Kinetics of chemical reactions decoding complexity
Gespeichert in:
| Hauptverfasser: | , |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Weinheim
Wiley-VCH
2011
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
MARC
| LEADER | 00000nam a2200000 c 4500 | ||
|---|---|---|---|
| 001 | BV039122711 | ||
| 003 | DE-604 | ||
| 005 | 20131118 | ||
| 007 | t| | ||
| 008 | 110706s2011 xx ad|| |||| 00||| eng d | ||
| 020 | |a 9783527317639 |9 978-3-527-31763-9 | ||
| 035 | |a (OCoLC)746135221 | ||
| 035 | |a (DE-599)BVBBV039122711 | ||
| 040 | |a DE-604 |b ger |e rakwb | ||
| 041 | 0 | |a eng | |
| 049 | |a DE-634 |a DE-29T |a DE-11 |a DE-19 |a DE-703 |a DE-91G |a DE-92 |a DE-355 |a DE-83 | ||
| 082 | 0 | |a 541.394 |2 22//ger | |
| 082 | 0 | |a 541.394 |2 22 | |
| 084 | |a VE 5800 |0 (DE-625)147124:253 |2 rvk | ||
| 084 | |a CHE 163f |2 stub | ||
| 100 | 1 | |a Marin, Guy B. |e Verfasser |0 (DE-588)1014012082 |4 aut | |
| 245 | 1 | 0 | |a Kinetics of chemical reactions |b decoding complexity |c Guy B. Marin and Gregory S. Yablonsky |
| 264 | 1 | |a Weinheim |b Wiley-VCH |c 2011 | |
| 300 | |a XVII, 428 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 650 | 0 | 7 | |a Reaktionskinetik |0 (DE-588)4048655-2 |2 gnd |9 rswk-swf |
| 689 | 0 | 0 | |a Reaktionskinetik |0 (DE-588)4048655-2 |D s |
| 689 | 0 | |5 DE-604 | |
| 700 | 1 | |a Yablonsky, Gregory S. |e Verfasser |0 (DE-588)1013915542 |4 aut | |
| 856 | 4 | 2 | |m DNB Datenaustausch |q application/pdf |u http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=024141238&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |3 Inhaltsverzeichnis |
| 943 | 1 | |a oai:aleph.bib-bvb.de:BVB01-024141238 | |
Datensatz im Suchindex
| DE-19_call_number | 1801/VE 5800 M337 |
|---|---|
| DE-19_location | 85 |
| DE-BY-TUM_call_number | 0302 CHE 163f 2011 A 7293 |
| DE-BY-TUM_katkey | 1785341 |
| DE-BY-TUM_location | 03 |
| DE-BY-TUM_media_number | 040071375509 040080105284 |
| DE-BY-UBM_katkey | 4497532 |
| DE-BY-UBM_media_number | 41624517320013 |
| _version_ | 1823054829759496192 |
| adam_text | IMAGE 1
CONTENTS
PREFACE XV
1 INTRODUCTION 1
1.1 OVERVIEW I
1.2 DECODING COMPLEXITY IN CHEMICAL KINETICS 2 1.3 THREE TYPES OF
CHEMICAL KINETICS 3 1.3.1 APPLIED KINETICS 3 1.3.2 DETAILED KINETICS 3
1.3.3 MATHEMATICAL KINETICS 4 1.4 CHALLENGES AND GOALS. HOW TO KILL
CHEMICAL COMPLEXITY 4 1.4.1 GRAY-BOX APPROACH 4 1.4.2 ANALYSIS OF
KINETIC FINGERPRINTS 5 1.4.3 NON-STEADY-STATE KINETIC SCREENING 6 1.5
WHAT OUR BOOK IS NOT ABOUT. OUR BOOK AMONG OTHER
BOOKS ON CHEMICAL KINETICS 6 1.6 THE LOGIC IN THE REASONING OF THIS BOOK
7 1.7 HOW CHEMICAL KINETICS AND MATHEMATICS ARE INTERWOVEN IN THIS BOOK
7 1.8 HISTORY OF CHEMICAL KINETICS 8
2 CHEMICAL REACTIONS AND COMPLEXITY 17
2.1 INTRODUCTION 17
2.2 ELEMENTARY REACTIONS AND THE MASS-ACTION LAW 19 2.2.1 HOMOGENEOUS
REACTIONS 19 2.2.2 HETEROGENEOUS REACTIONS 21 2.2.3 RATE EXPRESSIONS 22
2.3 THE REACTION RATE AND NET RATE OF PRODUCTION OF A
COMPONENT - A BIG DIFFERENCE 23 2.4 DIMENSION OF THE KINETIC PARAMETERS
AND THEIR ORDER OF MAGNITUDE 25
BIBLIOGRAFISCHE INFORMATIONEN HTTP://D-NB.INFO/1008658715
DIGITALISIERT DURCH
IMAGE 2
VI I CONTENTS
2.5 CONCLUSIONS 26
NOTATION 27
3 KINETIC EXPERIMENTS: CONCEPTS AND REALIZATIONS 29 3.1 INTRODUCTION 29
3.2 EXPERIMENTAL REQUIREMENTS 29 3.3 MATERIAL BALANCES 30
3.4 CLASSIFICATION OF REACTORS FOR KINETIC EXPERIMENTS 31 3.4.1
STEADY-STATE AND NON-STEADY-STATE REACTORS 31 3.4.2 TRANSPORT IN
REACTORS 32 3.4.3 IDEAL REACTORS 32
3.4.3.1 BATCH REACTOR 32 3.4.3.2 CONTINUOUS STIRRED-TANK REACTOR 33
3.4.3.3 PLUG-FLOW REACTOR 34 3.4.4 IDEAL REACTORS WITH SOLID CATALYST 35
3.4.4.1 BATCH REACTOR 35 3.4.4.2 CONTINUOUS STIRRED-TANK REACTOR 35
3.4.4.3 PLUG-FLOW REACTOR 36 3.4.4.4 PULSE REACTOR 37 3.4.5
DETERMINATION OF THE NET RATE OF PRODUCTION 37
3.5 FORMAL ANALYSIS OF TYPICAL IDEAL REACTORS 38 3.5.1 BATCH REACTOR 38
3.5.1.1 IRREVERSIBLE REACTION 38 3.5.1.2 REVERSIBLE REACTION 39 3.5.1.3
HOW TO DISTINGUISH PARALLEL REACTIONS FROM CONSECUTIVE REACTIONS 41
3.5.2 STEADY-STATE PLUG-FLOW REACTOR 46
3.5.3 NON-STEADY-STATE CONTINUOUS STIRRED-TANK REACTOR 46 3.5.3.1
IRREVERSIBLE REACTION 46 3.5.3.2 REVERSIBLE REACTION 47 3.5.4 THIN-ZONE
TEMPORAL-ANALYSIS-OF-PRODUCTS REACTOR 48 3.6 KINETIC-MODEL-FREE ANALYSIS
49 3.6.1 STEADY STATE 49
3.6.2 NON-STEADY STATE 52 3.6.2.1 CONTINUOUS STIRRED-TANK REACTOR 51
3.6.2.2 PLUG-FLOW REACTOR 52 3.7 DIAGNOSTICS OF KINETIC EXPERIMENTS IN
HETEROGENEOUS
CATALYSIS 52
3.7.1 GRADIENTS AT REACTOR AND CATALYST-PELLET SCALE 52 3.7.2
EXPERIMENTAL DIAGNOSTICS AND GUIDELINES 53 3.7.2.1 TEST FOR EXTERNAL
MASS TRANSFER EFFECT 54 3.7.2.2 TEST FOR INTERNAL MASS TRANSPORT EFFECT
55 3.7.2.3 GUIDELINES 56
IMAGE 3
CONTENTS VII
3.7.3 THEORETICAL DIAGNOSTICS 56
3.7.3.1 EXTERNAL MASS-TRANSFER 57 3.7.3.2 EXTERNAL HEAT-TRANSFER 59
3.7.3.3 INTERNAL MASS TRANSPORT 60 3.7.3.4 INTERNAL HEAT TRANSPORT 64
3.7.3.5 NON-STEADY-STATE OPERATION 64
NOTATION 65
4 CHEMICAL BOOK-KEEPING: LINEAR ALGEBRA IN CHEMICAL KINETICS 69 4.1
BASIC ELEMENTS OF LINEAR ALGEBRA 69 4.2 LINEAR ALGEBRA AND COMPLEXITY OF
CHEMICAL REACTIONS 71
4.2.1 ATOMIC COMPOSITION OF COMPONENTS: MOLECULES CONSIST OF ATOMS 72
4.2.1.1 MOLECULAR MATRIX 72 4.2.1.2 LINEAR ALGEBRA AND LAWS OF MASS
CONSERVATION 72
4.2.1.3 KEY COMPONENTS AND THEIR NUMBER 74 4.2.2 STOICHIOMETRY OF
CHEMICAL REACTIONS: REACTIONS CONSIST OF CHEMICAL COMPONENTS 76
4.2.2.1 STOICHIOMETRIC MATRIX 76 4.2.2.2 SIMILARITY AND DIFFERENCE
BETWEEN THE CONSERVATION LAW FOR
CHEMICAL ELEMENTS AND THE KINETIC MASS-CONSERVATION LAW 79 4.2.2.3
SIMILARITY AND DIFFERENCE BETWEEN THE NUMBER OF KEY COMPONENTS AND THE
NUMBER OF KEY REACTIONS 79 4.2.3 DETAILED MECHANISM OF COMPLEX
REACTIONS: COMPLEX REACTIONS
CONSIST OF ELEMENTARY REACTIONS 79 4.2.3.1 MECHANISMS AND HORIUTI
NUMBERS 79 4.2.3.2 MATRICES AND INDEPENDENT ROUTES OF COMPLEX REACTIONS
86 4.3 CONCLUSIONS 89
NOTATION 89
5 STEADY-STATE CHEMICAL KINETICS: A PRIMER 93 5.1 INTRODUCTION TO GRAPH
THEORY 93 5.2 REPRESENTATION OF COMPLEX MECHANISMS AS GRAPHS 94 5.2.1
SINGLE-ROUTE MECHANISMS 95
5.2.2 SINGLE-ROUTE MECHANISM WITH A BUFFER STEP 97 5.2.3 TWO-ROUTE
MECHANISMS 98 5.2.4 NUMBER OF INDEPENDENT CYCLES AND HORIUTI S RULE 100
5.3 HOW TO DERIVE THE REACTION RATE FOR A COMPLEX
REACTION 104
5.3.1 INTRODUCTION 104 5.3.2 KINETIC CRAMER S RULE AND TREES OF THE
CHEMICAL GRAPH 104
IMAGE 4
VIII CONTENTS
5.3.3 FORWARD AND REVERSE REACTION RATES 111
5.3.4 SINGLE-ROUTE LINEAR MECHANISM - GENERAL CASE 113 5.3.5 HOW TO FIND
THE KINETIC EQUATION FOR THE REVERSE REACTION: THE HORIUTI-BORESKOV
PROBLEM 114
5.3.6 WHAT ABOUT THE OVERALL REACTION - A PROVOCATIVE OPINION 116 5.4
DERIVATION OF STEADY-STATE KINETIC EQUATIONS FOR A SINGLE- ROUTE
MECHANISM - EXAMPLES 118
5.4.1 TWO-STEP MECHANISMS 119 5.4.1.1 MICHAELIS-MENTEN MECHANISM 119
5.4.1.2 WATER-GAS SHIFT REACTION 120 5.4.1.3 LIQUID-PHASE HYDROGENATION
121
5.4.2 THREE-STEP MECHANISMS 122 5.4.2.1 OXIDATION OF SO 2 122 5.4.2.2
COUPLING REACTION 123
5.4.3 FOUR-STEP MECHANISMS 124 5.4.4 FIVE-STEP MECHANISMS 126 5.4.5
SINGLE-ROUTE LINEAR MECHANISMS WITH A BUFFER STEP 127 5.5 DERIVATION OF
STEADY-STATE KINETIC EQUATIONS FOR MULTI-ROUTE
MECHANISMS: KINETIC COUPLING 129 5.5.1 CYCLES HAVING A COMMON
INTERMEDIATE 131 5.5.2 CYCLES HAVING A COMMON STEP 132 5.5.3 CYCLES
HAVING TWO COMMON STEPS 134 5.5.4 DIFFERENT TYPES OF COUPLING BETWEEN
CYCLES 134
NOTATION 135
6 STEADY-STATE CHEMICAL KINETICS: MACHINERY 139 6.1 ANALYSIS OF RATE
EQUATIONS 139 6.1.1 PARAMETERS: DEPENDENCE ON TEMPERATURE AND NUMBER OF
IDENTIFIABLE PARAMETERS 139
6.1.2 SIMPLIFYING ASSUMPTIONS 142 6.1.2.1 FAST STEP 142 6.1.2.2
RATE-LIMITING STEP 143 6.1.2.3 QUASI-EQUILIBRATED STEPS 144 6.1.2.4
IRREVERSIBLE STEP(S) 145
6.1.2.5 DEPENDENCE OF THE REACTION RATE ON CONCENTRATIONS 146 6.2
APPARENT KINETIC PARAMETERS: REACTION ORDER AND ACTIVATION ENERGY 147
6.2.1 DEFINITIONS 147
6.2.2 TWO-STEP MECHANISM OF AN IRREVERSIBLE REACTION 148 6.2.2.1
APPARENT PARTIAL REACTION ORDER 148 6.2.2.2 APPARENT ACTIVATION ENERGY
150 6.2.3 MORE COMPLICATED CASES 150 6.2.3.1 APPARENT PARTIAL REACTION
ORDER 151
IMAGE 5
CONTENTS IX
6.2.3.2 APPARENT ACTIVATION ENERGY 157
6.2.4 SOME FURTHER COMMENTS 158 6.3 HOW TO REVEAL MECHANISMS BASED ON
STEADY-STATE KINETIC DATA 158 6.3.1 ASSUMPTIONS 158 6.3.2 DIRECT AND
INVERSE PROBLEMS OF KINETIC MODELING 160
6.3.3 MINIMAL AND NON-MINIMAL MECHANISMS 160 6.3.3.1 TWO-STEP CATALYTIC
MECHANISMS 161 6.3.3.2 THREE-STEP CATALYTIC MECHANISMS 161 6.3.3.3
FOUR-STEP CATALYTIC MECHANISMS 163 63.3A FIVE-STEP CATALYTIC MECHANISMS
163 6.3.3.5 SUMMARY 163
6.3.4 WHAT KIND OF KINETIC MODEL DO WE NEED TO DESCRIBE STEADY-STATE
KINETIC DATA AND FOR DECODING MECHANISMS? 164 6.3.4.1 KINETIC RESISTANCE
164 6.3.4.2 ANALYSIS OF THE KINETIC RESISTANCE IN IDENTIFYING AND
DECODING
MECHANISMS AND MODELS 165 6.3.4.3 CONCENTRATION TERMS OF THE KINETIC
RESISTANCE AND THE STRUCTURE OF THE DETAILED MECHANISM 166 6.3.4.4
PRINCIPLE OF COMPONENT SEGREGATION 270 6.4 CONCLUSIONS 172
NOTATION 172
7 LINEAR AND NONLINEAR RELAXATION. STABILITY 275 7.1 INTRODUCTION 275
7.1.1 LINEAR RELAXATION 177 7.1.2 RELAXATION TIMES AND STEADY-STATE
REACTION RATE 179 7.1.2.1 RELAXATION TIMES AND KINETIC RESISTANCE 179
7.1.2.2 TEMKIN S RULE. IS IT VALID? 181 7.1.3 FURTHER COMMENTS 183
7.2 RELAXATION IN A CLOSED SYSTEM 283 7.2.1 PRINCIPLE OF DETAILED
EQUILIBRIUM 183 73 STABILITY - GENERAL CONCEPT 187
7.3.1 ELEMENTS OF THE QUALITATIVE THEORY OF DIFFERENTIAL EQUATIONS 287
7.3.2 LOCAL STABILITY - RIGOROUS DEFINITION 290 7.3.3 LOCAL STABILITY -
SYSTEM WITH TWO VARIABLES 291 7.3.3.1 REAL ROOTS 193 7.3.3.2 IMAGINARY
ROOTS 194 7.3.4 ANALYSIS OF GLOBAL DYNAMICS 295 7.4 SIMPLIFICATIONS OF
NON-STEADY-STATE MODELS 297 7.4.1 ABUNDANCE AND LINEARIZATION 197
7.4.2 FAST STEP - EQUILIBRIUM APPROXIMATION 2 98
IMAGE 6
CONTENTS
7.4.3 RATE-LIMITING STEP APPROXIMATION 199 7.4.4 QUASI-STEADY-STATE
APPROXIMATION 200 NOTATION 206
8 NONLINEAR MECHANISMS: STEADY STATE AND DYNAMICS 221 8.1 CRITICAL
PHENOMENA 211
8.2 ISOTHERMAL CRITICAL EFFECTS IN HETEROGENEOUS CATALYSIS: EXPERIMENTAL
FACTS 213 8.2.1 MULTIPLICITY OF STEADY STATES 213 8.2.2 SELF-SUSTAINED
OSCILLATIONS OF THE REACTION RATE IN
HETEROGENEOUS CATALYTIC REACTIONS 215 8.2.3 DIVERSITY OF CRITICAL
PHENOMENA AND THEIR CAUSES 226 8.3 IDEAL SIMPLE MODELS: STEADY STATE 217
8.3.1 PARALLEL AND CONSECUTIVE ADSORPTION MECHANISMS 227
8.3.2 IMPACT MECHANISMS 218 8.3.3 SIMPLEST MECHANISM FOR THE
INTERPRETATION OF MULTIPLICITY OF STEADY STATES 221 8.3.4 HYSTERESIS:
INFLUENCE OF REACTION REVERSIBILITY 227 8.3.5 COMPETITION OF
INTERMEDIATES 233 8.4 IDEAL SIMPLE MODELS: DYNAMICS 237 8.4.1 RELAXATION
CHARACTERISTICS OF THE PARALLEL ADSORPTION
MECHANISM 237
8.4.2 CATALYTIC OSCILLATORS 244 8.4.2.1 SIMPLEST CATALYTIC OSCILLATOR
244 8.4.2.2 RELAXATION OF SELF-SUSTAINED OSCILLATIONS: MODEL 250 8.4.2.3
OTHER CATALYTIC OSCILLATORS 250 8.4.3 FINE STRUCTURE OF KINETIC
DEPENDENCES 254 8.5 STRUCTURE OF THE DETAILED MECHANISM AND CRITICAL
PHENOMENA: RELATIONSHIPS 256 8.5.1 MECHANISMS WITHOUT INTERACTION
BETWEEN INTERMEDIATES 256 8.5.2 HORN-TACKSON-FEINBERG MECHANISM 258 8.6
NON-IDEAL FACTORS 262
8.7 CONCLUSIONS 263
NOTATION 263
9 KINETIC POLYNOMIALS 273
9.1 LINEAR INTRODUCTION TO THE NONLINEAR PROBLEM: REMINDER 273 9.2
NONLINEAR INTRODUCTION 276 9.3 PRINCIPLES OF THE APPROACH:
QUASI-STEADY-STATE
APPROXIMATION. MATHEMATICAL BASIS 278 9.3.1 INTRODUCTION 278
9.3.2 EXAMPLES 279
IMAGE 7
CONTENTS XI
9.4 KINETIC POLYNOMIALS: DERIVATION AND PROPERTIES 281
9.4.1 RESULTANT REACTION RATE: A NECESSARY MATHEMATICAL BASIS 281 9.4.2
PROPERTIES OF THE KINETIC POLYNOMIAL 283 9.4.3 EXAMPLES OF KINETIC
POLYNOMIALS 285 9.4.3.1 ELEY-RIDEAL MECHANISM 285 9.4.3.2 LANGMUIR
MECHANISM 286
9.5 KINETIC POLYNOMIAL: CLASSICAL APPROXIMATIONS AND SIMPLIFICATIONS 287
9.5.1 RATE-LIMITING STEP 288 9.5.2 VICINITY OF THERMODYNAMIC EQUILIBRIUM
290 9.5.3 THERMODYNAMIC BRANCH 291
9.6 APPLICATION OF RESULTS OF THE KINETIC-POLYNOMIAL THEORY: CYCLES
ACROSS AN EQUILIBRIUM 294 9.7 CRITICAL SIMPLIFICATION 301 9.7.1 CRITICAL
SIMPLIFICATION: A SIMPLE EXAMPLE 301 9.7.2 CRITICAL SIMPLIFICATION AND
LIMITATION 308 9.7.3 PRINCIPLE OF CRITICAL SIMPLIFICATION: GENERAL
UNDERSTANDING AND
APPLICATION 309
9.8 CONCLUDING REMARKS 310 APPENDIX 320 NOTATION 322
10 TEMPORAL ANALYSIS OF PRODUCTS: PRINCIPLES, APPLICATIONS AND THEORY
329 10.1 INTRODUCTION 319
10.2 THE TAP EXPERIMENT 321 10.3 DESCRIPTION AND OPERATION OF A TAP
REACTOR SYSTEM 322 10.4 BASIC PRINCIPLES OF TAP 324 10.5 POSITION OF TAP
AMONG OTHER KINETIC METHODS 326 10.5.1 UNIFORMITY OF THE ACTIVE ZONE 327
10.5.1.1 CONTINUOUS STIRRED-TANK REACTOR 327 10.5.1.2 PLUG-FLOW REACTOR
327 10.5.1.3 TAP REACTOR 327
10.5.2 DOMAIN OF CONDITIONS 327 10.5.3 POSSIBILITY OF OBTAINING RELEVANT
KINETIC INFORMATION 328 10.5.4 RELATIONSHIP BETWEEN OBSERVED KINETIC
CHARACTERISTICS AND CATALYST PROPERTIES 328
10.5.5 MODEL-FREE KINETIC DATA INTERPRETATION 329 10.5.6 SUMMARY 330
10.6 QUALITATIVE TAP DATA ANALYSIS. EXAMPLES 332 10.6.1 SINGLE-PULSE TAP
EXPERIMENTS 332 10.6.2 PUMP-PROBE TAP EXPERIMENTS 333 10.6.3 MULTIPULSE
TAP EXPERIMENTS 336
IMAGE 8
XII CONTENTS
10.7 QUANTITATIVE TAP DATA DESCRIPTION. THEORETICAL
ANALYSIS 338
10.7.1 ONE-ZONE REACTOR 338 10.7.1.1 DIFFUSION ONLY 338 10.7.1.2
IRREVERSIBLE ADSORPTION 342 10.7.1.3 REVERSIBLE ADSORPTION 343 10.7.2
TWO- AND THREE-ZONE REACTORS 344 10.7.3 THIN-ZONE TAP REACTOR
CONFIGURATION 345 10.7.4 MOMENT-BASED QUANTITATIVE DESCRIPTION OF TAP
EXPERIMENTS 347
10.8 KINETIC MONITORING: STRATEGY OF INTERROGATIVE KINETICS 350 10.8.1
STATE-BY-STATE KINETIC MONITORING. EXAMPLE: OXIDATION OF FURAN 350
10.8.2 STRATEGY OF INTERROGATIVE KINETICS 357 10.9 THEORETICAL FRONTIERS
358
10.9.1 GLOBAL TRANSFER MATRIX EQUATION 358 10.9.2 Y PROCEDURE 359
10.9.2.1 PRINCIPLES OF THE SOLUTION 360 10.9.2.2 EXACT MATHEMATICAL
SOLUTION 363 10.9.2.3 HOW TO RECONSTRUCT THE ACTIVE ZONE CONCENTRATION
AND
REACTION RATE IN PRACTICE 364 10.9.2.4 NUMERICAL EXPERIMENTS 366
10.9.2.5 SUMMARY OF THE Y PROCEDURE 369 10.9.3 PROBABILISTIC THEORY OF
SINGLE-PARTICLE TAP EXPERIMENTS 371
10.10 CONCLUSIONS: WHAT NEXT? 372 NOTATIONS 373
11 DECODING THE PAST 383
11.1 CHEMICAL TIME AND INTERMEDIATES. EARLY HISTORY 383 11.2 DISCOVERY
OF CATALYSIS AND CHEMICAL KINETICS 383 11.3 GULDBERG AND WAAGE S
BREAKTHROUGH 385 11.4 VAN T HOFPS REVOLUTION: ACHIEVEMENTS AND
CONTRADICTIONS 386 11.4.1 UNDISPUTABLE ACHIEVEMENTS 386 11.4.2
CONTRADICTIONS 386 11.5 POST-VAN T HOFF PERIOD: REACTION IS NOT A
SINGLE-ACT
DRAMA 387
11.6 ALL-IN-ALL CONFUSION: ATTEMPTS AT UNDERSTANDING 388 11.7 OUT OF
CONFUSION: PHYSICOCHEMICAL UNDERSTANDING 389 11.8 TOWARDS MATHEMATICAL
CHEMICAL KINETICS 390 NOTATION 395
IMAGE 9
CONTENTS I XIII
12 DECODING THE FUTURE 401
12.1 A GREAT ACHIEVEMENT, A GREAT ILLUSION 401 12.2 A NEW PARADIGM FOR
DECODING CHEMICAL COMPLEXITY 402 12.2.1 ADVANCED EXPERIMENTAL KINETIC
TOOLS 403 12.2.2 NEW MATHEMATICAL TOOLS: CHEMICAL KINETICS AND
MATHEMATICS 405
GLOSSARY 409 INDEX 415
|
| any_adam_object | 1 |
| author | Marin, Guy B. Yablonsky, Gregory S. |
| author_GND | (DE-588)1014012082 (DE-588)1013915542 |
| author_facet | Marin, Guy B. Yablonsky, Gregory S. |
| author_role | aut aut |
| author_sort | Marin, Guy B. |
| author_variant | g b m gb gbm g s y gs gsy |
| building | Verbundindex |
| bvnumber | BV039122711 |
| classification_rvk | VE 5800 |
| classification_tum | CHE 163f |
| ctrlnum | (OCoLC)746135221 (DE-599)BVBBV039122711 |
| dewey-full | 541.394 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 541 - Physical chemistry |
| dewey-raw | 541.394 |
| dewey-search | 541.394 |
| dewey-sort | 3541.394 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie Physik |
| format | Book |
| fullrecord | <?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01439nam a2200361 c 4500</leader><controlfield tag="001">BV039122711</controlfield><controlfield tag="003">DE-604</controlfield><controlfield tag="005">20131118 </controlfield><controlfield tag="007">t|</controlfield><controlfield tag="008">110706s2011 xx ad|| |||| 00||| eng d</controlfield><datafield tag="020" ind1=" " ind2=" "><subfield code="a">9783527317639</subfield><subfield code="9">978-3-527-31763-9</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(OCoLC)746135221</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-599)BVBBV039122711</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-604</subfield><subfield code="b">ger</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1="0" ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="049" ind1=" " ind2=" "><subfield code="a">DE-634</subfield><subfield code="a">DE-29T</subfield><subfield code="a">DE-11</subfield><subfield code="a">DE-19</subfield><subfield code="a">DE-703</subfield><subfield code="a">DE-91G</subfield><subfield code="a">DE-92</subfield><subfield code="a">DE-355</subfield><subfield code="a">DE-83</subfield></datafield><datafield tag="082" ind1="0" ind2=" "><subfield code="a">541.394</subfield><subfield code="2">22//ger</subfield></datafield><datafield tag="082" ind1="0" ind2=" "><subfield code="a">541.394</subfield><subfield code="2">22</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">VE 5800</subfield><subfield code="0">(DE-625)147124:253</subfield><subfield code="2">rvk</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">CHE 163f</subfield><subfield code="2">stub</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Marin, Guy B.</subfield><subfield code="e">Verfasser</subfield><subfield code="0">(DE-588)1014012082</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Kinetics of chemical reactions</subfield><subfield code="b">decoding complexity</subfield><subfield code="c">Guy B. Marin and Gregory S. Yablonsky</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="a">Weinheim</subfield><subfield code="b">Wiley-VCH</subfield><subfield code="c">2011</subfield></datafield><datafield tag="300" ind1=" " ind2=" "><subfield code="a">XVII, 428 S.</subfield><subfield code="b">Ill., graph. Darst.</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="650" ind1="0" ind2="7"><subfield code="a">Reaktionskinetik</subfield><subfield code="0">(DE-588)4048655-2</subfield><subfield code="2">gnd</subfield><subfield code="9">rswk-swf</subfield></datafield><datafield tag="689" ind1="0" ind2="0"><subfield code="a">Reaktionskinetik</subfield><subfield code="0">(DE-588)4048655-2</subfield><subfield code="D">s</subfield></datafield><datafield tag="689" ind1="0" ind2=" "><subfield code="5">DE-604</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Yablonsky, Gregory S.</subfield><subfield code="e">Verfasser</subfield><subfield code="0">(DE-588)1013915542</subfield><subfield code="4">aut</subfield></datafield><datafield tag="856" ind1="4" ind2="2"><subfield code="m">DNB Datenaustausch</subfield><subfield code="q">application/pdf</subfield><subfield code="u">http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=024141238&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA</subfield><subfield code="3">Inhaltsverzeichnis</subfield></datafield><datafield tag="943" ind1="1" ind2=" "><subfield code="a">oai:aleph.bib-bvb.de:BVB01-024141238</subfield></datafield></record></collection> |
| id | DE-604.BV039122711 |
| illustrated | Illustrated |
| indexdate | 2025-02-03T17:28:01Z |
| institution | BVB |
| isbn | 9783527317639 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-024141238 |
| oclc_num | 746135221 |
| open_access_boolean | |
| owner | DE-634 DE-29T DE-11 DE-19 DE-BY-UBM DE-703 DE-91G DE-BY-TUM DE-92 DE-355 DE-BY-UBR DE-83 |
| owner_facet | DE-634 DE-29T DE-11 DE-19 DE-BY-UBM DE-703 DE-91G DE-BY-TUM DE-92 DE-355 DE-BY-UBR DE-83 |
| physical | XVII, 428 S. Ill., graph. Darst. |
| publishDate | 2011 |
| publishDateSearch | 2011 |
| publishDateSort | 2011 |
| publisher | Wiley-VCH |
| record_format | marc |
| spellingShingle | Marin, Guy B. Yablonsky, Gregory S. Kinetics of chemical reactions decoding complexity Reaktionskinetik (DE-588)4048655-2 gnd |
| subject_GND | (DE-588)4048655-2 |
| title | Kinetics of chemical reactions decoding complexity |
| title_auth | Kinetics of chemical reactions decoding complexity |
| title_exact_search | Kinetics of chemical reactions decoding complexity |
| title_full | Kinetics of chemical reactions decoding complexity Guy B. Marin and Gregory S. Yablonsky |
| title_fullStr | Kinetics of chemical reactions decoding complexity Guy B. Marin and Gregory S. Yablonsky |
| title_full_unstemmed | Kinetics of chemical reactions decoding complexity Guy B. Marin and Gregory S. Yablonsky |
| title_short | Kinetics of chemical reactions |
| title_sort | kinetics of chemical reactions decoding complexity |
| title_sub | decoding complexity |
| topic | Reaktionskinetik (DE-588)4048655-2 gnd |
| topic_facet | Reaktionskinetik |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=024141238&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT maringuyb kineticsofchemicalreactionsdecodingcomplexity AT yablonskygregorys kineticsofchemicalreactionsdecodingcomplexity |