Synthesis and Original Reactivity of Copper and Gold Complexes Sigma-Bond Coordination, Oxidative Addition, Migratory Insertion
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| Format: | Abschlussarbeit Elektronisch E-Book |
| Sprache: | English |
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Cham [u.a.]
Springer International Publishing
2015
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| Schriftenreihe: | Springer Theses, Recognizing Outstanding Ph.D. Research
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| Online-Zugang: | DE-1046 DE-703 Volltext Inhaltsverzeichnis Abstract |
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Datensatz im Suchindex
| _version_ | 1819673654924935168 |
|---|---|
| adam_text | SYNTHESIS AND ORIGINAL REACTIVITY OF COPPER AND GOLD COMPLEXES
/ JOOST, MAXIMILIAN
: 2015
TABLE OF CONTENTS / INHALTSVERZEICHNIS
GENERAL INTRODUCTION
COPPER: Σ-SIH COORDINATION TO CU(I)
FUNDAMENTAL ELEMENTARY STEPS IN GOLD CHEMISTRY
GOLD: MIGRATORY INSERTION AT AU(I)
GOLD: OXIDATIVE ADDITION TO AU(I)
GENERAL CONCLUSION AND PERSPECTIVE
APPENDIX: CRYSTALLOGRAPHIC DATA
DIESES SCHRIFTSTUECK WURDE MASCHINELL ERZEUGT.
SYNTHESIS AND ORIGINAL REACTIVITY OF COPPER AND GOLD COMPLEXES
/ JOOST, MAXIMILIAN
: 2015
ABSTRACT / INHALTSTEXT
THIS THESIS ADDRESSES THE COORDINATION CHEMISTRY AND REACTIVITY OF
COPPER AND GOLD COMPLEXES WITH A FOCUS ON THE ELUCIDATION OF (I) THE
METAL-MEDIATED ACTIVATION OF Σ-BONDS AND (II) THE MIGRATORY INSERTION
REACTION. BOTH PROCESSES ARE OF CONSIDERABLE IMPORTANCE IN
ORGANOMETALLIC CHEMISTRY, BUT REMAIN ELUSIVE FOR CU AND AU COMPLEXES. IN
THIS WORK, THE AUTHOR CONTRIBUTES SIGNIFICANT ADVANCES: THE FIRST Σ-SIH
COMPLEXES OF COPPER ARE EXPERIMENTALLY AND COMPUTATIONALLY
CHARACTERIZED, YIELDING VALUABLE INSIGHTS INTO Σ-BOND ACTIVATION
PROCESSES FOR COPPER. EVIDENCE FOR A HIGHLY UNUSUAL MIGRATORY SYN
INSERTION OF UNSATURATED ORGANIC MOLECULES INTO THE GOLD-SILICON BOND OF
SILYLGOLD (I) COMPLEXES IS PROVIDED AND THE CORRESPONDING MECHANISM
IDENTIFIED. THE INTERMOLECULAR OXIDATIVE ADDITION OF Σ-SISI, Σ-CC AND
Σ-CX (X=HALOGEN) BONDS WITH MOLECULAR GOLD (I) COMPLEXES IS STUDIED IN
DETAIL, EFFECTIVELY DEMONSTRATING THAT THIS REACTION, USUALLY CONSIDERED
TO BE IMPOSSIBLE FOR GOLD, IS ACTUALLY HIGHLY FAVORED, PROVIDED AN
ADEQUATE LIGAND IS EMPLOYED. THE USE OF SMALL-BITE ANGLE BIS (PHOSPHINE)
GOLD (I) COMPLEXES ALLOWS FOR THE FIRST TIME THE OXIDATIVE ADDITION OF
Σ-CC AND Σ-CX BONDS FOR GOLD (I). THESE RESULTS SHED LIGHT ON AN
UNEXPECTED REACTIVITY PATTERN OF GOLD COMPLEXES AND MAY POINT THE WAY TO
2-ELECTRON REDOX TRANSFORMATIONS MEDIATED BY THIS METAL, OPENING UP NEW
PERSPECTIVES IN GOLD CATALYSIS
DIESES SCHRIFTSTUECK WURDE MASCHINELL ERZEUGT.
|
| any_adam_object | 1 |
| author | Joost, Maximilian |
| author_facet | Joost, Maximilian |
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| dewey-sort | 3547.05 |
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| discipline | Chemie / Pharmazie |
| doi_str_mv | 10.1007/978-3-319-18690-0 |
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| illustrated | Not Illustrated |
| indexdate | 2024-12-24T04:30:49Z |
| institution | BVB |
| isbn | 9783319186900 |
| language | English |
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| physical | 1 Online-Ressource (XXVI, 224 p. 328 illus., 55 illus. in color) |
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| publisher | Springer International Publishing |
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| series2 | Springer Theses, Recognizing Outstanding Ph.D. Research |
| spellingShingle | Joost, Maximilian Synthesis and Original Reactivity of Copper and Gold Complexes Sigma-Bond Coordination, Oxidative Addition, Migratory Insertion Chemistry Chemistry, Organic Chemistry, Physical organic Organometallic Chemistry Physical Chemistry Computer Applications in Chemistry Chemie |
| subject_GND | (DE-588)4113937-9 |
| title | Synthesis and Original Reactivity of Copper and Gold Complexes Sigma-Bond Coordination, Oxidative Addition, Migratory Insertion |
| title_auth | Synthesis and Original Reactivity of Copper and Gold Complexes Sigma-Bond Coordination, Oxidative Addition, Migratory Insertion |
| title_exact_search | Synthesis and Original Reactivity of Copper and Gold Complexes Sigma-Bond Coordination, Oxidative Addition, Migratory Insertion |
| title_full | Synthesis and Original Reactivity of Copper and Gold Complexes Sigma-Bond Coordination, Oxidative Addition, Migratory Insertion Maximilian Joost |
| title_fullStr | Synthesis and Original Reactivity of Copper and Gold Complexes Sigma-Bond Coordination, Oxidative Addition, Migratory Insertion Maximilian Joost |
| title_full_unstemmed | Synthesis and Original Reactivity of Copper and Gold Complexes Sigma-Bond Coordination, Oxidative Addition, Migratory Insertion Maximilian Joost |
| title_short | Synthesis and Original Reactivity of Copper and Gold Complexes |
| title_sort | synthesis and original reactivity of copper and gold complexes sigma bond coordination oxidative addition migratory insertion |
| title_sub | Sigma-Bond Coordination, Oxidative Addition, Migratory Insertion |
| topic | Chemistry Chemistry, Organic Chemistry, Physical organic Organometallic Chemistry Physical Chemistry Computer Applications in Chemistry Chemie |
| topic_facet | Chemistry Chemistry, Organic Chemistry, Physical organic Organometallic Chemistry Physical Chemistry Computer Applications in Chemistry Chemie Hochschulschrift |
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