High-pressure physics

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Sprache:English
Veröffentlicht: Boca Raton, FL [u.a.] CRC Press 2012
Schriftenreihe:Scottish graduate series
A Taylor & Francis book
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Datensatz im Suchindex

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adam_text Contents High-Pressure Devices 1 1 Introduction ............................. 1 2 The cylinder: the most common high-pressure device ...... 1 3 Belt type apparatuses ....................... 4 4 Opposed anvil devices: Bridgman, Drickamer and profiled anvils 5 4.1 Drickamer cells ....................... 5 4.2 Bridgman anvils ...................... 6 4.3 Profiled opposed anvils .................. 7 5 Multi-anvil devices ......................... 8 5.1 Tetrahedral pressure cells ................. 9 5.2 Cubic pressure cells .................... 9 5.3 Octahedral pressure cells ................. 9 6 The diamond anvil cell ....................... 11 6.1 Anvils ............................ 12 6.2 Backing seats ........................ 13 6.3 Thrust mechanisms ..................... 14 7 Other gem anvil cells: sapphire, moissanite and zirconia cells . 15 8 Pressure transmitting media .................... 16 9 Glossary ............................... 17 10 Acknowledgements ......................... 19 Instrumentation Development for High-Pressure Research 23 1 Introduction ............................. 23 2 Design flow ............................. 24 3 Pressure generation and the types of pressure cells ....... 25 4 Materials properties ........................ 26 5 Matériák selection ......................... 29 6 Technical drawings ......................... 31 7 Finite element analysis ....................... 33 8 Machining and tolerances ..................... 36 9 Testing and safety certification .................. 39 10 Acknowledgements ......................... 40 Electrical Transport Experiments at High Pressure 43 1 Introduction ............................. 43 2 Electrical measurement techniques with diamond anvil cells . . 44 3 Superconductivity under high pressure .............. 46 4 Iron ................................. 46 xi Xli 5 Oxygen ............................... 47 6 Conductivity experiments at high pressure and very high tem¬ peratures .............................. 49 7 Single-crystal experiments ..................... 50 8 Hall effect and magnetoresistance ................. 51 9 Photoconductivity ......................... 52 10 Other uses of electrical transport techniques ........... 53 11 Future directions .......................... 56 12 Acknowledgements ......................... 57 4 Advances in Customized Diamond Anvils 61 1 Introduction ............................. 61 2 Laser-drilled diamond anvils .................... 63 3 Designer diamond anvils ..................... 63 4 Designer-anvil fabrication process steps ............. 64 4.1 Lithography ......................... 64 4.2 Chemical vapor-deposition of diamond .......... 66 4.3 Diamond polishing ..................... 68 5 Types of designer anvils ...................... 68 6 Intelligent diamond anvils (iDAC) ............... 68 7 Integrated circuit technique using alumina films ......... 69 8 Focused ion beam (FIB) systems ................. 70 9 Further examples of the use of customized anvils in high- pressure experiments ........................ 71 9.1 Electrical conductivity of ferropericlase ......... 71 9.2 Magnetic susceptibility of holmium ............ 73 10 Future prospects .......................... 75 11 Further development of CVD diamond growth technology ... 77 12 Acknowledgements ......................... 78 5 Equations of State for Solids over Wide Ranges of Pressure and Temperature 81 1 Introduction ............................. 81 2 Parametric EOS forms ....................... 82 2.1 Invertible EOS ....................... 82 2.2 Finite strain EOS ..................... 83 2.3 Effective potential EOS .................. 84 3 Thennodynamic modeling ..................... 86 3.1 Static lattice ........................ 87 3.2 Quasi-harmonic phonons .................. 87 3.3 Mie-Grüneisen approach .................. SS 3.4 Anharmonicity ....................... 88 3.5 Conduction electrons .................... 90 3.6 Other contributions .................... 90 4 Comparison with experimental results .............. 91 Xlii 5 Comparison of thermodynamic and parametric formulations . . 92 6 Conclusions ............................. 93 6 High-Pressure Crystallography 95 1 Introduction ............................. 95 1.1 Resources .......................... 95 2 Technical developments ...................... 96 2.1 High energy X-ray scattering ............... 96 2.2 Background to the pair distribution function technique . 97 2.3 Quantitative total scattering studies at high PT .... 99 2.4 Quantitative high pressure pair distribution function (QHP-PDF) analysis: current practice .......... 101 2.5 Quantitative high pressure pair distribution function (QHP-PDF) analysis: next steps ............. 103 7 Optical Spectroscopy at High Pressure 111 1 Introduction ............................. Ill 2 General aspects ...........................112 3 The Raman and IR spectroscopy set-up .............113 4 Oxygen ...............................119 5 Carbon dioxide ...........................123 6 Concluding remarks ........................126 7 Acknowledgements .........................127 8 Inelastic Х -Ray Scattering on High-Pressure Fluids 131 1 Introduction .............................131 2 General aspects ...........................132 3 Instrumentation ...........................138 4 Systems ...............................142 9 Optical Spectroscopy in the Diamond Anvil Cell 155 1 Introduction .............................155 2 Spectroscopy units, spectral ranges and dimension constraints . 156 3 Basic principles ...........................158 4 Techniques .............................160 5 Probing of intra- and inter-molecular interactions under pres¬ sure — the example of hydrogen ..................162 6 Optical properties of minerals in the deep Earth interior .... 164 7 Prospects ..............................166 8 Acknowledgements .........................167 10 Magnetism and High Pressure 173 1 Magnetic equation of state, feedback instability .........173 2 Types of magnetic interactions ..................175 3 Magnetic phase transitions ....................181 XIV 4 Examples of high pressure magnetic measurement methods . . 184 4.1 Spectroscopie high pressure measurement methods . . .185 4.2 Inductive or SQUID-based methods ...........187 11 The Deep Earth 195 1 Introduction .............................195 2 Geophysical constraints ......................195 3 Phase transitions ..........................197 4 Refining the chemical composition of the deep reservoirs . . . .201 5 Core dynamics ...........................204 6 Differentiation of the Earth ....................204 7 Conclusions .............................206 12 Planetary Interiors 209 1 Introduction .............................209 2 Terrestrial planets .........................212 3 Giant planets ............................213 4 Conclusions .............................220 13 temperature Measurement and Control in High-Pressure Experiments 223 1 Introduction .............................223 2 Resistance heating and the thermocouple principle for temper¬ ature measurements ........................225 3 Large volume devices and sample assemblies .........226 4 Blackbody radiation and laser-heated diamond anvil cell exper¬ iments ................................235 14 Solid-State and Materials-Chemistry at High Pressure 245 1 Abstract ...............................245 2 Introduction .............................245 3 Diamond and related materials ..................246 4 High-pressure mineralogy and solid-state materials research . . 249 5 Superconductors, elemental alloys and high-hardness metals - . 252 6 Clathrates and new light element solids .............254 7 Summary ..............................257 8 Acknowledgements .........................258 15 Liquids and Amorphous Materials 265 1 Introduction .............................265 2 Definitions ..............................266 3 Exploring the liquid state .....................268 4 Amorphous materials ........................268 5 The glass transition ........................269 6 The influence of pressure ......................272 XV 7 Metastable melting .........................272 8 Two-state models ..........................274 9 Liquid fragility ...........................277 10 Polyamorphic systems .......................278 11 Experimental techniques ......................280 12 The role of diffraction .......................281 13 Glass and liquid structure .....................283 14 Case studies .............................285 14.1 Amorphous forms of H2O .................285 14.2 Amorphous silicon .....................288 14.3 Liquid phosphorous ....................290 15 Transitions in the strong amorphous network ..........292 16 Non-oxide glasses: GeSe^ .....................293 17 Future directions ..........................294 16 Dense Hydrogen 301 1 Introduction .............................301 2 The isolated molecule and low-density solid ...........303 3 Hydrogen under pressure ......................305 3.1 Phase diagram .......................309 3.2 Constraints on crystal structures .............310 3.3 Electronic properties ....................312 4 High pressures and temperatures .................313 4.1 Melting curve ........................315 4.2 High Ρ- Τ vibrational dynamics ..............316 5 Conclusions .............................318 Index 325 HIGH-PRESSURE PHYSICS High-pressure science has undergone a revolution in the last 15 years. The development of intense new x-ray and neutron sources, improved detectors, new instrumentation, greatly increased computation power, and advanced computational algorithms have enabled researchers to determine the behavior of matter at static pressures in excess of 400 GPa. Shock-wave techniques have allowed access to the experimental pressure-temperature range beyond 1 TPa and 10,000 K. lysics introduces the current state of the art in this field. Based on lectures presented by leading researchers at the 63rd Scottish Universities Summer School in Physics, the book summarizes the latest experimental and theoretical techniques. Highlighting applications in a range of physics disciplines—from novel materials synthesis to planetary interiors—this book cuts across many areas and supplies a solid grounding in high-pressure physics. Chapters cover a wide array of topics and techniques, including: • High-pressure devices • The design of pressure cells Electrical transport experiments The fabrication process for customizing diamond anvits Equations of state (EOS) for solids in a range of pressures and temperatures Crystallography, optical spectroscopy, and inelastic x-ray scattering (IXS) techniques Magnetism in solids • The internal structure of Earth and other planets Measurement and control of temperature in high-pressure experiments Solid state chemistry and materials research at high pressure • Liquids and glasses • The study of hydrogen at high density A resource for graduate students and young researchers, this accessible reference provides an overview of key research areas and applications in high-pressure physics. Cr-, I 6000 Broken Sound Parkway, NW КГеЅЅ Suite 300, ftoca Raton, FL 33487 δι f rancis Croup ! 711 Tbird Avenue New Vork, NY 10O1 7 3fnu business 2 Park Square, Milton Park ayforancrtranasgroupcom · Abingdort, Oxon OX? 4 4RN. UK K1G733 ISBN: 978-1 4398-1428-4 ЭОООО 81439I814284 www.crcpress.com
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A Taylor & Francis book
spelling High-pressure physics ed. by John Loveday
Boca Raton, FL [u.a.] CRC Press 2012
xv, 326 p. Ill., graph. Darst. 24 cm
txt rdacontent
n rdamedia
nc rdacarrier
Scottish graduate series
A Taylor & Francis book
Includes bibliographical references and index
High pressure (Science)
High pressure chemistry
Hochdruckchemie (DE-588)4160095-2 gnd rswk-swf
Hochdruckphysik (DE-588)4160113-0 gnd rswk-swf
Hochdruckapparat (DE-588)4160092-7 gnd rswk-swf
Hochdruckphysik (DE-588)4160113-0 s
Hochdruckapparat (DE-588)4160092-7 s
Hochdruckchemie (DE-588)4160095-2 s
DE-604
Loveday, John 1963- Sonstige (DE-588)1024793257 oth
Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=025721219&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis
Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=025721219&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA Klappentext
spellingShingle High-pressure physics
High pressure (Science)
High pressure chemistry
Hochdruckchemie (DE-588)4160095-2 gnd
Hochdruckphysik (DE-588)4160113-0 gnd
Hochdruckapparat (DE-588)4160092-7 gnd
subject_GND (DE-588)4160095-2
(DE-588)4160113-0
(DE-588)4160092-7
title High-pressure physics
title_auth High-pressure physics
title_exact_search High-pressure physics
title_full High-pressure physics ed. by John Loveday
title_fullStr High-pressure physics ed. by John Loveday
title_full_unstemmed High-pressure physics ed. by John Loveday
title_short High-pressure physics
title_sort high pressure physics
topic High pressure (Science)
High pressure chemistry
Hochdruckchemie (DE-588)4160095-2 gnd
Hochdruckphysik (DE-588)4160113-0 gnd
Hochdruckapparat (DE-588)4160092-7 gnd
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High pressure chemistry
Hochdruckchemie
Hochdruckphysik
Hochdruckapparat
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