pH measurement and titration

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Bibliographische Detailangaben
1. Verfasser: Mattock, G. (VerfasserIn)
Format: Buch
Sprache:English
Veröffentlicht: London Heywood & Comp. Ltd 1961
Schriftenreihe:Physical processes in the chemical industry 6
Online-Zugang:Inhaltsverzeichnis
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245 1 0 |a pH measurement and titration  |c G. Mattock. With a chapter by G. Ross Taylor 
264 1 |a London  |b Heywood & Comp. Ltd  |c 1961 
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adam_text pH Measurement and Titration G MATTOCK Electronic Instruments Ltd, Richmond, Surrey with a chapter by G ROSS TAYLOR Electronic Instruments Ltd, Richmond, Surrey LONDON HEYWOOD amp; COMPANY LTD CONTENTS PAGE FOREWORD v PREFACE VII ACKNOWLEDGEMENTS XI BASIC THEORETICAL PRINCIPLES I The Mature of Electrolyte Solutions—Ionic Activities— i Water—Electrochemical Cells and Electrode Potentials—Sign Conventions and Symbols—The Electrochemical pH Cell DEFINITIONS OF pH 1 6 pH Scales—pH Scales Based on the Dissociation of Weak Acids—The National Bureau of Standards Scale—The British Standards Institution Scale—Choice of a pH Scale— Non-aqueous Scales—Acidity and Basicity Functions in Non-aqueous Media BUFFER SOLUTIONS 39 The Principles of Buffer Action—Characteristics of Buffer Solutions—Standard Buffer Solutions—The Preparation of Buffer Solutions—Special Purpose Buffers—pH Control by Buffers COLORIMETRIC MEASUREMENT OF p H 58 I General Principles—Visual Measurement of pH—Photo- ! metric Measurement of pH—Sources of Error in Indicator | pH Measurement IpH MEASURING ELECTRODES : Low RESISTANCE TYPES 73 EMF Measurement of Low Resistance Systems—The Hydrogen Gas Electrode—The Quinhydrone Electrode— Metal-Metal Oxide Electrodes—The Oxygen Gas Electrode —Polymer Systems pH MEASURING ELECTRODES: THE GLASS ELECTRODE 93 The pH Function—The Construction of Glass Electrodes— Use of the Glass Electrode—Properties of Glass Electrodes— Properties of Electrode Glasses as a Function of Composition— Mechanism of the Electrode Function REFERENCEELECTRODES-138 General Requirements—Calomel Electrodes—Mercury-Mer- curous Sulphate Electrodes—Silver-Silver Chloride Electrodes —Industrial High Pressure Reference Electrode Designs— Non-aqueous Reference Electrodes—Other Reference Electrodes xiv CONTENTS 8 LIQUID JUNCTIONS 1 6 7 Liquid Junction Potentials—Theoretical Calculation of Liquid Junction Potentials—Factors Affecting the Junction Potential — Experimental Arrangements — Aqueous-Non- aqueous Boundaries 9EMF -TEMPERATURE CHARACTERISTICS OF pH CELLS 184 Sources of Temperature Errors in EMF -pH Measure­ ments—The Isopotential Concept 10 pH MEASURING INSTRUMENTS 1 9 8 This chapter is by G ROSS TAYLOR Null-point Detector Meters—Principles of the Direct- reading pH Meter—Mains-operated Direct-reading Instru­ ments—Battery-operated Direct-reading Portable Instru­ ments—Temperature Compensation 11 LABORATORY pH MEASUREMENTS WITH THE GLASS ELECTRODE 247 Types of Laboratory Assembly—pH Measurement—Dis­ cussion of Examples—Highly Accurate pH Measurements 12 INDUSTRIAL pH MEASUREMENTS AND AUTOMATIC pH N CONTROL 274 Electrode Assemblies—Commissioning and Maintenance— Discussion of Example Problems—Automatic pH Control 13 LABORATORY pH TITRATIONS 302 Titration Curves—Titration Errors—pH Titration with Colorimetric Endpoint Detection—pH Titration with E M F Endpoint Detection 14 NON-AQUEOUS ACID-BASE TITRATIONS 336 General Principles—Choice of Solvent and Titrant—Colori­ metric Endpoint Detection—Potentiometric Endpoint Detec­ tion—Properties of Solvents and Preparation of Solutions 15 AUTOMATIC pH TITRATIONS 359 General Requirements—Laboratory Automatic Titrators— Plant Automatic Titrators—pH and Acidity Control from Titrators APPENDIXES 389
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spelling Mattock, G. Verfasser aut
pH measurement and titration G. Mattock. With a chapter by G. Ross Taylor
London Heywood & Comp. Ltd 1961
XIV, 406 S. Ill., graph. Darst.
txt rdacontent
n rdamedia
nc rdacarrier
Physical processes in the chemical industry 6
Taylor, G. Ross Sonstige oth
Physical processes in the chemical industry 6 (DE-604)BV001898209 6
HEBIS Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027180678&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis
spellingShingle Mattock, G.
pH measurement and titration
Physical processes in the chemical industry
title pH measurement and titration
title_auth pH measurement and titration
title_exact_search pH measurement and titration
title_full pH measurement and titration G. Mattock. With a chapter by G. Ross Taylor
title_fullStr pH measurement and titration G. Mattock. With a chapter by G. Ross Taylor
title_full_unstemmed pH measurement and titration G. Mattock. With a chapter by G. Ross Taylor
title_short pH measurement and titration
title_sort ph measurement and titration
url http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027180678&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA
volume_link (DE-604)BV001898209
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