An introduction to ionic liquids
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RSC Publ.
2010
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| LEADER | 00000nam a2200000 c 4500 | ||
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| 001 | BV035905232 | ||
| 003 | DE-604 | ||
| 005 | 20110506 | ||
| 007 | t| | ||
| 008 | 091221s2010 xx d||| |||| 00||| eng d | ||
| 020 | |a 9781847551610 |c (hbk.) £39.95 |9 978-1-84755-161-0 | ||
| 020 | |a 1847551610 |c (hbk.) £39.95 |9 1-8475-5161-0 | ||
| 035 | |a (OCoLC)477137207 | ||
| 035 | |a (DE-599)GBV609434047 | ||
| 040 | |a DE-604 |b ger | ||
| 041 | 0 | |a eng | |
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| 084 | |a VE 6350 |0 (DE-625)147133:253 |2 rvk | ||
| 084 | |a CHE 142f |2 stub | ||
| 100 | 1 | |a Freemantle, Michael |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a An introduction to ionic liquids |c Michael Freemantle |
| 264 | 1 | |a Cambridge |b RSC Publ. |c 2010 | |
| 300 | |a XIV, 281 S. |b graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 500 | |a Includes index. | ||
| 650 | 4 | |a Ionic solutions | |
| 650 | 0 | 7 | |a Ionische Flüssigkeit |0 (DE-588)7548899-1 |2 gnd |9 rswk-swf |
| 689 | 0 | 0 | |a Ionische Flüssigkeit |0 (DE-588)7548899-1 |D s |
| 689 | 0 | |5 DE-604 | |
| 856 | 4 | 2 | |m Digitalisierung UB Bayreuth |q application/pdf |u http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=018762606&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |3 Inhaltsverzeichnis |
| 943 | 1 | |a oai:aleph.bib-bvb.de:BVB01-018762606 | |
Datensatz im Suchindex
| DE-BY-TUM_call_number | 0702 CHE 142f 2010 A 7309 |
|---|---|
| DE-BY-TUM_katkey | 1739935 |
| DE-BY-TUM_location | 07 |
| DE-BY-TUM_media_number | 040071336568 |
| _version_ | 1820855851237244928 |
| adam_text | Contents
Chapter
1
Introduction
1.1
Definition of Ionic Liquids
1
.2
Synonyms
1
.3
Attraction of Ionic Liquids
2
.4
Cations and Anions
3
.5
Shorthand Notation for Cations and Anions
4
.6
Apro
tic and Pro tic Ionic Liquids
5
1.7
Binary Mixtures
6
1.8
Organic and Inorganic Ionic Liquids
6
1.9
Deep Eutectic Solvents
6
1.10
Task-specific Ionic Liquids
7
1.11
Chiral Ionic Liquids
8
1.12
Generations of Ionic Liquids
8
References
10
Chapter
2
History
12
2.1
Origins
12
2.2
Key Dates in the History of Ionic Liquids
13
References
16
Chapter
3
Synthesis of Ionic Liquids
19
3.1
Introduction
19
3.2
Alkylation
20
3.3
Anion
Exchange
20
3.4
Microwave- and Ultrasound-assisted Synthesis
23
3.5
Halide-free Synthesis
23
An Introduction to Ionic Liquids
By Michael Freemantle
©
Michael Freemantle
2010
Published by the Royal Society of Chemistry, www.rsc.org
ix
x
Contents
3.6
Synthesis by
Protonation
24
3.7
Synthesis of Haloaluminate Ionic Liquids
25
3.8
Synthesis of Task-specific Ionic Liquids
25
3.9
Chiral Synthesis
27
References
29
Chapter
4
Properties of Ionic Liquids
31
4.1
Introduction
31
4.2
Liquid Range and Thermal Stability
32
4.3
Melting Points
32
4.4
Vapour Pressure
33
4.5
Heat Capacity and Heat Transfer
34
4.6
Viscosity
34
4.7
Density
35
4.8
Solubility and
Miscibili
ty
35
4.9
Water Stability
35
4.10
Conductivity
36
4.11
Electrochemical Potential Window
36
4.12
Surface Tension
36
4.13
Fluorescence
37
4.14
Refractive Indices
37
4.15
Impact of Impurities
38
References
39
Chapter
5
Ionic Liquids as Designer Solvents
41
5.1
Introduction
41
5.2
Solubility and Miscibility
42
5.3
Polarity and Solvation
43
5.4
Miscibility with Water
44
5.5
Miscibility with Organic Compounds
44
5.6
Solubility of Metal Salts
46
5.7
Gas Solubility
46
5.8
Biphasic Systems
48
5.9
Phase Diagrams
48
5.10
Partitioning of Solutes between Ionic Liquids and
Water
52
5.11
Biphasic Systems of Hydrophilic Ionic Liquids and
Water
53
5.12
Mutually Immiscible Ionic Liquids
53
5.13
Separations and Extractions
54
5.14
Extraction of Organic Compounds
54
5.15
Gas Separations
56
5.16
Carbon Dioxide Extractions and Separations
57
Contents xj
5.17
Metal Ion
Extractions
58
5.18
Extractive
Distillations
60
5.19
Membrane
Separations
61
References
62
Chapter
6
Green Credentials of Ionic Liquids
65
6.1
Introduction
65
6.2
Vapour Pressure
68
6.3
Flammability and Combustibility
70
6.4
Recycling
71
6.5
Environmental Exposure and
Toxicity
72
6.5.1
Release into the Environment
72
6.5.2
Spatiotemporal
Range
73
6.5.3
Biodegradability
73
6.5.4
Biological Activity
73
6.5.5
Bioaccumulation
75
References
77
Chapter
7
Electrochemistry
79
7.1
Introduction
79
7.2
Cyclic Voltammetry
80
7.3
Batteries
83
7.4
Fuel Cells
85
7.5
Dye-sensitized Solar Cells
86
7.6
Electrodeposition
88
7.7
Actuators
91
7.8
Supercapacitors
92
7.9
Electrosynthesis
94
References
95
Chapter
8
Catalysis
99
8.1
Introduction
99
8.2
Monophasic and Biphasic Catalysis
100
8.3
Solvents, Catalysts and Ligands
101
8.4
Catalyst Performance
105
8.5
Supported Ionic Liquid Catalysis
108
8.6
Nanoparticle Catalysts
110
8.7
Acid-Base Catalysis
112
8.8
Transition Metal Catalysis
113
8.9
Chiral Transition Metal Catalysis
115
8.10
Task-specific Ionic Liquids in Catalysis
117
References
118
Xli
Contents
Inorganic Chemistry
121
9.1
Introduction
121
9.2
Main Group Chemistry
121
9.3
Transition Metal Chemistry
124
9.4
Organometallic Compounds
125
9.5
Nuclear Chemistry
130
9.6
Nanoparticłes
132
9.7
Carbon Nanotubes
133
9.8
Metal and Semiconductor
Nanoparticłes
134
9.9
Alloy
Nanoparticłes
136
9.10
Metal Oxide
Nanoparticłes
137
9.11
Other
Nanoparticłes
137
9.12
Microspheres
138
9.13
Sol-Gel Synthesis of Porous Materials
140
9.14
Ionothermal Synthesis of Porous
Materials
141
References
143
Chapter
10
General Organic Reactions
146
146
146
148
149
151
152
152
155
155
157
159
160
161
162
166
168
169
171
174
175
176
179
183
10.1
Introduction
10.2
Aldol Condensation
10.3
Alkylation
10.4
Cracking
10.5
Cycloaddition
10.6
Debromination
10.7
Dimerization and Oligomerization
10.8
Electrophilic Reactions
10.9
Epoxidation
10.10
Esterification
10.11
Etherization
10.12
Halogenation
10.13
Hydroformylation
10.14
Hydrogénation
10.15
Hydrosilylation
10.16
Nitration of Aromatics
10.17
Nucleophilic Reactions
10.18
Olefin
Metathesis
10.19
Oxidation
10.20
Peptide
Synthesis
10.21
Photochemical Reactions
10.22
Polymerizations
References
Contents xjjj
Chapter
11
Named Organic Reactions
188
11.1
Baeyer-Villiger Oxidation
188
11.2
Baylis-Hillman Reaction
188
11.3 Beckmann
Rearrangement
190
11.4
Diels-Alder Reaction
190
11.5
Friedel-Crafts Reactions
193
11.6
Grignard Reaction
197
11.7
Heck Reaction
198
11.8
Knoevenagel Condensation and Robinson
Annulation
200
11.9 Mannich
Reaction
202
11.10
Michael Addition
203
11.11
Sonogashira Coupling
205
11.12 Stille
Coupling
206
11.13
Suzuki Cross-coupling
207
11.14
Swern Oxidation
208
11.15
Ullmann Coupling
209
11.16 Wacker
Oxidation
210
11.17 Wittig
Reaction
210
References
211
Chapter
12
Biotechnology
214
12.1
Introduction
214
12.2
Carbohydrate Solubility
214
12.3
Biomass Conversion
216
12.4
Enzyme Catalysis
218
12.5
Early Studies of Ionic Liquid-Enzyme
Systems
220
12.6
Lipases
222
12.7
Proteases,
Esterases
and other Enzymes
223
12.8
Enantioselectivity and Regioselectivity
225
12.9
Biphasic Systems and Separations
227
References
229
Chapter
13
Analysis
232
13.1
Introduction
232
13.2
Chromatography
232
13.3
Capillary Electrophoresis
234
13.4
Sensors
236
13.5
Gas Sensors
236
13.6
Ion-selective Electrodes
239
13.7
Biosensors
240
xiv Contents
13.8
Spectroscopy
241
13.9
Mass Spectrometry
242
References
244
Chapter
14
Applications
246
246
247
248
249
250
251
252
253
255
256
257
259
260
261
264
264
266
14.1
Introduction
14.2
Synthesis of 2,5-Dihydrofuran
14.3
Difasol Process
14.4
BASIL Process
14.5
Storage of Hazardous Gases
14.6
Lubrication
14.7
Compressors
14.8
Energetic Materials and Propellants
14.9
Optical Immersion Fluids
14.10
Lunar Liquid Mirror Telescope
14.11
Thermometers
14.12
Antimicrobial Agents
14.13
Active Pharmaceutical Ingredients
14.14
Nucleoside-based Antiviral Drugs
14.15
Embalming and Tissue Preservation Fluids
References
Subject Index
|
| any_adam_object | 1 |
| author | Freemantle, Michael |
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| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie Physik |
| format | Book |
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| isbn | 9781847551610 1847551610 |
| language | English |
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| spellingShingle | Freemantle, Michael An introduction to ionic liquids Ionic solutions Ionische Flüssigkeit (DE-588)7548899-1 gnd |
| subject_GND | (DE-588)7548899-1 |
| title | An introduction to ionic liquids |
| title_auth | An introduction to ionic liquids |
| title_exact_search | An introduction to ionic liquids |
| title_full | An introduction to ionic liquids Michael Freemantle |
| title_fullStr | An introduction to ionic liquids Michael Freemantle |
| title_full_unstemmed | An introduction to ionic liquids Michael Freemantle |
| title_short | An introduction to ionic liquids |
| title_sort | an introduction to ionic liquids |
| topic | Ionic solutions Ionische Flüssigkeit (DE-588)7548899-1 gnd |
| topic_facet | Ionic solutions Ionische Flüssigkeit |
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