Integrated reaction and separation operations modelling and experimental validation

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Hauptverfasser: Schmidt-Traub, Henner 1940-2020 (VerfasserIn), Górak, Andrzej 1951- (VerfasserIn)
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Sprache:English
Veröffentlicht: Berlin [u.a.] Springer 2006
Schriftenreihe:Verfahrenstechnik
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adam_text TABLE OF CONTENTS 1 INTRODUCTION ............................................................................................. 1 2 SYNTHESIS OF REACTIVE SEPARATION PROCESSES .......................................... 7 2.1 INTRODUCTION ...................................................................................... 7 .......................................... 2.2 FUNDAMENTAL PROCESS SYNTHESIS CONCEPTS 8 ............................................................... 2.3 PROCESS SYNTHESIS STRATEGY 17 ........................................................................... 2.3.1 PROCESS GOALS 18 2.3.2 DATA ACQUISITION / THERMODYNAMIC ANALYSIS ............................. 18 2.3.3 INVESTIGATION OF THE REACTION PHASE .......................................... 19 ...................................................... 2.3.4 IDENTIFICATION OF INCENTIVES 19 .......................................... 2.3.5 SELECTION OF THE SEPARATION PROCESS 19 2.3.6 KNOCK-OUT CNTERIA .................................................................... 21 ................... 2.3.7 ESTIMATION OF PRODUCT REGIONS FOR FULL INTEGRATION 21 ..................... 2.3.8 MEASURES TO ACHIEVE THE DESIRED PRODUCT QUALITY 25 ................................................... 2.3.9 NECESSITY OF ADDITIONAL STEPS 26 2.3.10 SIMULATION AND OPTIMIZATION ............................................... 26 .............................................................................. 2.3.1 1 EXAMPLES 27 ......................................................... 2.4 OPTIMIZATION OF THE PROCESS 6 1 ........................................................... 2.4.1 THE OPTIMIZATION MODEL 63 2.4.2 SOLUTION METHOD ....................................................................... 67 2.4.3 EXAMPLES ................................................................................. 70 .................................................................................... 2.5 CONCLUSIONS 84 .......................................................................................... 2.6 NOTATION 85 2.7 LITERATURE ........................................................................................ 88 3 CATALYTIC DISTILLATION .......................................................................... 95 .................................................................................... 3.1 INTRODUCTION 95 3.2 BASICS OF CATALYTIC DISTILLATION ......................................................... 96 ................................................................................. 3.2.1 CATALYST 9 8 ................................................................................. 3.2.2 INTERNALS 101 3.3 MODELING ....................................................................................... 103 ........................................................ 3.3.1 EQUILIBNUM STAGE MODEL 105 .............................................................. 3.3.2 RATE-BASED APPROACH 106 3.4 MODEL PARAMETERS ........................................................................ 110 ....................................................... 3.4.1 VAPOR-LIQUID EQUILIBRIUM 110 3.4.2 REACTION KINETICS ................................................................. 110 3.4.3 HYDRODYNAMICS AND MASS TRANSFER ....................................... 112 3.4.4 DIFFERENTIAL MODELS ............................................................. 114 X TABLE OF CONTENTS 3.5 CASE STUDIES .................................................................................. 115 3.5.1 METHYL ACETATE SYNTHESIS ..................................................... 115 3 .5.2 ETHYL ACETATE SYNTHESIS ......................................................... 119 3.5.3 ETHYL ACETATE TRANSESTERIFICATION ....................................... 123 3.5.4 DIMETHYL CARBONATE TRANSESTERIFICATION .................................. 127 3.6 CONCLUSIONS .................................................................................. 133 ........................................................................................ 3.7 NOTATION 135 ...................................................................................... 3.8 LITERATURE 137 4 REACTIVE GAS ADSORPTION ...................................................................... 149 4.1 INTRODUCTION .................................................................................. 149 4.1.1 GAS-PHASE ADSORPTIVE REACTORS - OPERATION AND REGENERATION ................................................................................ STRATEGIES 151 4.1.2 COMPARISON WITH RELATED REACTOR CONCEPTS ............................. 153 4.2 MODELING OF GAS-PHASE ADSORPTIVE REACTORS .................................. 155 4.2.1 MODEL EQUATIONS .................................................................... 155 4.2.2 MODEL IMPLEMENTATION AND NUMERICAL FEATURES ..................... 159 4.3 DESIGN PRINCIPLES OF ADSORPTIVE REACTORS ....................................... 160 .......... 4.4 CONVERSION ENHANCEMENT OF EQUILIBRIUM-LIMITED REACTIONS 161 ........................................................................ 4.4.1 CLAUS REACTION 161 4.4.2 HCN-SYNTHESIS FROM CO AND NH3 ........................................ 168 4.4.3 WATER-GAS SHIFI REACTION ......................................................... 172 4.5 YIELD AND SELECTIVITY ENHANCEMENT FOR COMPLEX REACTION SCHEMES ........................................................................................ 172 ......................... 4.5.1 DIRECT SYNTHESIS OF DME FROM SYNTHESIS GAS 173 4.5.2 OXIDATIVE DEHYDROGENATION OF ETHYLBENZENE TO STYRENE ......... 179 4.6 CONCLUSIONS .................................................................................. 184 4.7 NOTATION ..................................................................................... 185 4.8 LITERATURE ...................................................................................... 187 5 REACTIVE LIQUID CHROMATOGRAPHY ....................................................... 191 5.1 INTRODUCTION .................................................................................. 191 ........................................................................... 5.2 PROCESS CONCEPTS 192 ............................................. 5.2.1 CHROMATOGRAPHIC BATCH REACTOR 192 .................................................... 5.2.2 CONTINUOUS ANNULAR REACTOR 193 ................................................ 5.2.3 COUNTER-CURRENT FLOW REACTORS 194 ................................................ 5.2.4 DEGREE OF PROCESS INTEGRATION 199 5.3 MODELING OF SIMULATED MOVING BED REACTORS ................................ 200 5.3.1 RIGOROUS MODELS .................................................................... 202 ......................................................................... 5.3.2 TMBR MODEL 208 5.3.3 COMPARISON OF TMBR AND SMBR ........................................ 210 5.4 EXPERIMENTAL MODEL VALIDATION ................................................... 1 TABLE OF CONTENTS XI ...................................................... 5.4.1 PARAMETER DETERMINATION 211 .......................................... 5.4.2 PRODUCTION OF P-PHENETHYLACETATE 214 ................................ 5.4.3 THERMAL RACEMIZATION OF TROEGERS BASE 217 ................................. 5.5 SHORT-CUT DESIGN METHODS FOR SMB REACTORS 219 ........................................ 5.5.1 REACTIONS OF TYPE A + B T, C + D 220 ......................................................... 5.5.2 OTHER TYPES OF REACTION 224 ............... 5.5.3 SHORT-CUT CALCULATION FOR IRREVERSIBLE ESTERIFICATION 225 ............................................. 5.6 DESIGN OF CHROMATOGRAPHIC REACTORS 226 5.6.1 CHOICE OF THE CHROMATOGRAPHIC SYSTEM .................................. 226 5.6.2 MODEL BASED OPTIMIZATION OF DESIGN AND OPERATING PARAMETERS .............................................................................. 227 ...... 5.6.3 EVALUATION AND APPLICATION OF CHROMATOGRAPHIC REACTORS 229 5.7 NOTATION ........................................................................................ 234 ...................................................................................... 5.8 LITERATURE 236 6 REACTIVE EXTRACTION ........................................................................ 241 6.1 LNTRODUCTION .................................................................................. 241 6.2 REACTIVE EXTRACTION SYSTEMS ...................................................... 241 6.2.1 SEPARATION PROCESSES .............................................................. 242 ............................................................... 6.2.2 SYNTHESIS PROCESSES 243 6.3 SYSTEM ANALYSIS AND PLANT DESIGN ............................................... 244 ............................................. 6.3.1 ANALYSIS OF THE REACTION SYSTEM 246 6.4 MODELLING ...................................................................................... 248 . . 6.4.1 MINI-PLANT DESIGN ............................................................ 249 .................................... 6.5 EXPERIMENTS IN THE CONTINUOUS MINI-PLANT 254 6.6 CONCLUSIONS .................................................................................. 257 6.7 LITERATURE ...................................................................................... 258 7 OPTIMIZATION AND CONTROL OF REACTIVE CHROMATOGRAPHY ................... 259 7.1 INTRODUCTION .................................................................................. 259 7.2 THE SIMULATED MOVING BED PROCESS ........................................... 260 ................. 7.2.1 THE VARIABLE COLUMN LENGTH (VARICOL) PROCESS 263 7.3 INTEGRATION OF REACTION AND SEPARATION - THE HASHIMOTO SMB PROCESS .......................................................................................... 264 ............................................................... 7.4 MATHEMATICAL MODELLING 270 7.5 STEADY STATE OPTIMIZATION OF SMB PROCESSES ................................ 272 7.5.1 GENERAL APPROACH ................................................................... 272 ............................................................................ 7.5.2 EXAMPLES 2 7 4 ............ 7.6 OPTIMIZATION OF THE DESIGN OF A HASHIMOTO SMB PROCESS 282 7.7 CONTROL OF REACTIVE SMB PROCESSES .............................................. 286 ...................................................... 7.7.1 ONLINE OPTIMIZING CONTROL 287 ............................................................. 7.7.2 PARAMETER ESTIMATION 290 XI1 TABLE OF CONTENTS ............. 7.7.3 APPLICATION STUDY - RACEMISATION OF TROEGER S BASE 291 .............................................................................. 7.8 CONCLUSIONS 2 9 3 ........................................................................................ 7.9 NOTATION 294 7.10 LITERATURE .................................................................................... 296 8 CONTROUING REACTIVE DISTILLATION ......................................................... 299 8.1 INTRODUCTION ................................................................................ 299 ................................................... 8.2 THE REACTIVE DISTILLATION COLUMN 301 . . . .......................................................... 8.2.1 CHEMICAL PRELIMINANES 301 8.2.2 THE REACTIVE DISTILLATION COLUMN ............................................ 301 .......................................................... 8.3 CONTROL STRUCTURE SELECTION 304 ............................................................................ 8.3.1 MOTIVATION 3 04 8.3.2 DEGREES OF FREEDOM AND MEASUREMENT EQUIPMENT ................. 304 8.3.3 STEADY-STATE PROCESS OPERABILITY ............................................ 305 ................................................. 8.3.4 DYNARNIC PROCESS OPERABILITY 308 ........................ 8.4 MODEL REFINEMENT BY LINEAR SYSTEM IDENTIFICATION 312 ......................................... 8.4.1 CHOICE OF THE IDENTIFICATION SIGNAL 312 8.4.2 LINEAR MODEL IDENTIFICATION ................................................... 314 ......................................................... 8.4.3 MODEL ORDER REDUCTION 3 15 ............................................... 8.5 MODEL UNCERTAINTY ASSESSMENT 3 19 ................................................................. 8.5.1 MODEL ERROR MODEL 320 8.5.2 DATA-DRIVEN COMPUTATION OF UNCERTAINTY BOUNDS ................... 321 .................................................................... 8.6 CONTROLLER DESIGN 3 2 3 8.6.1 CONTROL PERFORMANCE SPECIFICATION ........................................ 324 8.6.2 CONTROLLER REDUCTION .......................................................... 328 ............................................................................ 8.7 CONCLUSIONS 3 3 4 8.8 LITERATURE ...................................................................................... 336 ................................................... 9 MULTIFUNCTIONALITY AT PARTICLE LEVEL 339 ............................................................................... 9.1 LNTRODUCTION 3 3 9 9.2 INTEGRATION OF ADSORPTIVE FUNCTIONALITY ON PARTICLE SCALE .............. 341 9.3 TEST REACTION SCHERNE ................................................................ 344 9.4 MODELING OF ADSORPTIVE CATALYST .................................................... 345 .................................................................. 9.5 RESULTS AND DISCUSSION 349 9.5.1 PARTICLE LEVEL INTEGRATION VS . CONVENTIONAL PARTICLES .............. 349 ................... 9.5.2 PARTICLE LEVEL INTEGRATION VS . PARTICLE STRUCTURING 350 9.5.3 RELEVANCE OF RNACRO- AND MICROSTRUCTURING ............................ 355 9.6 CONCLUSIONS ............................................................................... 357 9.7 LITERATURE ...................................................................................... 358 INDEX ........................................................................................................ 361
adam_txt TABLE OF CONTENTS 1 INTRODUCTION . 1 2 SYNTHESIS OF REACTIVE SEPARATION PROCESSES . 7 2.1 INTRODUCTION . 7 . 2.2 FUNDAMENTAL PROCESS SYNTHESIS CONCEPTS 8 . 2.3 PROCESS SYNTHESIS STRATEGY 17 . 2.3.1 PROCESS GOALS 18 2.3.2 DATA ACQUISITION / THERMODYNAMIC ANALYSIS . 18 2.3.3 INVESTIGATION OF THE REACTION PHASE . 19 . 2.3.4 IDENTIFICATION OF INCENTIVES 19 . 2.3.5 SELECTION OF THE SEPARATION PROCESS 19 2.3.6 KNOCK-OUT CNTERIA . 21 . 2.3.7 ESTIMATION OF PRODUCT REGIONS FOR FULL INTEGRATION 21 . 2.3.8 MEASURES TO ACHIEVE THE DESIRED PRODUCT QUALITY 25 . 2.3.9 NECESSITY OF ADDITIONAL STEPS 26 2.3.10 SIMULATION AND OPTIMIZATION . 26 . 2.3.1 1 EXAMPLES 27 . 2.4 OPTIMIZATION OF THE PROCESS 6 1 . 2.4.1 THE OPTIMIZATION MODEL 63 2.4.2 SOLUTION METHOD . 67 2.4.3 EXAMPLES . 70 . 2.5 CONCLUSIONS 84 . 2.6 NOTATION 85 2.7 LITERATURE . 88 3 CATALYTIC DISTILLATION . 95 . 3.1 INTRODUCTION 95 3.2 BASICS OF CATALYTIC DISTILLATION . 96 . 3.2.1 CATALYST 9 8 . 3.2.2 INTERNALS 101 3.3 MODELING . 103 . 3.3.1 EQUILIBNUM STAGE MODEL 105 . 3.3.2 RATE-BASED APPROACH 106 3.4 MODEL PARAMETERS . 110 . 3.4.1 VAPOR-LIQUID EQUILIBRIUM 110 3.4.2 REACTION KINETICS . 110 3.4.3 HYDRODYNAMICS AND MASS TRANSFER . 112 3.4.4 DIFFERENTIAL MODELS . 114 X TABLE OF CONTENTS 3.5 CASE STUDIES . 115 3.5.1 METHYL ACETATE SYNTHESIS . 115 3 .5.2 ETHYL ACETATE SYNTHESIS . 119 3.5.3 ETHYL ACETATE TRANSESTERIFICATION . 123 3.5.4 DIMETHYL CARBONATE TRANSESTERIFICATION . 127 3.6 CONCLUSIONS . 133 . 3.7 NOTATION 135 . 3.8 LITERATURE 137 4 REACTIVE GAS ADSORPTION . 149 4.1 INTRODUCTION . 149 4.1.1 GAS-PHASE ADSORPTIVE REACTORS - OPERATION AND REGENERATION . STRATEGIES 151 4.1.2 COMPARISON WITH RELATED REACTOR CONCEPTS . 153 4.2 MODELING OF GAS-PHASE ADSORPTIVE REACTORS . 155 4.2.1 MODEL EQUATIONS . 155 4.2.2 MODEL IMPLEMENTATION AND NUMERICAL FEATURES . 159 4.3 DESIGN PRINCIPLES OF ADSORPTIVE REACTORS . 160 . 4.4 CONVERSION ENHANCEMENT OF EQUILIBRIUM-LIMITED REACTIONS 161 . 4.4.1 CLAUS REACTION 161 4.4.2 HCN-SYNTHESIS FROM CO AND NH3 . 168 4.4.3 WATER-GAS SHIFI REACTION . 172 4.5 YIELD AND SELECTIVITY ENHANCEMENT FOR COMPLEX REACTION SCHEMES . 172 . 4.5.1 DIRECT SYNTHESIS OF DME FROM SYNTHESIS GAS 173 4.5.2 OXIDATIVE DEHYDROGENATION OF ETHYLBENZENE TO STYRENE . 179 4.6 CONCLUSIONS . 184 4.7 NOTATION . 185 4.8 LITERATURE . 187 5 REACTIVE LIQUID CHROMATOGRAPHY . 191 5.1 INTRODUCTION . 191 . 5.2 PROCESS CONCEPTS 192 . 5.2.1 CHROMATOGRAPHIC BATCH REACTOR 192 . 5.2.2 CONTINUOUS ANNULAR REACTOR 193 . 5.2.3 COUNTER-CURRENT FLOW REACTORS 194 . 5.2.4 DEGREE OF PROCESS INTEGRATION 199 5.3 MODELING OF SIMULATED MOVING BED REACTORS . 200 5.3.1 RIGOROUS MODELS . 202 . 5.3.2 TMBR MODEL 208 5.3.3 COMPARISON OF TMBR AND SMBR . 210 5.4 EXPERIMENTAL MODEL VALIDATION . 1 TABLE OF CONTENTS XI . 5.4.1 PARAMETER DETERMINATION 211 . 5.4.2 PRODUCTION OF P-PHENETHYLACETATE 214 . 5.4.3 THERMAL RACEMIZATION OF TROEGERS BASE 217 . 5.5 SHORT-CUT DESIGN METHODS FOR SMB REACTORS 219 . 5.5.1 REACTIONS OF TYPE A + B T, C + D 220 . 5.5.2 OTHER TYPES OF REACTION 224 . 5.5.3 SHORT-CUT CALCULATION FOR IRREVERSIBLE ESTERIFICATION 225 . 5.6 DESIGN OF CHROMATOGRAPHIC REACTORS 226 5.6.1 CHOICE OF THE CHROMATOGRAPHIC SYSTEM . 226 5.6.2 MODEL BASED OPTIMIZATION OF DESIGN AND OPERATING PARAMETERS . 227 . 5.6.3 EVALUATION AND APPLICATION OF CHROMATOGRAPHIC REACTORS 229 5.7 NOTATION . 234 . 5.8 LITERATURE 236 6 REACTIVE EXTRACTION . 241 6.1 LNTRODUCTION . 241 6.2 REACTIVE EXTRACTION SYSTEMS . 241 6.2.1 SEPARATION PROCESSES . 242 . 6.2.2 SYNTHESIS PROCESSES 243 6.3 SYSTEM ANALYSIS AND PLANT DESIGN . 244 . 6.3.1 ANALYSIS OF THE REACTION SYSTEM 246 6.4 MODELLING . 248 . . 6.4.1 MINI-PLANT DESIGN . 249 . 6.5 EXPERIMENTS IN THE CONTINUOUS MINI-PLANT 254 6.6 CONCLUSIONS . 257 6.7 LITERATURE . 258 7 OPTIMIZATION AND CONTROL OF REACTIVE CHROMATOGRAPHY . 259 7.1 INTRODUCTION . 259 7.2 THE SIMULATED MOVING BED PROCESS . 260 . 7.2.1 THE VARIABLE COLUMN LENGTH (VARICOL) PROCESS 263 7.3 INTEGRATION OF REACTION AND SEPARATION - THE HASHIMOTO SMB PROCESS . 264 . 7.4 MATHEMATICAL MODELLING 270 7.5 STEADY STATE OPTIMIZATION OF SMB PROCESSES . 272 7.5.1 GENERAL APPROACH . 272 . 7.5.2 EXAMPLES 2 7 4 . 7.6 OPTIMIZATION OF THE DESIGN OF A HASHIMOTO SMB PROCESS 282 7.7 CONTROL OF REACTIVE SMB PROCESSES . 286 . 7.7.1 ONLINE OPTIMIZING CONTROL 287 . 7.7.2 PARAMETER ESTIMATION 290 XI1 TABLE OF CONTENTS . 7.7.3 APPLICATION STUDY - RACEMISATION OF TROEGER'S BASE 291 . 7.8 CONCLUSIONS 2 9 3 . 7.9 NOTATION 294 7.10 LITERATURE . 296 8 CONTROUING REACTIVE DISTILLATION . 299 8.1 INTRODUCTION . 299 . 8.2 THE REACTIVE DISTILLATION COLUMN 301 . . . . 8.2.1 CHEMICAL PRELIMINANES 301 8.2.2 THE REACTIVE DISTILLATION COLUMN . 301 . 8.3 CONTROL STRUCTURE SELECTION 304 . 8.3.1 MOTIVATION 3 04 8.3.2 DEGREES OF FREEDOM AND MEASUREMENT EQUIPMENT . 304 8.3.3 STEADY-STATE PROCESS OPERABILITY . 305 . 8.3.4 DYNARNIC PROCESS OPERABILITY 308 . 8.4 MODEL REFINEMENT BY LINEAR SYSTEM IDENTIFICATION 312 . 8.4.1 CHOICE OF THE IDENTIFICATION SIGNAL 312 8.4.2 LINEAR MODEL IDENTIFICATION . 314 . 8.4.3 MODEL ORDER REDUCTION 3 15 . 8.5 MODEL UNCERTAINTY ASSESSMENT 3 19 . 8.5.1 MODEL ERROR MODEL 320 8.5.2 DATA-DRIVEN COMPUTATION OF UNCERTAINTY BOUNDS . 321 . 8.6 CONTROLLER DESIGN 3 2 3 8.6.1 CONTROL PERFORMANCE SPECIFICATION . 324 8.6.2 CONTROLLER REDUCTION . 328 . 8.7 CONCLUSIONS 3 3 4 8.8 LITERATURE . 336 . 9 MULTIFUNCTIONALITY AT PARTICLE LEVEL 339 . 9.1 LNTRODUCTION 3 3 9 9.2 INTEGRATION OF ADSORPTIVE FUNCTIONALITY ON PARTICLE SCALE . 341 9.3 TEST REACTION SCHERNE . 344 9.4 MODELING OF ADSORPTIVE CATALYST . 345 . 9.5 RESULTS AND DISCUSSION 349 9.5.1 PARTICLE LEVEL INTEGRATION VS . CONVENTIONAL PARTICLES . 349 . 9.5.2 PARTICLE LEVEL INTEGRATION VS . PARTICLE STRUCTURING 350 9.5.3 RELEVANCE OF RNACRO- AND MICROSTRUCTURING . 355 9.6 CONCLUSIONS . 357 9.7 LITERATURE . 358 INDEX . 361
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id DE-604.BV021786531
illustrated Illustrated
index_date 2024-07-02T15:43:05Z
indexdate 2024-11-25T17:26:05Z
institution BVB
isbn 3540301488
9783540301486
language English
oai_aleph_id oai:aleph.bib-bvb.de:BVB01-014999242
oclc_num 70573826
open_access_boolean
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physical XII, 366 S. Ill., graph. Darst. 235 mm x 155 mm
publishDate 2006
publishDateSearch 2006
publishDateSort 2006
publisher Springer
record_format marc
series2 Verfahrenstechnik
spellingShingle Schmidt-Traub, Henner 1940-2020
Górak, Andrzej 1951-
Integrated reaction and separation operations modelling and experimental validation
Chemical process control
Chemical reactions
Separation (Technology)
Reaktionstechnik (DE-588)4136173-8 gnd
Chemische Verfahrenstechnik (DE-588)4069941-9 gnd
Kombinationsverfahren (DE-588)4533702-0 gnd
Trennverfahren (DE-588)4078395-9 gnd
Grundoperation (DE-588)4306211-8 gnd
subject_GND (DE-588)4136173-8
(DE-588)4069941-9
(DE-588)4533702-0
(DE-588)4078395-9
(DE-588)4306211-8
title Integrated reaction and separation operations modelling and experimental validation
title_auth Integrated reaction and separation operations modelling and experimental validation
title_exact_search Integrated reaction and separation operations modelling and experimental validation
title_exact_search_txtP Integrated reaction and separation operations modelling and experimental validation
title_full Integrated reaction and separation operations modelling and experimental validation Henner Schmidt-Traub ; Andrzej Górak
title_fullStr Integrated reaction and separation operations modelling and experimental validation Henner Schmidt-Traub ; Andrzej Górak
title_full_unstemmed Integrated reaction and separation operations modelling and experimental validation Henner Schmidt-Traub ; Andrzej Górak
title_short Integrated reaction and separation operations
title_sort integrated reaction and separation operations modelling and experimental validation
title_sub modelling and experimental validation
topic Chemical process control
Chemical reactions
Separation (Technology)
Reaktionstechnik (DE-588)4136173-8 gnd
Chemische Verfahrenstechnik (DE-588)4069941-9 gnd
Kombinationsverfahren (DE-588)4533702-0 gnd
Trennverfahren (DE-588)4078395-9 gnd
Grundoperation (DE-588)4306211-8 gnd
topic_facet Chemical process control
Chemical reactions
Separation (Technology)
Reaktionstechnik
Chemische Verfahrenstechnik
Kombinationsverfahren
Trennverfahren
Grundoperation
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work_keys_str_mv AT schmidttraubhenner integratedreactionandseparationoperationsmodellingandexperimentalvalidation
AT gorakandrzej integratedreactionandseparationoperationsmodellingandexperimentalvalidation