Energetic materials based on isocyanuric acid and 1,2,4-oxadiazole derivatives synthesis and characterization
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Abschlussarbeit Buch |
| Sprache: | English |
| Veröffentlicht: |
2013
|
| Schlagworte: | |
| Online-Zugang: | kostenfrei https://nbn-resolving.org/urn:nbn:de:bvb:19-162379 Inhaltsverzeichnis |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
MARC
| LEADER | 00000nam a2200000 c 4500 | ||
|---|---|---|---|
| 001 | BV041601242 | ||
| 003 | DE-604 | ||
| 005 | 20140214 | ||
| 007 | t| | ||
| 008 | 140130s2013 gw ad|| m||| 00||| eng d | ||
| 015 | |a 13,H12 |2 dnb | ||
| 016 | 7 | |a 1044668237 |2 DE-101 | |
| 035 | |a (OCoLC)869893781 | ||
| 035 | |a (DE-599)DNB1044668237 | ||
| 040 | |a DE-604 |b ger |e rakddb | ||
| 041 | 0 | |a eng | |
| 044 | |a gw |c XA-DE | ||
| 049 | |a DE-12 |a DE-19 |a DE-384 |a DE-473 |a DE-703 |a DE-1051 |a DE-824 |a DE-29 |a DE-91 |a DE-1049 |a DE-92 |a DE-739 |a DE-898 |a DE-355 |a DE-706 |a DE-20 |a DE-1102 | ||
| 082 | 0 | |a 547.595 |2 22/ger | |
| 084 | |a 540 |2 sdnb | ||
| 100 | 1 | |a Mayr, Norbert Thorsten |d 1978- |e Verfasser |0 (DE-588)1044668083 |4 aut | |
| 245 | 1 | 0 | |a Energetic materials based on isocyanuric acid and 1,2,4-oxadiazole derivatives |b synthesis and characterization |c Norbert Thorsten Mayr |
| 264 | 1 | |c 2013 | |
| 300 | |a XIV, 327 S. |b Ill., graph. Darst. |c 30 cm | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 502 | |a München, Univ., Diss., 2013 | ||
| 655 | 7 | |0 (DE-588)4113937-9 |a Hochschulschrift |2 gnd-content | |
| 776 | 0 | 8 | |i Erscheint auch als |n Online-Ausgabe |o urn:nbn:de:bvb:19-162379 |
| 776 | 0 | 8 | |i Erscheint auch als |n Online-Ausgabe |a Mayr, Norbert |t Energetic materials based on isocyanuric acid and 1,2,4-oxadiazole derivatives |
| 856 | 4 | 1 | |u http://edoc.ub.uni-muenchen.de/16237/ |x Verlag |z kostenfrei |3 Volltext |
| 856 | 4 | |u https://nbn-resolving.org/urn:nbn:de:bvb:19-162379 |x Resolving-System | |
| 856 | 4 | 2 | |m DNB Datenaustausch |q application/pdf |u http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027042843&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |3 Inhaltsverzeichnis |
| 912 | |a ebook | ||
| 943 | 1 | |a oai:aleph.bib-bvb.de:BVB01-027042843 | |
Datensatz im Suchindex
| _version_ | 1819629813068988416 |
|---|---|
| adam_text | INTRODUCTION
1 TABLE OF CONTENTS
PART I INTRODUCTION 15
1 INTRODUCTION 16
1.1 GENERAL 16
1.2 PYROTECHNICS 17
1.3 DEVELOPMENTS IN ENERGETIC MATERIALS RESEARCH 17
1.4 STABILITY AND PERFORMANCE 19
1.5 EXPLOSIVES AND ENVIRONMENT 19
2 OBJECTIVES OF THE RESEARCH IN
THIS THESIS 20
3 PARTS AND CHAPTERS 21
4 INTRODUCTION OF USED METHODS 21
4.
1 THEORY OF EXPLOSION AND EXPLOSION PRODUCTS
22
4.1.1 PHYSICAL AND CHEMICAL
EXPLOSION 22
4.1.2 BURNING, DEFLAGRATION AND DETONATION 22
4.1.3 DEFLAGRATION TO DETONATION TRANSITION 23
4.1.4 BRISANCE VS. EXPLOSIVENESS 23
4.2
CALCULATION OF ENERGETIC PROPERTIES USING EPXL05 CODE
1291
24
4.2.1 SHOCK WAVE PROPAGATION
AND CHAPMAN-JOUGUET
VELOCITY 24
4.2.2 BECKER-KISTIAKOVSKY-WILSON EQUATION
OF STATE (BKW-EOS) 24
4.2.3 EXPLOSION PRODUCTS
- KISTIAKOVSKY-WILSON
AND SPRINGALL-ROBERTS
RULES
12
* 24
4.2.4 INPUT PARAMETERS: OXYGEN BALANCE,
HEAT OF FORMATION AND DENSITY 25
4.3
PRACTICAL METHODS
25
4.3.1 SENSITIVITY TESTING 25
4.3.2 DETERMINATION OF DENSITY 27
4.3.3 MEASURING THE
HEAT OF FORMATION 28
5 REFERENCES 28
PART 11 EXPLOSIVE UREA DERIVATIVES 31
CHAPTER I A COMPREHENSIVE STUDY ON
N,N -BIS{TRIS(NITRATOMETHYL)METHYL)OXAMIDE 33
1 INTRODUCTION 34
2 RESULTS AND DISCUSSION 35
2.
1 COMPARISON OF CRYSTAL STRUCTURES 35
2.2 VIBRATIONAL AND THERMODYNAMICAL DATA AND CALCULATIONS 39
2.2.1 THERMODYNAMICAL CALCULATION
AND EXPERIMENTAL DATA 42
2.3 ELECTROSTATIC POTENTIAL (ESP) AND DECOMPOSITION
45
2.4
THERMOSTABILITY: DSC AND RADEX MEASUREMENTS
47
2.5
ENERGETIC PROPERTIES 48
2.5.1 COMPARISON OF ENERGETIC PROPERTIES OF BTNMMOXAMIDE TO COMMON
EXPLOSIVES 48
2.5.2 KOENEN (STEEL SLEEVES) TEST 49
3 CONCLUSIONS 50
4 EXPERIMENTAL 51
4.
1 CRYSTAL STRUCTURES 51
4.2 PROPERTIES 51
4.3 SPECTROSCOPIC DATA AND ELEMENTAL ANALYSIS 51
4.4 PREPARATION 51
5 REFERENCES 52
CHAPTER II ENERGETIC CYANURIC ACID
DERIVATIVES 55
1 INTRODUCTION 56
1.1.1 NITRO UREA COMPOUNDS 57
2 DISCUSSION 59
2.1 SYNTHESIS 59
HTTP://D-NB.INFO/1044668237
INTRODUCTION
2.2 VIBRATIONAL SPECTROSCOPY 59
2.2.1 N,N ,N -TRIS-(NITROXYMETHYL)-ISOCYANURIC ACID (3) 59
2.3 THERMOSTABILITY 61
2.3.1 N,N ,N -TRIS-(NITROXYMETHYL)-ISOCYANURIC ACID (3) 61
2.4 CRYSTAL STRUCTURE 62
2.4.1 N,N ,N -TRIS-(NITROXYMETHYL)-ISOCYANURIC ACID
(3) 62
2.4.2 L,3,5-TRIS(HYDROXYETHYL)CYANURIC ACID(2) 65
2.4.3 L,3,5-TRIS(NITRATOETHYL)-CYANURIC ACID (4) 66
2.5
CALCULATION OF THERMODYNAMIC DATA AND SURFACE POTENTIAL 68
2.5.1 ELECTROSTATIC SURFACE POTENTIAL OF
N,N ,N -TRIS-(NITROXYMETHYL)-ISOCYANURIC ACID(3) 68
2.5.2 ELECTROSTATIC SURFACE
POTENTIAL OF N,N ,N -TRIS-(NITROXYETHYL)- ISOCYANURIC ACID (4) 69
2.5.3 CALCULATION OF THE ENTHALPY OF FORMATION 69
2.1 ENERGETIC PROPERTIES 71
2.1.1 DETONATION PARAMETERS 71
3 CONCLUSIONS 72
4 EXPERIMENTAL 73
4.1 CRYSTAL STRUCTURES 73
4.2 PROPERTIES 73
4.3 SPECTROSCOPIC DATA AND ELEMENTAL ANALYSIS 73
4.4 PREPARATION 73
5 REFERENCES 75
CHAPTER III N
2/
N
4
,N
6
-TRIS(TRIS(NITRATOMETHYL)METHYL)-1,3,5-TRIAZINO-2,4,6-TRICARBOXAMIOE
(NOX-
1) - BIG AND BANG 79
1 INTRODUCTION 80
2 DISCUSSION 81
2.1 STRUCTURE OF TRIAZINE DERIVATIVES 81
2.1.1 DESCRIPTION OF THE MOLECULE STRUCTURE AND THE MONOCLINIC CRYSTAL
STRUCTURE IN COMPARISON TO
THE REPORTED HEXAGONAL STRUCTURE 83
2.2
SYNTHESIS 88
2.3 THERMODYNAMICAL AND SPECTROSCOPIC CHARACTERIZATION 89
2.4 CRYSTAL STRUCTURE DATA 91
2.5 ENERGETIC DATA 93
3 CONCLUSIONS 93
4 EXPERIMENTAL PART 94
4.1 INSTRUMENTAL SETUPS T 94
PD-XRAY 94
IR SAMPLES 94
NMR-SAMPLES 94
RAMAN SAMPLES 94
DSC MEASUREMENTS 94
SC-XRAY DATA 94
NCS-ELEMENTAL ANALYSIS 94
MASS SPECTROMETRY 94
FRICTION AND
IMPACT SENSITIVITY 94
4.2
PREPARTATION 94
4.2.1 [L,3,5]TRIAZINE-2,4,6-TRICARBOXYLIC ACID TRIETHYL ESTER (2) 94
4.2.2 N
2
,N
4
,N
6
-TRIS(TRIS(HYDROXYMETHYL)METHYL)-L,3,5-TRIAZINO-2,4,6-TRICARBOXAMIDE
(TTHMM-TCA,
3)
95
4.2.3 N
2
,N
4
,N
6
-TRIS(TRIS(NITRATOMETHYL)METHYL)-L,3,5-TRIAZINO-2,4,6-TRICARBOXAMIDE
(TTNMM-TCA,
NOX, 4) 95
5 REFERENCES 96
PART 111 ENERGETIC MATERIALS BASED ON 1,2,4-OXADIAZOLE DERIVATIVES 99
INTRODUCTION
CHAPTER IV 3,3 -BIS-{1,2,4-OXADIAZOL-5-ONE) AND
DERIVATIVES
- A COMPREHENSIVE
STUDY^ 101
1 COMPARISON OF 3,3 -BIS-1,2,4-OXADIAZOL-5-ONE AND 5,5 -BIS-1H-TETRAZOLE
102
1.1 INTRODUCTION 102
1.2 DISCUSSION 102
1.3 SYNTHESIS 106
1.4 CONCLUSIONS 107
1.5 EXPERIMENTAL 107
1.5.1 CRYSTAL STRUCTURES 107
1.5.2 PROPERTIES 107
1.5.3 SPECTROSCOPIC DATA AND ELEMENTAL
ANALYSIS 107
1.5.4 PREPARATION 107
1.6 REFERENCES 108
2 INSENSITIVE EXPLOSIVES AND PROPELLANTS BASED
1,2,4-OXADIAZOL DERIVATIVES 110
2.1 INTRODUCTION 110
2.2 SYNTHESES 111
2.3 CRYSTAL STRUCTURES 112
2.3.1 DIAMMONIUM BIS-(L,2,4-OXADIAZOL-5-ONATE ) 112
2.3.2 DIHYDRAZINIUM BIS-(L,2,4-OXADIAZOL-5-ONATE) 114
2.3.3 DIGUANIDINIUM BIS-(L,2,4-OXADIAZOL-5-ONATE) (G
2
OD, 6) 116
2.3.4 BIS-AMINOGUANIDINIUM 3,3 -BIS-(L,2,4-OXADIAZOL-5-ONATE) (AG
2
OD,
7) 119
2.3.5 DI-TRIAMINOGUANIDINIUM 3,3 -BIS-(L,2,4-OXADIAZOL-5-ONATE) (TA6
2
OD, 9) 121
2.4 ENERGETIC PROPERTIES 123
2.5 CONCLUSIONS
124
2.6 EXPERIMENTAL 125
2.6.1 CRYSTAL STRUCTURES 125
2.6.2 PROPERTIES 125
2.6.3 SPECTROSCOPIC DATA AND
ELEMENTAL ANALYSIS 125
2.6.4 PREPARATION 125
2.7 REFERENCES 128
3 SMOKELESS PYROTECHNICAL COLORANTS BASED ON
3,3 -BIS-(1,2,4-OXADIAZOL-5-ONE SALTS 130
3.1 INTRODUCTION 130
3.2 DISCUSSION 131
3.2.1 SYNTHESES 131
3.2.2 CRYSTAL STRUCTURES 132
TETRAAQUA-3.3 -BIS( 1
^^-OXADIAZOLO-ONVATO COPPER(II) 135
3.2.3 THERMOSTABILITY 142
3.3
CONCLUSION 144
3.4 EXPERIMENTAL 144
3.4.1 CRYSTAL STRUCTURES 144
3.4.2 PROPERTIES 144
3.4.3 SPECTROSCOPIC DATA AND ELEMENTAL
ANALYSIS 144
3.4.4 PREPARATION 145
3.5 REFERENCES 146
CHAPTER V 3,5-DIAMINO-1,2,4-OXADIAZOLE
- A SUBSTITUTE
FOR GUANYLUREA IN
ENERGETIC MATERIALS
149
1 INTRODUCTION 150
2 RESULTS AND DISCUSSION 151
2.1 SYNTHESIS AND CHARACTERIZATION OF 3,5-DIAMINO-L,2,4-OXADIAZOLE
(DAOD, 1) 151
2.1.1 3,5-DIAMINO- 1,2,4-OXADIAZOLE
(L, DAOD) 151
2.2 SYNTHESES OF3,5-DIAMINO-L,2,4(4H)-OXADIAZOLIUM SALTS
159
2.2.1 THE 3,5-DIAMINO-L,2,4(4H)-OXADIAZOLIUM CATION 159
2.2.2 3,5-DIAMINO-L,2,4-OXADIAZOLIUM NITRATE (2) 162
2.2.3 3,5-DIAMINO-L,2,4-OXADIAZOLIUM PERCHLORATE (3) 163
INTRODUCTION
2.2.4 3,5-DIAMINO-L,2,4-OXADIAZOLIUM PICRATE (4) 169
2.2.5 3,5-DIAMINO-L,2,4-OXADIAZOLIUM DINITRAMIDE (5) 172
2.2.6 2.3.6 3,5-DIAMINO-L,2,4-OXADIAZOLIUM-5-AMINOTETRAZOLATE (6) 174
2.2.7 3,5-DIAMINO-L,2,4-OXADIAZOLIUM-5-NITROTETRAZOLAT (IX) 175
2.2.8 3,5-DIAMINO-L,2,4-OXADIAZOLIUM-5,5 -AZOTETRAZOLATE (X) 176
2.2.9 3,5-DIAMINO-4-METHYL-L,2,4-OXADIAZOLIUM IODIDE (XI) 177
2.3 SYNTHESIS OF COMPLEX BOND 3,5-DIAMINO-L,2,4-OXADIAZOLE (7) 177
2.4 DIAZOTATION REACTION OF 1 BY SODIUM NITRITE (I) 178
2.5 OXIDATION AND NITRATION OF 3,5-DIAMINO-L,2,4-OXADIAZOLE (1) 179
2.5.1 OXIDATION OR NITRATION WITH HNOJ (100
%) 181
2.5.2 OXIDATION OR NITRATION WITH HN0
3
(100 %) AND
H
2
S0
4
(CONC.) 181
2.5.3 OXIDATION OR NITRATION BY SODIUM NITRITE (II-IV) 181
2.5.4 OXIDATION WITH H
2
SO
A
(CONC.), H
2
0
2
(30 %) AND
(NH
4
)JS
2
08 (V) 182
2.5.5 OXIDATION BY POTASSIUM
PERMANGANATE (VI) 182
2.5.6 OXIDATION BY AMMONIUM DICHROMATE (VII) 183
2.5.7 OXIDATION BY BROMINE (VIII) 183
2.5.8 NITRATION WITH HN0
3
(100%) AND AC
2
0 184
2.6 ENERGETIC DATA 184
3 SUMMARY AND CONCLUSIONS 185
3.1 SUMMARY 185
3.1.1 ENERGETIC SALTS OF DAOD 186
3.1.2 OXIDATION, NITRATION AND DIAZOTATION
OF DAOD. 186
3.2 CONCLUSION AND OUTLOOK 187
4 EXPERIMENTAL PART 187
4.1 COMMON 187
4.2 ANALYTICAL APPARATUS 187
4.3 CALCULATIONS 189
4.4 PREPARATION OF ENERGETIC DAOD (1) AND SALTS THEREOF 191
4.5 OXIDATION AND NITRATION PRODUCTS OF DAOD(L) 194
5 REFERENCES 197
CHAPTER VI 3-AMINO-1,2,4-OXADIAZOL-5-ONE
- THE INSENSITIVE 5-AMINO-TETRAZOLE ? COMMONS AND
DIFFERENCES
201
1 INTRODUCTION . 202
2 RESULTS AND DISCUSSION 204
2.1 SYNTHESIS OF AOD 204
2.1.1 OVERVIEW 205
2.1.2 SYNTHETIC ROUTE A 206
2.1.3 SYNTHESIS ROUTE
B 209
2.1.4 ONE-POT-SYNTHESIS ACCORDING
TO ROUTE B 219
2.1.5 SUMMARY .220
2.2 SOLUBILITY OFAOD 220
2.3 AZO-COUPLING OFAOD .221
2.4 SALTS OFAOD 222
2.4.1 COPPER AOD (9) 222
2.4.2 SILVER AOD (10) 223
2.4.3 STRONTIUM AOD
(11) TRIHEMIHYDRATE 223
2.4.4 BARIUM AOD (12) 224
2.4.5 AMINOGUANIDINIUM AOD (13) 224
2.4.6 SODIUM AOD (14)
MONOHYDRATE 225
2.4.7 SUMMARY 229
2.5 METHYLATION OF3-AMINO-L,2,4(4H)-OXADIAZOL-5-ONE 230
2.6 SYNTHESIS OF SALTS WITH
AODH* AS CATION 231
2.6.1 SUMMARY 241
INTRODUCTION
2.7
ENERGETIC DATA 242 *
3 CONCLUSIONS,. 245
4 OUTLOOK 245
5 EXPERIMENTAL PART 246
5.
1 CHEMICALS AND METHODS 246
5.2 PREPARATION _ 246
5.2.1 DIPOTASSIUM CYANODITHIOIMIDOCARBONATE (4) 246
5.2.2 DIMETHYLCYANODITHIOIMIDOCARBONAT (5) 247
5.2.3 POTASSIUM S-METHYL-N-CYANOCARBAMATE
(3) 247
5.2.4 3-AMINO-L,2,4(4H)-OXADIAZOL-5-ONE (A) {1) 248
5.2.5 (Z)-AMINO[{ETHOXYCARBONYL)AMINO]-N-HYDROXYMETHANIMINIUM CHLORIDE
/N-(ETHOXYCARBONYL)-
/V -HYDROXY-GUANIDINIUM CHLORIDE (8) 248
5.2.6 3-AMINO-L,2,4(4H)-OXADIAZOL-5-ONE (B) (X) 249
5.2.1 ONE-POT-SYNTHESIS OF AMINO-L,2,4(4H)-OXADIAZOL-5-ONE (B) (1) 250
5.2.1 COPPER AOD 2 H
2
0
(9) 251
5.2.2 SILVER AOD (10) __ 251
5.2.3 STRONTIUM AOD X 1.5
H
2
0
(11) _ 251
5.2.4 BARIUM AOD (12) 252
5.2.5 AMINOGUANIDINIUM AOD
(13) 252
5.2.6 SODIUM AOD (14) 253
5.3 SOLUBILITY IN DIFFERENT SOLVENTS
253
5.4 FURTHER INVESTIGATED REACTIONS 253
5.4.1 (Z)-AMINO[(METHOXYCARBONYL)AMINO] A/-HYDROXYMETHANIMINIUM CHLORIDE
(B I) 253
5.4.2 ALTERNATIVE RING CLOSURE REACTION
FOR AOD (1) WITH
DIPHOSGEN (B III, 6) 254
5.5
SYNTHESIS OF AOD SALTS WITH AODH
+
AS CATION: 254
5.5.1 SYNTHESIS OF AODH
F
NITRATE 254
5.5.2 SYNTHESIS OF AODH* PERCHLORATE 255
5.5.3 SYNTHESIS OF AODH* PICRATE 256
5.6 AZO-COUPLING OF AOD (15)
256
5.
7 METHYLATION OFAOD (16A, 16B)
257
6 REFERENCES 258
CHAPTER VII 3-DINITROMETHYLENYL-1,2,4(4H)-OXADIAZOL-5-ONE AND
DERIVATIVES
- HIGH EXPLOSIVE,
STABLE, INSENSITIVE 261
1 INTRODUCTION 262
2 SYNTHESIS 263
2.1 BY-PRODUCT (6) 264
2.2 SALTS OF DNM-OD (7,9)
265
3 DISCUSSION 266
3.1 SPECTROSCOPIC PROPERTIES
266
3.2 CRYSTAL STRUCTURES
267
3.2.1 2- ETHYL-3-AMINO-3-(HYDROXYIMIN)-PROPANOATE (2) 267
3.2.1 ETHYL (3Z)-3-AMINO-{[(METHOXYCARBONYL)OXY]IMINO}-PROPANOAT (3A)
267
3.2.1 DINITRO-([L,2,4]OXADIAZOL-5-ON-3-YL)-ACETIC ACID ETHYL ESTER (5)
268
3.2.1 SODIUM
(4-{2-[(ETHOXYCARBONYL)OXY]PROPAN-2-YL}-5-OXO-4,5-DIHYDRO-L,2,4-OXADIAZOL-3-
YL)(DINITRO)METHANIDE MONOHYDRATE (REARRANGEMENT PRODUCT) (6) 269
3.2.2 DI-SODIUM DNM-OD DIHYDRATE (7B) 271
3.2.3 DI-AMMONIUM DNM-OD (9B) 272
3.2.4 BIS-GUANIDINIUM DNM-OD (9A) 274
3.3 CALCULATIONS - THERMODYNAMICAL PROPERTIES
275
3.4 STRUCTURE OPTIMIZATION OF DNM-OD AND DNM-OD
2
~
275
3.5
ENERGETIC PROPERTIES
276
3.5.1 PYROTECHNICAL COLORANTS 276
3.5.2 HIEH-NITROEEN CONTAINING CATIONS 276
INTRODUCTION
4 CONCLUSIONS 277
5 OUTLOOK 278
6 EXPERIMENTAL 278
6.1 COMMON 278
6.2 ANALYTICAL APPARATUS 278
6.3 PREPARATION 280
6.3.1 2-ETHYL-3-AMINO-3-(HYDROXYIMIN)-PROPANOATE (1) 280
6.3.1 ETHYL-2-(L,2,4-OXADIAZOL-5-ON-3-YL) ACETATE - TWO STEP REACTION
(10) 280
6.3.2 ETHYL-(3Z)-3-AMINO-{[{METHOXYCARBONYL)OXY]IMINO}-PROPANOAT (9) 280
6.3.3 3-ETHYL (5-OXO-4,5-DIHYDRO-L,2,4-OXADIAZOL-3-YL)-ACETATE (2) 281
6.3.4 DINITRO-([L,2,4]OXADIAZOL-5-ON-3-YL)-ACETIC ACID ETHYL ESTER (3)
282
6.3.5 SODIUM
(4-{2-[(ETHOXYCARBONYL)OXY]PROPAN-2-YL}-5-OXO-4,5-DIHYDRO-L,2,4-OXADIAZOL-3-
YL)(DINITRO)METHANIDE MONOHYDRATE (REARRANGEMENT PRODUCT) (5) 282
6.4 ALKALINE AND ALKALINE EARTH METAL SALTS OF DNM-OD (7) 282
6.4.1 GENERAL PROCEDURE 282
6.4.2 LITHIUM DNM-OD 283
6.4.3 SODIUM DNM-OD X 2 H
2
0 283
6.4.4 POTASSIUM DNM-OD 283
6.4.5 BARIUM DNM-OD X 3.5
H
2
0 283
6.5 NITROGEN RICH SALTS OF DNM-OD 283
6.5.1 BIS-GUANIDINIUM DNM-OD X H
2
0
(9A) 284
6.5.1 DI-AMMONIUM DNM-OD
X H
2
0 (9B) 284
7 REFERENCES 284
PART IV CONCLUSIONS AND OUTLOOK 287
1 PART II
- UREA BASED DERIVATIVES 288
1.1 CONCLUSIONS 288
1.2 OUTLOOK 288
2 PART III
-1,2,4- OXADIAZOLE AND 1,2,4-OXDIAZOL-5-ONE
BASED COMPOUNDS 288
2.1 CONCLUSIONS 288
2.2 OUTLOOK 289
PARTV APPENDIX 291
CHAPTER VIII TABLES OF CRYSTAL STRUCTURES 293
1 COMPOUNDS- CHAPTER I 294
2 COMPOUNDS
- CHAPTER II 295
3 COMPOUNDS
- CHAPTER III 296
4 COMPOUNDS -
CHAPTER IV 297
4.1 METAL SALTS 297
4.2 NITROGEN RICH SALTS 298
5 COMPOUNDS
- CHAPTER V 299
6 COMPOUNDS
- CHAPTER VI 300
7 COMPOUNDS-CHAPTER VII 301
CHAPTER IX INDEX OF ABBREVIATIONS 303
CHAPTER X ABSTRACT AND SUMMARY 307
CHAPTER XI CURRICULUM VITAE 309
PART VI INDEX 313
CHAPTER XII FIGURES 315
CHAPTER XIII TABLES 323
|
| any_adam_object | 1 |
| author | Mayr, Norbert Thorsten 1978- |
| author_GND | (DE-588)1044668083 |
| author_facet | Mayr, Norbert Thorsten 1978- |
| author_role | aut |
| author_sort | Mayr, Norbert Thorsten 1978- |
| author_variant | n t m nt ntm |
| building | Verbundindex |
| bvnumber | BV041601242 |
| collection | ebook |
| ctrlnum | (OCoLC)869893781 (DE-599)DNB1044668237 |
| dewey-full | 547.595 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 547 - Organic chemistry |
| dewey-raw | 547.595 |
| dewey-search | 547.595 |
| dewey-sort | 3547.595 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie |
| format | Thesis Book |
| fullrecord | <?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01810nam a2200397 c 4500</leader><controlfield tag="001">BV041601242</controlfield><controlfield tag="003">DE-604</controlfield><controlfield tag="005">20140214 </controlfield><controlfield tag="007">t|</controlfield><controlfield tag="008">140130s2013 gw ad|| m||| 00||| eng d</controlfield><datafield tag="015" ind1=" " ind2=" "><subfield code="a">13,H12</subfield><subfield code="2">dnb</subfield></datafield><datafield tag="016" ind1="7" ind2=" "><subfield code="a">1044668237</subfield><subfield code="2">DE-101</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(OCoLC)869893781</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-599)DNB1044668237</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-604</subfield><subfield code="b">ger</subfield><subfield code="e">rakddb</subfield></datafield><datafield tag="041" ind1="0" ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="044" ind1=" " ind2=" "><subfield code="a">gw</subfield><subfield code="c">XA-DE</subfield></datafield><datafield tag="049" ind1=" " ind2=" "><subfield code="a">DE-12</subfield><subfield code="a">DE-19</subfield><subfield code="a">DE-384</subfield><subfield code="a">DE-473</subfield><subfield code="a">DE-703</subfield><subfield code="a">DE-1051</subfield><subfield code="a">DE-824</subfield><subfield code="a">DE-29</subfield><subfield code="a">DE-91</subfield><subfield code="a">DE-1049</subfield><subfield code="a">DE-92</subfield><subfield code="a">DE-739</subfield><subfield code="a">DE-898</subfield><subfield code="a">DE-355</subfield><subfield code="a">DE-706</subfield><subfield code="a">DE-20</subfield><subfield code="a">DE-1102</subfield></datafield><datafield tag="082" ind1="0" ind2=" "><subfield code="a">547.595</subfield><subfield code="2">22/ger</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">540</subfield><subfield code="2">sdnb</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Mayr, Norbert Thorsten</subfield><subfield code="d">1978-</subfield><subfield code="e">Verfasser</subfield><subfield code="0">(DE-588)1044668083</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Energetic materials based on isocyanuric acid and 1,2,4-oxadiazole derivatives</subfield><subfield code="b">synthesis and characterization</subfield><subfield code="c">Norbert Thorsten Mayr</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2013</subfield></datafield><datafield tag="300" ind1=" " ind2=" "><subfield code="a">XIV, 327 S.</subfield><subfield code="b">Ill., graph. Darst.</subfield><subfield code="c">30 cm</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="502" ind1=" " ind2=" "><subfield code="a">München, Univ., Diss., 2013</subfield></datafield><datafield tag="655" ind1=" " ind2="7"><subfield code="0">(DE-588)4113937-9</subfield><subfield code="a">Hochschulschrift</subfield><subfield code="2">gnd-content</subfield></datafield><datafield tag="776" ind1="0" ind2="8"><subfield code="i">Erscheint auch als</subfield><subfield code="n">Online-Ausgabe</subfield><subfield code="o">urn:nbn:de:bvb:19-162379</subfield></datafield><datafield tag="776" ind1="0" ind2="8"><subfield code="i">Erscheint auch als</subfield><subfield code="n">Online-Ausgabe</subfield><subfield code="a">Mayr, Norbert</subfield><subfield code="t">Energetic materials based on isocyanuric acid and 1,2,4-oxadiazole derivatives</subfield></datafield><datafield tag="856" ind1="4" ind2="1"><subfield code="u">http://edoc.ub.uni-muenchen.de/16237/</subfield><subfield code="x">Verlag</subfield><subfield code="z">kostenfrei</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="856" ind1="4" ind2=" "><subfield code="u">https://nbn-resolving.org/urn:nbn:de:bvb:19-162379</subfield><subfield code="x">Resolving-System</subfield></datafield><datafield tag="856" ind1="4" ind2="2"><subfield code="m">DNB Datenaustausch</subfield><subfield code="q">application/pdf</subfield><subfield code="u">http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027042843&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA</subfield><subfield code="3">Inhaltsverzeichnis</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">ebook</subfield></datafield><datafield tag="943" ind1="1" ind2=" "><subfield code="a">oai:aleph.bib-bvb.de:BVB01-027042843</subfield></datafield></record></collection> |
| genre | (DE-588)4113937-9 Hochschulschrift gnd-content |
| genre_facet | Hochschulschrift |
| id | DE-604.BV041601242 |
| illustrated | Illustrated |
| indexdate | 2024-12-24T04:00:11Z |
| institution | BVB |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-027042843 |
| oclc_num | 869893781 |
| open_access_boolean | 1 |
| owner | DE-12 DE-19 DE-BY-UBM DE-384 DE-473 DE-BY-UBG DE-703 DE-1051 DE-824 DE-29 DE-91 DE-BY-TUM DE-1049 DE-92 DE-739 DE-898 DE-BY-UBR DE-355 DE-BY-UBR DE-706 DE-20 DE-1102 |
| owner_facet | DE-12 DE-19 DE-BY-UBM DE-384 DE-473 DE-BY-UBG DE-703 DE-1051 DE-824 DE-29 DE-91 DE-BY-TUM DE-1049 DE-92 DE-739 DE-898 DE-BY-UBR DE-355 DE-BY-UBR DE-706 DE-20 DE-1102 |
| physical | XIV, 327 S. Ill., graph. Darst. 30 cm |
| psigel | ebook |
| publishDate | 2013 |
| publishDateSearch | 2013 |
| publishDateSort | 2013 |
| record_format | marc |
| spellingShingle | Mayr, Norbert Thorsten 1978- Energetic materials based on isocyanuric acid and 1,2,4-oxadiazole derivatives synthesis and characterization |
| subject_GND | (DE-588)4113937-9 |
| title | Energetic materials based on isocyanuric acid and 1,2,4-oxadiazole derivatives synthesis and characterization |
| title_auth | Energetic materials based on isocyanuric acid and 1,2,4-oxadiazole derivatives synthesis and characterization |
| title_exact_search | Energetic materials based on isocyanuric acid and 1,2,4-oxadiazole derivatives synthesis and characterization |
| title_full | Energetic materials based on isocyanuric acid and 1,2,4-oxadiazole derivatives synthesis and characterization Norbert Thorsten Mayr |
| title_fullStr | Energetic materials based on isocyanuric acid and 1,2,4-oxadiazole derivatives synthesis and characterization Norbert Thorsten Mayr |
| title_full_unstemmed | Energetic materials based on isocyanuric acid and 1,2,4-oxadiazole derivatives synthesis and characterization Norbert Thorsten Mayr |
| title_short | Energetic materials based on isocyanuric acid and 1,2,4-oxadiazole derivatives |
| title_sort | energetic materials based on isocyanuric acid and 1 2 4 oxadiazole derivatives synthesis and characterization |
| title_sub | synthesis and characterization |
| topic_facet | Hochschulschrift |
| url | http://edoc.ub.uni-muenchen.de/16237/ https://nbn-resolving.org/urn:nbn:de:bvb:19-162379 http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027042843&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT mayrnorbertthorsten energeticmaterialsbasedonisocyanuricacidand124oxadiazolederivativessynthesisandcharacterization |