Symmetry and structure readable group theory for chemists
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| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Hoboken, N.J.
Wiley
2007
|
| Ausgabe: | 3. ed. |
| Schlagworte: | |
| Online-Zugang: | Table of contents only Inhaltsverzeichnis |
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| 100 | 1 | |a Kettle, Sidney F. A. |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Symmetry and structure |b readable group theory for chemists |c Sidney F. A. Kettle |
| 250 | |a 3. ed. | ||
| 264 | 1 | |a Hoboken, N.J. |b Wiley |c 2007 | |
| 300 | |a VIII, 426 S. |b graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 650 | 4 | |a Liaisons chimiques | |
| 650 | 4 | |a Molécules | |
| 650 | 4 | |a Structure chimique | |
| 650 | 4 | |a Symétrie (Physique) | |
| 650 | 4 | |a Théorie des groupes | |
| 650 | 4 | |a Chemical structure | |
| 650 | 4 | |a Symmetry (Physics) | |
| 650 | 4 | |a Group theory | |
| 650 | 4 | |a Chemical bonds | |
| 650 | 4 | |a Molecules | |
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Datensatz im Suchindex
| DE-19_call_number | 1701/Ma 8196 1801/VE 5700 K43(3) |
|---|---|
| DE-19_location | 1701 85 |
| DE-BY-TUM_call_number | 0302 CHE 158f 1995 A 2903(3) |
| DE-BY-TUM_katkey | 1603660 |
| DE-BY-TUM_location | 03 |
| DE-BY-TUM_media_number | 040030187856 |
| DE-BY-UBM_katkey | 3890860 |
| DE-BY-UBM_media_number | 99995647009 41624516200016 |
| _version_ | 1823054009683935232 |
| adam_text | Contents
Preface to Third Edition ix
1 Theories in conftict 1
1.1 Introduction 1
1.2 The ammonia molecule 1
1.2.1 The atomic orbital model 2
1.2.2 The hybrid orbital model 3
1.2.3 The electron-repulsion model 4
1.2.4 The electron-spin-repulsion model 6
1.2.5 Accurate calculations 7
2 The symmetry of the water molecule 11
2.1 Symmetry operations and symmetry elements 11
2.2 Multipliers associated with symmetry operations 19
2.3 Group multiplication tables 36
2.4 Character tables 40
2.5 Summary 43
3 The electronic structure of the water molecule 45
3.1 The orthonormal properties of irreducible representations 45
3.2 The transformation properties of atomic orbitals
in the water molecule 47
3.3 A reducible representation 51
3.4 Symmetry-adapted combinations 54
3.5 The bonding interactions in H20 and their angular dependence 59
3.6 The molecular orbital energy level diagram for H20 65
3.7 Comparison with experiment 67
3.8 The Walsh diagram for triatomic dihydrides 68
3.9 Simple modeis for the bonding in H20 70
3.10 A rapprochement between simple and symmetry modeis 73
3.11 Summary 74
4 Vibrational spectra of the water molecule 75
4.1 Vibrations of the water molecule: Part 1 (easy) 76
4.2 Vibrations of the water molecule: Part 2 (less easy!) 80
4.3 Product functions 92
vi Contents
4.4 Direct products and quantüm mechanical integrals 96
4.5 Spectroscopic selection rules 99
4.6 The vibrational spectroscopy of the water molecule 103
4.7 Optical activity 1°7
4.8 Summary 108
5 D2h character table and the electronic structu^s of ethene
(ethylene) and diborane 1°9
5.1 The symmetry of the ethene molecule 109
5.2 The character and multiplication tables of the ß h group 112
5.3 Direct products of groups H4
5.4 Nodal patterns of the irreducible represerttations of the O2h group 117
5.5 The symmetries of the carbon atomic Orbitals in ethene 121
5.6 The symmetries of the hydrogen ls orbital in ethene 128
5.7 The projection Operator method !29
5.8 Bonding in the ethene molecule l34
5.9 Bonding in the diborane rnolecule I36
5.10 Comparison with other modeis l41
5.11 Summary l44
6 The electronic structure of bromine pentafluoride, BrF5 145
6.1 Symmetry operations of the C*v group l4
6.2 Problems in using the Cm group I50
6.3 Orthonormality relationships l52
6.4 The derivation of the C character table u$ing the orthonormality
theorems l55
6.5 Nodal patterns of the irreducible represen^tions of Gw l6°
6.6 The bonding in the BrF5 molecule l62
6.7 Summary l7
7 The electronic structure of the ammonia moiecuic 1
7.1 The symmetry of the ammonia molecule -1
7.2 Nodal patterns of the irreducible representations of C3v l7
7.3 The bonding in the ammonia molecule ^
7.4 Summary l8
8 The electronic structures of some octahedral nioiecuies 1O
8.1 The symmetry operations of the octahedron 19
8.2 Nodal patterns of the irreducible representations of the 0h group 19
8.3 The bonding in the SF6 molecule 2 g
8.4 Octahedral transition metai complexes g
8.5 Summary 2
9 Point groups and their relationships 231
9.1 The deterrnination of the point group of 3 molecule 5
9.2 The relationships between point groups
CONTENTS VÜ
9.3 Correlation tables 240
9.4 Summary 244
10 Tetrahedral, icosahedral and spherical symmetries 245
10.1 An overview 245
10.2 The tetrahedron 247
10.3 The icosahedron 251
10.4 Spherical symmetry 254
10.5 Linear molecules 261
10.6 Summary 262
11 7r-Electron Systems 263
11.1 Square cydobutadiene and the C4 point group 263
11.2 Working with complex characters4 268
11.3 The n orbitals of cydobutadiene 269
11.4 The energies of the n orbitals of cydobutadiene
in the Hückel approximation 271
11.5 Symmetry and chemical reactions 276
11.6 Summary 280
12 The group theory of electron spin 281
12.1 The problem of electron spin 281
12.2 More about the symmetry of product functions 288
12.3 Configurations and terms 289
12.4 The inclusion of electron spin 294
12.5 Summary 297
13 Space groups 299
13.1 The crystal Systems 299
13.2 The Bravais lattices 308
13.3 The crystallographic point groups 311
13.4 The symmorphic space groups 317
13.5 The non-symmorphic space groups 322
13.6 Unitcells 325
13.7 Wigner-Seitz unit cells 327
13.8 Summary 330
14 Spectroscopic studies of crystals 331
14.1 Translational invariance 331
14.2 The factor group and unit cell group modeis 333
14.3 Examples of use of the factor and unit cell group modeis 336
14.3.1 The v(C0) spectra of crystalline (C6H6)Cr(CO)3 336
14.3.2 The vibrational spectrum of a M(fe0)3 species crystallizing
in the C2/c (C2h6) space group using the unit cell model 340
14.4 Summary 344
Viii CONTENTS
Appendix 1 Groups and classes: definitions and examples 345
Al.l Groups 345
AI.2 Some examples of groups 347
AI.3 The classes of a group 349
A1.4 Classalgebra 352
Appendix 2 Matrix algebra and group theory 355
A2.1 Matrix algebra and symmetry operations 355
A2.2 Direct products 363
Appendix 3 Character tables of the more important point groups 369
Appendix 4 The fluorine group orbitals of n symmetry in SF6 391
A4.1 Ligand group orbitals of complex ions 397
Appendix 5 The Hermann-Mauguin notation 404
Appendix 6 Non-symmorphic relatives of the point group D2 407
A6.1 The space group P2a/c(C^) 416
Index 421
|
| any_adam_object | 1 |
| author | Kettle, Sidney F. A. |
| author_facet | Kettle, Sidney F. A. |
| author_role | aut |
| author_sort | Kettle, Sidney F. A. |
| author_variant | s f a k sfa sfak |
| building | Verbundindex |
| bvnumber | BV022619443 |
| callnumber-first | Q - Science |
| callnumber-label | QD471 |
| callnumber-raw | QD471 |
| callnumber-search | QD471 |
| callnumber-sort | QD 3471 |
| callnumber-subject | QD - Chemistry |
| classification_rvk | VE 5700 |
| classification_tum | CHE 130f CHE 158f CHE 150f |
| ctrlnum | (OCoLC)237893166 (DE-599)DNB 2007014664 |
| dewey-full | 541/.22015122 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 541 - Physical chemistry |
| dewey-raw | 541/.22015122 |
| dewey-search | 541/.22015122 |
| dewey-sort | 3541 822015122 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie Physik |
| edition | 3. ed. |
| format | Book |
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| id | DE-604.BV022619443 |
| illustrated | Illustrated |
| indexdate | 2025-02-03T17:14:18Z |
| institution | BVB |
| isbn | 9780470060407 0470060409 |
| language | English |
| lccn | 2007014664 |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-015825532 |
| oclc_num | 237893166 |
| open_access_boolean | |
| owner | DE-91G DE-BY-TUM DE-20 DE-19 DE-BY-UBM DE-11 DE-384 |
| owner_facet | DE-91G DE-BY-TUM DE-20 DE-19 DE-BY-UBM DE-11 DE-384 |
| physical | VIII, 426 S. graph. Darst. |
| publishDate | 2007 |
| publishDateSearch | 2007 |
| publishDateSort | 2007 |
| publisher | Wiley |
| record_format | marc |
| spellingShingle | Kettle, Sidney F. A. Symmetry and structure readable group theory for chemists Liaisons chimiques Molécules Structure chimique Symétrie (Physique) Théorie des groupes Chemical structure Symmetry (Physics) Group theory Chemical bonds Molecules Molekülsymmetrie (DE-588)4170385-6 gnd Symmetrie (DE-588)4058724-1 gnd Chemische Struktur (DE-588)4009857-6 gnd Chemische Bindung (DE-588)4009843-6 gnd Molekülstruktur (DE-588)4170383-2 gnd Gruppentheorie (DE-588)4072157-7 gnd |
| subject_GND | (DE-588)4170385-6 (DE-588)4058724-1 (DE-588)4009857-6 (DE-588)4009843-6 (DE-588)4170383-2 (DE-588)4072157-7 |
| title | Symmetry and structure readable group theory for chemists |
| title_auth | Symmetry and structure readable group theory for chemists |
| title_exact_search | Symmetry and structure readable group theory for chemists |
| title_full | Symmetry and structure readable group theory for chemists Sidney F. A. Kettle |
| title_fullStr | Symmetry and structure readable group theory for chemists Sidney F. A. Kettle |
| title_full_unstemmed | Symmetry and structure readable group theory for chemists Sidney F. A. Kettle |
| title_short | Symmetry and structure |
| title_sort | symmetry and structure readable group theory for chemists |
| title_sub | readable group theory for chemists |
| topic | Liaisons chimiques Molécules Structure chimique Symétrie (Physique) Théorie des groupes Chemical structure Symmetry (Physics) Group theory Chemical bonds Molecules Molekülsymmetrie (DE-588)4170385-6 gnd Symmetrie (DE-588)4058724-1 gnd Chemische Struktur (DE-588)4009857-6 gnd Chemische Bindung (DE-588)4009843-6 gnd Molekülstruktur (DE-588)4170383-2 gnd Gruppentheorie (DE-588)4072157-7 gnd |
| topic_facet | Liaisons chimiques Molécules Structure chimique Symétrie (Physique) Théorie des groupes Chemical structure Symmetry (Physics) Group theory Chemical bonds Molecules Molekülsymmetrie Symmetrie Chemische Struktur Chemische Bindung Molekülstruktur Gruppentheorie |
| url | http://www.loc.gov/catdir/toc/ecip0715/2007014664.html http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=015825532&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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