A concise introduction to additives for thermoplastic polymers
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| 100 | 1 | |a Fink, Johannes Karl |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a A concise introduction to additives for thermoplastic polymers |c Johannes Karl Fink |
| 264 | 1 | |a Hoboken, N.J. |b Wiley |c 2010 | |
| 264 | 1 | |a Salem, Mass. |b Scrivener Pub. | |
| 300 | |a xiii, 267 p. |b ill. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 500 | |a Includes bibliographical references and index | ||
| 650 | 4 | |a Polymers |x Additives | |
| 650 | 4 | |a Thermoplastics | |
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| adam_text | Distils the essence of the twenty-one
most important and commonly used additives
A Concise Introduction to Additives for Thermoplastic Polymers
focuses on additives for thermoplastic polymers and describes
21
of the
most important and commonly used additives from Plasticizers and Fillers
to Optical Brighteners and Anti-Microbial additives. It also includes
chapters on safety and hazards, and prediction of service time models.
While there are many exhaustive and complex books dealing with additives
for polymers, the size of them deter students and many industry engineers
from using them. The purpose of this book, therefore, is to fill this void
and present a concise introduction to this important subject.
Written in an accessible and practical style, the author introduces the
reader to the complex subject of plastics additives in an engaging manner.
His ability to be concise is the result of his teaching courses on the subject
and using his own lecture notes for material. This book comprises the
author s course notes so that a larger public can benefit from his knowledge.
A Concise Introduction to Additives for Thermoplastic Polymers is
the ideal primer for students who will later work in polymer science or
the development of plastics formulation, as well as industry engineers and
specialists who want to have a deeper knowledge of the plastics industry.
JOHANNES KARL FINK PhD is Professor of Macromolecular
Chemistry at
Montanuniversität, Loeben,
Austria. His industry
and academic career spans more than
30
years in the fields of
polymers, and his research interests include characterization,
flame retardancy, thermodynamics and degradation of polymers,
pyrolysis, and adhesives. Professor Fink has published several books on
physical chemistry and polymer science.
ISBN
WILEY
wiley.com www.scrivenerpublishing.com
609552
Contents
Preface
xiii
1
Introduction
1
1.1
Classification
1
References
3
2
Plasticizers
5
2.1
Principle of Action
6
2.2
Principle of Selection
6
2.3
Characterization
7
2.4
Risks and Drawbacks
8
2.4.1
Leaching
8
2.4.2
Inherent
Toxicity
9
2.5
Classes of Plasticizers
9
2.5.1
Phthalate Plasticizers
9
2.5.2
Cyclohexanoic Diesters
12
2.5.3
Phophate Plasticizers
13
2.5.4
Aliphatic Esters
13
2.5.5
Polymeric Plasticizers
14
2.5.6
Ionic Liquids
15
2.6
Specific Examples of Application
16
2.6.1
Heat Shrinkable Films
16
2.6.2
Adhesive Compositions
17
2.6.3
Interlayer Films for Safety Glasses
17
2.6.4
Electrolyte Membranes
18
2.6.5
Porous Electrodes
18
2.6.6
Biodegradable Polymers
19
2.6.7
Plasticizers for Energetic Polymers
20
References
21
vi
Contents
3
Fillers
25
3.1
Surface Modification
25
3.1.1
Siloxanes
25
3.1.2
Dispersion and Coupling Additives
25
3.2
Special Applications
29
3.2.1
Rame Retardant
Fillers
29
3.2.2
Conductive Fillers
30
3.2.3
Solder Precoated Fillers
32
3.2.4
Nano
Clays
33
3.2.5
Mixed Matrix Membranes
34
References
34
4
Colorants
37
4.1
Physics Behind a Color
37
4.1.1
Human Eye
37
4.1.2
Tristimulus Values
37
4.1.3
Color Spaces
39
4.2
Color Index
40
4.3
Test Standards
41
4.4
Pigments
43
4.5
Organic Colorants
43
References
47
5
Optical Brighterners
49
5.1
Basic Principles
50
5.2
Measurement
51
5.3
Inorganic Brighteners
52
5.4
Organic Optical Brighteners
52
5.4.1
Reactive Optical Brighteners
52
5.4.2
Melt Extrusion
54
5.4.3
Photographic Supports
55
References
56
6
Antimicrobial Additives
59
6.1
Modes of Action
59
6.1.1
Types of Irritations
60
6.2
Plasticizers
60
Contents
vii
6.3 Special
Formulations
65
6.3.1
Contact
Lenses
65
6.3.2
Food Packaging
66
6.3.3
Polymers with Inherent
Antimicrobial Properties
67
References
68
Flame
Retardants
71
7.1
Mechanisms of Flame
Retardants
71
7.1.1
Flame Cooling of Halogens
71
7.2
Smoke Suppressants
73
7.3
Admixed Additives
74
7.4
Bonded Additives
77
7.4.1
Examples of Polymers
77
References
83
Lubricants
87
8.1
Principle of Action
87
8.2
Methods of Incorporation
88
8.2.1
Conventional Method
88
8.2.2
Separate Delivery of the Lubricant
88
8.3
Types of Lubricants
89
8.3.1
Alcohols
89
8.3.2
Fatty Acids, Esters and Amides
90
8.3.3
Waxes
90
8.3.4
Polymeric Lubricants
91
8.4
Special Applications
91
8.4.1
PVC
91
8.4.2
Chlorinated
PVC
91
8.4.3
Electically Conductive Polymers
92
References
92
Antistatic Additives
95
9.1
Types of Additives
95
9.2
Areas of Application
96
9.3
Additives in Detail
98
9.3.1
Conventional Additives
98
9.3.2
Polymeric Additives
100
viti
Contents
9.3.3
External Antistatic
Additives 101
9.3.4
Intrinsically Antistatic Compositions
101
9.3.5
Conductive Fillers
101
References
104
10
Slip Agents
107
10.1
Basic Principles of Action
107
10.2
Compounds
109
10.3
Special Formulations
110
10.3.1
Polyethylene terephthalate)
110
10.3.2
Formulations for Poly(ethylene) 111
References 111
11
Surface Improvers
113
11.1
Additives
114
11.1.1
Fluorocarbon Compounds
114
11.1.2
Acrylics
114
11.1.3
Modified Pigments
115
11.1.4
Organic Salts
116
References
116
12
Nucleating Agents
119
12.1
Crystalline Polymers
120
12.1.1
Crystal Structures
120
12.1.2
Modification of Properties by
Crystallinity
120
12.2
Experimental Methods
121
12.2.1
Nucleation Technologies
121
12.2.2
Characterization of Polymer
Crystallization
121
12.3
Classes of Nucleating Agents
122
12.3.1
Inorganic Nucleating Agents
122
12.3.2
Sorbitol Compounds
123
12.3.3
Phosphates
124
12.3.4
Carbon Nanotubes
124
12.3.5
Coupled Nucleating Agents
124
Contents ix
12.4
Crystallization Accelerators
124
12.5
Clarifying Agents
125
References
125
13
Antifogging Additives
127
13.1
Field of Use
127
13.2
Principles of Action
128
13.2.1
Thermodynamics of Surfaces
128
13.3
Conventional Compounds
130
13.4
Compounds for Grafting
133
References
135
14
Antiblocking Additives
137
14.1
Examples of Uses
138
14.1.1
Film Resins
138
14.1.2
Sealable Coatings
140
14.1.3
Membranes
141
14.1.4
Poly(vinyl butyral)
142
References
144
15
Hydrolysis
145
15.1
Hydrolytic Degradation
145
15.1.1
Ordinary Hydrolysis
145
15.1.2
Enzymatic Hydrolysis
146
15.1.3
Stabilization
146
15.2
Polymers
146
15.2.1
Poly(ester)s
147
15.2.2
Poly(ester urethane)s
147
15.2.3
Poly(lactide)s
148
References
149
16
Dehydrochlorination Stabilizers
151
16.1
Dehydrochlorination of
PVC
151
16.2
Stabilizers
152
16.2.1
Alkyl
Tin Compounds
154
16.2.2
Mixed Metal Compounds
155
16.2.3 ß-Diketones 155
χ
Contents
16.2.4
Epoxidized fatty acids
155
16.2.5
Hydrotalcite Clays
156
16.2.6
Zeolites
157
16.2.7
Costabilizers
158
References
158
17
Acid Scavengers
161
17.1
Acid Scavenging
161
17.2
Examples of Formulation
162
17.2.1
Poly(olefin)s
162
17.2.2
Polyethylene terephthalate)
163
17.2.3
Poly(urethane)s
163
References
163
18
Metal Deactivators
165
18.1
Action of Metals in Polymers
165
18.2
Usage
166
18.2.1
Residues of Catalysts
166
18.2.2
Metallic Reinforcing Parts
166
18.3
Examples of Metal Deactivators
167
18.3.1
Side Effects
169
References
170
19
Oxidative Degradation
173
19.1
Autoxidation
173
19.2
Inhibition of Autoxidation
174
References
183
20
Degradation by Light
185
20.1
Photolysis
189
20.1.1
Redox
Catalysis
190
20.1.2
Scavenging
190
20.2
Photooxdation
191
20.3
UV Stabilizers
193
References
195
21
Blowing Agents
197
21.1
Blowing Agents
197
21.1.1
Physical Blowing Agents
198
Contents xi
21.1.2 Chemical
Blowing
Agents
199
21.2
Ozone Depletion
Potential 202
21.3 Test
Methods
203
21.4 Special Applications 203
21.4.1 Poly(urethane)
Foams
203
21.4.2 Poly(imide)
Foams
205
21.4.3
Poly(ethylene)
Foams
205
References
206
22
Compatibilizers
209
22.1
Estimation of Compatibility
210
22.1.1
Glass Transition Temperature
210
22.1.2 Hildebrand
Solubility Parameters
211
22.2.
Compatibilizers
215
22.2.1
Classification
217
22.2.2
Reactive Processing
221
22.3
Special Examples
221
22.3.1
Block Copolymers as Compatibilizers
221
22.3.2
Poly(olefin) Blends
222
22.3.3
Poly(amide) Blends
223
22.3.4
Polycarbonate) Blends
224
22.3.5
Composites of
PVC
and Cellulosic
Materials
225
22.3.6
Packaging Applications
226
References
227
23
Prediction of Service Time
233
23.1
Accelerated Aging
233
23.1.1
Cumulative Material Damage
233
23.1.2
Arrhenius Extrapolation
234
23.1.3
Interference of Phase Transitions
235
23.2
Theory of Critical Distances
235
23.3
Monte Carlo Methods
236
23.4
Issues in Matrix Composites
236
References
236
24
Safety and Hazards
239
24.1
Plasticizers
239
24.1.1
Di(2-ethylhexyl)phthalate
239
xii Contents
24.1.2 Ingestion
of PVC
240
24.1.3 Tricresyl Phosphate
242
24.2 Flame
Retardants
242
24.2.1 HET-Acid
242
24.2.2 Brominated Diphenyl
Ethers
243
24.3 Antifogging
Agents
243
24.4
Other
244
24.4.1 Bisphenol
A
244
24.4.2 Azodicarbonamide
244
References
245
Index
249
Acronyms
249
Chemicals
251
General Index
261
|
| any_adam_object | 1 |
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| dewey-hundreds | 600 - Technology (Applied sciences) |
| dewey-ones | 668 - Technology of other organic products |
| dewey-raw | 668.4/23 |
| dewey-search | 668.4/23 |
| dewey-sort | 3668.4 223 |
| dewey-tens | 660 - Chemical engineering |
| discipline | Chemie / Pharmazie Physik |
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| id | DE-604.BV039591728 |
| illustrated | Illustrated |
| indexdate | 2024-07-10T00:06:58Z |
| institution | BVB |
| isbn | 9780470609552 |
| language | English |
| lccn | 2009051011 |
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| record_format | marc |
| spelling | Fink, Johannes Karl Verfasser aut A concise introduction to additives for thermoplastic polymers Johannes Karl Fink Hoboken, N.J. Wiley 2010 Salem, Mass. Scrivener Pub. xiii, 267 p. ill. txt rdacontent n rdamedia nc rdacarrier Includes bibliographical references and index Polymers Additives Thermoplastics Thermoplast (DE-588)4059844-5 gnd rswk-swf Zusatz (DE-588)4132717-2 gnd rswk-swf Polymere (DE-588)4046699-1 gnd rswk-swf Polymere (DE-588)4046699-1 s Thermoplast (DE-588)4059844-5 s DE-604 Zusatz (DE-588)4132717-2 s Digitalisierung UB Bayreuth application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=024442808&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis Digitalisierung UB Bayreuth application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=024442808&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA Klappentext |
| spellingShingle | Fink, Johannes Karl A concise introduction to additives for thermoplastic polymers Polymers Additives Thermoplastics Thermoplast (DE-588)4059844-5 gnd Zusatz (DE-588)4132717-2 gnd Polymere (DE-588)4046699-1 gnd |
| subject_GND | (DE-588)4059844-5 (DE-588)4132717-2 (DE-588)4046699-1 |
| title | A concise introduction to additives for thermoplastic polymers |
| title_auth | A concise introduction to additives for thermoplastic polymers |
| title_exact_search | A concise introduction to additives for thermoplastic polymers |
| title_full | A concise introduction to additives for thermoplastic polymers Johannes Karl Fink |
| title_fullStr | A concise introduction to additives for thermoplastic polymers Johannes Karl Fink |
| title_full_unstemmed | A concise introduction to additives for thermoplastic polymers Johannes Karl Fink |
| title_short | A concise introduction to additives for thermoplastic polymers |
| title_sort | a concise introduction to additives for thermoplastic polymers |
| topic | Polymers Additives Thermoplastics Thermoplast (DE-588)4059844-5 gnd Zusatz (DE-588)4132717-2 gnd Polymere (DE-588)4046699-1 gnd |
| topic_facet | Polymers Additives Thermoplastics Thermoplast Zusatz Polymere |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=024442808&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=024442808&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT finkjohanneskarl aconciseintroductiontoadditivesforthermoplasticpolymers |