Kinetics of multistep reactions
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| Format: | Elektronisch E-Book |
| Sprache: | English |
| Veröffentlicht: |
Amsterdam
Elsevier
2004
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| Ausgabe: | 2nd ed |
| Schriftenreihe: | Comprehensive chemical kinetics
v. 40 |
| Schlagworte: | |
| Online-Zugang: | Volltext |
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| 100 | 1 | |a Helfferich, Friedrich G. |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Kinetics of multistep reactions |c F.G. Helfferich |
| 250 | |a 2nd ed | ||
| 264 | 1 | |a Amsterdam |b Elsevier |c 2004 | |
| 300 | |a 1 Online-Ressource (xviii, 488 p.) | ||
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| 490 | 0 | |a Comprehensive chemical kinetics |v v. 40 | |
| 500 | |a Rev. ed. of: Kinetics of homogeneous multistep reactions. 1st ed. 2001 | ||
| 500 | |a Includes bibliographical references and indexes | ||
| 500 | |a This book addresses primarily the engineer in industrial process development, the research chemist in academia and industry, and the graduate student intending to become a reaction engineer. In industry, competitive pressures put a premium on scale-up by large factors to cut development time. To be safe, such development should be based on "fundamental" kinetics that reflect the elementary steps of which the reaction consists. The book forges fundamental kinetics into a practical tool by presenting new, effective methods for elucidation of mechanisms and reduction of complexity without unacceptable sacrifice in accuracy: fewer equations (lesser computational load), fewer coefficients (fewer experiment to determine them). For network elucidation, new rules relating network configurations to observable kinetic behaviour allow incorrect networks to be ruled out by whole classes instead of one by one. For modelling, general equations and algorithms are given from which equations for specific networks can be recovered by simple substitutions. The procedures are illustrated with examples of industrial reactions including, among others, paraffin oxidation, ethoxylation, hydroformylation, hydrocyanation, shape-selective catalysis, ethane pyrolysis, styrene polymerization, and ethene oligomerization. Many of the rate equations have not been published before. The expanded edition of the 2001 title, Kinetics of Homogeneous Multistep Reactions includes new chapters on heterogeneous catalysis and periodic and chaotic re-actions; new sections on adsorption, statistical methods, and lumping; and other new detail. * Contains new chapters on heterogeneous catalysis, oscillations and chaos * Includes new sections on statistical methods, lumping adsorption and software and databases * Provides a better understanding of complex reaction mechanisms | ||
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| 700 | 1 | |a Helfferich, Friedrich G. |e Sonstige |4 oth | |
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Datensatz im Suchindex
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|---|---|
| any_adam_object | |
| author | Helfferich, Friedrich G. |
| author_facet | Helfferich, Friedrich G. |
| author_role | aut |
| author_sort | Helfferich, Friedrich G. |
| author_variant | f g h fg fgh |
| building | Verbundindex |
| bvnumber | BV042313767 |
| collection | ZDB-33-ESD ZDB-33-EBS |
| ctrlnum | (OCoLC)162129933 (DE-599)BVBBV042313767 |
| dewey-full | 541/.394 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 541 - Physical chemistry |
| dewey-raw | 541/.394 |
| dewey-search | 541/.394 |
| dewey-sort | 3541 3394 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie |
| edition | 2nd ed |
| format | Electronic eBook |
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| id | DE-604.BV042313767 |
| illustrated | Not Illustrated |
| indexdate | 2024-12-24T04:19:47Z |
| institution | BVB |
| isbn | 9780444516534 0444516530 9780080473185 0080473180 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-027750758 |
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| physical | 1 Online-Ressource (xviii, 488 p.) |
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| publishDate | 2004 |
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| publisher | Elsevier |
| record_format | marc |
| series2 | Comprehensive chemical kinetics |
| spelling | Helfferich, Friedrich G. Verfasser aut Kinetics of multistep reactions F.G. Helfferich 2nd ed Amsterdam Elsevier 2004 1 Online-Ressource (xviii, 488 p.) txt rdacontent c rdamedia cr rdacarrier Comprehensive chemical kinetics v. 40 Rev. ed. of: Kinetics of homogeneous multistep reactions. 1st ed. 2001 Includes bibliographical references and indexes This book addresses primarily the engineer in industrial process development, the research chemist in academia and industry, and the graduate student intending to become a reaction engineer. In industry, competitive pressures put a premium on scale-up by large factors to cut development time. To be safe, such development should be based on "fundamental" kinetics that reflect the elementary steps of which the reaction consists. The book forges fundamental kinetics into a practical tool by presenting new, effective methods for elucidation of mechanisms and reduction of complexity without unacceptable sacrifice in accuracy: fewer equations (lesser computational load), fewer coefficients (fewer experiment to determine them). For network elucidation, new rules relating network configurations to observable kinetic behaviour allow incorrect networks to be ruled out by whole classes instead of one by one. For modelling, general equations and algorithms are given from which equations for specific networks can be recovered by simple substitutions. The procedures are illustrated with examples of industrial reactions including, among others, paraffin oxidation, ethoxylation, hydroformylation, hydrocyanation, shape-selective catalysis, ethane pyrolysis, styrene polymerization, and ethene oligomerization. Many of the rate equations have not been published before. The expanded edition of the 2001 title, Kinetics of Homogeneous Multistep Reactions includes new chapters on heterogeneous catalysis and periodic and chaotic re-actions; new sections on adsorption, statistical methods, and lumping; and other new detail. * Contains new chapters on heterogeneous catalysis, oscillations and chaos * Includes new sections on statistical methods, lumping adsorption and software and databases * Provides a better understanding of complex reaction mechanisms SCIENCE / Chemistry / Physical & Theoretical bisacsh Chemical kinetics fast Chemie Chemical kinetics Helfferich, Friedrich G. Sonstige oth http://www.sciencedirect.com/science/book/9780444516534 Verlag Volltext |
| spellingShingle | Helfferich, Friedrich G. Kinetics of multistep reactions SCIENCE / Chemistry / Physical & Theoretical bisacsh Chemical kinetics fast Chemie Chemical kinetics |
| title | Kinetics of multistep reactions |
| title_auth | Kinetics of multistep reactions |
| title_exact_search | Kinetics of multistep reactions |
| title_full | Kinetics of multistep reactions F.G. Helfferich |
| title_fullStr | Kinetics of multistep reactions F.G. Helfferich |
| title_full_unstemmed | Kinetics of multistep reactions F.G. Helfferich |
| title_short | Kinetics of multistep reactions |
| title_sort | kinetics of multistep reactions |
| topic | SCIENCE / Chemistry / Physical & Theoretical bisacsh Chemical kinetics fast Chemie Chemical kinetics |
| topic_facet | SCIENCE / Chemistry / Physical & Theoretical Chemical kinetics Chemie |
| url | http://www.sciencedirect.com/science/book/9780444516534 |
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