Organorhenium and organomolybdenum oxides synthesis and application as olefin epoxidation catalysts
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| Format: | Abschlussarbeit Buch |
| Sprache: | English |
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2012
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| Online-Zugang: | kostenfrei https://nbn-resolving.org/urn:nbn:de:bvb:91-diss-20121120-1115642-0-7 Inhaltsverzeichnis |
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| 100 | 1 | |a Hauser, Simone Antonia |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Organorhenium and organomolybdenum oxides |b synthesis and application as olefin epoxidation catalysts |c Simone Antonia Hauser |
| 264 | 1 | |c 2012 | |
| 300 | |a VI, 112 S. |b graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 502 | |a München, Techn. Univ., Diss., 2012 | ||
| 650 | 0 | 7 | |a Katalyse |0 (DE-588)4029921-1 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Alkene |0 (DE-588)4001207-4 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Epoxidation |0 (DE-588)4152560-7 |2 gnd |9 rswk-swf |
| 655 | 7 | |0 (DE-588)4113937-9 |a Hochschulschrift |2 gnd-content | |
| 689 | 0 | 0 | |a Alkene |0 (DE-588)4001207-4 |D s |
| 689 | 0 | 1 | |a Epoxidation |0 (DE-588)4152560-7 |D s |
| 689 | 0 | 2 | |a Katalyse |0 (DE-588)4029921-1 |D s |
| 689 | 0 | |5 DE-604 | |
| 776 | 0 | 8 | |i Erscheint auch als |n Online-Ausgabe |o urn:nbn:de:bvb:91-diss-20121120-1115642-0-7 |
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| 912 | |a ebook | ||
| 943 | 1 | |a oai:aleph.bib-bvb.de:BVB01-025743740 | |
Datensatz im Suchindex
| DE-BY-TUM_call_number | 0001 DM 30437 |
|---|---|
| DE-BY-TUM_katkey | 1911889 |
| DE-BY-TUM_location | Mag |
| DE-BY-TUM_media_number | TEMP3218695 |
| DE-BY-UBR_katkey | 5087429 |
| _version_ | 1822745635676225536 |
| adam_text | IMAGE 1
CONTENTS
1 EPOXIDATION OF OLEFINS WITH HOMOGENEOUS CATALYSTS - QUO VADLS7 1
1.1 BACKGROUND 2
1.2 EPOXIDATION O F CW-CYCLOOCTENE 3
1.3 MORE DEMANDING SUBSTRATES 4
1.3.1 1-OCTENE 4
1.3.2 STYRENE 6
1.4 TERPENES 6
1.4.1 LIMONENE 7
1.4.2 A-PINENE 8
1.4.3 CAMPHENE 8
1.4.4 GERANIOL 8
1.5 PROCHIRAL OLEFINS 9
1.5.1 ARYL-SUBSTITUTED OLEFINS 9
1.5.2 CYCLIC ALKENES 11
1.5.3 A,^-UNSATURATED KETONES 12
1.6 EPOXIDATION O F INDUSTRIALLY RELEVANT BULK OLEFINS 13
1.6.1 ETHYLENE 13
1.6.2 PROPYLENE 13
1.7 CONCLUSION 14
1.8 REFERENCES 16
2 OBJECTIVES 21
2.1 METHYLTRIOXORHENIUM 22
2.2 MOLYBDENUM COMPLEXES 22
2.3 REFERENCES 24
3 CHROMOPHORLC LEWIS BASE ADDUCTS OF METHYLTRIOXORHENIUM: SYNTHESIS,
CATALY S I S A N D PHOTOCHEMISTRY 2 5
3.1 BACKGROUND 26
3.2 RESULTS AND DISCUSSION 26
3.2.1 SYNTHESIS AND SPECTROSCOPIC CHARACTERISATION 26
3.2.2 X-RAY CRYSTAL STRUCTURE O F LIGAND 5 AND COMPLEXES 8-14 2 8
3.2.3 DETERMINATION O F FORMATION CONSTANTS 29
3.2.4 APPLICATION IN EPOXIDATION CATALYSIS 30
3.2.5 PHOTOSTABILITY O F THE SYNTHESISED COMPOUNDS 31
3.3 CONCLUSION 33
3.4 EXPERIMENTAL SECTION 33
3.4.1 MATERIALS AND METHODS 3 3
3.4.2 LIGAND SYNTHESIS 34
II
HTTP://D-NB.INFO/1033250090
IMAGE 2
3.4.3 TYPICAL PROCEDURE FOR THE PREPARATION O F THE CHROMOPHORIC LEWIS
BASE
ADDUCTS O F MTO 34
3.4.4 SINGLE-CRYSTAL X-RAY STRUCTURE DETERMINATION 34
3.4.5 FORMATION CONSTANT MEASUREMENTS 36
3.4.6 CATALYSIS 36
3.4.7 TESTING THE PHOTOSTABILITY O F THE COMPLEXES 36
3.5 REFERENCES 37
4 CATALYTIC OLEFIN EPOXIDATLON WITH A FLUORINATED ORGANOMOLYBDENUM
COMPLEX 39 4.1 BACKGROUND 4 0
4.2 RESULTS AND DISCUSSION 41
4.2.1 OLEFIN EPOXIDATION WITH A FLUORINATED ORGANOMOLYBDENUM CATALYST .
. 41 4.2.2 CATALYTIC INVESTIGATIONS 45
4.2.3 CATALYSIS IN IONIC LIQUIDS 50
4.3 CONCLUSION 51
4.4 EXPERIMENTAL SECTION 51
4.4.1 MATERIALS AND METHODS 51
4.4.2 SYNTHESIS O F THE COMPLEXES 52
4.4.3 KINETIC STUDIES 52
4.4.4 COMPUTATIONAL DETAILS 53
4.5 REFERENCES 54
5 THE QUEST OF T H E MECHANISM OF OLEFIN EPOXIDATION CATALYSED BY
MONOMERIC ORGANOMOLYBDENUM COMPLEXES 59
5.1 BACKGROUND 60
5.2 EXPERIMENTAL APPROACH 63
5.3 RESULTS AND DISCUSSION 63
5.3.1 ACTIVITY O F THE CATALYST PRECURSORS - [CP MO(CO) 3R] 63
5.3.2 CATALYTIC ACTIVITY O F THE CHLORO DERIVATIVES 65
5.3.3 COMPARISON O F [CP MO(0 2)(0)R]-TYPE COMPLEXES 66
5.3.4 MECHANISTIC STUDIES WITH [CPMO(0) 2CL] 69
5.3.5 MECHANISTIC INVESTIGATIONS BY MEANS O F L 3 C NMR SPECTROSCOPY . .
. 71 5.4 CONCLUSION 72
5.5 EXPERIMENTAL SECTION 73
5.5.1 MATERIALS AND METHODS 73
5.5.2 SYNTHESIS O F THE COMPLEXES 73
5.5.3 CATALYSIS STUDIES 73
5.6 REFERENCES 74
6 T H E [RI 5-(C 5H5)MO(CO)3R] COMPOUND CLASS: SIMILARITIES A N D
DIFFERENCES 7 7 6.1 BACKGROUND 78
6.2 RESULTS AND DISCUSSION 78
6.2.1 VIBRATIONAL SPECTRA 7 9
6.2.2 MOLECULAR STRUCTURES 85
6.3 CONCLUSION 87
6.4 EXPERIMENTAL SECTION 88
6.5 REFERENCES 89
III
IMAGE 3
7 SUMMARY 91
7.1 METHYLTRIOXORHENIUM 92
7.2 MOLYBDENUM COMPLEXES 92
8 APPENDIX A 9 5
9 APPENDIX B 109
I V
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| dewey-ones | 547 - Organic chemistry |
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| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie |
| format | Thesis Book |
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| indexdate | 2024-12-24T03:08:14Z |
| institution | BVB |
| language | English |
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| physical | VI, 112 S. graph. Darst. |
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| publishDate | 2012 |
| publishDateSearch | 2012 |
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| spellingShingle | Hauser, Simone Antonia Organorhenium and organomolybdenum oxides synthesis and application as olefin epoxidation catalysts Katalyse (DE-588)4029921-1 gnd Alkene (DE-588)4001207-4 gnd Epoxidation (DE-588)4152560-7 gnd |
| subject_GND | (DE-588)4029921-1 (DE-588)4001207-4 (DE-588)4152560-7 (DE-588)4113937-9 |
| title | Organorhenium and organomolybdenum oxides synthesis and application as olefin epoxidation catalysts |
| title_auth | Organorhenium and organomolybdenum oxides synthesis and application as olefin epoxidation catalysts |
| title_exact_search | Organorhenium and organomolybdenum oxides synthesis and application as olefin epoxidation catalysts |
| title_full | Organorhenium and organomolybdenum oxides synthesis and application as olefin epoxidation catalysts Simone Antonia Hauser |
| title_fullStr | Organorhenium and organomolybdenum oxides synthesis and application as olefin epoxidation catalysts Simone Antonia Hauser |
| title_full_unstemmed | Organorhenium and organomolybdenum oxides synthesis and application as olefin epoxidation catalysts Simone Antonia Hauser |
| title_short | Organorhenium and organomolybdenum oxides |
| title_sort | organorhenium and organomolybdenum oxides synthesis and application as olefin epoxidation catalysts |
| title_sub | synthesis and application as olefin epoxidation catalysts |
| topic | Katalyse (DE-588)4029921-1 gnd Alkene (DE-588)4001207-4 gnd Epoxidation (DE-588)4152560-7 gnd |
| topic_facet | Katalyse Alkene Epoxidation Hochschulschrift |
| url | http://mediatum.ub.tum.de/node?id=1115642 https://nbn-resolving.org/urn:nbn:de:bvb:91-diss-20121120-1115642-0-7 http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=025743740&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT hausersimoneantonia organorheniumandorganomolybdenumoxidessynthesisandapplicationasolefinepoxidationcatalysts |