Solid state chemistry and its applications
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| 100 | 1 | |a West, Anthony R. |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Solid state chemistry and its applications |c Anthony R. West |
| 250 | |a 2. ed., student ed. | ||
| 264 | 1 | |a Chichester |b Wiley |c 2014 | |
| 300 | |a XXIV, 556 S. |b Ill., zahlr. graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
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| 338 | |b nc |2 rdacarrier | ||
| 650 | 4 | |a Solid state chemistry | |
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| _version_ | 1823055794024742912 |
| adam_text | Contents
Preface
xvii
Chemistry
-
Solid State Chemistry
-
Materials Chemistry
-
Materials Science and Engineering
xix
Companion Website
xxiii
CrystalViewer
xxiii
Crystal Structure Library
xxiv
Biography
xxv
1
Crystal Structures and Crystal Chemistry
1
1.1
Unit Ceils and Crystal Systems
І
1.2
Symmetry
3
1.2.1
Rotational Symmetry: Symmetry Elements and Operations
3
1.2.2
Quasicrystals
6
1.2.3
Mirror Symmetry
6
1.2.4
Centre of Symmetry and inversion Axes
6
1.2.5
Point Symmetry and Space-Symmetry
9
1
.3
Symmetry and Choice of Unit
Celi
1
1)
1.4
Lattice,
Bravais
Lattice
11
1.5
Lattice Planes and Miller Indices
14
1.6
indices of Directions
16
1.7
¿/-Spacing Formulae
17
1.8
Crystal Densities and Unit Cell Contents
і
7
1.9
Description of Crystal Structures
18
LIO
Close Packed Structures
-
Cubi
с
and Hexagonal Close Packing
19
1.11
Relationship between Cubic Close Packed and Face Centred Cubic
21
1.12
Hexagonal Unit Cell and Close Packing
21
1.13
Density of Close Packed Structures
22
í
. 14
Unit Cell Projections and Atomic Coordinates
24
1.15
Materials That Can Be Described as Close Packed
25
1.15.
і
Metals
25
1.15.2
Alloys
25
1.15.3
Ionic Structures
26
Contents
viii
1.15.3.1 Tetrahedral
and Octahedral Sites
26
1.15.3.2
Relative Sizes of Tetrahedral and Octahedral Sites
28
1.15.3.3
Location of Tetrahedral and Octahedral Sites in an fee Unit Cell:
Bond Length Calculations
29
1.15.3.4
Description of Crystal Structures; Fractional Atomic Coordinates
30
1.15.4
Covalent Network Structures
31
1.15.5
Molecular Structures
31
1.15.6
Fullerenes
and
Ful
lerides
31
1.16
Structures Built of Space-Filling Polyhedra
33
1.17
Some Important Structure Types
35
1.17.1
Rock Salt (NaCl), Zinc Blende or Sphalerite (ZnS),
Fluorite
(CaF2).
Antifluorite
(Na2O)
35
1.17.1.1
Rock Salt Structure
37
1.17.1.2
Zinc Blende
(
Sphalerite
)
Structure
38
1.17.1.3
Antifluorite/Fluorite
Structure
39
1.17.1.4
Bond Length
Cal
culations
41
1.17.2
Diamond
42
1.
1
7.3
Wurt/ite (ZnS) and Nickel Arsenide
(Ni
As)
43
1.17.4
Caesium Chloride (CsCl)
47
1.17.5
Other AX Structures
48
1.17.6
Rutile
(TiO2)s Cadmium Iodide (Cdl2
),
Cadmium Chloride (CdCb) and
Caesium Oxide (Cs2O)
49
1.17.7
Perovskite (SrTiO3)
54
1.17.7.1
Tolerance Factor
57
1.17.7.2
BaTiO,
57
1.17.7.3
Tilted Perovskites: Glazer Notation
58
1.17.7.4
СаСизТЈЦОи, ССТО
62
1.17.7.5
Anion-
Deficient Perovskites
62
1.17.7.6
Stoichiometry-Property Relations
62
1.17.8
Rhenium Trioxide (ReOj
),
Perovskite Tungsten Bronzes, Tetragonal Tungsten
Bronzes and Tunnel Structures
63
1.17.9
Spinel
66
1.17.10
Olivine
70
1.17.11
Corundum, llmenite and LiNbOj
72
1.17.12
Fluorite-Related Structures and
Pyrochlore
72
1.17.13
Garnet
75
1.17.14
Perovskite-Roek Salt Intergrowth Structures:
K2NÌF4,
Ruddlesden-Popper
Phases and Layered Cuprate Superconductors
76
1.17.15
The Aluminium Diboride Structure (A1B2) 80
1.17.16
Silicate Structures
-
Some Tips to Understanding Them
81
2
Crystal Defects. Non-Stoichiometry and Solid Solutions
83
2.1
Perfect and Imperfect Crystals
83
2.2
Types of Defect: Point Defects
84
2.2.1
Schottky Defect
85
2.2.2
Frenkel Defect
85
2.2.2.1
The
Kroger-Vink
Notation for Crystal Detects
86
2.2.2.2
Themiodvnamics of Schottkv and Frenkel Detect Formation
87
їх
Contents
.2.3
2
.2.4
2
.2.5
9
.2.6
2.3
S
olid
2
.3.1
2
.3.2
9
.33
2
.3.4
2
.3.5
Colour
Centres
90
Vacancies and Interstitials in Non-Stoichiometrie Crystals: Extrinsic and
Intrinsic Defects
91
Defect Clusters or Aggregates
92
Interchanged Atoms: Order-Disorder Phenomena
95
lutions
95
Substitutional Solid Solutions
96
Interstitial Solid Solutions
98
More Complex Solid Solution Mechanisms: Aliovalent Substitution
99
2.3.3.1
Ionic Compensation Mechanisms
99
2.3.3.2
Electronic Compensation: Metals, Semi- and Superconductors
102
Thermodynamieally Stable and Metastable Solid Solutions
104
Experimental Methods for Studying Solid Solutions
104
2.3.5.1
X-ray Powder Diffraction, XRD
104
2.3.5.2
Density Measurements
105
2.3.5.3
Changes in Other Properties
-
Thermal Activity and DTA/DSC 1
07
2.4
Extended Defects
108
2.4.1
Crystallographic Shear Structures
108
2.4.2
Stacking Faults
110
2.4.3
Subgrain Boundaries and Antiphase Domains (Boundaries) 1
10
2.5
Dislocations and Mechanical Properties of Solids
111
2.5.1
Edge Dislocations
112
2.5.2
Screw Dislocations
114
2.5.3
Dislocation Loops
115
2.5.4
Dislocations and Crystal Structure
117
2.5.5
Mechanical Properties of Metals
1
1
8
2.5.6
Dislocations, Vacancies and Stacking Faults
120
2.5.7
Dislocations and Grain Boundaries
122
3
Bonding in Solids
125
3.1
Overview: Ionic. Covalent, Metallic, van
der Waals
and Hydrogen Bonding
in Solids
125
3.2
Ionic Bonding
126
3.2.
J
Ions and Ionic Radii
126
3.2.2
Ionic
Structures
-
General Principles
130
3.2.3
The Radius Ratio Rules
133
3.2.4
Borderline Radius Ratios and Distorted Structures
135
3.2.5
Lattice Energy of ionic Crystals
136
3.2.6
Kapusiinskii s Equation
140
3.2.7
The Bom-Habcr Cycle and
Thermochemicał
Calculations
141
3.2.8
Stabilities of Real and Hypothetical tonic Compounds
143
3.2.8.1
inert Gas Compounds
143
3.2.8.2
Lower and Higher Valence Compounds 1
44
3.2.9
Effect of
Partía!
Covalent Bonding on Crystal Structures
! 45
3.2
JO Effective Nuclear Charge
147
3.2.1
і
Eleetronegativity and Partially Charged Atoms
147
3.2.1.2
Coordinated Polymeric
Structures
-
Sanderson s Model
149
3.2.13
Mooser-Pearson Plots and Ionicities
150
Contents
χ
3.2.14
Bond Valence and Bond Length
151
3.2.15
Non-Bonding Electron Effects
153
3.2.15.1
d-Electron Effects
153
3.2.15.2
Inert Pair Effect
161
3.3
Covalenti
Bonding
161
3.3.1
Particle-Wave Duality, Atomic
Orbitals,
Wavefunctions and Nodes
162
3.3.2
Orbital Overlap, Symmetry and Molecular
Orbitals 163
3.3.3
Valence Bond Theory, Electron Pair Repulsion, Hybridisation and
Oxidation States
169
3.4
Metallic Bonding and Band Theory
173
3.4.1
Band Structure of Metals
179
3.4.2
Band Structure of Insulators
179
3.4.3
Band Structure of Semiconductors: Silicon
179
3.4.4
Band Structure of Inorganic Solids
181
3.4.4.1
III-V,
П
-VI
and I-VII Compounds 1
81
3.4.4.2
Transition Metal Compounds
182
3.4.4.3
Fullerenes
and Graphite
184
3.5
Bands or Bonds: a Final Comment
185
Synthesis, Processing and Fabrication Methods
4.1
General Observations
187
4.2
Solid State Reaction or Shake w Bake Methods
187
4.2.1
Nucleation and Growth, Epitaxy and Topotaxy
188
4.2.2
Practical Considerations and Some Examples of Solid State Reactions
191
4.2.2.1
LÌ4SÌO4
193
4.2.2.2
YBa2Cu30M
193
4.2.2.3
Na
β/β
alumina
193
4.2.3
Combustion Synthesis
194
4.2.4
Mechanosynthesis
195
4.3
Low Temperature or
Chimie
Douce Methods
196
4.3.1
Alkoxide Sol-Gel Method
196
4.3.1.1
Synthesis of MgA!2O4
197
4.3.1.2
Synthesis of Silica Glass
197
4.3.1.3
Spinning of Alumina Fibres
197
4.3.
1
.4
Preparation of Indium Tin Oxide
(ITO)
and Other Coatings
198
4.3.
1
.5
Fabrication of YSZ Ceramics
198
4.3.2
Sol-Gel Method Using Oxyhydroxides and Colloid Chemistry
198
4.3.2.1
Synthesis of Zeolites
199
4.3.2.2
Preparation of Alumina-Based Abrasives and Films
200
4.3.3
Citrate Gel and
Pechini
Processes
20Ü
4.3.4
Use of Homogeneous, Single-Source Precursors
201
4.3.5 Hydrothermal
and Solvothermal Synthesis
202
4.3.6
Microwave Synthesis
204
4.3.7
Intercalation and Demterealation
205
4.3.7.1
Graphite Intercalation Compounds
207
4.3.7.2
Pillared Clays and Layered Double Hydroxides
208
4.3.7.3
Synthesis of
Graphenê
209
xi
Contents
4.3.8
Example of a Difficult Synthesis Made Possible by
Chimie Douce
Methods: BiFeO.,
211
4.3.9
Molten Salt Synthesis,
MSS
212
4.4
Gas-Phase Methods
213
4.4.1
Vapour-Phase Transport
213
4.4.2
Chemical Vapour Deposition, CVD
216
4.4.2.1
Amorphous Silicon
217
4.4.2.2
Diamond Films
219
4.4.3
Sputtering and Evaporation
221
4.4.4
Atomic Layer Deposition, ALD
222
4.4.5
Aerosol Synthesis and Spray Pyrolysis
223
4.5
High-Pressure Methods
225
4.6
Crystal Growth
226
4.6.1
Czochrał
ski Method
226
4.6.2
Bridgman and Stockbarger Methods
226
4.6.3
Zone Melting
227
4.6.4
Precipitation from Solution or Melt: Flux Method
227
4.6.5
Verneuil Flame Fusion Method
228
5
Crystallography and Diffraction Techniques
229
5.1
General Comments: Molecular and Non-Molecular Solids
229
5.1.1
identification
of Crystalline Solids
229
5.1.2
Structure of Non-Molecular Crystalline Solids
229
5.1.3
Defects, Impurities and Stoichiometry of Crystalline Solids
230
5.2
Characterisation of Solids
231
5.3
Х
-Ray Diffraction
232
5.3.1
Generation of X-Rays
232
5.3.1.1
Laboratory Sources Utilising Inner Shell Electronic Transitions
232
5.3.
Î
.2
Synchrotron X-ray Sources
235
5.3.2
Interaction of
Х
-Rays with Mailer
235
5.3.3
Optical Grating and Diffraction of Light
236
5.3.4
Crystals and Diffraction of X-Rays
238
5.3.4.1
The
Laue
Equations
238
5.3.4.2
Bragg s Law
239
5.3.5
Х
-Ray Diffraction Methods
240
5.3.6
The Powder Method
-
Principles and Uses
240
5.3.6.1
Focusing of X-rays: Theorem of a Circle
243
5.3.6.2
Crystal Monochromators
244
5.3.6.3
Powder Diffiractometers
244
5.3.6.4
Guinier Focusing Cameras
245
5.3.6.5
A Powder Pattern of a Crystalline Phase is its Fingerprint
246
5.3.6.6
Powder Patterns and Crystal Structures
247
5.3.7
Intensities
248
5.3.7.1
Scattering of X-rays by an Atom: Atomic Scattering Factors or Form
Factors
249
5.3.7.2
Scattering of X-rays by a Crystal
-
Systematic Absences
250
5.3.7.3
General Equation for Phase Difference,
8 253
Contents xii
5.3.7.4
Intensities and Structure Factors
255
5.3.7.5
Temperature Factors
258
5.3.7.6
R-Factors and Structure Determination
259
5.3.7.7
Structure Refinement from Powder Data:
Rietveld
Refinement
259
5.3.8
Х
-Ray Crystallography and Structure Determination
-
What is Involved?
260
5.3.8.1
The Patterson Method
263
5.3.8.2
Fourier Methods
264
5.3.8.3
Direct Methods
264
5.3.8.4
Electron Density Maps
265
5.4
Electron Diffraction
265
5.5
Neutron Diffraction
266
5.5.1
Crystal Structure Determination
267
5.5.2
Magnetic Structure Analysis
268
5.5.3
Inelastic Scattering. Soft Modes and Phase Transitions
269
Other Techniques: Microscopy, Spectroscopy, Thermal Analysis
271
6.1
Diffraction and Microscopic Techniques: What Do They Have in Common?
271
6.2
Optical and Electron Microscopy Techniques
272
6.2.1
Optical Microscopy
272
6.2.1.1
Polarising Microscope
273
6.2.1.2
Reflected Light Microscope
276
6.2.2
Electron Microscopy
276
6.2.2.1
Scanning Electron Microscopy
280
6.2.2.2
Electron Probe Microanalysis,
ЕРМА,
and Energy-Dispersive X-ray
Spectroscopy, EDS or EDX
281
6.2.2.3
Auger Electron (Emission) Microscopy and Spectroscope AES
282
6.2.2.4
Cathodoluminescence, CL
284
6.2.2.5
Transmission Electron Microscopy,
ТЕМ,
and Scanning
Transmission Electron Microscopy, STEM
287
6.2.2.6
Electron Energy Loss Spectroscopy, EELS
288
6.2.2.7
High-Angle Annular Dark Field. HAADF/Z-Contrast STEM
289
6.3
Spectroscopie
Techniques
291
6.3.1
Vibrational Spectroscopy:
IR
and Raman
293
6.3.2
Visible and Ultraviolet
(
U
V) Spectroscopy
296
6.33
Nuclear Magnetic Resonance (NMR) Spectroscopy
298
6.3.4
Electron Spin Resonance (ESR) Spectroscopy
301
6.3.5
Х
-Ray
Spectroscopie«:
XRF, AEFS, EXAFS
303
6.3.5.1
Emission Techniques
303
6.3.5.2
Absorption Techniques
305
6.3.6
Electron
Spectroscopie«:
ESCA,
XPS, UPS, AES, EELS
308
6.3.7
Mössbauer
Spectroscopy
312
6.4
Thermal Analysis
(ТА)
314
6.4.1
Thermogravimetry
(TG)
315
6.4.2
Differential Thermal Analysis (DTA) and
Differential
Scanning
Catarimetry (DSC)
315
6.4.3
Applications
317
6.5
Strategy to Identify, Analyse and Characterise Unknown Solids
321
xiii
Contants
7
Phase
Diagrams and their Interpretation
325
7.1
The Phase Rule, the Condensed Phase Rule and Some Definitions
325
7.2
One-Component Systems
330
7.2.1
The System H2O
331
7.2.2
The System SiO2
332
7.2.3
Condensed One-Component Systems
333
7.3
Two-Component Condensed Systems
333
7.3.1
A Simple Eutectic System
333
7.3.1.1
Liquidus and
Solidas
335
7.3.1.2
Eutcetie
335
7.3.1.3
Lever Rule
335
7.3.1.4
Eutectic Reaction
336
7.3.1.5
The Liquidus, Saturation Solubilities and Freezing Point Depression
337
7.3.2
Binary Systems with Compounds
337
7.3.2.1
Congruent Melting
337
7.3.2.2
Incongruent
Melting, Periteetic Point, Peritectic Reaction
337
7.3.2.3
Non-Ěquilibrium
Effects
339
7.3.2.4
Upper and Lower Limits of Stability
340
7.3.3
Binary Systems with Solid Solutions
340
7.3.3.1
Complete Solid Solution
340
7.3.3.2
Fractional Crystallisation
341
7.3.3.3
Thermal Maxima and Minima
342
7.3.3.4
Partial Solid Solution Systems
342
7.3.4
Binary Systems with Solid-Solid Phase Transitions
344
7.3.5
Binary Systems with Phase Transitions and Solid Solutions: Eutectoids
and Peritectoids
345
7.3.
в
Binary Systems with Liquid Immiscibility: MgO-SiCb
347
7.3.7
Some Technologically Important Phase Diagrams
348
7.3.7.1
The System
Fe
-С:
Iron and Steel Making
348
7.3.7.2
The System CaO-SiCK Cement Manufacture
349
7.3.7.3
The System Na-S: Na/S Batteries
350
7.3.7.4
The System NazO-SiO?: Glass Making
351
7.3.7.5
The System
LiSO-SiC^:
Metastable Phase Separation and Synthetic
Opals
352
7.3.7.6
Purification
of Semiconducting Si by Zone Refining
353
7.3.7.7
The System ZrOz-YzCb: Yttrk-Stabilised
Zirconio , YSZ.
Solid
Electrolyte
354
7.3.7.8
The System
В 1203~¥е20з:
Multifcrraic
ВШеО3
354
7.4
Some Tips and Guidelines for Constructing Binary Phase Diagrams
355
8
Electrical Properties
359
8.1
Survey of Electrical Properties and Electrical Materials
359
8.2
Metallic Conductivity
361
8.2.
Î
Organic Metals: Conjugated Systems
362
8.2.1
Л
Polyacetylene
362
8.2.1.2
РоІу-р-РІіейуіепе
arid
Polypyrroìe
364
8.2.2
Organic Metals:
Charge-Transfer
Complexes
365
Contents
XIV
8.3
Superconductivity
366
8.3.1
The Property of Zero Resistance
366
8.3.2
Perfect Diamagnetism; the Meissner Effect
368
8.3.3
Critical Temperature
Гс,
Critical Field Hc and Critical Current Jc
368
8.3.4
Type I and Type II Superconductors: The Vortex (Mixed) State
370
8.3.5
Survey of Superconducting
Materiais
371
8.3.6
Crystal Chemistry of Cuprate Perovskites
374
8.3.7
YBaÄOy^, YBCO
376
8.3.7.1
Crystal Structure
376
8.3.7.2
Atom Valences and the Superconducting Mechanism
378
8.3.7.3
Oxygen Content of
УВагСизО?-«
378
8.3.7.4
Determination of Oxygen Content,
Ί-8
380
8.3.8
Fuller
і
des
381
8.3.9
Applications of Superconductors
381
8.4
Semiconductivity
382
8.4.1
Elemental and Compound Semiconductors with Diamond and
Zinc Blende Structures
384
8.4.2
Electrical Properties of Semiconductors
386
8.4.3
Oxide Semiconductors
388
8.4.4
Applications of Semiconductors
389
8.5
Ionic Conductivity
392
8.5.1
Alkali Halides: Vacancy Conduction
393
8.5.1.1
Activation Energy for Ion Hopping: Geometric Considerations
394
8.5.1.2
Ionic Conductivity of NaCl Crystals
396
8.5.1.3
Extrinsic Conductivity in NaCl: Control by Aliovalent Doping
397
8.5.2
Silver Chloride: Interstitial Conduction
399
8.5.3
Alkaline Earth Fluorides
401
8.5.4
Solid Electrolytes (or Fast Ion Conductors, Superionic Conductors)
401
8.5.4.1
General Considerations
401
8.5.4.2
l-Alumina
403
8.5.4.3
Nasicon
409
8.5.4.4
Hollandses and Priderites
409
8.5.4.5
Silver and Copper Ion Conductors
411
8.5.4.6
Fluoride Ion Conductors
413
8.5.4.7
Oxide Ion Conductors
414
8.5.4.8
Li4 Ion Conductors
418
8.5.4.9
Proton Conductors
421
8.5.4.10
Mixed Ionic/Electronic Conductors
421
8.5.4.11
Applications of Solid Electrolytes and Mixed Conductors
422
8.6
Dielectric Materials
430
8.6.1
From Dielectrics to Conductors
433
8.7
Ferroelectries
436
8.8
Pyraeleetrics
441
8.9
Piezoelectrics
441
8.10
Applications of
Ferm-.
Pvro- and Piezoelectrics
441
xv Contents
9
Magnetic
Properties
445
9.1
Physical Properties
445
9.1.1
Behaviour of Substances in a Magnetic Field
446
9.
1
.2
Effects of Temperature: Curie and Curie-Weiss Laws
448
9.1.3
Magnetic Moments
449
9.1.4
Mechanisms of
Ferro-
and Antiferromagnetic Ordering: Superexchange
452
9.1.5
Some More Definitions
453
9.2
Magnetic Materials, their Structures and Properties
455
9.2.1
Metals and Alloys
455
9.2.2
Transition Metal Monoxides
458
9.2.3
Transition Metal Dioxides
459
9.2.4
Spinels
459
9.2.5
Garnets
462
9.2.6
Ilmenites and Perovskites
464
9.2.7
Magnetoplumbites
464
9.3
Applications: Structure-Property Relations
464
9.3.1
Transformer Cores
464
9.3.2
Permanent Magnets
466
9.3.3
Magnetic Information Storage
466
9.4
Recent Developments
467
9.4.1 Magnetoresistance:
Giant and Colossal
467
9.4.2
Multifcrroics
469
10
Optical Properties: Luminescence and Lasers
473
10.1
Visible Light and the Electromagnetic Spectrum
473
10.2
Sources of Light, Thermal Sources, Black Body Radiation and Electronic Transitions
473
10.3
Scattering Processes: Reflection. Diffraction and Interference
476
10.4
Luminescence and Phosphors
476
10.5
Configurational Coordinate Model
478
10.6
Some Phosphor Materials
480
10.7
Ant i-Stokes Phosphors
481
Î
0.8
Stimulated Emission, Amplification of Light and Lasers
482
10.8.1
The Ruby Laser
484
10.8.2
Neodymium Lasers
485
10.8.3
Semiconductor Lasers and the Light-Emitting Diode, LED
486
10.9
Photodetectors
488
10.10
Fibre-Optics
490
10.11
Solar Cells
492
Further Reading
493
Appendix A: Interplanar Spacings and Unit Cell Volumes
505
Appendix B: Model Building
507
Appendix C: Geometrical Considerations in Crystal Chemistry
511
Contents
xvi
Appendix
D:
How to Recognise Close Packed (Eutactic) Structures
515
Appendix E: Positive and Negative Atomic Coordinates
517
Appendix F: The Elements and Some of Their Properties
519
Questions
525
Index
537
SOLID STATE
CHEMISTRY
AND ITS APPLICATIONS
STUDENT EDITION !
SECOND EDITION
ANTHONY R. WEST
Department of Materials Science and Engineering, University of Sheffield, UK
Solid State Chemistry and its Applications, Second Edition: Student Edition is an
extensive update and sequel to the bestselling textbook Basic Solid State Chemistry,
the classic text for undergraduate teaching in solid state chemistry worldwide.
Solid state chemistry lies at the heart of many significant scientific advances from recent
decades, including the discovery of high-temperature superconductors, new forms of carbon
and countless other developments in the synthesis, characterisation and applications of
inorganic materials. Looking forward, solid state chemistry will be crucial for the development
of new functional materials in areas such as energy, catalysis and electronic materials.
This revised edition of Basic Solid State Chemistry has been completely rewritten and expanded
to present an up-to-date
aecöunt
of the essential topics and recent developments in this exciting
field of inorganic chemistry. Each section commences with a gentle introduction, covering
basic principles, progressing seamlessly to a more advanced level in order to present a
comprehensive overview of the subject.
This new Student Edition includes the following updates and new features:
•
Expanded coverage of bonding in solids, including a new section on covalent bonding
and more extensive treatment of metallic bonding.
•
Synthetic methods are covered extensively and new topics include microwave synthesis,
combinatorial synthesis, mechano-synthesis, atomic layer deposition and spray pyrolysis.
•
Revised coverage of electrical, magnetic and optical properties, with additional material
on semiconductors, giant and colossal magnetoresistance, multiferroics,
LEDs,
fibre
optics and solar cells, lasers, graphene and quasicrystats.
•
Extended chapters on crystal defects and characterisation techniques.
•
Published in full colour to aid comprehension.
•
Extensive coverage of crystal structures for1 important families of inorganic solids is
complemented by access to CrystaiMaker® visualization software, allowing readers
to view
впа
rotate over
100
crystal
structures
in three dimensions,
•
Solutions to exercises and supplementary lecture material are available online.
|
| any_adam_object | 1 |
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| author_facet | West, Anthony R. |
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| callnumber-label | QD478 |
| callnumber-raw | QD478 |
| callnumber-search | QD478 |
| callnumber-sort | QD 3478 |
| callnumber-subject | QD - Chemistry |
| classification_rvk | VE 9300 |
| classification_tum | CHE 194f |
| ctrlnum | (OCoLC)880328986 (DE-599)BVBBV041390191 |
| dewey-full | 541/.0421 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 541 - Physical chemistry |
| dewey-raw | 541/.0421 |
| dewey-search | 541/.0421 |
| dewey-sort | 3541 3421 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie Physik |
| edition | 2. ed., student ed. |
| format | Book |
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| id | DE-604.BV041390191 |
| illustrated | Illustrated |
| indexdate | 2025-02-03T17:41:49Z |
| institution | BVB |
| isbn | 9781119942948 |
| language | English |
| lccn | 013029528 |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-026837983 |
| oclc_num | 880328986 |
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| owner_facet | DE-703 DE-11 DE-91G DE-BY-TUM DE-355 DE-BY-UBR DE-29T DE-83 DE-384 DE-19 DE-BY-UBM |
| physical | XXIV, 556 S. Ill., zahlr. graph. Darst. |
| publishDate | 2014 |
| publishDateSearch | 2014 |
| publishDateSort | 2014 |
| publisher | Wiley |
| record_format | marc |
| spellingShingle | West, Anthony R. Solid state chemistry and its applications Solid state chemistry Festkörperchemie (DE-588)4129288-1 gnd |
| subject_GND | (DE-588)4129288-1 |
| title | Solid state chemistry and its applications |
| title_auth | Solid state chemistry and its applications |
| title_exact_search | Solid state chemistry and its applications |
| title_full | Solid state chemistry and its applications Anthony R. West |
| title_fullStr | Solid state chemistry and its applications Anthony R. West |
| title_full_unstemmed | Solid state chemistry and its applications Anthony R. West |
| title_short | Solid state chemistry and its applications |
| title_sort | solid state chemistry and its applications |
| topic | Solid state chemistry Festkörperchemie (DE-588)4129288-1 gnd |
| topic_facet | Solid state chemistry Festkörperchemie |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=026837983&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=026837983&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA |
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