Biorefineries an introduction
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| 245 | 1 | 0 | |a Biorefineries |b an introduction |c ed. by Michele Aresta ... |
| 264 | 1 | |a Berlin [u.a.] |b de Gruyter |c 2015 | |
| 300 | |a XVIII, 348 S. |b Ill., graph. Darst., Kt. | ||
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Datensatz im Suchindex
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| adam_text |
CONTENTS
PREFACE * V
CONTRIBUTING AUTHORS*XV
ABBREVIATIONS*XIX
INTRODUCTION TO BIOREFINERY 1
MICHELE ARESTA, ANGELA DIBENEDETTO, AND FRANCK DUMEIGNIL
1 CATALYSIS, GROWTH, AND SOCIETY * 5
MYRSINI CHRISTOU, EFTHYMIA ALEXOPOULOU, LOANNIS ELEFTHERIADIS, LOANNA
PAPAMICHAEL,
KOSTAS TSIOTAS,
MARIUSZ STOLARSKI, MICHAL KRZYZANIAK, AND CHARLES THEMISTOCLES
2 TERRESTRIAL BIOMASS PRODUCTION *13
2.1
INTRODUCTION 13
2.1.1
LAND AVAILABILITY 14
2.1.2 THE CROPS 14
2.1.2.1 THE OIL
CROPS 15
2.1.2.2 THE LIGNOCELLULOSIC CROPS
16
2.2 LAND SUITABILITY 18
2.2.1 OIL CROPS 18
2.2.1.1 DATA SETS 18
2.2.1.2 DETERMINATION OF SELECTION CRITERIA 19
2.2.2 LIGNOCELLULOSIC CROPS
25
2.3 CROP SETTING UP 26
2.3.1 OIL CROPS 26
2.3.1.1 SOIL PREPARATION 26
2.3.1.2 SOWING 27
2.3.1.3 IRRIGATION 30
2.3.1.4 FERTILIZATION 30
2.3.1.5
WEEDING 31
2.3.1.6 CROP ROTATIONS 32
2.3.2 LIGNOCELLULOSIC CROPS 32
2.3.2.1 SOIL TYPE REQUIREMENT * -32
2.3.2.2 SOIL PREPARATION 33
2.3.2.3 PLANTING 33
2.3.2.4 IRRIGATION 34
2.3.2.5
FERTILIZATION 35
2.3.2.6 WEEDING 35
HTTP://D-NB.INFO/1061098958
VIII CONTENTS
2.4
YIELDS 35
2.4.1
OIL CROPS 35
2.4.1.1
EXPERIMENTAL DESIGN * 36
2.4.1.2 RESULTS 36
2.4.2 LIGNOCELLULOSICS 40
2.4.2.1 GIANT REED * 40
2.5
CROP HARVESTING 46
2.5.1 OIL CROPS 46
2.5.1.1 CASTOR 46
2.5.1.2 CRAMBE 47
2.5.1.3 SAFFLOWER 48
2.5.2 GIANT REED * 48
2.6 FUEL CHARACTERIZATION 51
BIBLIOGRAPHY 53
ANGELA DIBENEDETTO AND ANTONELLA COLUCCI
3 PRODUCTION AND USES OF AQUATIC BIOMASS * 57
3.1 INTRODUCTION 57
3.2 CLASSIFICATION OF AQUATIC BIOMASS 58
3.2.1 MACROALGAE 58
3.2.2 MICROALGAE 58
3.2.3 PLANTS 59
3.3 CULTIVATION OF AQUATIC BIOMASS 60
3.3.1 MACROALGAE 60
3.3.2 MICROALGAE 62
3.4 HARVESTING OF AQUATIC BIOMASS 65
3.4.1 MACROALGAE 65
3.4.2 MICROALGAE 66
3.5 COMPOSITION OF AQUATIC BIOMASS 67
3.5.1 BIO-OIL CONTENT OF AQUATIC BIOMASS 69
3.5.2 THE QUALITY OF BIO-OIL 71
3.6 TECHNOLOGIES FOR ALGAL OIL AND CHEMICALS
EXTRACTION * 73
3.6.1 FRACTIONATION OF ALGAL BIOMASS 73
3.6.2 EXTRACTION USING CHEMICO-PHYSICAL METHODS
3.6.3 CONVENTIONAL SOLVENT EXTRACTION 75
3.6.4 SUPERCRITICAL FLUID EXTRACTION (SFE) 75
3.6.5 BIOLOGICAL EXTRACTION 76
3.7 CONCLUSIONS 76
BIBLIOGRAPHY 77
CONTENTS IX
CHRISTIN GROEGER, WAEL
SABRA, AND AN-PING
ZENG
4 INTRODUCTION TO BIOCONVERSION AND DOWNSTREAM PROCESSING: PRINCIPLES
AND PROCESS EXAMPLES * 81
4.1 INTRODUCTION 81
4.2 PRINCIPLES OF BIOCONVERSION PROCESS 83
4.3 EXAMPLES OF BIOCONVERSION PROCESSES * 85
4.3.1 MICROBIAL PRODUCTION OF 1,3-PROPANEDIOL FROM GLYCEROL * 85
4.3.2 BIOPRODUCTION OFN-BUTANOL 86
4.4 DOWNSTREAM PROCESSING 91
4.4.1 GENERAL SCHEME OF DOWNSTREAM PROCESSING
OF FERMENTATION BROTH 91
4.4.2 DOWNSTREAM PROCESSING METHODS FOR 1,3-PDO AND
N-BUTANOL * 94
4.4.2.1 EVAPORATION AND DISTILLATION 95
4.4.2.2 GAS STRIPPING 96
4.4.2.3 EXTRACTION METHODS 97
4.4.2.4 PERVAPORATION/MEMBRANE SEPARATION 99
4.4.2.5 ADSORPTION AND CHROMATOGRAPHY 100
4.5 CONCLUDING REMARKS 102
BIBLIOGRAPHY 104
GENNARO AGRIMI,
ISABELLA PISANO, MARIA ANTONIETTA RICCI, AND LUIGI PALMIERI
5 MICROBIAL STRAIN SELECTION AND DEVELOPMENT FOR THE PRODUCTION
OF SECOND-GENERATION BIOETHANOL *109
5.1 INTRODUCTION 109
5.2 ENZYMATIC HYDROLYSIS 111
5.2.1 IDENTIFICATION AND DEVELOPMENT OF BIOCATALYSTS FOR CELLULOSE
AND HEMICELLULOSE HYDROLYSIS 112
5.3 FERMENTATION INHIBITORS IN LIGNOCELLULOSIC HYDROLYZATE 117
5.3.1 WEAK ACIDS 117
5.3.2 FURAN DERIVATIVES: FURFURAL AND HMF 118
5.3.3 PHENOLIC COMPOUNDS 118
5.3.4 OTHER INHIBITORS 119
5.3.5 DETOXIFICATION 120
5.3.5.1 PHYSICAL AND CHEMICAL DETOXIFICATION METHODS 120
5.3.5.2 BIOLOGICAL DETOXIFICATION METHODS 120
5.3.6 DEVELOPMENT OF BIOCATALYSTS WITH ENHANCED RESISTANCE
TO FERMENTATION INHIBITORS 121
5.4 FERMENTATION 122
5.4.1 SEPARATE HYDROLYSIS AND FERMENTATION (SHF) *123
X CONTENTS
5.4.2 SIMULTANEOUS SACCHARIFICATION AND
FERMENTATION (SSF) 123
5.4.3 SIMULTANEOUS SACCHARIFICATION AND
CO-FERMENTATION (SSCF) 125
5.4.4 CONSOLIDATED BIOPROCESSING (CBP) 125
5.4.5 HIGH-GRAVITY FERMENTATION *126
5.5 MICROBIAL BIOCATALYSTS 127
5.5.1 ESCHERICHIA COLI 127
5.5.2 ZYMOMONAS MOBILIS 128
5.5.3 OTHER BACTERIA 129
5.5.4 SACCHAROMYCES CEREVISIAE 129
5.5.4.1 EXPRESSION OF THE FUNGAL XYLOSE UTILIZATION PATHWAY 130
5.5.4.2 EXPRESSION OF THE BACTERIAL XYLOSE UTILIZATION PATHWAY *132
5.5.4.3 EXPRESSION OF THE ARABINOSE UTILIZATION PATHWAY 132
5.5.5 OTHER YEASTS 133
5.6 STRAIN DEVELOPMENT FOR CBP 134
BIBLIOGRAPHY 136
BENJAMIN KATRYNIOK, FRANCOIS JEROME, ERIC MONFLIER, SEBASTIEN PAUL,
AND FRANCK DUMEIGNIL
6 BIOMASS-DERIVED MOLECULES CONVERSION TO CHEMICALS USING HETEROGENEOUS
AND HOMOGENEOUS CATALYSIS *141
6.1 INTRODUCTION 141
6.2 LIGNOCELLULOSIC BIOMASS 142
6.2.1 NATURAL POLYMERS PROCESSING 142
6.2.1.1 GLUCIDIC POLYMERS 142
6.2.1.2 LIGNIN 143
6.2.2 C1-C6 MOLECULES 146
6.2.2.1 CI STARTING MATERIALS: BIOGAS AND SYNGAS 146
6.2.2.2 C2 MOLECULE - ETHANOL 147
6.2.2.3 C3 MOLECULES - GLYCEROL AND LACTIC ACID *148
6.2.2.4 C4 MOLECULES - SUCCINIC ACID, 1,4-BUTANEDIOL, Y-BUTYROLACTONE,
BUTANOL, /SO-BUTANOL, AND OLEFINS *150
6.2.2.5 C5 MOLECULES - XYLOSE, FURFURAL, LEVULINIC ACID, AND
ISOPRENE 152
6.2.2.6 C6 MOLECULES - 5-HYDROXYMETHYLFURFURAL, 2,5-FURANDICARBOXYLIC
ACID,
AND SORBITOL 153
6.3 OLEAGINOUS BIOMASS 154
6.3.1 SEPARATION AND PRIMARY PRODUCTS 154
6.3.1.1 TRIGLYCERIDES 155
6.3.1.2 FATTY ACIDS AND ESTERS 156
6.4 CONCLUSION 160
BIBLIOGRAPHY 160
CONTENTS XL
ALFONSO GRASSI, ANTONIO BUONERBA, AND SHEILA ORTEGA SANCHEZ
7 BIO-SOURCED POLYOLEFINS 165
7.1 INTRODUCTION: WHY RENEWABLE POLYMERS? 165
7.2 BIODERIVED CONVENTIONAL POLYOLEFINS: THE DROP-IN
SYNTHESIS OF OLEFINS 168
7.3 NEW POLYOLEFINS FROM BIODERIVED MONOMERS *175
7.4 OUTLOOK AND PERSPECTIVE 188
BIBLIOGRAPHY 190
ELENI HERACLEOUS, EFTERPI
S. VASILIADOU, ELENI F. ILIOPOULOU, ANGELOS A. LAPPAS,
AND ANGELIKI A. LEMONIDOU
8 CONVERSION OF LIGNOCELLULOSIC BIOMASS-DERIVED INTERMEDIATES
TO HYDROCARBON FUELS *197
8.1 INTRODUCTION 197
8.2 UPGRADING OF BIO-OIL FROM BIOMASS PYROLYSIS 198
8.2.1 UPGRADING OF BIO-OIL TO HYDROCARBONS BY HYDRODEOXYGENATION 200
8.2.2 UPGRADING OF BIO-OIL VIA C-C COUPLING REACTIONS 202
8.2.3 UPGRADING OF BIO-OIL TO HYDROCARBONS BY FLUID CATALYTIC
CRACKING (FCC) 204
8.3 SUGARS TO HYDROCARBON FUELS 208
8.4 UPGRADING OF BUTANOL TO FUELS 212
8.5 CHALLENGES - OUTLOOK 214
BIBLIOGRAPHY 216
MARCO RICCI AND CARLO PEREGO
9 USE OF BIO-SOURCED
SYNGAS * 219
9.1 INTRODUCTION 219
9.2 USES OF SYNGAS 220
9.2.1 SYNGAS AS A FUEL 220
9.2.2 SYNGAS AS A CHEMICAL FEEDSTOCK * 220
9.2.2.1 HYDROGEN PRODUCTION AND USES 221
9.2.2.2 AMMONIA PRODUCTION AND USES 222
9.2.2.3 UREA PRODUCTION AND USE * 222
9.2.2.4 METHANOL PRODUCTION AND USES 223
9.2.2.5 OXO CHEMICALS PRODUCTION AND USES 224
9.2.3 TRANSPORTATION FUELS FROM SYNGAS: THE FISCHER-TROPSCH
PROCESS 225
9.2.3.1 FISCHER-TROPSCH TO FUELS: BIOMASS-TO-LIQUIDS PROCESSES 225
9.2.3.2 FISCHER-TROPSCH TO OLEFINS 228
9.2.3.3 FEEDING FISCHER-TROPSCH
REACTIONS WITH C0
2
229
9.3 SYNGAS FERMENTATION * 230
9.4 PERSPECTIVES 232
BIBLIOGRAPHY 232
XII CONTENTS
JEAN-LUC COUTURIER AND JEAN-LUC DUBOIS
10 OIL CHEMISTRY: CHEMICALS, POLYMERS, AND FUELS * 235
10.1 INTRODUCTION 235
10.2 INDUSTRIAL APPLICATIONS OF OIL CHEMISTRY * 238
10.3 EUROBIOREF CASE STUDIES 241
10.3.1 GENERAL DESCRIPTION OF THE VALUE CHAINS * 241
10.3.2 OIL PRODUCTION 243
10.3.3 COMPETITION ANALYSIS 244
10.3.4 TECHNOLOGY ANALYSIS 247
10.3.4.1 IPSCORE ANALYSIS 247
10.3.4.2 RISK AND SWOT
ANALYSIS 248
10.3.4.3 LIFE CYCLE ASSESSMENT (LCA) 249
10.3.4.4 TECHNOLOGY READINESS LEVEL
(TRL) ASSESSMENT - ACTUAL
DEMONSTRATION STATUS 249
10.3.5 COSTS ANALYSIS 252
10.3.5.1 CAPITAL EXPENDITURE (CAPEX) EVALUATION 252
10.3.5.2 PRODUCTION COSTS EVALUATION 252
10.3.5.3 JOB CREATION 252
10.3.5.4 BUSINESS MODEL 253
10.3.5.5 CO-LOCATION IN EXISTING ASSETS 254
10.4 CONCLUSIONS 254
BIBLIOGRAPHY 255
HEIKO LANGE, ELISAVET D. BARTZOKA, AND CLAUDIA CRESTINI
11 LIGNIN BIOREFINERY: STRUCTURE, PRETREATMENT
AND USE 257
11.1
INTRODUCTION 257
11.2
ORIGIN AND CHARACTERISTICS OF LIGNIN 258
11.2.1
LIGNIN OCCURRENCE AND LOCATION 258
11.2.2
LIGNIN STRUCTURE 258
11.3
POTENTIAL SOURCES OF BIOREFINERY LIGNIN 262
11.3.1
LIGNIN PRETREATMENT 262
11.3.2
KRAFT LIGNIN PROCESS * 262
11.3.3
THE SULFITE PULPING PROCESS 263
11.3.4
ORGANOSOLV LIGNIN 264
11.3.5
PYROLYSIS PROCESS 265
11.3.6
STEAM EXPLOSION LIGNIN 266
11.3.7
OTHER PROCESSES 266
11.4
THE USE OF LIGNIN IN CURRENT AND FUTURE BIOREFINERY SCHEMES 266
11.4.1
POWER - GREEN FUELS - SYNGAS * 269
11.4.2
MACROMOLECULES 269
11.4.3
AROMATICS AND CHEMICALS 271
CONTENTS XIII
11.4.4 APPLICATIONS IN NANOMATERIALS 273
11.4.4.1 CAPSULES^*273
11.4.4.2 NANOPARTICLES 274
11.4.4.3 MICROPOROUS AND NANOPOROUS MATERIALS 275
11.5 CONCLUSIONS AND PERSPECTIVES 276
BIBLIOGRAPHY 276
RAFROELANT, FABRIZIO CAVANI,
CARLA S.M. PEREIRA,
AND ALFRIO E. RODRIGUES
12 UTILIZATION OF EXISTING ASSETS 283
12.1 INTRODUCTION 283
12.1.1 WHY UTILIZING EXISTING PLANTS TO IMPLEMENT BIO-BASED
TECHNOLOGY? 283
12.1.2 KINDS OF INTEGRATION SCENARIOS 284
12.2 CASE STUDY
1: MALEIC ANHYDRIDE PRODUCTION IN A PHTHALIC
ANHYDRIDE PLANT 285
12.2.1 GENERAL 285
12.2.2 TECHNOLOGICAL ASPECTS OF THE RETROFIT 286
12.2.3 ECONOMIC EVALUATION 288
12.2.4 DEMONSTRATION STATUS 290
12.2.5 STRENGTHS, WEAKNESSES, OPPORTUNITIES, AND THREATS ANALYSIS 292
12.2.6 VALUE CREATION 292
12.2.7 CONCLUDING REMARKS 293
12.3 CASE STUDY 2:1,1-DIBUTOXYETHANE PRODUCTION ADDED TO
AN /7-BUTANOL PLANT IN EUROPE 293
12.3.1 GENERAL 293
12.3.2 TECHNOLOGICAL ASPECTS 294
12.3.3 DEMONSTRATION STATUS 295
12.3.4 STRENGTHS, WEAKNESSES, OPPORTUNITIES, AND THREATS ANALYSIS 297
12.3.5 VALUE CREATION 297
12.3.6 CONCLUDING REMARKS 298
12.4 PERSPECTIVE VIEW 299
BIBLIOGRAPHY 299
MICHELE ARESTA
13 BIOGAS FROM WET BIOMASS: BASIC SCIENCE AND APPLICATIONS
13.1 INTRODUCTION 301
13.1.1 THE "AEROBIC" AND "ANAEROBIC" PROCESSES FOR WET WB
13.2 STRUCTURE OF RAW MATERIALS USED FOR BIOGAS PRODUCTION
13.2.1 CELLULOSE 304
13.2.2 HEMICELLULOSE 305
13.2.3 LIGNIN 305
13.2.4 PECTIN 306
301
301
304
XIV
CONTENTS
13.2.5 STARCH 306
13.2.6 LIPIDS 307
13.2.7 PROTEINS 307
13.3 THE PHASES OF BIOGAS PRODUCTION 308
13.3.1 ANAEROBIC DIGESTION: A NATURE-BASED BIOTECHNOLOGY 309
13.3.2 HYDROLYTIC BACTERIA AND ACIDOGENESIS 310
13.3.2.1 TRANSITIONAL BACTERIA 311
13.3.2.2 ACETOGENESIS 312
13.3.2.3 BACTERIAL FLORA COMPOSITION 312
13.4 ROLE OF HYDROGENASES 313
13.4.1 [FEFE]H
2
-ASE 313
13.4.2 [FES]H
2
-ASE 314
13.4.3 [NIFE]H
2
-ASE AND [FE-NI-SE]-ASE 314
13.4.4 MOLYBDENUM-IRON-CONTAINING N
2
-ASE 316
13.5 METHANOGENIC BACTERIA * 317
13.5.1 METHANOGENESIS 318
13.5.2 THE LABORATORY EQUIPMENT FOR BIOGAS PRODUCTION AND SYSTEM
INVESTIGATION 320
13.6 INDUSTRIAL REACTORS 322
13.6.1 TYPES OF REACTORS AND CONFIGURATION OF BIOGAS PLANTS 327
13.6.1.1 SOLID CONTENT 327
13.6.1.2 TEMPERATURE 327
13.6.1.3 LIQUID AND SOLID RETENTION TIME 327
13.6.1.4 CONTINUITY OF THE PROCESS 327
13.6.2 BIOGAS FROM WASTEWATERS 329
BIBLIOGRAPHY 331
INDEX 339 |
| any_adam_object | 1 |
| author2 | Aresta, Michele 1940- |
| author2_role | edt |
| author2_variant | m a ma |
| author_GND | (DE-588)1059262282 |
| author_facet | Aresta, Michele 1940- |
| building | Verbundindex |
| bvnumber | BV042873492 |
| classification_rvk | WF 9795 ZP 3760 |
| ctrlnum | (OCoLC)925434604 (DE-599)DNB1061098958 |
| dewey-full | 660.63 |
| dewey-hundreds | 600 - Technology (Applied sciences) |
| dewey-ones | 660 - Chemical engineering |
| dewey-raw | 660.63 |
| dewey-search | 660.63 |
| dewey-sort | 3660.63 |
| dewey-tens | 660 - Chemical engineering |
| discipline | Chemie / Pharmazie Biologie Energietechnik |
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| id | DE-604.BV042873492 |
| illustrated | Illustrated |
| indexdate | 2024-08-03T02:40:07Z |
| institution | BVB |
| isbn | 9783110331530 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-028302556 |
| oclc_num | 925434604 |
| open_access_boolean | |
| owner | DE-634 DE-11 DE-29T DE-703 DE-1102 DE-83 |
| owner_facet | DE-634 DE-11 DE-29T DE-703 DE-1102 DE-83 |
| physical | XVIII, 348 S. Ill., graph. Darst., Kt. |
| publishDate | 2015 |
| publishDateSearch | 2015 |
| publishDateSort | 2015 |
| publisher | de Gruyter |
| record_format | marc |
| series2 | de Gruyter graduate |
| spelling | Biorefineries an introduction ed. by Michele Aresta ... Berlin [u.a.] de Gruyter 2015 XVIII, 348 S. Ill., graph. Darst., Kt. txt rdacontent n rdamedia nc rdacarrier de Gruyter graduate Bioraffinerie (DE-588)7742513-3 gnd rswk-swf Biomasse (DE-588)4006877-8 gnd rswk-swf Biochemie (DE-588)4006777-4 gnd rswk-swf Chemieanlage (DE-588)4121084-0 gnd rswk-swf Bioverfahrenstechnik (DE-588)4307166-1 gnd rswk-swf Fachhochschul-/Hochschulausbildung Renewable Resources, Alternative Energy, Biomass Conversion, Bioraffinerie (DE-588)7742513-3 s DE-604 Bioverfahrenstechnik (DE-588)4307166-1 s Chemieanlage (DE-588)4121084-0 s Biochemie (DE-588)4006777-4 s Biomasse (DE-588)4006877-8 s Aresta, Michele 1940- (DE-588)1059262282 edt Erscheint auch als Online-Ausgabe, EPUB 978-3-11-038999-9 Erscheint auch als Online-Ausgabe, PDF 978-3-11-033158-5 X:MVB text/html http://deposit.dnb.de/cgi-bin/dokserv?id=4828469&prov=M&dok_var=1&dok_ext=htm Inhaltstext DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=028302556&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Biorefineries an introduction Bioraffinerie (DE-588)7742513-3 gnd Biomasse (DE-588)4006877-8 gnd Biochemie (DE-588)4006777-4 gnd Chemieanlage (DE-588)4121084-0 gnd Bioverfahrenstechnik (DE-588)4307166-1 gnd |
| subject_GND | (DE-588)7742513-3 (DE-588)4006877-8 (DE-588)4006777-4 (DE-588)4121084-0 (DE-588)4307166-1 |
| title | Biorefineries an introduction |
| title_auth | Biorefineries an introduction |
| title_exact_search | Biorefineries an introduction |
| title_full | Biorefineries an introduction ed. by Michele Aresta ... |
| title_fullStr | Biorefineries an introduction ed. by Michele Aresta ... |
| title_full_unstemmed | Biorefineries an introduction ed. by Michele Aresta ... |
| title_short | Biorefineries |
| title_sort | biorefineries an introduction |
| title_sub | an introduction |
| topic | Bioraffinerie (DE-588)7742513-3 gnd Biomasse (DE-588)4006877-8 gnd Biochemie (DE-588)4006777-4 gnd Chemieanlage (DE-588)4121084-0 gnd Bioverfahrenstechnik (DE-588)4307166-1 gnd |
| topic_facet | Bioraffinerie Biomasse Biochemie Chemieanlage Bioverfahrenstechnik |
| url | http://deposit.dnb.de/cgi-bin/dokserv?id=4828469&prov=M&dok_var=1&dok_ext=htm http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=028302556&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT arestamichele biorefineriesanintroduction |