Organic chemistry structure and function

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Hauptverfasser: Vollhardt, Kurt Peter C. 1946- (VerfasserIn), Schore, Neil E. (VerfasserIn)
Format: Buch
Sprache:English
Veröffentlicht: New York [u.a.] Freeman 2007
Ausgabe:5. ed.
Schlagworte:
Online-Zugang:http://www.whfreeman.com/vollardtschore5e
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Datensatz im Suchindex

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adam_text Preface: A User s Guide to Organic Chemistry: Structure and Function I Structure and Bonding in Organic Molecules 1-1 Chemical Highlight Organic Compounds in Commercial Use 1-2 1-3 1-4 1-5 1-6 of Electrons Around the Nucleus 1-7 1-8 1-9 Chapter integration Problems Important Concepts Problems j Structure and Reactivity: Acids and Bases, Polar and 2-1 2-2 Chemical Highlight and Food Digestion 2-3 2-4 2-5 2-6 2-7 Chemical Highlight Chemical Mimicry 2-8 Chapter integration Problems Important Concepts Problems CONTENTS . ■> 3-1 3-2 3-3 Chemical Highlight Our Main Energy Sources 3-4 Chain Mechanism 3-5 3-6 and Selectivity 3-7 and Bromine 3-8 3-9 Stratospheric Ozone Layer Chemical Highlight 3-Ю of Alkanes Chapter Integration Problems Important Concepts Problems 4 4-1 4-2 4-3 4-4 4-5 4-6 4-7 Chemical Highlight as Explosives: Octanitrocubane Chemical Highlight How Bad Is It? Chemical Highlight to RU-486 Chapter Integration Problems Important Concepts Problems CONTENTS 5 5-1 Chemical Highlight 5-2 5-3 Chemical Highlight A Historical Note 1S1 5-4 5-5 Chemical Highlight 5-6 5-7 Chemical Highlight Enantiomerically Pure? Chemical Highlight 5-8 Chapter Integration Problems Important Concepts Problems і Nucleophilic Substitution 6-1 Chemical Highlight and 6-2 6-3 Using Electron-Pushing Arrows 6-4 Mechanism: Kinetics 6-5 the SN2 Reaction 6-6 6-7 6-8 6-9 Chemical Highlight Highly Useful but Also Highly Toxic Chapter Integration Problems Important Concepts Problems viii CONTENTS і Substitution and Pathways of Elimination 7-1 7-2 7-3 7-4 Unimoiecular Substitution 7-5 Carbocation Stability Chemical Highlight in 7-6 7-7 7-8 Structure Determines Function 7-9 Chapter Integration Problems New Reactions Important Concepts Problems a Hydroxy Functional Group: Alcohols: Properties, Preparation, ■ 8-1 8-2 8-3 8-4 8-5 8-6 Between Alcohols and Carbonyl Compounds Chemical Highlight Chemical Highlight 8-7 Carbon for Alcohol Synthesis 8-8 Chemical Highlight Cross-Coupling Reactions 8-9 Chapter Integration Problems New Reactions Important Concepts Problems CONTENTS ix 9 9-1 9-2 Ions in Substitution and Elimination Reactions of Alcohols 9-3 9-4 9-5 9-6 Chemical Highlight 1 9-7 9-8 Chemical Highlight 9-9 Chemical Highlight Oxacyclopropanes 9-10 9-11 Chemical Highlight Chapter Integration Problems New Reactions Important Concepts Problems • to Deduce 10-1 10-2 10-3 Chemical Highlight 10-4 The Proton Chemical Shift 10-5 Chemical Highlight 10-6 10-7 Neighboring Hydrogens 10-8 Chemical Highlight Hydrogens 10-9 X Chemical Highlight 10-4 and HETCOR Chemical Highlight 10-5 Products: Antioxidants from Grape Seeds Chapter Integration Problems Important Concepts Problems 11 Alkenes; Infrared Spectroscopy and Mass Spectrometry 11-1 11-2 11-3 11-4 Chemical Highlight 11 -5 11-6 Mass Spectrometry 11 -7 11-8 Molecular Structure 11-9 of Double Bonds 11-10 Sulfonates: Bimolecular Elimination Revisited 11-11 Chemical Highlight a-Terpineol Chapter Integration Problems New Reactions Important Concepts Problems 12 12-1 12-2 12-3 Addition of Hydrogen Halides 12-4 Thermodynamic Control 12-5 12-6 CONTENTS xi 12-7 Hlectrophilic Addition Chemical Highlight against Insect-Borne Diseases 12-8 Anti-Markovnikov Hydration 520 12-9 12-10 Peroxycarboxylic Acids 12-1 1 Chemical Highlight Synthesis of 12-12 12-13 12-14 12-15 Chemical Highlight Chemical Highlight Chemical Libraries 12-16 12-17 Chemical Highlight Constructing Medium and Large Rings Chapter integration Problems New Reactions Important Concepts Problems ] Alkynes: The Carbon-Carbon 13-І 13-2 13-3 13-4 13-5 13-6 Two Pi Bonds 13-7 13-8 13-9 13-10 Chemical Highlight Sonogashira Coupling Reactions xii CONTENTS 13-11 Chapter Integration Problems New Reactions Important Concepts Problems ■ і * 14-1 Delocalization in the 2-Propenyl (Allyl) System 14-2 14-3 14-4 Nucleophiles 14-5 14-6 Kinetic and Thermodynamic Control Chemical Highlight Wine: Sorbic Acid 14-7 Conjugation and Benzene 14-8 Cycloaddition Chemical Highlight for the Future? Chemical Highlight 14-9 Chemical Highlight of 14-10 14-1 1 Chemical Highlight to the Characterization of Viniferone Chapter Integration Problems New Reactions Important Concepts Problems INTERLUDE: A Summary of Organic Reaction Mechanisms 15 15-1 15-2 Look at Aromaticity CONTENTS xiii 15-3 15-4 15-5 Chemical Highlight Diamond, and Fullerenes 15-6 Chemical Highlight Rings in Fused Hydrocarbons 15-7 15-8 Aromatic Substitution 15-9 15-10 15-11 15-12 15-13 Chapter Integration Problems New Reactions Important Concepts Problems ./ 0 16-1 Benzene Ring 16-2 16-3 the Benzene Ring Chemical Highlight 16-4 16-5 16-6 16-7 Chapter Integration Problems New Reactions Important Concepts Problems If Aldehydes and Ketones: The Carbonyl Group 17-1 17-2 17-3 xiv CONTENTS 17-4 17-5 Mechanisms of Addition 17-6 17-7 17-8 17-9 Chemical Highlight 17-10 17-11 17-12 Chemical Highlight 17-13 The Baeyer-Villiger Oxidation 17-14 Chapter Integration Problems New Reactions Important Concepts Problems л 10 18-1 18-2 18-3 18-4 18-5 Aldol Condensation 18-6 Chemical Highlight Aldol Condensations in Nature 18-7 Chemical Highlight Crossed Aldol Condensations 18-8 Chemical Highlight in Nature: The Chemistry of Vision 18-9 and Ketones 18-10 1,2- 18-11 and Robinson CONTENTS xv Chemical Highlight 18-4 Prostaglandins: a.ß-Dialkylation in Chapter New Important Concepts Problems 847 1С 19-1 19-2 Chemical Highlight 19-3 Carboxylic Acids 19-4 19-5 19-6 19-7 The Addition-Elimination Mechanism 19-8 and Anhydrides 19-9 19-10 19-11 Aluminum Hydride 19-12 The Hell-Volhard-Zelinsky Reaction 19-13 Chemical Highlight Chemical Highlight Chemical Highlight Chapter Integration Problems New Reactions Important Concepts Problems 20 Carboxylic 20-1 Carboxylic Acid Derivatives 20-2 20-3 20-4 20-5 xvi CONTENTS Chemical Highlight 20-1 Alternatives Vegetable Oil 20-6 Chemical Highlight 20-7 Rearrangement Chemical Highlight Insecticides, and Safety in the Chemical Industry 20-8 Acid Derivatives Chapter Integration Problems New Reactions Important Concepts Problems 2 21-1 21-2 Chemical Highlight and Weight Control 21 -3 21-4 Chemical Highlight Organic Compounds by Aqueous Extraction Techniques 21-5 21-6 21-7 21-8 21-9 21-10 Chemical Highlight Chemical Highlight Chapter integration Problems New Reactions Important Concepts Problems .. LL and Benzenanines 22-1 Resonance Stabilization CONTENTS xvii 22-2 Benzylic 22-3 Chemical Highlight Bisphenol 22-4 22-5 Chemical Highlight 22-6 22-7 The Claisen Rearrangement 22-8 Chemical Highlight The Bombardier Beetle 22-9 22-10 22-11 Diazo Coupling Chemical Highlight Industrial and Medicinal Chemistry Chapter Integration Problems New Reactions Important Concepts Problems 1 ß-Dicarbonyl 23-1 ß-Dicarbonyl Chemical Highlight 23-2 ß-Dicarbonyl 23-3 ß-Dicarbonyl 23-4 a-Hydroxyketones Chemical Highlight Active Thiazolium Salt Chapter Integration Problems New Reactions Important Concepts Problems 24 24-1 24-2 24-3 xviii CONTENTS 24-4 Polyfunctional Carboxylic Acids 24-5 24-6 24-7 24-8 Chemical Highlight Imaging the Human Brain Chemical Highlight 24-9 Chemical Highlight 24-10 Structure Determination 24-11 Chemical Highlight 24-12 Chapter Integration Problem New Reactions Important Concepts Problems 2$ 25-1 25-2 Chemical Highlight Chemical Highlight 25-3 25-4 25-5 25-6 Chemical Highlight Nicotinamide 25-7 Chemical Highlight 25-8 in Nature Chemical Highlight Natural Pesticides Chapter Integration Problems New Reactions Important Concepts Problems CONTENTS xix Amino Nitrogen-Containing Polymers in Nature 26-1 Chemical Highlight Biochemistry and Medicine 26-2 Carboxylic Acid Chemistry 26-3 Chemical Highlight Phase-Transfer Catalysis 26-4 and Polymers 26-5 Amino 26-6 Application of Protecting Groups 26-7 26-8 Proteins Myoglobin and Hemoglobin 26-9 Chemical Highlight Nucleosides in Medicine 26-10 26-11 DNA Gene Technology Chemical Highlight Chapter Integration Problems New Reactions Important Concepts Problems MC Answers to Exercises A-l Photograph Credits C-l Index
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author Vollhardt, Kurt Peter C. 1946-
Schore, Neil E.
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spellingShingle Vollhardt, Kurt Peter C. 1946-
Schore, Neil E.
Organic chemistry structure and function
Chemische structuur gtt
Functionele groepen gtt
Organische chemie gtt
Organische verbindingen gtt
Química orgânica larpcal
Reactiviteit gtt
Spectrometrie gtt
Chemistry, Organic Textbooks
Organische Chemie (DE-588)4043793-0 gnd
subject_GND (DE-588)4043793-0
(DE-588)4123623-3
title Organic chemistry structure and function
title_auth Organic chemistry structure and function
title_exact_search Organic chemistry structure and function
title_full Organic chemistry structure and function K. Peter C. Vollhardt ; Neil E. Schore
title_fullStr Organic chemistry structure and function K. Peter C. Vollhardt ; Neil E. Schore
title_full_unstemmed Organic chemistry structure and function K. Peter C. Vollhardt ; Neil E. Schore
title_short Organic chemistry
title_sort organic chemistry structure and function
title_sub structure and function
topic Chemische structuur gtt
Functionele groepen gtt
Organische chemie gtt
Organische verbindingen gtt
Química orgânica larpcal
Reactiviteit gtt
Spectrometrie gtt
Chemistry, Organic Textbooks
Organische Chemie (DE-588)4043793-0 gnd
topic_facet Chemische structuur
Functionele groepen
Organische chemie
Organische verbindingen
Química orgânica
Reactiviteit
Spectrometrie
Chemistry, Organic Textbooks
Organische Chemie
Lehrbuch
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