Investigations into the gas phase chemistry of supramolecular assemblies = Untersuchungen der Gasphasenchemie supramolekularer Verbindungen
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| Format: | Abschlussarbeit Buch |
| Sprache: | English |
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2014
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| 245 | 1 | 0 | |a Investigations into the gas phase chemistry of supramolecular assemblies |b = Untersuchungen der Gasphasenchemie supramolekularer Verbindungen |c vorgelgt von Marc Simon von Gernler |
| 246 | 1 | 1 | |a Untersuchungen der Gasphasenchemie supramolekularer Verbindungen |
| 264 | 1 | |c 2014 | |
| 300 | |a XXIII, 333 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 502 | |a Erlangen-Nürnberg, Univ., Diss., 2014 | ||
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Datensatz im Suchindex
| _version_ | 1804151993898369024 |
|---|---|
| adam_text | CONTENTS
ABSTRACT VII
ACRONYMS XIII
LIST OF FIGURES XV
LIST OF TABLES XXIII
INTRODUCTION 1
1. FUNDAMENTALS 5
1.1. FUNDAMENTALS OF MASS SPECTROMETRY 5
1.1.1. UNITS 6
1.1.2. MASS RESOLUTION AND MASS ACCURACY 7
1.1.3. DETERMINATION OF THE CHARGE STATE AND CHARGE DECONVOLUTION 8
1.2. ELECTROSPRAY IONISATION 12
1.2.1. HISTORY 12
1.2.2. ESI - PRINCIPLE OF OPERATION 13
1.2.3. SAMPLE PREPARATION 19
1.3. MATRIX-ASSISTED LASER DESORPTION/IONISATION 20
1.3.1. HISTORY 20
1.3.2. MALDI - PRINCIPLE OF OPERATION 20
1.3.3. SAMPLE PREPARATION 23
1.4. QUADRUPOLE ION TRAP 25
1.4.1. HISTORY 25
1.4.2. QIT - PRINCIPLE OF OPERATION 26
IX
HTTP://D-NB.INFO/104825867X
CONTENTS
1.4.3. ION MOTION 34
1.4.4. RESONANT EJECTION 35
1.4.5. MS/MS IN THE QUADRUPOLE ION TRAP 37
1.5. TIME-OF-FLIGHT 39
1.5.1. HISTORY 39
1.5.2. LINEAR TOF 40
1.5.3. REFLECTRON TOF 48
1.5.4. MS/MS IN THE TOF ANALYSER 50
1.6. INSTRUMENTATION 55
1.6.1. ION TRANSFER 57
1.6.2. SOFTWARE 63
1.7. GAS PHASE ION CHEMISTRY 64
1.7.1. PROTON AFFINITY AND GAS PHASE BASICITY 64
1.7.2. METHODS FOR THERMOCHEMICAL DETERMINATIONS 64
1.8. FULLERENES 70
1.8.1. HISTORY 71
1.8.2. SYNTHESIS 72
1.8.3. STRUCTURE 73
1.8.4. FUNCTIONALISATION AND MODIFICATION 77
1.9. CONSUMABLES 81
2. AMINO ACIDS - A STUDY OF GAS PHASE CLUSTER CHEMISTRY 83
2.1. INTRODUCTION 83
2.2. SCOPE OF WORK 88
2.3. EXPERIMENTAL 88
2.4. RESULTS 88
2.4.1. DISSOCIATION OF THE CLUSTER COMPLEXES 95
2.4.2. ASPARTIC AND GLUTAMIC ACID 108
2.4.3. MULTIPLY CHARGED CLUSTERS 112
2.4.4. DISSOCIATION OF DOUBLY CHARGED CLUSTERS 115
2.5. CONCLUSION 122
X
CONTENTS
3. THE GAS PHASE ION CHEMISTRY OF FULLERENE DERIVATIVES 125
3.1. SODIUM ION AFFINITIES OF FUNCTIONALISED FULLERENES 125
3.1.1. INTRODUCTION 125
3.1.2. SCOPE OF WORK 127
3.1.3. EXPERIMENTAL 127
3.1.4. RESULTS 129
3.1.5. CONCLUSION 139
3.2. COULOMB EXPLOSION OF DOUBLY CHARGED FULLERENE-ESTER/ALKALI
AGGREGATES . . . 141
3.2.1. INTRODUCTION 141
3.2.2. EXPERIMENTAL 143
3.2.3. RESULTS 143
3.2.4. CONCLUSION 159
3.3. CROWN ETHER/FULLERENE CONJUGATES 161
3.3.1. INTRODUCTION 161
3.3.2. EXPERIMENTAL 165
3.3.3. RESULTS 166
3.3.4. CONCLUSION 184
4. STRUCTURE AND STABILITY OF METALLA CROWN COMPLEXES 187
4.1. INTRODUCTION 187
4.2. EXPERIMENTAL 193
4.3. RESULTS 193
4.3.1. MS/MS EXPERIMENTS 198
4.3.2. EXCHANGE EXPERIMENTS 205
4.4. CONCLUSION 211
5. POLYOXOPALLADATES 213
5.1. INTRODUCTION 213
5.2. SCOPE OF WORK 215
5.3. EXPERIMENTAL 216
5.4. RESULTS 217
5.4.1. POSITIVELY CHARGED POLYOXOMETALATES 219
5.4.2. DISSOCIATION OF THE MPDPHAS CATIONS 223
5.4.3. NEGATIVELY CHARGED POLYOXOMETALATES 226
XI
CONTENTS
5.4.4. DISSOCIATION OF THE POLYANIONS 229
5.5. CONCLUSION 231
SUMMARY 233
A. AMINO ACID SPECTRAL CATALOGUE 241
B. BIBLIOGRAPHY 303
INDEX 329
ACKNOWLEDGEMENT 333
XII
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| any_adam_object | 1 |
| author | Gernler, Marc Simon von |
| author_GND | (DE-588)1048085023 |
| author_facet | Gernler, Marc Simon von |
| author_role | aut |
| author_sort | Gernler, Marc Simon von |
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| building | Verbundindex |
| bvnumber | BV041717794 |
| ctrlnum | (OCoLC)876467623 (DE-599)BVBBV041717794 |
| dewey-full | 541.0423 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 541 - Physical chemistry |
| dewey-raw | 541.0423 |
| dewey-search | 541.0423 |
| dewey-sort | 3541.0423 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie |
| format | Thesis Book |
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| genre_facet | Hochschulschrift |
| id | DE-604.BV041717794 |
| illustrated | Illustrated |
| indexdate | 2024-07-10T01:03:39Z |
| institution | BVB |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-027164845 |
| oclc_num | 876467623 |
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| owner_facet | DE-188 DE-29 DE-12 DE-29T DE-355 DE-BY-UBR |
| physical | XXIII, 333 S. Ill., graph. Darst. |
| publishDate | 2014 |
| publishDateSearch | 2014 |
| publishDateSort | 2014 |
| record_format | marc |
| spelling | Gernler, Marc Simon von Verfasser (DE-588)1048085023 aut Investigations into the gas phase chemistry of supramolecular assemblies = Untersuchungen der Gasphasenchemie supramolekularer Verbindungen vorgelgt von Marc Simon von Gernler Untersuchungen der Gasphasenchemie supramolekularer Verbindungen 2014 XXIII, 333 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Erlangen-Nürnberg, Univ., Diss., 2014 Gasphase (DE-588)4156038-3 gnd rswk-swf Fullerene (DE-588)4305238-1 gnd rswk-swf Kronenether (DE-588)4165804-8 gnd rswk-swf Supramolekulare Struktur (DE-588)4208977-3 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Supramolekulare Struktur (DE-588)4208977-3 s Kronenether (DE-588)4165804-8 s Fullerene (DE-588)4305238-1 s Gasphase (DE-588)4156038-3 s DE-604 DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027164845&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Gernler, Marc Simon von Investigations into the gas phase chemistry of supramolecular assemblies = Untersuchungen der Gasphasenchemie supramolekularer Verbindungen Gasphase (DE-588)4156038-3 gnd Fullerene (DE-588)4305238-1 gnd Kronenether (DE-588)4165804-8 gnd Supramolekulare Struktur (DE-588)4208977-3 gnd |
| subject_GND | (DE-588)4156038-3 (DE-588)4305238-1 (DE-588)4165804-8 (DE-588)4208977-3 (DE-588)4113937-9 |
| title | Investigations into the gas phase chemistry of supramolecular assemblies = Untersuchungen der Gasphasenchemie supramolekularer Verbindungen |
| title_alt | Untersuchungen der Gasphasenchemie supramolekularer Verbindungen |
| title_auth | Investigations into the gas phase chemistry of supramolecular assemblies = Untersuchungen der Gasphasenchemie supramolekularer Verbindungen |
| title_exact_search | Investigations into the gas phase chemistry of supramolecular assemblies = Untersuchungen der Gasphasenchemie supramolekularer Verbindungen |
| title_full | Investigations into the gas phase chemistry of supramolecular assemblies = Untersuchungen der Gasphasenchemie supramolekularer Verbindungen vorgelgt von Marc Simon von Gernler |
| title_fullStr | Investigations into the gas phase chemistry of supramolecular assemblies = Untersuchungen der Gasphasenchemie supramolekularer Verbindungen vorgelgt von Marc Simon von Gernler |
| title_full_unstemmed | Investigations into the gas phase chemistry of supramolecular assemblies = Untersuchungen der Gasphasenchemie supramolekularer Verbindungen vorgelgt von Marc Simon von Gernler |
| title_short | Investigations into the gas phase chemistry of supramolecular assemblies |
| title_sort | investigations into the gas phase chemistry of supramolecular assemblies untersuchungen der gasphasenchemie supramolekularer verbindungen |
| title_sub | = Untersuchungen der Gasphasenchemie supramolekularer Verbindungen |
| topic | Gasphase (DE-588)4156038-3 gnd Fullerene (DE-588)4305238-1 gnd Kronenether (DE-588)4165804-8 gnd Supramolekulare Struktur (DE-588)4208977-3 gnd |
| topic_facet | Gasphase Fullerene Kronenether Supramolekulare Struktur Hochschulschrift |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027164845&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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