Multidimensional HPLC of polymers
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| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Heidelberg [u.a.]
Springer
2013
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| Schriftenreihe: | Springer laboratory: manuals in polymer science
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| 245 | 1 | 0 | |a Multidimensional HPLC of polymers |c Harald Pasch ; Bernd Trathnigg |
| 264 | 1 | |a Heidelberg [u.a.] |b Springer |c 2013 | |
| 300 | |a XIV, 280 S. |b Ill., graph. Darst. | ||
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| 700 | 1 | |a Trathnigg, Bernd |d 1947- |e Verfasser |0 (DE-588)115488448 |4 aut | |
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Datensatz im Suchindex
| _version_ | 1806325312031555584 |
|---|---|
| adam_text |
1 INTRODUCTION 1
1.1 MOLECULAR HETEROGENEITY OF COMPLEX POLYMERS 2
1.2 LIQUID CHROMATOGRAPHY OF POLYMERS 6
1.3 MULTIDIMENSIONAL SEPARATION OF COMPLEX POLYMERS 10
REFERENCES 15
2 THEORY OF POLYMER CHROMATOGRAPHY 17
2.1 SIZE EXCLUSION CHROMATOGRAPHY 17
2.2 LIQUID ADSORPTION CHROMATOGRAPHY 18
2.3 LIQUID CHROMATOGRAPHY AT CRITICAL CONDITIONS 21
2.4 THERMODYNAMICS OF POLYMER CHROMATOGRAPHY 23
REFERENCES 25
3 INTERACTIVE MODES OF POLYMER CHROMATOGRAPHY 27
3.1 LIQUID ADSORPTION AND GRADIENT CHROMATOGRAPHY 28
3.2 LIQUID CHROMATOGRAPHY AT CRITICAL CONDITIONS 30
3.3 TEMPERATURE GRADIENT INTERACTION CHROMATOGRAPHY 32
REFERENCES 34
4 EQUIPMENT AND MATERIALS 37
4.1 INSTRUMENTAL SETUP 37
4.2 STATIONARY PHASES 39
4.3 MOBILE PHASES 42
4.4 DETECTORS 42
4.4.1 CONCENTRATION SENSITIVE DETECTORS 44
4.4.2 MOLAR MASS SENSITIVE DETECTORS 47
4.4.3 SPECTROSCOPIC DETECTORS 52
REFERENCES 52
5 MULTIDETECTOR SIZE EXCLUSION CHROMATOGRAPHY 55
5.1 ANALYSIS OF COPOLYMERS BY SEC WITH DUAL CONCENTRATION
DETECTION 59
5.1.1 ANALYSIS OF PMMA-B-PDMA BLOCK COPOLYMERS BY SEC
WITH D-RI DETECTION 62
5.1.2 ANALYSIS OF PEO-B-PPO BLOCK COPOLYMERS BY SEC WITH
D-RI DETECTION 67
VII
HTTP://D-NB.INFO/1028990588
VIII
CONTENTS
5.2 ANALYSIS OF POLYMERS BY SEC WITH MOLAR MASS SENSITIVE
DETECTION 69
5.2.1 RI-MALLS DETECTION 69
5.2.2 RL-VISCOMETER DETECTION 84
REFERENCES 90
6 TWO-DIMENSIONAL LIQUID CHROMATOGRAPHY 95
6.1 INTRODUCTION 95
6.2 EXPERIMENTAL ASPECTS OF 2D SEPARATIONS 98
6.2.1 SEQUENCE OF SEPARATION METHODS 100
6.2.2 DETECTABILITY AND SENSITIVITY IN THE SECOND DIMENSION . 101
6.2.3 OTHER EXPERIMENTAL FACTORS AFFECTING 2D SEPARATIONS . 101
6.3 SEPARATION TECHNIQUES FOR THE FIRST AND SECOND DIMENSIONS 102
6.4 DATA AQUISITION AND PROCESSING 105
6.5 COUPLING OF GRADIENT HPLC AND SEC 107
6.5.1 ANALYSIS OF THE GRAFTING REACTION OF METHYL METHACRYLATE
ONTO EPDM 110
6.5.2 ANALYSIS OF THE GRAFTING REACTION OF STYRENE ONTO
POLYBUTADIENE 117
6.5.3 BRANCHING ANALYSIS OF STAR-SHAPED POLYSTYRENES 121
6.6 COUPLING OF LCCC AND SEC 130
6.6.1 CHARACTERIZATION OF ALIPHATIC POLYESTERS 131
6.6.2 ANALYSIS OF EPOXY RESINS 134
6.6.3 CHARACTERIZATION OF STAR-SHAPED POLYLACTIDES 147
6.6.4 ANALYSIS OF PS-PDMS BLOCK COPOLYMERS 153
6.7 OTHER METHOD COMBINATIONS IN 2D-LC 162
6.7.1 ANALYSIS OF COMB-SHAPED PS BY TGIC-GRADIENT HPLC . 162
6.7.2 ANALYSIS OF FATTY ALCOHOL ETHOXYLATES BY LCCC-LAC . 167
6.8 FURTHER APPLICATIONS AND OUTLOOK 173
REFERENCES 178
7 HYPHENATION OF POLYMER CHROMATOGRAPHY WITH INFORMATION-RICH
DETECTORS 183
7.1 COUPLING WITH FTIR SPECTROSCOPY 183
7.1.1 ANALYSIS OF CROSS-LINKED STYRENE-BUTADIENE RUBBER
BY SEC AND FTIR SPECTROSCOPY 189
7.1.2 FAST CHEMICAL COMPOSITION ANALYSIS OF RANDOM
STYRENE-B UTYLACRYLATE COPOLYMERS BY HPLC-FTIR 197
7.2 COUPLING WITH MASS SPECTROSCOPY 204
7.2.1 MOLAR MASS DISTRIBUTION OF POLYESTER COPOLYMERS 210
7.2.2 MOLAR MASS AND CHEMICAL COMPOSITION ANALYSIS
OF PNBMA-B-PMMA BLOCK COPOLYMERS 212
CONTENTS IX
7.3 COUPLING WITH'H-NMR 219
7.3.1 ANALYSIS OF OCTYLPHENYL-TERMINATED PEO 223
7.3.2 ANALYSIS OF MICROSTRUCTURE OF POLYSTYRENE 227
7.3.3 MICROSTRUCTURE ANALYSIS OF PI-B-PMMA BLOCK
COPOLYMERS 233
7.4 CONCLUSIONS AND OUTLOOK 242
REFERENCES 242
8 POLYOLEFIN ANALYSIS BY MULTIDIMENSIONAL LIQUID CHROMATOGRAPHY . 247
8.1 COUPLED HT-SEC-FTIR 248
8.2 COUPLED HT-SEC-
1
H-NMR 251
8.3 HIGH-TEMPERATURE 2D LIQUID CHROMATOGRAPHY 254
8.3.1 ANALYSIS OF POLYPROPYLENES BY TACTICITY AND MOLAR
MASS 260
8.3.2 ANALYSIS OF ETHYLENE-VINYL ACETATE COPOLYMERS 263
8.4 CONCLUSIONS AND OUTLOOK 268
REFERENCES 269
9 CONCLUSIONS AND FUTURE TRENDS 273
REFERENCES 276
INDEX 277 |
| any_adam_object | 1 |
| author | Pasch, Harald 1952- Trathnigg, Bernd 1947- |
| author_GND | (DE-588)1048212629 (DE-588)115488448 |
| author_facet | Pasch, Harald 1952- Trathnigg, Bernd 1947- |
| author_role | aut aut |
| author_sort | Pasch, Harald 1952- |
| author_variant | h p hp b t bt |
| building | Verbundindex |
| bvnumber | BV041137145 |
| classification_rvk | UV 2600 VG 7500 ZM 5100 |
| ctrlnum | (OCoLC)855539826 (DE-599)DNB1028990588 |
| dewey-full | 547.7046 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 547 - Organic chemistry |
| dewey-raw | 547.7046 |
| dewey-search | 547.7046 |
| dewey-sort | 3547.7046 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie Physik Werkstoffwissenschaften / Fertigungstechnik |
| format | Book |
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| illustrated | Illustrated |
| indexdate | 2024-08-03T00:47:36Z |
| institution | BVB |
| isbn | 3642360793 9783642360794 |
| language | English |
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| oclc_num | 855539826 |
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| owner_facet | DE-11 DE-703 DE-29T DE-634 DE-83 |
| physical | XIV, 280 S. Ill., graph. Darst. |
| publishDate | 2013 |
| publishDateSearch | 2013 |
| publishDateSort | 2013 |
| publisher | Springer |
| record_format | marc |
| series2 | Springer laboratory: manuals in polymer science |
| spelling | Pasch, Harald 1952- Verfasser (DE-588)1048212629 aut Multidimensional HPLC of polymers Harald Pasch ; Bernd Trathnigg Heidelberg [u.a.] Springer 2013 XIV, 280 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Springer laboratory: manuals in polymer science HPLC (DE-588)4072641-1 gnd rswk-swf Polymere (DE-588)4046699-1 gnd rswk-swf Polymere (DE-588)4046699-1 s HPLC (DE-588)4072641-1 s DE-604 Trathnigg, Bernd 1947- Verfasser (DE-588)115488448 aut Erscheint auch als Online-Ausgabe 978-3-642-36080-0 X:MVB text/html http://deposit.dnb.de/cgi-bin/dokserv?id=4212946&prov=M&dok_var=1&dok_ext=htm Inhaltstext DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=026112864&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Pasch, Harald 1952- Trathnigg, Bernd 1947- Multidimensional HPLC of polymers HPLC (DE-588)4072641-1 gnd Polymere (DE-588)4046699-1 gnd |
| subject_GND | (DE-588)4072641-1 (DE-588)4046699-1 |
| title | Multidimensional HPLC of polymers |
| title_auth | Multidimensional HPLC of polymers |
| title_exact_search | Multidimensional HPLC of polymers |
| title_full | Multidimensional HPLC of polymers Harald Pasch ; Bernd Trathnigg |
| title_fullStr | Multidimensional HPLC of polymers Harald Pasch ; Bernd Trathnigg |
| title_full_unstemmed | Multidimensional HPLC of polymers Harald Pasch ; Bernd Trathnigg |
| title_short | Multidimensional HPLC of polymers |
| title_sort | multidimensional hplc of polymers |
| topic | HPLC (DE-588)4072641-1 gnd Polymere (DE-588)4046699-1 gnd |
| topic_facet | HPLC Polymere |
| url | http://deposit.dnb.de/cgi-bin/dokserv?id=4212946&prov=M&dok_var=1&dok_ext=htm http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=026112864&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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