Fundamentals of nanotechnology

This textbook is for the next generation of nanotechnologists. It surveys the field's broad landscape, exploring the physical basics such as nanorheology, nanofluidics, and nanomechanics as well as industrial concerns such as manufacturing, reliability, and safety. The authors then explore the...

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adam_text Titel: Fundamentals of nanotechnology Autor: Hornyak, Gabor L Jahr: 2009 ONTENTS Preface xvii Acknowledgments xxi Authors xxv Chapter Opening Captions and Credits xxix SECTION 1: PERSPECTIVES 1 Chapter 1 Introduction 3 1.0 Perspectives of Nanotechnology 4 1.0.1 Review of Definitions 5 1.0.2 Technology Revolution or Evolution ? 6 1.0.3 Outlook 9 1.0.4 The Nano Perspective 10 1.1 The Business of Nanotechnology 10 1.1.1 Background 11 1.1.2 Companies 12 1.1.3 Sources of Nanotechnology Inventions 13 1.1.4 Founding a Company?What to Do First? 14 1.1.5 Business Structures 16 1.1.6 Registering a Company? Where ? 18 1.1.7 Finances 20 1.1.8 Managing the Company 20 1.1.9 Developing and Manufacturing a Product 21 1.1.10 Marketing 22 1.1.11 Exits 22 1.2 Education and Workforce Development 23 1.2.1 Technological Revolutions?The Workforce Point of View 24 1.2.2 The State of Education and Workforce Development 25 1.2.3 Current Workforce and Education Programs 27 1.2.4 The Workforce of the Future 27 1.2.5 Planning Ahead and Potential Career Paths 28 VI 1.3 Buildings for Nanotech 29 1.3.1 Nanotechnology in Buildings?Environmental Aspects 30 1.3.2 The Needs of Scientists and Engineers (And Equipment and Instrumentation) 33 1.3.3 Advanced Facilities That Support Nano and Biotech 39 1.4 National and International Infrastructure 42 1.4.1 Research and Development Organizations 43 1.4.2 Economic Development Organizations 44 1.4.3 Organizations Centered on Societal Implications 44 1.4.4 Nanotechnology News Services 45 1.4.5 International Organizations and Institutes 46 1.5 Nanotechnology Products 47 Acknowledgments 48 References 48 Problems 50 Chapter 2 Nanometrology: Standards and Nanomanufacturing 53 2.0 The Transition, the Need 56 2.0.1 Background to Nanometrology 57 2.0.2 Background to Nanomanufacturing 61 2.0.3 The Nano Perspective 62 2.1 Nanometrology and Uncertainty 64 2.1.1 Nanometrology 66 2.1.2 Uncertainty 66 2.1.3 Heisenberg Uncertainty 68 2.1.4 Quantum Entanglement 71 2. J. 5 Applications 76 2.2 Quantum Metrology 78 2.2.1 Atomic Clocks, the Meter, and Time 79 2.2.2 The Quantum Triangle 84 2.2.3 The Single-Electron Transistor 88 2.3 Nanometrology Tools 90 2.3.1 Electron Beam and Atomic Force Tools 90 2.3.2 Spectroscopic Tools 93 2.3.3 Nanomechanical Tools 96 2.4 Nanometrology and Nanomanufacturing Standards 98 2.4.1 Standards for Nanotechnology 99 2.4.2 NIST Efforts 100 2.4.3 IEEE Roadmap for Nanoelectronics 101 VII 2.5 Nanomanufacturing and Molecular Assembly 2.5. J Lithographies 102 2.5.2 Nanomanipulators and Grippers 103 2.5.3 Bottom-Up Manufacturing 105 2.5.4 Molecular Scale Assembly Lines 107 2.6 Concluding Remarks 112 References 112 Problems 119 102 SECTION 2: ELECTROMAGNETIC NANOENGINEERING 121 Chapter 3 Nanoelectronics 123 3.0 Electronics and Nanoelectronics 124 3.0.1 Basic Electronic Terminology and Symbols 124 3.0.2 Fundamental Types of Electronic Materials (and Nanomaterials) 124 3.0.3 Fundamental Kinds of Electronic Devices 126 3.0.4 The Nano Perspective 129 3.1 Microelectronics 130 3.1.1 Introduction to Band Structure 130 3.1.2 Basic Conductor and Semiconductor Physics 135 3.1.3 Transistors 149 3.2 Nanoscale Electronics 150 3.2.1 Background 150 3.2.2 The Current State of Microelectronics and Extensions to the Nanoscale 150 3.2.3 Nanotechnology-Based Strategies: Single-Electron Tunneling 151 3.2.4 Nanotechnology-Based Strategies: Molecular Wires 157 References 163 Problems 164 Chapter 4 Nano-Optics 165 4.0 Introduction to Optics 166 4.0.1 Interactions of Light with Matter 169 4.0.2 The Nano Perspective 172 4.1 The Surface Plasmon 173 4.1.1 The Surface Plasmon Resonance 173 4. J.2 Scattering 179 4.1.3 Color Generation from Nanoparticles and Nanostructures 181 4.1.4 Applications of Nanoplasmonics 182 VIII 4.2 Quantum Dots 184 4.2.1 The Bohr Exciton Radius 184 4.2.2 Tuning the Gap 185 4.2.3 Luminescence 186 4.2.4 Applications 187 4.3 Near-Field Microscopies 191 4.3.1 The Diffraction Limit 191 4.3.2 Near-Field M icroscopy 192 4.3.3 Applications 193 4.4 Nanophotonics 194 4.4.1 Photonics 194 4.4.2 Photonic Structures in Living Systems 195 4.4.3 Photonic Crystals 196 4.4.4 Fabrication of Nanophotonic Crystals 199 References 200 Problems 202 Chapter 5 Nanomagnetism 203 5.0 Introduction 204 5.0.1 History 204 5.0.2 Magnetic Phenomena and Their Classical Interpretation 205 5.0.3 The Nano Perspective 207 5.1 Characteristics of Nanomagnetic Systems 208 5.1.1 Introduction to Nanomagnetism 208 5.1.2 Characteristics of Nanomagnetic Materials 211 5.1.3 Magnetization and Nanostructures 212 5.2 Magnetism in Reduced Dimensional Systems 218 5.2.1 Two-Dimensional Systems 218 5.2.2 One-Dimensional Systems 219 5.2.3 Zero-Dimensional Systems 219 5.3 Physical Properties of Magnetic Nanostructures 220 5.3.1 Substrate Effects on Structures and Related Properties 220 5.3.2 Oscillatory Exchange Coupling 220 5.3.3 Spin-Polarized Tunneling 220 5.3.4 Magnetoresistivity 221 5.3.5 Magnetic Moments of 3d Transition Metal Clusters 221 5.3.6 The Temperature Dependence of Magnetic Moments 222 5.4 Recent Progress in Nanoscale Sample Preparation 223 5.4.1 Epitaxial Methods 223 IX 5.5 Nanomagnetism Applications 223 5.5.1 Overview 223 5.5.2 Current Status of Spin-Based Electronics Devices 226 5.5.3 Sensors 229 5.5.4 Nanomagnetism for Biomedical Applications 230 References 234 Problems 234 SECTION 3: MECHANICAL NANOENGINEERING 237 Chapter 6 Nanomechanics 239 6.0 Introduction 240 6.0.1 Two-Atom Chain Mechanics 240 6.0.2 Interaction Potentials 241 6.0.3 External Forces 247 6.0.4 Dynamic Motion 248 6.1 Three-Atom Chain 249 6.2 Lattice Mechanics 250 6.3 Stress and Strain 253 6.4 Linear Elasticity Relations 255 6.4.1 Orthotopic and Isotropic Materials 256 6.4.2 Crystalline Materials 256 6.5 Molecular Dynamics 258 6.5.1 Verlet Algorithms 258 6.5.2 NordsieckfGear Predictor-Corrector Methods 259 6.5.3 Molecular Dynamics Applications 261 6.5.4 Nanomachines 264 6.5.5 Wear at the Nanometer Level 265 6.6 Structure and Mechanical Properties of Carbon Nanotubes 266 6.6.1 Structure of Carbon Nanotubes 266 6.6.2 Mechanical Properties of Carbon Nanotubes 268 6.7 Nanomechanical Measurement Techniques and Applications 269 6.7.1 AFM Measurements: Mechanical Properties of CNTs 270 6.7.2 Nanoindentation 272 6.8 Nano-Microelectromechanical Systems (NEMS/MEMS) 274 6.8.1 MEMS Fabrication Techniques 274 6.8.2 NEMS Fabrication Techniques 279 6.8.3 NEMS/MEMS Motion Dynamics 280 6.8.4 MEMS Devices and Applications 282 6.8.5 NEMS Devices and Applications 284 6.9 Summary 285 Acknowledgments 285 References 286 Problems 289 Chapter 7 Nanostructure and Nanocomposite Thin Films 293 7.0 Introduction 294 7.1 Classification of Nanostructured, Nanocomposite Tribological Coatings 294 7.1.1 Nanoscale Multilayer Coatings 294 7.1.2 Nanocomposite Coatings 296 7.1.3 Functionally Graded Coatings 300 7.2 Background of Nanostructured Super-Hard Coatings 301 7.2.1 Nanoscale Multilayer Coatings 303 7.2.2 Single-Layer Nanocomposite Coatings 304 7.3 New Directions for Nanostructured Super-Tough Coatings 306 7.3.1 Functionally Graded Multilayer Coatings 306 7.3.2 Functionally Graded Nanocomposite Coatings 308 7.4 Processing Techniques and Principles 309 7.4.1 Plasma Definition 310 7.4.2 Chemical Vapor Deposition 311 7.4.3 Physical Vapor Deposition 314 7.5 General Considerations and Practical Aspects of Sputtering Deposition 331 7.5.1 Reactive Sputtering Deposition Process Stability 332 7.5.2 Film Structure Control (Structure Zone Models) 334 7.5.3 Sputtering Glow Discharges 337 7.5.4 Energetic Enhanced Deposition 339 References 347 Problems 358 Chapter8 Applications of Thin Films 361 8.0 Technological Applications of Thin Films Unbalanced Magnetron Sputtering of Ti-Al-Si-N Coatings 362 Unbalanced Magnetron Sputtering of Ti-Si-B-C-N Coatings 365 362 8.1 8.2 8.3 Pulsed Closed Field Unbalanced Magnetron Sputtering of Cr-Al-N Coatings 370 8.4 Concluding Remarks 379 References 380 Problems 381 SECTION 4: CHEMICAL NANOENGINEERING 383 Chapter 9 Nanocatalysis 385 9.0 Introduction to Catalytic and Nanocatalytic Materials 387 9.0.1 The Importance of Catalysis in a Modern Society 387 9.0.2 What Is a Catalyst? 387 9.0.3 The Nano Perspective 388 9.1 Fundamentals of Catalysis 390 9.1.1 Adsorption of a Molecule on a Catalyst Surface 390 9.1.2 Adsorption Theory 392 9.1.3 Surface Reactions 395 9.2 Synthesis 398 9.2.1 Synthesis Requirements 398 9.2.2 Example of a Conventional Synthetic Technique 9.2.3 Nontraditional Methods for Preparing Nanocatalysts 400 9.3 Catalyst Characterization 401 9.3.1 Overview 401 9.3.2 Bulk Characterization Techniques 402 9.3.3 Surface Characterization Techniques 404 Acknowledgments 405 References 406 399 Chapter 10 Nanocomposites and Fibers 407 10.0 Nanocomposites and Fibers 408 10.0.1 Background 410 10.0.2 Overview of Engineering Materials 412 10.0.3 Types of Composite Materials and Generic Structures 414 10.0.4 The Nano Perspective 416 10.1 Physical and Chemical Properties of Materials 418 10.1.1 Mechanical Properties 418 10.1.2 Thermal Properties 428 10.1.3 Electronic Properties 430 10.1.4 Chemical Properties 432 XII 10.2 Natural Nanocomposites 434 10.2.1 Skin of the Sea Cucumber 434 10.2.2 Hard Natural Nanocomposites 434 10.3 Carbon Fibers and Nanotubes 437 10.3.1 Types of Fibers, Whiskers, and Nanotubes 439 10.3.2 Synthesis of Fibers and Nanotubes 441 10.3.3 Chemical Modification of Carbon Nanotubes 446 10.3.4 Carbon Nanotube Applications 448 10.4 Organic Polymer Nanocomposites 451 10.4.1 Introduction to Polymers 452 10.4.2 Interfacial Area 454 10.4.3 Nanofilled Composite Design, Synthesis, and Properties 456 JO.4.4 Enhanced Polymer Nanocomposites 457 10.5 Metal and Ceramic Nanocomposites 462 10.5.1 Metal Nanocomposites 462 10.5.2 Inorganic Nanofibers 463 10.5.3 Cermets 464 10.5.4 Concrete 465 10.6 Clay Nanocomposite Materials 467 10.6.1 Polypropylene-Clay Nanocomposites 467 10.6.2 Montmorillonite Clay Nanocomposites 469 10.6.3 Halloysite Nanotube Clay Composites 470 References 472 Problems 478 SECTION 5: BIOLOGICAL AND ENVIRONMENTAL NANOENGINEERING 479 Chapter 11 Nanobiotechnology 481 11.0 Introduction to Nanobiotechnology 482 11.0.1 Definitions 483 11.0.2 Biotechnology 483 11.0.3 Bio-Nanotechnology 483 11.0.4 Biomolecular Nanotechnology 483 11.0.5 Biomedical Nanotechnology 484 11.0.6 Nanobiotechnology 484 11.1 The Biological Immune System 484 11.1.1 Natural Molecular Recognition 484 11.1.2 The Innate Immune System 486 11.1.3 The Adaptive Immune System 486 11.1.4 White Blood Celb and Antibodies 488 XIII 11.2 Using Antibodies in Biosensors: Immunoassays 490 11.2.1 Antibodies in Molecular Recognition Sensors 490 11.2.2 Production of Antibodies 490 11.2.3 Monoclonal Antibodies 490 11.2.4 Reverse Transcriptase 491 11.2.5 Recombinant DNA 491 11.2.6 Antibodies as Selection Tools for Biosensors 491 11.3 Cantilevers as Nano-Biosensors 492 11.3.1 Sensing Physical Properties 492 11.3.2 Cantilevers and Selective Binding 493 11.3.3 Active Cantilever Sensors 493 11.3.4 Passive Cantilever Sensors 493 11.3.5 Surface Effects on Nanocantilevers 494 11.3.6 Steric Effects 494 11.3.7 Surface Free Energy at the Nanoscale 495 11.4 Micro-and Nanosensors and Applications 495 11.4.1 Biomedical Cantilever Applications 495 11.4.2 Cantilever Sensor for Cancer Screening 496 11.4.3 Biotechnology Applications of Cantilevers 496 11.4.4 Surface Acoustic Wave Nanosensors 497 11.4.5 Electrochemical Nanosensors 498 11.5 Optical Nanosensors 500 11.5.1 Photonic Nanosensors 500 11.5.2 Surface Plasmon Nanosensors 501 11.5.3 Nanoscale Optical Resonance Grids?Using the Butterfly Wing Effect 503 11.5.4 Guided-Mode Resonance Sensors 503 11.5.5 Applications of Guided Mode Sensors 504 11.6 Nanotechnology for Manipulation of Biomolecules 506 11.6.1 Optical Tweezers 506 11.6.2 Dielectrophoresis 507 11.6.3 Some Dielectrophoresis Applications 508 11.6.4 M icro- and Nanofluidics 510 11.6.5 Biochips, Labs on Chips, and Integrated Systems 511 11.7 Summary 513 Acknowledgments 513 References 513 Problems 519 XIV Chapter 12 Biomimetics 521 12.0 The Bio Sciences and Technologies 522 12.0.1 Biomimetics, Bioengineering, and Other Bioengineering Fields 522 12.0.2 Biomimetics as an Emerging Science and Engineering Discipline 526 12.0.3 Biomimetic Systems 526 12.0.4 The Nano Perspective 527 12.1 Biomimetic Design of Molecules 528 12.1.1 Design and Discovery of Drugs 529 12.1.2 Targeting with Magic Bullets 530 12.1.3 Aspirin: Signaling Pathways Revealed by the Willow 532 12.1.4 Taxol: Novel Drug Actions on the Nanolevel 536 12.1.5 Pyrethrum: Learning from the Daisy 538 12.2 Biomimetic Nanomaterials 540 12.2.1 Biomimetic Mineral Nanoparticles 541 12.2.2 Shell as a Biomodel 542 12.2.3 Nanoengineering Bone 546 12.2.4 Sponge Fiber Photonics 548 12.2.5 The Lesson of the Lotus? Nanocon trol of Surfaces 551 12.2.6 Gecko Glue and Other Biomimetic Nanoadhesives 554 12.2.7 Biomimetic Membranes and Nanocapsules 565 12.2.8 Some Other Biomimetic Materials 567 12.3 Biomimetic Nanoengineering 568 12.3.1 Artificial Muscles 568 12.3.2 Viral Energy Storage 571 12.3.3 Photosynthesis 572 12.3.4 Sensors Based on Biomimetic Moieties 582 12.3.5 Biomimetic Molecular Nanoengines 583 12.4 Conclusion 586 References 587 Problems 603 Chapter 13 Medical Nanotechnology 605 13.0 Introduction to Medical Nanotechnology 607 13.0.1 Definitions: Medicine and Medical Nanoscience 607 13.0.2 Historical Origins: Medical Breakthroughs 608 13.0.3 Medical Nanoscience: Roots in Medical Science 611 XV 13.0.4 Future Possibilities for Medical Nanotechnology: Nanomedicine 612 13.0.5 Putting Medical Nanoscience into Practice: Medical Nanotechnology 616 13.1 Nanoparticles and Nanoencapsulation for Medical Applications 617 13.1.1 Nanoparticles for Medical Imaging 618 13.1.2 Nanoparticles for Targeting Cancer Cells 619 13.1.3 Nanoencapsulation for Drug Delivery to Tumors 620 13.1.4 Nanoencapsulation for Penetration of the Blood-Brain Barrier 621 13.1.5 Nanoparticles and Nanoencapsulation for Insulin Delivery 623 13.1.6 Nanoencapsulation for Protection of Implants from the Immune System 626 13.2 Guiding and Stimulating Tissue Function and Growth 627 13.2.1 Nanoguides for Neural Growth and Repair 627 13.2.2 Neuronal Stimulation and Monitoring 634 13.2.3 Neurostimulation for Pain and Nervous Disorders 635 13.2.4 Neuroprosthetics 636 13.2.5 Neuroprosthetics for the Ear 653 13.2.6 Vision Prosthetics 658 13.3 Summary 662 Acknowledgments 663 References 663 Problems 682 Chapter 14 Environmental Nanotechnology 683 14.0 The Environment (and Technology) 684 14.0.1 Background 685 14.0.2 Traditional Methods of Detecting Environmental Contaminants 686 14.0.3 Types of Environmental Sensors 687 14.0.4 Introduction to Environmental Mitigation 695 14.0.5 National Security and Defense 700 14.0.6 The Nano Perspective 706 14.1 Water and Soil Quality, Monitoring, and Mitigation 708 14.1.1 Traditional Water Treatment 709 14.1.2 Nanomaterial Contamination in Aqueous Environments 711 XVI 14.1.3 Activated Carbon?A Simple Traditional Nanotechnology 713 14.1.4 Membranes and Separation Technology 716 14.1.5 Oil Spills 721 14.1.6 Chemical and Biological Sensors and Detectors 722 14.2 Air Quality, Monitoring, and Mitigation 722 14.2.1 Gas Separation: Advanced Membrane Technology 723 14.2.2 C02 Mitigation 726 14.2.3 Hydrogen Production and Purification 727 14.2.4 Chemical Sensing and Detection 728 14.3 Energy 728 14.3.1 Solar Energy and Nano 730 14.3.2 Batteries 739 14.3.3 Hydrogen Production and Storage 742 14.3.4 Fuel Cells 748 14.3.5 Solar Heating and Power Generation 751 14.4 Epilogue 751 14.4.1 SAMMS 752 14.4.2 One More Pass at Hydrogen Storage 753 14.4.3 Concluding Thoughts 755 Acknowledgments 755 References 755 Problems 767 Index 769
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Nanostructured materials industry
Nanotechnology
Nanostruktur (DE-588)4204530-7 gnd
Nanotechnologie (DE-588)4327470-5 gnd
subject_GND (DE-588)4204530-7
(DE-588)4327470-5
title Fundamentals of nanotechnology
title_alt Introduction to nanotechnology
title_auth Fundamentals of nanotechnology
title_exact_search Fundamentals of nanotechnology
title_full Fundamentals of nanotechnology Gabor L. Hornyak ...
title_fullStr Fundamentals of nanotechnology Gabor L. Hornyak ...
title_full_unstemmed Fundamentals of nanotechnology Gabor L. Hornyak ...
title_short Fundamentals of nanotechnology
title_sort fundamentals of nanotechnology
topic Nanochimie
Nanomatériaux - Industrie
Nanosciences
Nanosystèmes électromécaniques
Nanotechnologie
Nanoélectronique
Nanostructured materials industry
Nanotechnology
Nanostruktur (DE-588)4204530-7 gnd
Nanotechnologie (DE-588)4327470-5 gnd
topic_facet Nanochimie
Nanomatériaux - Industrie
Nanosciences
Nanosystèmes électromécaniques
Nanotechnologie
Nanoélectronique
Nanostructured materials industry
Nanotechnology
Nanostruktur
url http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016381286&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA
work_keys_str_mv AT hornyakgaborl fundamentalsofnanotechnology
AT hornyakgaborl introductiontonanotechnology