Materials science for dentistry
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| Format: | Buch |
| Sprache: | English |
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Boca Raton, Fla. [u.a.]
CRC Press [u.a.]
2009
Oxford [u.a.] Woodhead Publishing |
| Ausgabe: | 9. ed. |
| Schriftenreihe: | Woodhead publishing in materials
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| 020 | |a 9781439801055 |9 978-1-4398-0105-5 | ||
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| 100 | 1 | |a Darvell, Brian W. |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Materials science for dentistry |c B. W. Darvell |
| 250 | |a 9. ed. | ||
| 264 | 1 | |a Boca Raton, Fla. [u.a.] |b CRC Press [u.a.] |c 2009 | |
| 264 | 1 | |a Oxford [u.a.] |b Woodhead Publishing | |
| 300 | |a XXII, 662 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 490 | 0 | |a Woodhead publishing in materials | |
| 650 | 4 | |a Dental materials | |
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| 776 | 0 | 8 | |i Erscheint auch als |n Online-Ausgabe |z 978-1-84569-667-2 |
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Datensatz im Suchindex
| DE-BY-UBR_call_number | 00/YP 5900 D227(9) |
|---|---|
| DE-BY-UBR_katkey | 4527243 |
| DE-BY-UBR_location | 00 |
| DE-BY-UBR_media_number | 069036348641 |
| _version_ | 1822735387333754880 |
| adam_text | Contents
Preface
xv
Preface
to the 5th Edition
xvii
Introduction
xix
How To Use This Book
xxi
Conventions
xxiii
A Note on References
xxiii
Greek Alphabet
xxiii
1
Mechanical Testing
1
1.
Initial Ideas
2
tension, compression, shear, need to define properties
2.
The Equations of Deformation
4
Hooke s Law, stress, strain, proportional limit, Young s modulus,
elastic limit,
Poisson
ratio, shear modulus, bulk modulus
3.
Plastic Deformation
11
yield point, necking, strength testing
4.
Work of Deformation
14
toughness, resilience, flexibility
5.
Modelling
16
mechanical analogues, strain hardening, physical modelling, friction
6.
Strength Testing
19
direct tensile, indirect tensile, compression, flexure
7.
Griffith s Law
21
critical stress, surface energy, size effect, structure scale
8.
Hardness
25
Brinell ball, Vickers indenter,
Knoop indenter
9.
Dynamic Behaviour
28
timescale, time constant, relaxation time
10.
Impact
29
Charpy, Izod, notch sensitivity, impact strength
11.
Creep
31
flow, atomic diffusion, activation energy
12.
Fatigue
32
load cycling, endurance limit
13.
Elastic Moduli
33
initial, tangent, secant, average, non-Hookean behaviour
14.
Comparative Properties
34
relative values of different classes of material
15.
Ideality
35
limitations, development
2
Gypsum Materials
37
1.
Basic Reactions
38
plaster, dehydration, setting
2.
Mixing Liquid
39
bulk density, volume fraction, gauging volume, dilatancy, mixing volume, wetting
3.
Dental Products
42
plaster, stone, minimum mixing volume
4.
Mixing Proportions
43
mass fraction, excess water
5.
Setting Dimensional Change
44
crystal growth effects, density change, spherulites, hygroscopic expansion
vi
___ ________Contents
6.
Setting Reaction
47
induction period, nucleation, thermal expansion
7.
Modifiers
49
syngenite, crystal habit, anti-expansion solution
8.
Porosity
52
excess water, critical porosity, bubbles
9.
Wet or Dry?
55
strength, slurry water
10.
Storage
56
deterioration, humidity, setting time, strength
11.
Setting Time
57
Gillmore needle, setting rate, working time
3
Polymers
60
1.
Basic Structure
61
addition and condensation polymerisation, monomer, copolymerisation
2.
Configuration and Conformation
62
stereoisomerism, tacticity, bond rotation, energy variation, geometry
3.
Viscosity
66
molecular basis, activation energy
4.
Glass Transition
69
crystallinity, free volume, side chains, drawing, orientation, strain hardening
5.
Time-Temperature Equivalence
76
failure envelope, test behaviour
6.
Plasticizers and Cross-linking
78
water, temperature equivalence, branching and cross-linking
4
Rheology
82
1.
First Thoughts
83
rate of deformation, reversible vs. permanent change, relaxation time
2.
Elasticity
83
Hookean model
3.
Newtonian Flow
84
boundary layer, shear gradient, coefficient of viscosity, pure flow
4.
The Maxwell Body
87
elastic-plastic behaviour
5.
The Kelvin-
Voigt
Body
88
retardation time, time constant, damped flow, reversibility
6.
Viscoelasticity
89
summation of effects, continuum of behaviour
7.
Classification of Flow Behaviour
92
Newtonian, plastic,
pseudoplastic,
shear thinning,
dilatant,
thixotropic
8.
The Compression Set Test
99
interpretation
9.
Fillers
101
purposes, mechanism, effects, settling
10.
Stokes Law
104
application to wax viscosity determination
11.
Poiseuille s Law
105
flow development in tubes, practical implications
5
Acrylic
108
1.
Polymerization Reactions
109
chain initiation, propagation, termination, transfer, tacticity
2.
Heat-cured Acrylic
1
11
benzoyl peroxide, resin manufacture, shrinkage,
exotherm,
residual monomer
need for initiator, Trommsdorff effect, equilibria
3.
Cold-cured Resins
j
ţg
activator, tertiary amines
4.
Inhibitors J20
need, mechanism
Contents___________
vii
5.
Cracks
&
Crazes
121
glass transition, viscoelasticity, crazing
6.
Modifications
125
water absorption, plasticizers, cross-linking
6
Resin Restorative Materials
128
1.
Direct Acrylic Resin Restorative Materials
129
setting, discolouration, compromises, shrinkage, temperature effects, structure
2.
The Effects of Fillers
132
thermal expansion, matrix constraint, internal stresses, stress freezing, importance
of bonding, isostrain and
isostress
models, modulus, coupling agents, crack growth
3.
Filler Loading
144
differential wear, filler selection, volume fraction, product variations
4.
Resin Chemistry
147
bis-phenol A, bis-GMA, mechanical properties during setting
5.
Light-Cured Materials
151
photolytic initiation, photosensitizer, fluorescence, phosphorescence,
hazards, visible light, camphoroquinone, amines, curing lamps, depth of cure
6.
Oxygen Inhibition
161
free radicals, barriers, bleaching agents
7
Flexible Impression Materials
163
1.
Basic Requirements
164
purpose, compromises
2.
Deformation
164
effective chain segments, non-Hookean behaviour, failure, cause of elasticity,
affine
deformation
3.
Effects of Fillers
169
strain, Mullins effect, modulus, importance of bonding
4.
Polysulphide
173
chemistry, setting, stress relaxation
5.
Polyether
176
chemistry, setting, water sorption
6.
Silicones
177
chemistry, setting, condensation, addition
7.
Polysaccharides
181
basic structure, importance of hydrogen bonds
8.
Agar
. 182
chemistry, structure of water, structure of gels, tempering
9.
Alginates
185
chemistry, setting, gel structure
10.
Water Gain and Loss
188
sensitivity of gels, synaeresis
11.
Stress Set
190
bond-exchange, stress-aided reaction, chain effects
12.
Other Accuracy Issues
192
molecular processes, physical effects, practical matters
13.
Mould Seal
195
sodium alginate solution
8
Composition and Phase Diagrams
197
1.
Plotting Composition
198
mixture line,
3
components, multiple components
2.
States and Phases
201
definitions,
pressure-temperature
diagram, phase field, stoichiometric phases
3.
The Phase Rule
204
chemical potential, equilibrium, degrees of freedom, isothermal tie-lines, lever rule
4.
Critical Points
211
two liquids, phase separation, ternary liquid system, plait point
viii Contents
9
Cements and Liners
214
1.
General Principles
215
types, applicability
2.
Zinc Oxide
-
Eugenol
216
chemistry, setting, alternatives
3.
Background Chemistry
219
zinc oxide, oxide selection, acidity
4.
Cements as Composite Materials
221
general principles, effect of porosity
5.
Zinc Phosphate
222
chemistry, setting, explanation of clinical handling, etching
6.
Zinc Polycarboxylate
233
chelation, network structure, adhesion
7.
Ion-leachable Glasses
234
general chemistry, role of aluminium, fluoride, silicates
8.
Glass Ionomer Cement
238
chemistry, glass and acid design, setting reactions, cermet, water status,
fluoride, other fillers
9.
Film Thickness
246
fit of crowns, geometry, force of seating
10.
Calcium Hydroxide Liners
248
purpose, chemistry
11.
Cavity Varnish
249
purpose, fluoride
12.
MTA
250
manufacture, setting reactions
10
Surfaces
253
1.
Wetting
254
contact angle, surface tension, surface energy, crack formation, work of adhesion,
effect of roughness
2.
Capillarity
260
meniscus, capillary rise and depression, bubble pressure, penetration coefficient,
porous bodies
3.
Aspects of Chemical Bonding
268
van
der Waals, dipoles,
force vs. distance, origin of strength
4.
The Hydrogen Bond
271
chemical nature, consequences
5.
Dental Adhesives
272
types, deficiencies
6.
Enamel
&
Dentine Etching and Bonding
273
differential etching, cyanoacrylate, urethane
7.
Fluoride
276
types of preparation, chemistry, surface energy
8.
Surfactants
277
detergents, wetting agents
11
Metals I
:
Structure
280
1.
What is a Metal?
281
metallic bonding, delocalized electrons, graphite
2.
Freezing
282
cooling curves, supercooling, critical radius, nucleation
3.
Crystal Structure
289
space lattice, unit cell, face-centred, body-centred, hexagonal close-packed,
atom counting, stacking layers, solid solution, radius ratio limit
4.
Grain Structure
295
grain boundary, grain growth, energy, Hall-Petch relation
5.
Slip
297
homogeneous, preferred directions, ductility, malleability, energy
6.
Dislocations
299
defects, inhomogeneous slip, pile-up, strain hardening, cold work, annealing,
recrystallization, strength
Contents___ ix
12 Metals
II
:
Constitution
306
1.
Segregation
307
continuous solid solution, liquidus, solidus, freezing and melting
partition, equilibria, annealing, quenching, cooling curves
2.
Metallography
312
use of polished sections, etching
3.
Eutectics
314
Ag-Cu system, cooling curves, cored structure, solvus, supercooling, eutectoid
4.
Phase Diagram Conventions and Layout
319
arbitrariness, electron compounds, structure types, phase labelling convention
5.
The Cu-Sn System
322
reading reactions from a phase diagram, eutectoids, peritectoids
13
Corrosion
325
1.
Basic Considerations
326
oxidation, reduction, anode and cathode, corrosion cell,
galvanic couple, equilibrium, plating cell
2.
Polarization
329
cause, back e.m.f., depolarization
3.
Cathode Processes
330
electron sinks, oxygen,
pH
effects
4.
Corrosion Protection
330
protective plating, sacrificial plating, paint, oxygen concentration cell,
pitting and crevice corrosion, inhibitors
5.
Passive Metals
335
passivation process,
Al, Cr,
Ti,
risks
6.
Other Factors
337
stress corrosion, electrode potential, rough surfaces, effect of polishing, tarnish
7.
Deliberate Corrosion
340
electropolishing, etching, mechanical key, plating
14
Silver Amalgam
342
1.
Basic Setting Reactions
343
Ag-Sn, Ag-Hg, Hg-Sn, effect of Cu, strength, Ag-Cu-Hg-Sn constitution
2.
Alloy Powder Manufacture
348
turning, milling, atomization
3.
Cooling Rate and Constitution
350
presence of eutectic, coring, effects on setting, homogenization, pre-amalgamation
4.
Mixing Proportions
355
gauging and dilatancy, mercury requirements
5.
Constitution of Set Amalgam
357
metallography, effect of heat
6.
Dimensional Changes
360
causes, effects, factors affecting, Zn, creep
7.
Mechanical Properties
364
creep, temperature effects
8.
Porosity
365
causes, strength
9.
Corrosion
367
multiphase, gamma-2, Cu, alloy tarnish
10.
Quality of Work
369
dependence of performance on care taken
15
Mixing
371
1.
Amalgamation
372
history,
trituration,
machine mixing
2.
Amalgam Mixer Analysis
373
energy required, coherence, power rating, length:amplitude ratio, need for pestle
3.
Other Capsule Products
379
viscosity, proportion accuracy
4.
Alginate Proportioning
379
powder and water, propagation of errors
Contents
5.
Tubes
382
impression materials, settling
6.
Other Powder-Liquid Products
383
proportioning, mixing
7.
Theory
385
turbulence, shearing, Baker s transformation, diffusion, effect on properties
8.
Spatulas
388
mechanical and chemical considerations
16
Waxes
390
1.
Chemistry
391
chemistry, melting, general description
2.
Properties
393
thermal expansion, modulus of elasticity, residue
3.
Flow
396
measuring, temperature sensitivity, residual stress
4.
Burn out
398
purpose, requirements
5.
Impression Compound
399
description
6.
Other Applications
400
sticky wax, articulating paper, floss
17 Casting Investments
401
1.
Requirements
402
refractory, expansion
2.
Chemistry of Silica
404
bonding, polymorphs, displacive and reconstructive transformations,
density, dimensional changes
3.
Gypsum-bonded Investments
410
silica proportion, expansion, particle size effect, undesirable reactions, limitations
4.
Phosphate-bonded Investments
413
reactions, slag
5.
Silica-bonded Investments
416
setting, properties
6.
Ring Liner
417
purpose, use, expansion
7.
Porosity
418
need for, obtaining, limitations
18
Casting
420
1.
Models and Investments
421
requirements, shear-thinning, vacuum
2.
Metal Casting
422
wetting, surface tension, viscosity, oxidation
3.
Physics of Casting
424
centrifugal machines, casting pressure, surface detail, air pressure, vacuum
4.
Dimensional Considerations and Defects
429
sources of change, patterns of cooling, causes of defects
5.
Flame
433
diffusion and premixed types, soot, reducing and oxidising zones, hazards
19
Casting Alloys
435
1.
Gold Alloys
436
pure gold, Ag-Cu, ordered phases, superlattice, coherency strain, colour,
precipitation hardening, ageing, grain refining, related alloys
2.
Chromium Alloys
445
Cr-systems, properties, dissolved carbon, carbides, thermal history,
sigma
phase
Contents xi
20
Cutting,
Abrasion
and Polishing
450
1.
Background
451
complications of conditions and substrates
2.
Bonded Abrasives
451
process of abrasion, temperature effects with polymers, hardness, lubricants
3.
Cutting Tools
457
terminology, comparison with bonded abrasives, relative hardness, rubbing wear
4.
Erosion
461
differential erosion, grit blasting, energy, ductile and brittle substrates, liquid honing
5.
Electrolytic Polishing
465
current-voltage plot, depth of plastic strain
6.
Roughness
465
definition, waviness, measures, centre-line average
7.
Heating
468
friction, effect on pulp and materials
8.
Diamond
470
characteristics and use
21
Steel and Cermet
471
1.
Carbon Steel
472
structure, carbon solubility,
С
-Fe,
martensitic transformation, strength,
toughness, steel grades, uses
2.
Stainless Steel
476
basis, properties, structures, heat-affected zone, weld decay, pitting
3.
Cermet
479
cutting device requirements, WC-Co, sintering, formation reactions, assembly
22
Soldering and Welding
485
1.
Definitions and Conditions
486
soldering, welding, spot welding, energy input, melting point restrictions
2.
Fluxes
487
purpose, formulation, reactions, use of fluoride
3.
Solder Design and Selection
489
properties, limitations, thermal effects, brazing
4.
Amalgamation
493
comparison and contrasts with soldering
23
Mechanics
494
1.
Work and Moment
495
basic equations, sign conventions
2.
Simple Beams
496
cantilever, shearing force and moment diagrams, additivity, equations,
3-
and
4-point bend, neutral axis, neutral surface, stress distribution, pre-stress
3.
The Second Moment of Inertia
504
definition, shape factor, flexural rigidity, additivity, use in design, tubes
4.
Deflections of Loaded Beams
507
example of method, cantilever,
3-
and 4-point beams
5.
The Finger-Spring Analysed
510
stepwise treatment, interpretation of result, work hardening
6.
Coils
&
Braiding
512
benefits to flexibility
7.
Hand Instruments
513
design, instability
24
Light and Colour
515
1.
The Sensation of Colour
516
psychophysical sensation, matching, colour gamut, the spectrum
2.
The
Chromatický
Diagram
519
geometry, spectral locus, chromaticity coordinates, purple line
3.
Colour Specification
522
hue, saturation, grey scale, photometric intensity, reflectance, other colour systems,
meaning of white
xii Contents
4.
Colour Matching in Practice
526
principles, persistence of matches, dependence on
illuminant,
daylight,
tungsten and fluorescent lamps, phosphors, metamerism, shade guides
5.
Physics of Light
534
reflection, refractive index, specular transmission, diffusion, scattering
6.
Chemistry of Colour
540
energy absorption processes, delocalized electrons, conjugated systems,
metal complexes, spectrochemical series, fluorescence, hydroxyapatite,
dyes and pigments
25
Porcelain
546
1.
Structure
547
silicates, glass, alumina-potash-silica
2.
Firing Reactions
550
potash feldspar,
leucite,
kaolin, high-, medium- and low fusing porcelain
3.
Alumina Strengthening
553
energy of crack growth, importance of bonding, expansion matching
4.
The Firing Process
554
sintering, trapped air, densification, vacuum, bubble shrinkage
5.
Strengthening Treatments
559
overglazing, pre-stress, ion-exchange, crack diagnosis, thermal shock
6.
Metal
-
Ceramics
562
thermal stress, bonding, mechanical key
7.
Colouring
563
metal oxides
8.
Boric Oxide
564
devitrification, hydrolysis
9.
Other Approaches
565
castable and machinable ceramics, infiltration
10.
Etching
567
hydrogen fluoride reactions, problems
26
Radiography
568
1.
Atomic Structure
569
Aufbau
and
Pauli
Exclusion principles, characteristic X-rays
2.
X-ray Generation
570
electron volt, wavelength minimum, x-ray tube, emission spectra, Moseley s Law
3.
Lambert s Law
.
573
linear absorption coefficient, mass absorption coefficient, calculation, filtration,
rectification
4.
Absorption and Scattering
577
absorption edge, true absorption, fluorescence, Compton Effect, coherent scattering,
ionization
5. Radiographic
Film Density
581
optical density vs. exposure, fog, base density, working range,
sensitivity, contrast
6.
Experimental Attenuation Coefficient
586
effective mass attenuation coefficient
7.
Screens
537
fluorescence, intensification, limitations
8.
Image Properties 5gg
projection, thickness distortion, inverse square law, exposure correction,
parallelism, blurring, heel effect, target ageing
9.
Alternative Imaging techniques
592
zeroradiography, photo-stimulable phosphor,
CCD, TFT
10.
Digital Images
59g
control, grey scale, digital representation, calculation
Contents xiii
27
More
Polymers 600
1.
Polyisoprene
601
rubber,
gutta
percha,
properties, degradation, vulcanization, oxidation, chicle
2.
Polysaccharides
604
cellulose, wet strength, absorbent points, bibs, starch,
carboxymethylcellulose, impression plaster, regenerated cellulose, acetate, nitrate,
chition, chitosan
3.
Polypeptides
608
gut sutures, collagen properties, proteins, structure, Ramachandran plot, silk, yarns
4.
Polyesters
613
polyiglycolic acid), Terylene,
Dacron,
Mylar
28
More Metals
614
1.
Titanium
615
commercially-pure, twinning, casting, corrosion
2.
Nickel-Titanium
619
transformations, shape-memory, pseudoelasticity, corrosion, applications
3.
Metal Forming
625
press-forming, hydraulic, explosive,
superplastic, electroforming,
wire
4.
Pure Gold
629
use, forms, properties
5.
Mirrors
630
requirements, design
6.
Mercury
631
properties, spillage, clean-up, storage, copper amalgam, sensitivity
7.
Beryllium
636
problems, safety
8.
Other Alloys
636
Elgiloy, lead-tin
9.
Silver
638
use, composition, corrosion
29
More Mechanical Testing
640
1.
Shear
641
equivalence, Mohr s circle, meaning of strength
2.
Plastic-Brittle Transition
646
behavioural scale factor
3.
Bend Strength
647
generalized equation, derivation of formulae, limitation
Index
649
Materials Science
for Dentistry has established itself as a standard reference for
undergraduate and postgraduate courses in dentistry. It provides a fundamental
understanding of the materials on which dentistry depends, covering those aspects of
structure and chemistry which govern the behaviour and performance of materials in use.
Particular materials discussed include gypsum, polymers, acrylic, cements, waxes, porcelain
and metals. Other chapters review topics such as surfaces, corrosion, mixing, casting,
cutting and bonding as well as mechanical testing. This edition, which adds a chapter
on further aspects of mechanical testing, has been extensively revised with, for example,
new material on condensation
silicone
and phosphate-bonded investment chemistries,
mixing,
MTA
and alternative
radiographie
imaging techniques.
Now in its ninth edition, Materials Science for Dentistry continues its reputation as the
most authoritative available reference for students of dentistry. It will also be a valuable
resource for academics and practitioners in the field.
Dr
Brian W. Darvell DSc CChem CSci FRSC
FIM
FSS FADM is former Reader in Dental
Materials Science at The University of Hong Kong, China.
|
| any_adam_object | 1 |
| author | Darvell, Brian W. |
| author_facet | Darvell, Brian W. |
| author_role | aut |
| author_sort | Darvell, Brian W. |
| author_variant | b w d bw bwd |
| building | Verbundindex |
| bvnumber | BV035730440 |
| callnumber-first | R - Medicine |
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| callnumber-raw | RK652.5 |
| callnumber-search | RK652.5 |
| callnumber-sort | RK 3652.5 |
| callnumber-subject | RK - Dentistry |
| classification_rvk | YP 5900 ZM 3000 |
| ctrlnum | (OCoLC)244418624 (DE-599)BVBBV035730440 |
| dewey-full | 617.695 |
| dewey-hundreds | 600 - Technology (Applied sciences) |
| dewey-ones | 617 - Surgery & related medical specialties |
| dewey-raw | 617.695 |
| dewey-search | 617.695 |
| dewey-sort | 3617.695 |
| dewey-tens | 610 - Medicine and health |
| discipline | Werkstoffwissenschaften / Fertigungstechnik Medizin |
| edition | 9. ed. |
| format | Book |
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| id | DE-604.BV035730440 |
| illustrated | Illustrated |
| indexdate | 2024-12-23T22:27:38Z |
| institution | BVB |
| isbn | 1439801053 9781439801055 9781845695293 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-018007042 |
| oclc_num | 244418624 |
| open_access_boolean | |
| owner | DE-355 DE-BY-UBR DE-83 |
| owner_facet | DE-355 DE-BY-UBR DE-83 |
| physical | XXII, 662 S. Ill., graph. Darst. |
| publishDate | 2009 |
| publishDateSearch | 2009 |
| publishDateSort | 2009 |
| publisher | CRC Press [u.a.] Woodhead Publishing |
| record_format | marc |
| series2 | Woodhead publishing in materials |
| spellingShingle | Darvell, Brian W. Materials science for dentistry Dental materials Dentalwerkstoff (DE-588)4133661-6 gnd Werkstoffkunde (DE-588)4079184-1 gnd |
| subject_GND | (DE-588)4133661-6 (DE-588)4079184-1 |
| title | Materials science for dentistry |
| title_auth | Materials science for dentistry |
| title_exact_search | Materials science for dentistry |
| title_full | Materials science for dentistry B. W. Darvell |
| title_fullStr | Materials science for dentistry B. W. Darvell |
| title_full_unstemmed | Materials science for dentistry B. W. Darvell |
| title_short | Materials science for dentistry |
| title_sort | materials science for dentistry |
| topic | Dental materials Dentalwerkstoff (DE-588)4133661-6 gnd Werkstoffkunde (DE-588)4079184-1 gnd |
| topic_facet | Dental materials Dentalwerkstoff Werkstoffkunde |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=018007042&sequence=000005&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=018007042&sequence=000006&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT darvellbrianw materialssciencefordentistry |