATED WACKER-TYPE REACTIONS 139
REINHARD LIRA
9.1 INTRODUCTION 139
9.2 CHEMISTRY AND CATALYSIS 140
9.2.1 OXIDATION OF OLEFINIC COMPOUNDS TO CARBONYL COMPOUNDS 140
9.2.2 KINETICS AND MECHANISM 140
9.2.3 CATALYTIC OXIDATION OF ETHYLENE 145
9.2.3.1 OXIDATION OF ETHYLENE TO ACETALDEHYDE IN THE PRESENCE OF
CUCL2 145
923.2 OXIDATION OF ETHYLENE TO 2-CHLOROETHANOL 147
9.3 PROCESS TECHNOLOGY (WACKER PROCESS) 148
9.3.1 SINGLE-STAGE ACETALDEHYDE PROCESS FROM ETHYLENE 148
9.3.2 TWO-STAGE ACETALDEHYDE PROCESS FROM ETHYLENE 149
9.4 OTHER DEVELOPMENTS 151
REFERENCES 155
FURTHER READING 158
10 1,4-BUTANEDIOL FROM 1,3-BUTADIENE 159
YUSUKE IZAWA AND TOSHIHARU YOKOYAMA
10.1 INTRODUCTION 159
10.2 CHEMISTRY AND CATALYSIS 160
10.2.1 SHORT OVERVIEW OF NON-BUTADIENE-BASED ROUTES TO
1,4-BUTANEDIOL 160
10.2.1.1 ACETYLENE-BASED REPPE PROCESS 160
10.2.1.2 BUTANE-BASED PROCESS; SELECTIVE OXIDATION OF BUTANE TO MALEIC
ANHYDRIDE 161
10.2.1.3 PROPYLENE-BASED PROCESS: HYDROFORMYLATION OF ALLYL ALCOHOL 161
10.2.2 BUTADIENE-BASED ROUTES TO 1,4-BUTANEDIOL 162
10.2.2.1 OXYHALOGENATION OF 1,3-BUTADIENE 162
10.2.2.2 OXIDATIVE ACETOXYLATION OF 1,3-BUTADIENE 162
10.3 PROCESS TECHNOLOGY 164
10.3.1 MITSUBISHI CHEMICALS 1,4-BUTANEDIOL MANUFACTURING PROCESS:
FIRST-GENERATION PROCESS 165
10.3.1.1 OXIDATIVE ACETOXYLATION STEP 165
10.3.1.2
10.3.1.3
10.3.2
10.4
10.4.1
10.4.2
10.5
11
11.1
11.2
11.2.1
11
.
2
.
1.1
11
.
2.2
11.2.3
11.3
11.3.1
11.3.2
11.3.3
11.3.4
11.4
12
12.1
12
.
1.1
12
.
1.2
12.2
12
.
2.1
12
.
2.2
12.2.3
12.2.3.1
12.2.3.2
HYDROGENATION STEP 165
HYDROLYSIS STEP 166
MITSUBISHI CHEMICALS 1,4-BUTANEDIOL MANUFACTURING PROCESS:
SECOND-GENERATION PROCESS 167
NEW DEVELOPMENTS 168
IMPROVEMENT OF THE CURRENT PROCESS 168
DEVELOPMENT OF ALTERNATIVE PROCESSES 169
SUMMARY AND CONCLUSIONS 169
REFERENCES 170
MITSUBISHI CHEMICALS LIQUID PHASE PALLADIUM-CATALYZED OXIDATION
TECHNOLOGY: OXIDATION OF CYCLOHEXENE, ACROLEIN, AND METHYL ACRYLATE
TO USEFUL INDUSTRIAL CHEMICALS
173
YOSHIYUKI TANAKA, JUN P. TAKAHARA, TOHRU SETOYAMA, AND HANS E. B.
LEMPERS
INTRODUCTION 173
CHEMISTRY AND CATALYSIS 174
AEROBIC PALLADIUM-CATALYZED OXIDATION OF CYCLOHEXENE TO
1,4-DIOXOSPIRO-[4,5]-DECANE 174
OPTIMIZATION OF THE REACTION CONDITIONS 174
AEROBIC PALLADIUM-CATALYZED OXIDATION OF OTHER TYPES OF
OLEFINS 176
AEROBIC PALLADIUM-CATALYZED OXIDATION OF ACROLEIN TO
MALONALDEHYDE BIS-(L,3-DIOXAN-2-YL)-ACETAL FOLLOWED BY
HYDROLYSIS/HYDROGENATION TO 1,3-PROPANEDIOL 178
PROSPECTS FOR SCALE-UP 180
AEROBIC PALLADIUM-CATALYZED OXIDATION OF METHYL ACRYLATE (MA)
TO 3,3-DIMETHOXY METHYL PROPIONATE: PROCESS OPTIMIZATION AND
SCALE-UP 180
SMALL-SCALE REACTION OPTIMIZATION 181
LARGE-SCALE METHYL ACRYLATE OXIDATION REACTION AND WORK-UP 184
REACTION SIMULATION STUDIES AS AID FOR FURTHER SCALE-UP 184
CONCLUSION 187
REFERENCES 187
OXIDATIVE CARBONYLATION: DIPHENYL CARBONATE 189
GRIGORII L. SOLOVEICHIK
INTRODUCTION 189
DIPHENYL CARBONATE IN THE MANUFACTURING OF POLYCARBONATES 189
HISTORY OF DIRECT DIPHENYL CARBONATE PROCESS AT GE 190
CHEMISTRY AND CATALYSIS 192
MECHANISM OF OXIDATIVE CARBONYLATION OF PHENOL 192
CATALYSTS FOR OXIDATIVE CARBONYLATION OF PHENOL 193
COCATALYSTS FOR OXIDATIVE CARBONYLATION OF PHENOL 196
ORGANIC COCATALYSTS 196
INORGANIC COCATALYSTS 196
12.2.4 MULTICOMPONENT CATALYTIC PACKAGES 199
12.2.5 ROLE OF BROMIDE IN DIRECT SYNTHESIS OF DIPHENYL CARBONATE 199
12.3 PROSPECTS FOR SCALE-UP 201
12.3.1 CATALYST OPTIMIZATION 201
12.3.2 WATER REMOVAL IN DIRECT DIPHENYL CARBONATE PROCESS 202
12.3.3 DOWNSTREAM PROCESSING AND CATALYST RECOVERY 203
12.4 CONCLUSIONS AND OUTLOOK 203
ACKNOWLEDGMENTS 204
REFERENCES 205
13 AEROBIC OXIDATIVE ESTERIFICATION OF ALDEHYDES WITH ALCOHOLS: THE
EVOLUTION FROM PD-PB INTERMETALLIC CATALYSTS TO AU-NIOX NANOPARTICLE
CATALYSTS FOR THE PRODUCTION OF METHYL METHACRYLATE 209
KEN SUZUKI AND SETSUO YAMAMATSU
13.1 INTRODUCTION 209
13.2 CHEMISTRY AND CATALYSIS 210
13.2.1 DISCOVERY OF THE P D-P B CATALYST 210
13.2.2 P D-P B INTERMETALLIC COMPOUNDS 210
13.2.3 MECHANISM 212
13.2.4 THE ROLE OF PB IN THE PD-P B CATALYST 213
13.2.5 INDUSTRIAL CATALYST 213
13.3 PROCESS TECHNOLOGY 214
13.4 NEW DEVELOPMENTS 215
13.5 CONCLUSION AND OUTLOOK 217
REFERENCES 218
PART IV ORGANOCATALYTIC AEROBIC OXIDATION 219
14 QUINONES IN HYDROGEN PEROXIDE SYNTHESIS AND CATALYTIC AEROBIC
OXIDATION REACTIONS 221
ALISON WENDIANDT AND SHANNON 5.
STAHL
14.1 INTRODUCTION 221
14.2 CHEMISTRY AND CATALYSIS: ANTHRAQUINONE OXIDATION (AO)
PROCESS 223
14.2.1 AUTOXIDATION PROCESS (HYDROQUINONE TO QUINONE) 223
14.2.2 HYDROGENATION PROCESS (QUINONE TO HYDROQUINONE) 225
14.3 PROCESS TECHNOLOGY 227
14.4 FUTURE DEVELOPMENTS: SELECTIVE AEROBIC OXIDATION REACTIONS
CATALYZED BY QUINONES 229
14.4.1 AEROBIC DDQ-CATALYZED REACTIONS USING NO* COCATALYSTS 229
14.4.2 AEROBIC QUINONE-CATALYZED REACTIONS USING OTHER
COCATALYSTS 230
14.4.3 CAO MIMICS AND SELECTIVE OXIDATION OF AMINES 231
REFERENCES 234
15 N0X COCATALYSTS FOR AEROBIC OXIDATION REACTIONS: APPLICATION
TO ALCOHOL OXIDATION 239
SUSAN L ZULTANSKI AND SHANNON 5.
STAHL
15.1 INTRODUCTION 239
15.2 CHEMISTRY AND CATALYSIS 241
15.2.1 AEROBIC ALCOHOL OXIDATION WITH NO* IN THE ABSENCE OF OTHER REDOX
COCATALYSTS 241
15.2.2 AEROBIC ALCOHOL OXIDATION WITH NO* AND ORGANIC NITROXYL
COCATALYSTS 242
15.3 PROSPECTS FOR SCALE-UP 247
15.4 CONCLUSIONS 249
REFERENCES 249
16 /V-HYDROXYPHTHALIMIDE (NHPI)-ORGANOCATALYZED AEROBIC OXIDATIONS:
ADVANTAGES, LIMITS, AND INDUSTRIAL PERSPECTIVES 253
LUCIO MELONE AND CARLO PUNTA
16.1 INTRODUCTION 253
16.2 CHEMISTRY AND CATALYSIS 254
16.2.1 ENTHALPIE EFFECT 256
16.2.2 POLAR EFFECT 256
16.2.3 ENTROPIE EFFECT 257
16.3 PROCESS TECHNOLOGY 257
16.3.1 OXIDATION OF ADAMANTANE TO ADAMANTANOLS 257
16.3.2 OXIDATION OF CYCLOHEXANE TO ADIPIC ACID 258
16.3.3 EPOXIDATION OF OLEFINS 259
16.3.4 OXIDATION OF ALKYLAROMATICS TO CORRESPONDING
HYDROPEROXIDES 260
16.4 NEW DEVELOPMENTS 262
ACKNOWLEDGMENTS 264
REFERENCES 264
17 CARBON MATERIALS AS NONMETAL CATALYSTS FOR AEROBIC OXIDATIONS: THE
INDUSTRIAL GLYPHOSATE PROCESS AND NEW DEVELOPMENTS 267
17.1 INTRODUCTION 267
MARK KUIL AND ANNEMARIE E. W. BEERS
17.2 CHEMISTRY AND CATALYSIS 268
MARK KUIL AND ANNEMARIE E. W. BEERS
17.3 PROCESS TECHNOLOGY 270
MARK KUIL AND ANNEMARIE E. W. BEERS
17.3.1 OXYGEN PRESSURE 271
17.3.2 OXYGEN FLOW 271
17.3.3 ACTIVATED CARBON PORE SIZE DISTRIBUTION 271
17.3.4 ACTIVATED CARBON H20 2 TIME 271
17.3.5 ACTIVATED CARBON NITROGEN CONTENT 272
17.4 NEW DEVELOPMENTS 274
PAUL L ALSTERS
17.4.1 AEROBIC CARBON MATERIAL CATALYSIS 275
17.4.1.1 OXYGENATIONS AND OXIDATIVE CLEAVAGE REACTIONS 275
17.4.1.2 DEHYDROGENATIONS AND DEHYDROGENATIVE COUPLING REACTIONS 279
17.4.2 AEROBIC GRAPHITIC CARBON NITRIDE CATALYSIS 280
17.4.2.1 OXYGENATIONS AND OXIDATIVE CLEAVAGE REACTIONS 280
17.4.2.2 DEHYDROGENATIONS AND DEHYDROGENATIVE COUPLING REACTIONS 281
17.5 CONCLUDING REMARKS 283
REFERENCES 283
PART V BIOCATALYTIC AEROBIC OXIDATION 289
18 ENZYME CATALYSIS: EXPLOITING BIOCATALYSIS AND AEROBIC OXIDATIONS FOR
HIGH-VOLUME AND HIGH-VALUE PHARMACEUTICAL SYNTHESES 291
ROBERT L OSBORNE AND ERIKA M. MILCZEK
18.1 INTRODUCTION 291
18.2 CHEMISTRY AND CATALYSIS 293
18.2.1 DIRECTED EVOLUTION OF BVMOS FOR THE MANUFACTURING OF
ESOMEPRAZOLE 295
18.2.2 DIRECTED EVOLUTION AND INCORPORATION OF A MONOAMINE OXIDASE FOR
THE MANUFACTURING OF BOCEPREVIR 298
18.3 PROCESS TECHNOLOGY 302
18.4 NEW DEVELOPMENTS 304
REFERENCES 306
PART VI OXIDATIVE CONVERSION OF RENEWABLE FEEDSTOCKS 311
19 FROM TEREPHTHALIC ACID TO 2,5-FURANDICARBOXYLIC ACID: AN INDUSTRIAL
PERSPECTIVE 313
JAN C VAN DER WAAL, ETIENNE MAZOYER, HENDRIKUSJ. BAARS,
AND GERT-JAN M. GRUTER
19.1 INTRODUCTION 313
19.1.1 THE AVANTIUM YXY TECHNOLOGY TO PRODUCE PEE, A NOVEL RENEWABLE
POLYMER 314
19.2 CHEMISTRY AND CATALYSIS 314
19.2.1 PRODUCTION OF 2,5-FURANDICARBOXYLIC ACID USING HETEROGENEOUS
CATALYSTS 316
19.2.2 PRODUCTION OF 2,5-FURANDICARBOXYLIC ACID USING HOMOGENEOUS
CATALYSTS 318
19.3 PROCESS TECHNOLOGY 320
19.3.1 PROCESS ECONOMICS AND ENGINEERING CHALLENGES 320
19.3.1.1 GAS COMPOSITION CONTROL 322
19.3.1.2 TEMPERATURE CONTROL 323
19.3.1.3 OXYGEN MASS TRANSFER LIMITATIONS 324
19.3.1.4 OVERALL SAFETY OPERATION 324
19.4 NEW DEVELOPMENTS 325
19.4.1 OUTLOOK FOR CO/MN/BR IN THE AIR OXIDATION OF BIOMASS-DERIVED
MOLECULES 325
19.5 CONCLUSION 327
LIST OF ABBREVIATIONS 327
REFERENCES 327
20 AZELAIC ACID FROM VEGETABLE FEEDSTOCK VIA OXIDATIVE CLEAVAGE WITH
OZONE OR OXYGEN 331
ANGELA KOECKRITZ
20.1 INTRODUCTION 331
20.1.1 CURRENT TECHNICAL PROCESS: OZONOLYSIS 332
20.1.1.1 ANALYTICAL INVESTIGATIONS OF THE MECHANISM OF OZONOLYSIS 336
20.2 CHEMISTRY AND CATALYSIS 336
20.2.1 DIRECT AEROBIC CLEAVAGE OF THE DOUBLE BOND OF OLEIC ACID OR
METHYL
OLEATE 336
20.2.2 AEROBIC OXIDATION STEP WITHIN A TWO-STAGE CONVERSION OF OLEIC
ACID
OR METHYL OLEATE 337
20.2.3 AEROBIC OXIDATION STEP WITHIN A THREE-STAGE CONVERSION OF OLEIC
ACID OR METHYL OLEATE 339
20.2.4 BIOCATALYSIS 339
20.3 PROSPECTS FOR SCALE-UP 341
20.4 CONCLUDING REMARKS AND PERSPECTIVES 342
20.4.1 NEW PROMISING DEVELOPMENTS 342
20.4.2 SUMMARY 343
REFERENCES 344
21 OXIDATIVE CONVERSION OF RENEWABLE FEEDSTOCK: CARBOHYDRATE
OXIDATION 349
CRISTINA DELLA PINA, ERMELINDA FALLETTA, AND MICHELE ROSSI
21.1 INTRODUCTION 349
21.2 CHEMISTRY AND CATALYSIS 351
21.2.1 OXIDATION OF MONOSACCHARIDES 354
21.2.2 OXIDATION OF DISACCHARIDES 358
21.2.3 POLYSACCHARIDE OXIDATION 361
21.3 PROSPECTS FOR SCALE-UP 362
21.3.1 ENZYMATIC PROCESS VERSUS CHEMICAL PROCESS: GLUCOSE OXIDATION AS A
MODEL REACTION 362
21.3.2 ENZYMATIC OXIDATION: INDUSTRIAL PROCESS AND PROSPECTS 363
21.3.3 CHEMICAL OXIDATION: INDUSTRIAL PROCESS AND PROSPECTS 364
21.3.3.1 METAL CATALYSTS: CONCEPTS GUIDING CHOICE AND DESIGN 364
21.4 CONCLUDING REMARKS AND PERSPECTIVES 366
REFERENCES 367
|
| any_adam_object | 1 |
| author2 | Stahl, Shannon S. 1970- Alsters, Paul L. 1965- |
| author2_role | edt edt |
| author2_variant | s s s ss sss p l a pl pla |
| author_GND | (DE-588)111408445X (DE-588)1067830901 |
| author_facet | Stahl, Shannon S. 1970- Alsters, Paul L. 1965- |
| building | Verbundindex |
| bvnumber | BV043768533 |
| classification_rvk | VE 7040 VK 5570 VN 7340 |
| ctrlnum | (OCoLC)958840600 (DE-599)DNB1081676205 |
| dewey-full | 540 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 540 - Chemistry and allied sciences |
| dewey-raw | 540 |
| dewey-search | 540 |
| dewey-sort | 3540 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie |
| format | Book |
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| id | DE-604.BV043768533 |
| illustrated | Illustrated |
| indexdate | 2024-12-24T05:15:28Z |
| institution | BVB |
| institution_GND | (DE-588)16179388-5 |
| isbn | 3527337814 9783527337811 9783527690121 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-029179712 |
| oclc_num | 958840600 |
| open_access_boolean | |
| owner | DE-11 DE-29T DE-83 |
| owner_facet | DE-11 DE-29T DE-83 |
| physical | XXII, 429 Seiten Illustrationen, Diagramme |
| publishDate | 2016 |
| publishDateSearch | 2016 |
| publishDateSort | 2016 |
| publisher | Wiley-VCH Verlag GmbH & Co. KGaA |
| record_format | marc |
| spellingShingle | Liquid phase aerobic oxidation catalysis industrial applications and academic perspectives Aerobe Behandlung (DE-588)4429879-1 gnd Flüssigphasenoxidation (DE-588)4154733-0 gnd Katalytische Oxidation (DE-588)4163425-1 gnd |
| subject_GND | (DE-588)4429879-1 (DE-588)4154733-0 (DE-588)4163425-1 |
| title | Liquid phase aerobic oxidation catalysis industrial applications and academic perspectives |
| title_auth | Liquid phase aerobic oxidation catalysis industrial applications and academic perspectives |
| title_exact_search | Liquid phase aerobic oxidation catalysis industrial applications and academic perspectives |
| title_full | Liquid phase aerobic oxidation catalysis industrial applications and academic perspectives edited by Shannon S. Stahl and Paul L. Alsters |
| title_fullStr | Liquid phase aerobic oxidation catalysis industrial applications and academic perspectives edited by Shannon S. Stahl and Paul L. Alsters |
| title_full_unstemmed | Liquid phase aerobic oxidation catalysis industrial applications and academic perspectives edited by Shannon S. Stahl and Paul L. Alsters |
| title_short | Liquid phase aerobic oxidation catalysis |
| title_sort | liquid phase aerobic oxidation catalysis industrial applications and academic perspectives |
| title_sub | industrial applications and academic perspectives |
| topic | Aerobe Behandlung (DE-588)4429879-1 gnd Flüssigphasenoxidation (DE-588)4154733-0 gnd Katalytische Oxidation (DE-588)4163425-1 gnd |
| topic_facet | Aerobe Behandlung Flüssigphasenoxidation Katalytische Oxidation |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=029179712&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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