Ionic transport processes in electrochemistry and membrane science
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Datensatz im Suchindex
| _version_ | 1819633107010060288 |
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| adam_text | LONIC TRANSPORT PROCESSES IN ELECTROCHEMISTRY AND MEMBRANE SCIENCE
KYOESTI KONTTURI AND LASSE MURTOMAKI HELSINKI UNIVERSITY OF TECHNOLOGY,
FINLAND JOSE A. MANZANARES UNIVERSITY OF VALENCIA, SPAIN OXPORD
UNIVERSITY PRESS CONTENTS THERMODYNAMICS OF IRREVERSIBLE PROCESSES 1 1.1
FUNDAMENTAL CONCEPTS 1 1.1.1 SPACE AND TIME SCALES OF OBSERVATION 1
1.1.2 LOCAL THERMODYNAMIC EQUATIONS 2 1.1.3 ELECTROLYTE SOLUTIONS 4 1.2
BALANCE EQUATIONS 7 1.2.1 INTRODUCTION 7 1.2.2 GENERAL FORM OF THE
BALANCE EQUATIONS 9 1.2.3 TOTAL AND COMPONENT MASS-BALANCE EQUATIONS 13
1.2.4 ELECTRIC CHARGE-BALANCE EQUATION 14 1.2.5 LINEAR MOMENTUM-BALANCE
EQUATION 16 1.2.6 ENERGY- AND ENTROPY-BALANCE EQUATIONS IN A NON-VISCOUS
FLUID 20 1.2.7 ENERGY- AND ENTROPY-BALANCE EQUATIONS IN A NEWTONIAN
VISCOUS FLUID 24 1.2.8 ELECTROMAGNETIC ENERGY AND LINEAR MOMENTUM 27
EXERCISES 34 REFERENCES 36 TRANSPORT EQUATIONS 38 2.1 LINEAR
PHENOMENOLOGICAL EQUATIONS 38 2.1.1 INTRODUCTION 38 2.1.2 IONIC
TRANSPORT EQUATIONS 39 2.1.3 BINARY ELECTROLYTE SOLUTION 42 2.1.4
ELECTRIC CONDUCTION 44 2.1.5 COMPONENT TRANSPORT EQUATIONS 44 2.1.6
TERNARY ELECTROLYTE SOLUTIONS 46 2.2 THE FICKIAN APPROACH 47 2.2.1
INTRODUCTION 47 2.2.2 FICK S LAW 47 2.2.3 DIFFUSION-CONDUCTION EQUATIONS
49 2.3 THE NERNST-PLANCK APPROXIMATION 50 2.3.1 INTRODUCTION 50 2.3.2
NERNST-PLANCK EQUATION 51 2.3.3 ELECTRICAL COUPLING BETWEEN THE IONIC
FLUXES 52 2.3.4 DIFFUSION POTENTIAL 54 2.3.5 INTEGRATION OF THE
TRANSPORT EQUATIONS IN MULTI-IONIC SOLUTIONS 56 XII CONTENTS 2.3.6
BINARY ELECTROLYTE SOLUTION 57 2.3.7 TERNARY ELECTROLYTE SOLUTIONS 58
2.3.8 WEAK ELECTROLYTES . 61 2.3.9 MODERATELY CONCENTRATED SOLUTIONS 63
2.4 THE STEFAN-MAXWELL APPROACH 64 2.4.1 INTRODUCTION 64 2.4.2 DIFFUSION
OF A NEUTRAL COMPONENT 65 2.4.3 BINARY ELECTROLYTE SOLUTION 66 2.4.4
MULTI-IONIC SYSTEMS 69 EXERCISES 70 REFERENCES 76 3 TRANSPORT AT
ELECTRODES 78 78 80 80 81 82 83 84 89 95 98 98 105 107 110 110 112 115
118 120 EXERCISES 122 REFERENCES 124 4 TRANSPORT IN MEMBRANES 126 4.1
TRANSPORT ACROSS NEUTRAL POROUS MEMBRANES 126 4.1.1 QUASI-STEADY
DIFFUSIVE TRANSPORT BETWEEN TWO CLOSED COMPARTMENTS 126 4.1.2 LAG TIME
IN DIFFUSION 129 4.1.3 IONTOPHORETIC ENHANCEMENT 133 4.1.4 LAG TIME IN
ELECTRODIFFUSION 136 4.1.5 CIRCULATION OF COMPARTMENTS 139 4.1.6
CONVECTIVE ELECTROPHORESIS 140 4.1.7 LIQUID-JUNCTION POTENTIAL 143 4.1.8
UPHILL TRANSPORT 148 3.1 FARADAY S LAW 3.2 ELECTRODE PROCESSES IN
STATIONARY STATE 3.2.1 3.2.2 3.2.3 3.2.4 3.2.5 3.2.6 3.2.7 NERNST
DIFFUSION BOUNDARY LAYER LIMITING CURRENT DENSITY TRANSPORT EQUATIONS IN
MULTI-IONIC SOLUTIONS TRACE IONS SOLUTIONS WITH ONLY ONE ELECTROACTIVE
ION SOLUTIONS WITH SEVERAL ELECTROACTIVE SPECIES TRANSPORT IN SPHERICAL
GEOMETRY 3.3 HYDRODYNAMIC ELECTRODES 3.3.1 3.3.2 3.3.3 ROTATING-DISC
ELECTRODE CHANNEL-FLOW ELECTRODE WALL-JET ELECTRODE 3.4 NON-STATIONARY
OR TRANSIENT ELECTRODE PROCESSES 3.4.1 3.4.2 3.4.3 3.4.4 3.4.5
INTRODUCTION CURRENT STEP IN THE ABSENCE OF MIXING CURRENT STEP WITH
MIXING CURRENT SCAN VOLTAGE STEP CONTENTS XIII 4.2 DONNAN EQUILIBRIUM IN
CHARGED MEMBRANES 152 4.2.1 ION-EXCHANGE MEMBRANES 152 4.2.2 DONNAN
EQUILIBRIUM 152 4.2.3 ION-EXCHANGE EQUILIBRIUM 157 4.2.4 ELECTRICAL
DOUBLE LAYER AT THE MEMBRANE/ EXTERNAL SOLUTION INTERFACE 160 4.2.5
INFLUENCE OF THE MEMBRANE HETEROGENEITIES 163 4.3 STEADY-STATE TRANSPORT
ACROSS ION-EXCHANGE MEMBRANES 167 4.3.1 TRANSPORT COEFFICIENTS AND THEIR
EQUILIBRIUM VALUES 167 4.3.2 THE DIFFUSION-CONDUCTION FLUX EQUATION
INSIDE CHARGED MEMBRANES 170 4.3.3 DIFFUSION OF A BINARY ELECTROLYTE 173
4.3.4 MEMBRANE PERMSELECTIVITY 182 4.3.5 COUNTERION INTERDIFFUSION
THROUGH AN IDEALLY PERMSELECTIVE MEMBRANE 191 4.3.6 BI-IONIC POTENTIAL
195 4.3.7 TRANSPORT IN MULTI-IONIC SOLUTIONS 196 4.3.8 CONCENTRATION
POLARIZATION IN ION-EXCHANGE MEMBRANE SYSTEMS 199 4.3.9 INFLUENCE OF THE
DIFFUSION BOUNDARY LAYERS ON THE PERMSELECTIVITY 202 4.4 STEADY-STATE
TRANSPORT ACROSS CHARGED POROUS MEMBRANES 205 4.4.1 THE RADIAL
ELECTRICAL DOUBLE LAYER 205 4.4.2 ELECTRO-OSMOTIC CONVECTION 212 4.4.3
TRANSPORT MECHANISMS IN CHARGED POROUS MEMBRANES 217 4.4.4 THEORETICAL
APPROACHES FOR DESCRIBING TRANSPORT IN POROUS MEMBRANES 219 EXERCISES
221 REFERENCES 229 5 TRANSPORT THROUGH LIQUID MEMBRANES 232 5.1
DISTRIBUTION EQUILIBRIA IN LIQUID MEMBRANE SYSTEMS 232 5.1.1 LIQUID
MEMBRANES 232 5.1.2 EQUILIBRIUM PARTITIONING AT THE AQUEOUS/ORGANIC
SOLUTION INTERFACE 233 5.1.3 FINITE-VOLUME EFFECTS ON THE PARTITIONING
OF A NEUTRAL SOLUTE 235 5.1.4 FINITE-VOLUME EFFECTS ON THE PARTITIONING
OF AN IONIC SOLUTE 237 5.2 ION TRANSFER ACROSS A LIQUID MEMBRANE 239 5.3
CARRIER-MEDIATED TRANSPORT 243 5.3.1 SOLUTE PERMEABILITY IN A SUPPORTED
LIQUID MEMBRANE 243 5.3.2 FREE SOLUTE TRANSPORT: THE
SOLUBILITY-DIFFUSION MECHANISM 244 5.3.3 THE EFFECT OF THE DIFFUSION
BOUNDARY LAYERS ON FREE SOLUTE TRANSPORT 245 CONTENTS 5.3.4
CARRIER-MEDIATED SOLUTE TRANSPORT: THE FACILITATION FACTOR 246 5.3.5 THE
EFFECT OF THE DIFFUSION BOUNDARY LAYERS ON CARRIER-MEDIATED TRANSPORT
252 5.3.6 EXTRACTION OF AN ACID 255 5.3.7 ADDITIONAL COMMENTS ON THE
MODELLING OF CARRIER-MEDIATED TRANSPORT 260 5.4 CARRIER-MEDIATED COUPLED
TRANSPORT 261 5.4.1 INTRODUCTION 261 5.4.2 COMPETITIVE BINDING OF TWO
NEUTRAL SOLUTES TO A CARRIER 262 5.4.3 SEQUENTIAL BINDING OF TWO NEUTRAL
SOLUTES TO A CARRIER 267 5.4.4 POLYELECTROLYTE EXTRACTION BY
CARRIER-MEDIATED CO-TRANSPORT WITH AN ACID 270 5.4.5 POLYELECTROLYTE
EXTRACTION BY CARRIER-MEDIATED COUNTERTRANSPORT WITH AN ACID 273
EXERCISES 276 REFERENCES 276 LIST OF SYMBOLS 278 INDEX 285
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| author | Kontturi, Kyösti Murtomäki, Lasse Manzanares, José A. |
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| indexdate | 2024-12-23T20:59:51Z |
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| isbn | 9780199533817 9780198719991 |
| language | English |
| lccn | 2008001077 |
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| spellingShingle | Kontturi, Kyösti Murtomäki, Lasse Manzanares, José A. Ionic transport processes in electrochemistry and membrane science Irreversible processes Ion flow dynamics Transport theory Liquid-liquid interfaces Nonequilibrium thermodynamics Membran (DE-588)4038571-1 gnd Ionentransport (DE-588)4162351-4 gnd Elektrochemie (DE-588)4014241-3 gnd |
| subject_GND | (DE-588)4038571-1 (DE-588)4162351-4 (DE-588)4014241-3 |
| title | Ionic transport processes in electrochemistry and membrane science |
| title_auth | Ionic transport processes in electrochemistry and membrane science |
| title_exact_search | Ionic transport processes in electrochemistry and membrane science |
| title_full | Ionic transport processes in electrochemistry and membrane science Kyösti Kontturi and Lasse Murtomäki, José A. Manzanares |
| title_fullStr | Ionic transport processes in electrochemistry and membrane science Kyösti Kontturi and Lasse Murtomäki, José A. Manzanares |
| title_full_unstemmed | Ionic transport processes in electrochemistry and membrane science Kyösti Kontturi and Lasse Murtomäki, José A. Manzanares |
| title_short | Ionic transport processes |
| title_sort | ionic transport processes in electrochemistry and membrane science |
| title_sub | in electrochemistry and membrane science |
| topic | Irreversible processes Ion flow dynamics Transport theory Liquid-liquid interfaces Nonequilibrium thermodynamics Membran (DE-588)4038571-1 gnd Ionentransport (DE-588)4162351-4 gnd Elektrochemie (DE-588)4014241-3 gnd |
| topic_facet | Irreversible processes Ion flow dynamics Transport theory Liquid-liquid interfaces Nonequilibrium thermodynamics Membran Ionentransport Elektrochemie |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016465069&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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