Polymer processing principles and design
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| Sprache: | English |
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2014
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| 100 | 1 | |a Baird, Donald G. |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Polymer processing |b principles and design |c Donald G. Baird ; Dimitris I. Collias |
| 250 | |a 2. ed. | ||
| 264 | 1 | |a Hoboken, NJ |b Wiley |c 2014 | |
| 300 | |a XV, 393 S. |b graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
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Datensatz im Suchindex
| _version_ | 1819655168459800576 |
|---|---|
| adam_text | CONTENTS
Preface
xi
Preface
to the First Edition
xiii
Acknowledgments
xv
1 Importance of Process Design
1
1.1 Classification of Polymer Processes,
1
1.2
Film Blowing: Case Study,
5
1.3
Basics ol Polymer Process Design,
7
References,
8
2
Isothermal Flow of Purely Viscous Non-Newtonian Fluids
9
Design Problem I Design of a Blow Molding Die,
9
2.
1 Viscous Behavior of Polymer Melts, 1
0
2.2
One-Dimensional Isothermal Flows,
13
2.2.1
Flow Through an Annular Die,
14
2.2.2
Flow in a Wire Coating Die,
17
2.3
Filiations of Change for Isothermal Systems,
19
2.4
Useful Approximations,
26
2.5
Solution to Design Problem I,
27
2.5.1
Lubrication Approximation Solution,
27
2.5.2
Computer Solution,
29
Problems,
30
References,
34
3
Viscoelastic Response of Polymeric Fluids and Fiber Suspensions
37
Design Problem II Design of
a Parison
Die for a Viscoelastic Fluid,
37
3.1
Material Functions for Viscoelastic Fluids,
38
3.1.1
Kinematics,
38
3.1.2
Stress Tensor Components,
39
3.
1
.3
Material Functions for Shear Flow,
40
3.1.4
Shear-Free Flow Material Functions,
43
vi
CONTENTS
3.2
Nonlinear Constitutive Equations,
44
3.2.1
Description of Several Models,
44
3.2.2
Fiber Suspensions,
52
3.3
Rheometry,
55
3.3.1
Shear Flow Measurements,
56
3.3.2
Shear-Free Flow Measurements, 5H
3.4
Useful Relations for Material Functions,
60
3.4.1
Effect of Molecular Weight,
60
3.4.2
Relations Between Linear Viscoelaslic Properties and
Viscometric Functions,
61
3.4.3
Branching,
61
3.5
Rheological Measurements and Polymer Processabilily. f>2
3.6
Solution to Design Problem II,
64
Problems,
66
References,
70
4
Diffusion and Mass Transfer
73
Design Problem III Design of a Dry-Spinning System,
73
4.1
Mass Transfer Fundamentals,
74
4.1.1
Définitions
of Concentrations anil Velocities,
74
4.1.2
Fluxes and Their Relationships,
76
4.
1
.3
Fick s First Law of Diffusion,
76
4.1.4
Microscopic Material Balance, 7S
4.1.5
.Similarity with Heal
Transfer:
Simple Applications,
N0
4.2
Diffusi
vily.
Solubility, and Permeability in Polymer Systems,
N4
4.2.1
Diltusivily and Solubility of Simple
(
lases, X4
4.2.2
Permeability of Simple
(lases
ami IVrmachor, S7
4.2.3
Moisture
Sorption
and Diffusion,
90
4.2.4
Permeation of Higher-Activity Permeanls, MO
4.2.5
Polymer Polymer Diffusion,
93
4.2.6
Measurement
Techniques
and Their Mathematics,
94
4.3
Non-l iekian Transport,
95
4.4
Mass Transfer Coefficients,
96
4.4.1
Definitions,
96
4.4.2
Analogies Between Heat and Mass Transfer,
97
4.5
Solution to Design Problem III,
99
Problems,
10!
References,
5
Nonisothermal Aspects of Polymer Processing
111
Design Problem IV Casting of Polypropylene Film, I
1
I
5.1
Temperature Effects on Rheological Properties, I
1
I
5.2
The Energy Equation,
1 13
5.2.1
Shell Energy Balances,
1
1
3
5.2.2
Equation of Thermal Energy,
117
5.3
Thermal Transport Properties,
120
5.3.1
Homogeneous Polymer Systems,
120
5.3.2
Thermal Properties of Composite Systems,
123
5.4
Heating and Cooling of Nondeforming Polymeric Materials,
124
5.4.1
Transient Heat Conduction in Nondeforming Systems,
125
5.4.2
Heat Transfer Coefficients,
130
5.4.3
Radiation Heat Transfer,
132
CONTENTS
vii
5.5
Crystallization, Morphology, and
Orientation,
135
5.5.1
Crystallization in the Quiescent State,
136
5.5.2
Other Factors Affecting Crystallization,
142
5.5.3
Polymer Molecular Orientation,
143
5.6
Solution to Design Problem IV,
145
Problems,
147
References,
150
6
Mixing
153
Design Problem V Design of a Multilayered Extrusion Die,
153
6.1
Description of Mixing,
154
6.2
Characterization of the State of Mixture,
156
6.2.1
Statistical Description of Mixing,
157
6.2.2
Scale and Intensity of Segregation,
161
6.2.3
Mixing Measurement Techniques,
163
6.3
Striation Thickness and Laminar Mixing,
164
6.3.1
Striation Thickness Reduction from Geometrical Arguments,
164
6.3.2
Striation Thickness Reduction from Kinematical Arguments,
169
6.3.3
Laminar Mixing in Simple Geometries,
171
6.4
Residence Time and Strain Distributions,
174
6.4.1
Residence Time Distribution,
174
6.4.2
Strain Distribution,
177
6.5
Dispersive Mixing,
180
6.5.1
Dispersion of Agglomerates,
180
6.5.2
Liquid-Liquid Dispersion,
182
6.6
Thermodynamics of Mixing,
188
6.7
Chaotic Mixing,
189
6.8
Solution to Design Problem V,
191
Problems,
194
References,
198
7
Extrusion Dies
201
Design Problem VI Coextrusion Blow Molding Die,
201
7.1
Extrudate Nonuniformities,
202
7.2
Viscoelastic Phenomena,
203
7.2.1
Flow Behavior in Contractions,
203
7.2.2
Extrusion Instabilities,
203
7.2.3
Die Swell,
207
7.3
Sheet and Film Dies,
212
7.4
Annular Dies,
216
7.4.1
Center-Fed Annular Dies,
216
7.4.2
Side-Fed and Spiral Mandrel Dies,
217
7.4.3
Wire Coating Dies,
217
7.5
Profile Extrusion Dies,
220
7.6
Multiple Layer Extrusion,
222
7.6.1
General Considerations,
222
7.6.2
Design Equations,
224
7.6.3
Flow Instabilities in Multiple Layer Flow,
227
7.7
Solution to Design Problem VI,
228
Problems,
230
References,
234
viii
CONTKNTS
8 Extruders 235
Design Problem
VII
Design
of a Devolatili/.ation Section
l or a
Single-Screw Extruder,
235
8.1
Description of Extruders,
235
8.1.1
Single-Screw Extruders,
237
8.1.2
Twin-Screw Extruders,
238
8.2
Hopper Design,
239
8.3
Plasticatili»
Single-Screw Extruders,
242
8.3.1
Solids Transport.
242
8.3.2
Delay and Melting/ones,
246
8.3.3
Metering Section,
250
8.4
Twin-Screw
Extruders, 253
8.4.1
Self-wiping
Coroiat
¡ng Twin-Screw Extruders.
253
8.4.2
Intermeshing Counierrolating Extruders.
256
8.5
Mixing, Devolatilizalion, and Reactions in Extruders,
258
8.5.1
Mixing,
258
8.5.2
Devolatili/ation in Extruders,
262
8.5.3
Reactive Extrusion,
264
8.6
Solution to Design Problem
VII,
265
8.6.1
Dimensional Analysis.
265
8.6.2
Diffusion Theory,
267
Problems,
268
References,
272
9
Post die Processing
275
Design Problem
VIII
Design of
л
Film Blowing Process
loi
(ìarbagc
Hags,
275
9.1 Eiber
Spinning,
276
9.1.1
Isothermal
Newtonian
Model.
278
9.1.2
Noiiisothennal Newtonian Model,
281
9.1.3
Isothermal Viscoelastic Model.
285
9.1.4
High-Speed Spinning and Structure Formation.
287
9.1.5
Instabilities in Fiber Spinning,
290
9.2
Film Casting and Stretching,
293
9.2.1
Him Casting,
293
9.2.2
Stability of Film Casting,
296
9.2.3
Film Stretching and Properties,
297
9.3
Film Blowing.
297
9.3.1
Isothermal Newtonian Model,
299
9.3.2
Noiiisothennal Newtonian Model,
302
9.3.3
Nonisothermal Non-Newtonian Model,
303
9.3.4
Biaxial Stretching and Mechanical Properties,
304
9.3.5
Stability of Film Blowing,
304
9.3.6
Scaleup,
305
9.4
Solution to Design Problem
VIII, 305
Problems,
306
References,
308
CONTENTS
¡X
10
Molding and Forming
311
Design Problem IX Design of a Compression Molding Process,
31 1
10.1
Injection Molding,
311
10.
1
.
1 General Aspects of Injection Molding,
31
I
10.1.2
Simulation of Injection Molding,
315
10.1.3
Microinjection
Molding,
318
10.2
Compression Molding,
319
10.2.1
(¡encrai
Aspects of Compression Molding,
319
10.2.2
Simulation of Compression Molding,
320
10.3
Thermoforming,
322
10.3.1
General Aspects of Thermoforming,
322
10.3.2
Modeling of Thermoforming,
324
10.4
Blow Molding,
328
10.4.1
Technological Aspects of Blow Molding,
328
10.4.2
Simulation of Blow Molding,
330
10.5
Solution to Design Problem IX,
332
Problems,
335
References,
340
1
1
Process
Engineering
for Recycled and Renewable Polymers
343
11.1
Lite-Cycle Assessment,
343
11.2
Primary Recycling,
348
1 1.3
Mechanical or Secondary Recycling,
351
I
1.3.1
Rheology of Mixed Systems,
352
I
1.3.2
Filtration,
352
1 1.4
Tertiary or Feedstock Recycling,
354
I
1.5
Renewable Polymers and Their Processability.
357
I 1
.5.
1 Thermal Stability and Processing of Renewable Polymers,
358
Problems,
362
References,
363
Nomenclature
365
Appendix A Rheological Data for Several Polymer Melts
373
Appendix
В
Physical Properties and Friction Coefficients for Some
Common Polymers in the Bulk State
379
Appendix
С
Thermal Properties of Materials
381
Appendix I) Conversion Table
385
Index
387
Fundamental concepts coupled with
practical, step-by-step guidance
With its emphasis on cor· principles, this text equips readers with the skills and knowledge to design the
many processes needed to safely and successfully manufacture thermoplastic parts. The first half of the
text sets forth the general theory and concepts underlying polymer processing, such as the vlscoelastic
response of polymeric fluids and diffusion and mass transfer. Next, the text explores specific practical
aspects of polymer processing, including mixing, extrusion dies, and post-die processing. By addressing
a broad range of design issues and methods, the authors demonstrate how to solve most common
processing problems.
This S0cond Edition of the highly acclaimed Polymer Processing has been thoroughly updated to reflect
current polymer processing issues and practices. New areas of coverage include:
•
Micro-injection molding to produce objects weighing a fraction of a gram, such as miniature gears
and
biomedical
devices
•
New chapter dedicated to the recycling of thermoplastics and the processing of renewable
polymers
•
Life-cycle assessment, a systematic method for determining whether recycling is appropriate and
which form of recycling is optimal
•
Rheology of polymers containing fibers
Chapters feature problem sets, enabling readers to assess and reinforce their knowledge as they
progress through the text. There are also special design problems throughout the text that reflect
real-world polymer processing issues, A companion website features numerical subroutines as well as
guidance for using
MATLAB ,
IMSL
,
and Excel to solve the sample problems from the text. By providing
both underlying theory and practical step-by-step guidance, Polymtr Processing is recommended for
students in chemical, mechanical, materials, and polymer engineering.
DONALD G. BAIRD, PhD, is the Alexander F.
Ciacco
and Harry
С
Wyatt Professor of Chemical
Engineering at Virginia Tech. His research centers on the use of fundamental non-Newtonian fluid
mechanics to develop improved processing operations for polymers and polymer composites, Among
his many honors, the Society of Plastics Engineers has awarded him the International Award, the
International Award for Research, and the International Award for Education, A holder of seven patents,
Dr. Baird has published some
300
refereed publications.
DIMITRIS I. COLLIAS, PhD, is with the corporate R&D department of the Procter
&
Gamble Co in
Cincinnati, Ohio. He earned his PhD degree from Princeton University. With twenty years of industry
experience in polymers, polymer processing, packaging, paper, and activated carbon, his current
research focuses on developing renewable materials and processes for key products in the company s
portfolio. Dr. Collies holds fifty-four issued U.S. patents and is inventor or co-inventor in more than thirty
U.S. patent applications.
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|
| any_adam_object | 1 |
| author | Baird, Donald G. Collias, Dimitris I. |
| author_facet | Baird, Donald G. Collias, Dimitris I. |
| author_role | aut aut |
| author_sort | Baird, Donald G. |
| author_variant | d g b dg dgb d i c di dic |
| building | Verbundindex |
| bvnumber | BV041293357 |
| classification_rvk | UV 9150 ZM 5250 |
| ctrlnum | (OCoLC)879617512 (DE-599)BVBBV041293357 |
| dewey-full | 668.4/23 668.423 |
| dewey-hundreds | 600 - Technology (Applied sciences) |
| dewey-ones | 668 - Technology of other organic products |
| dewey-raw | 668.4/23 668.423 |
| dewey-search | 668.4/23 668.423 |
| dewey-sort | 3668.4 223 |
| dewey-tens | 660 - Chemical engineering |
| discipline | Chemie / Pharmazie Physik Werkstoffwissenschaften / Fertigungstechnik |
| edition | 2. ed. |
| format | Book |
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| id | DE-604.BV041293357 |
| illustrated | Illustrated |
| indexdate | 2024-12-24T03:49:33Z |
| institution | BVB |
| isbn | 9780470930588 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-026742293 |
| oclc_num | 879617512 |
| open_access_boolean | |
| owner | DE-703 DE-83 DE-29T DE-861 |
| owner_facet | DE-703 DE-83 DE-29T DE-861 |
| physical | XV, 393 S. graph. Darst. |
| publishDate | 2014 |
| publishDateSearch | 2014 |
| publishDateSort | 2014 |
| publisher | Wiley |
| record_format | marc |
| spellingShingle | Baird, Donald G. Collias, Dimitris I. Polymer processing principles and design Thermoplastics Kunststoffverarbeitung (DE-588)4114335-8 gnd Mathematische Methode (DE-588)4155620-3 gnd Thermoplast (DE-588)4059844-5 gnd Verarbeitung (DE-588)4537851-4 gnd |
| subject_GND | (DE-588)4114335-8 (DE-588)4155620-3 (DE-588)4059844-5 (DE-588)4537851-4 |
| title | Polymer processing principles and design |
| title_auth | Polymer processing principles and design |
| title_exact_search | Polymer processing principles and design |
| title_full | Polymer processing principles and design Donald G. Baird ; Dimitris I. Collias |
| title_fullStr | Polymer processing principles and design Donald G. Baird ; Dimitris I. Collias |
| title_full_unstemmed | Polymer processing principles and design Donald G. Baird ; Dimitris I. Collias |
| title_short | Polymer processing |
| title_sort | polymer processing principles and design |
| title_sub | principles and design |
| topic | Thermoplastics Kunststoffverarbeitung (DE-588)4114335-8 gnd Mathematische Methode (DE-588)4155620-3 gnd Thermoplast (DE-588)4059844-5 gnd Verarbeitung (DE-588)4537851-4 gnd |
| topic_facet | Thermoplastics Kunststoffverarbeitung Mathematische Methode Thermoplast Verarbeitung |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=026742293&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=026742293&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT bairddonaldg polymerprocessingprinciplesanddesign AT colliasdimitrisi polymerprocessingprinciplesanddesign |