Soft matter 2 Complex colloidal suspensions

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DE-BY-TUM_call_number 0302/CHE 710f 2006 A 724-2
DE-BY-TUM_katkey 1539970
DE-BY-TUM_media_number 040030182011
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adam_text CONTENTS 1 PHASE BEHAVIOR OF ROD-LIKE VIRUSES AND VIRUS-SPHERE MIXTURES 1 ZVONIMIR DOGIC UND SETH FRADEN LNTRODUCTION I ENTROPY-DRIVEN ORDERING WITHIN THE SECOND VIRIAL APPROXIMATION 3 ISOTROPIC-NEMATIC PHASE TRANSITION WITHIN THE SECOND VIRIAL APPROXIMATION 4 EXTENSION OF ONSAGER THEORY TO CHARGED RODS 7 EXTENSION OF ONSAGER THEORY TO SEMI-FLEXIBLE RODS 9 EXTENSION OF ONSAGER THEORY TO RODS WITH FINITE ASPECT RATIO USING SCALED PARTIDE THEORY 10 NEMATIC-SMECTIC PHASE TRANSITION WITHIN THE SECOND VIRIAL APPROXIMATION 11 PHASE BEHAVIOR OF A BINARY MIXTURE OF HARD PARTICLES 13 EXPERIMENTAL PHASE DIAGRAM OF AN FD VIRUS SUSPENSION 14 PROPERTIES AND PREPARATION OF FILAMENTOUS BACTERIOPHAGE 15 ISOTROPIE-CHOLESTERIC PHASE TRANSITION IN FD VIRUS SUSPENSIONS 18 POLYMER-COATEDFD VIRUS AND ITS LSOTROPIC-CHOLESTERIC PHASE TRANSITION 22 CHOLESTERIC PHASE OFFD VIRUS 24 NEMATIC ORDER PARAMETER OF FD VIRUS SUSPENSIONS 26 SMECTIC PHASE OFFD VIRUS 29 BULK PHASE BEHAVIOR OF ROD-SPHERE AND ROD-POLYMER MIXTURES 34 DEPLETION INTERACTION BETWEEN HARD SPHERES 34 PHASE DIAGRAMS OF HARD SPHERES AND POLYMERS OR ISOTROPIC HARD RODS 37 LNFLUENCE OF NON-ADSORBING POLYMER ON THE ISOTROPIC-NEMATIC PHASE TRANSITION 41 SOFL MATTER, VOL. 2: COMPLEX COLLOIDAL SUSPENSIONS. EDITED BY G. GOMPPER AND M. SCHICK COPYRIGHT @ 2006 WILEY-VCH VERLAG GMBH &CO. KGAA, WEINHEIM ISBN: 3-527-31369-9 VLLL CONTENTS I ENTROPICALLY DRIVEN MICROPHASE SEPARATION IN ROD-SPHERE MIXTURES 46 LAMELLAR PHASE IN ROD-POLYMER AND ROD-SPHERE MIXTURES 48 COLUMNAR PHASE AND CHAIN-LIKE STRUCTURES IN MIXTURES OF FD VIRUS AND HARD SPHERES 51 SELF-ASSEMBLED COLLOIDAL MEMBRANES AND TWISTED RIBBONS 55 MONTE CARLO SIMULATION OF COLLOIDAL MEMBRANES 61 CRYSTALLINE MEMBRANES 63 SURFACE-INDUCED SMECTIC ORDERING IN ROD-POLYMER MIXTURES 64 KINETICS OF LIQUID-CRYSTALLINE PHASE TRANSITIONS 67 KINETICS OF THE ISOTROPIE-NEMATIC AND NEMATIC-SMECTIC PHASE TRANSITIONS IN HARD-ROD SUSPENSIONS 68 KINETICS OF THE ISOTROPIC-SMECTIC PHASE TRANSITION 69 FILAMENTOUS STMCTURES ASSOCIATED WITH NEMATIC-SMECTIC PHASE TRANSITIONS 72 MULTIPLE PATHWAYS OBSEMED IN MELTING OFTHE LAMELLAR PHASE 74 CONCLUSIONS AND OPEN QUESTIONS 78 FIELD THEORY OF POLYMER-COLLOID LNTERACTIONS 87 ERICH EISENRIEGLER INTRODUCTION 87 POLYMERS AND FIELD THEORY 90 POLYMERS INTERACTING WITH BOUNDARIES 96 POLYMERS INTERACTING WITH A PLANAR WALL 100 IDEAL POLYMERS 100 BEHAVIOR NEAR THE WALL: DENSITY-PRESSURE RELATION AND BOUNDARY OPERATOR EXPANSION 101 SLIGHTLY DEFORMED PLANAR WALL 105 SURFACE TENSION I 06 SPHERICAL PARTICLE IN A POLYMER SOLUTION 108 IDEAL POLYMERS 108 END DENSITY 108 FREE ENERGY OF IMMERSION 108 MONOMER DENSITY PROFILE AND THE DENSITY-PRESSURE RELATION 11 I SMALL-SPHERE EXPANSION I 12 POLYMER SOLUTION OF ARBITRARY OVERLAP 115 PARALLEL PLATES AND PLATE-WALL LNTERACTION 117 CHAIN TRAPPED BETWEEN TWO PARALLEL PLATES 11 7 FORCE ON THE PLATES 11 7 LDEAL CHAIN I 18 MONOMER DENSITY PROFILE AND DENSITY-FORCE RELATION 118 PLATE-WALL LNTERACTION 11 9 SPHERE-WALL LNTERACTION 121 DERJAGUIN APPROXIMATION FOR A LARGE SPHERE 122 SMALL-PARTICLE EXPANSION FOR A SMALL SPHERE 123 ARBITRARY SIZE RATIOS 124 INTERACTION BETWEEN TWO OR MORE SPHERES 127 DERJAGUIN APPROXIMATION FOR LARGE SPHERES 127 TWO SMALL SPHERES 128 THREE SMALL SPHERES 130 ARBITRARY SIZE RATIOS 130 SMALL ANISOTROPIC PARTICLES 13 1 OPERATOR EXPANSIONS FOR SMALL ANISOTROPIC PARTICLES 132 DUMBBELLS 133 ELLIPSOIDS 137 INTERACTION BETWEEN AN ANISOTROPIC PARTICLE AND A WALL 139 SUMMARY AND CONCLUDING REMARKS 142 ROD-LIKE BROWNIAN PARTICLES IN SHEAR FLOW 147 ]AN K. G. DHONT AND WIM]. BRIELS INTRODUCTION 148 THE VELOCITY-GRADIENT TENSOR 151 HYDRODYNAMICS 153 THE CONTINUITY EQUATION 154 THE NAVIER-STOKES EQUATION 155 THE CREEPING FLOW EQUATIONS 159 THE OSEEN TENSOR 161 HYDRODYNAMIC FRICTION OF A SINGLE ROD 163 TRANSLATIONAL FRICTION 165 ROTATIONAL FRICTION 169 MOTION OF NON-BROWNIAN RODS IN SHEAR FLOW: JEFFERY ORBITS 173 JEFFERY ORBITS IN ELONGATIONAL FLOW 174 JEFFERY ORBITS IN SIMPLE SHEAR FLOW 176 AN EXPERIMENT 179 BROWNIAN MOTION OF A FREE ROD (WITHOUT SHEAR FLOW) 181 NEWTON S EQUATIONS OF MOTION FOR A RIGID BODY 181 THE LANGEVIN EQUATION FOR A LONG AND THIN ROD 184 BROWNIAN TIME SCALE: RELAXATION RATES OF TRANSLATIONAL AND ROTATIONAL VELOCITY 186 BROWNIAN LENGTH SCALE AND BROWNIAN ANGLE 187 CALCULATION OF FLUCTUATION STRENGTHS 189 X CONTENTS I 3.6.6 TRANSLATIONAL BROWNIAN MOTION OF A ROD 192 3.6.7 ORIENTATIONAL CORRELATIONS 194 3.7 EQUATIONS OF MOTION FOR INTERACTING RODS 198 3.7.1 THE N-PARTICLE SMOLUCHOWSKI EQUATION 199 3.7.2 TRANSLATIONAL AND ROTATIONAL DIFFUSION OF NON-INTERACTING RODS WITHOUT SHEAR FLOW 206 3.8 THE ORIENTATIONAL ORDER PARAMETER 208 3.9 NON-INTERACTING BROWNIAN RODS IN SHEAR FLOW 210 3.9.1 ELONGATIONAL FLOW 212 3.9.2 SIMPLE SHEAR FLOW 213 3.10 THE DOI-EDWARDS EQUATION OF MOTION AND THE MAIER-SAUPE POTENTIAL 21 6 3.10.1 EQUATION OF MOTION FOR P(&, T) 216 3.10.2 EQUATION OF MOTION FOR S(T) 219 3.10.3 DENSITY EXPANSION OF THE PAIR CORRELATION FUNCTION 221 3.10.4 ORIENTATIONAL CLOSURE RELATION 222 3.11 PARANEMATIC-NEMATIC SPINODALS AND THE BINODAL UNDER SHEAR FLOW 224 3.11.1 SPINODALS 225 3.11.2 THE BINODAL 229 3.11.3 A REMARK ON PATTERN FORMATION AND TIME-PERIODIC STATES 230 3.12 HOW IMPORTANT ARE DYNAMIC CORRELATIONS? 231 3.13 THE STRESS TENSOR FOR ROD SUSPENSIONS 233 3.13.1 THE BASIC IDEA 233 3.1 3.1.1 PARTICLE-PARTICLE STRESS TENSOR CI P 235 3.13.1.2 PARTICLE-SOLVENT STRESS TENSOR CPS 236 3.13.1.3 SOLVENT-SOLVENT STRESS TENSOR C 239 3.13.2 TOTAL STRESS TENSOR 242 3.13.3 STRESS TENSOR FOR HOMOGENEOUS SUSPENSIONS 243 3.13.4 EXPLICIT EVALUATION OF STRESS TENSOR FOR VERY LONG AND THIN RODS 244 3.13.5 STRESS TENSOR FOR A HOMOGENEOUS SYSTEM EXPRESSED IN TERMS OF ORDER PARAMETER 248 3.14 VISCOELASTIC RESPONSE FUNCTIONS 249 3.14.1 SHEAR VISCOSITY AND NORMAL STRESSES FOR LOW SHEAR RATES 250 3.14.2 VISCOELASTIC RESPONSE AT HIGH SHEAR RATES 253 3.14.3 NONLINEAR VISCOELASTIC RESPONSE 255 3.14.4 COMPARISON WITH OTHER THEORIES, SIMULATIONS, AND EXPERIMENTS 257 3.15 CURRENT RESEARCH TOPICS 266 3.15.1 SHEAR-BANDING TRANSITIONS 266 3.15.1.1 VORTICITY BANDING 267 GRADIENT BANDING 268 NON-EQUILIBRIUM PHASE DIAGRAM UNDER SHEAR FLOW 270 PHASE SEPARATION KINETICS UNDER FLOW CONDITIONS 271 APPENDIX 271 BEAD INDEX SUMMATIONS 271 USEFUL MATHEMATICAL IDENTITIES 273 ON THE ACCURACY OF THE CLOSURE RELATION (3.227) 273 EVALUATION OF SUMS OVER BEAD LNDEX NUMBERS 274 DERIVATION OF EQ. (3.279) 278 LNDEX 285
adam_txt CONTENTS 1 PHASE BEHAVIOR OF ROD-LIKE VIRUSES AND VIRUS-SPHERE MIXTURES 1 ZVONIMIR DOGIC UND SETH FRADEN LNTRODUCTION I ENTROPY-DRIVEN ORDERING WITHIN THE SECOND VIRIAL APPROXIMATION 3 ISOTROPIC-NEMATIC PHASE TRANSITION WITHIN THE SECOND VIRIAL APPROXIMATION 4 EXTENSION OF ONSAGER THEORY TO CHARGED RODS 7 EXTENSION OF ONSAGER THEORY TO SEMI-FLEXIBLE RODS 9 EXTENSION OF ONSAGER THEORY TO RODS WITH FINITE ASPECT RATIO USING SCALED PARTIDE THEORY 10 NEMATIC-SMECTIC PHASE TRANSITION WITHIN THE SECOND VIRIAL APPROXIMATION 11 PHASE BEHAVIOR OF A BINARY MIXTURE OF HARD PARTICLES 13 EXPERIMENTAL PHASE DIAGRAM OF AN FD VIRUS SUSPENSION 14 PROPERTIES AND PREPARATION OF FILAMENTOUS BACTERIOPHAGE 15 ISOTROPIE-CHOLESTERIC PHASE TRANSITION IN FD VIRUS SUSPENSIONS 18 POLYMER-COATEDFD VIRUS AND ITS LSOTROPIC-CHOLESTERIC PHASE TRANSITION 22 CHOLESTERIC PHASE OFFD VIRUS 24 NEMATIC ORDER PARAMETER OF FD VIRUS SUSPENSIONS 26 SMECTIC PHASE OFFD VIRUS 29 BULK PHASE BEHAVIOR OF ROD-SPHERE AND ROD-POLYMER MIXTURES 34 DEPLETION INTERACTION BETWEEN HARD SPHERES 34 PHASE DIAGRAMS OF HARD SPHERES AND POLYMERS OR ISOTROPIC HARD RODS 37 LNFLUENCE OF NON-ADSORBING POLYMER ON THE ISOTROPIC-NEMATIC PHASE TRANSITION 41 SOFL MATTER, VOL. 2: COMPLEX COLLOIDAL SUSPENSIONS. EDITED BY G. GOMPPER AND M. SCHICK COPYRIGHT @ 2006 WILEY-VCH VERLAG GMBH &CO. KGAA, WEINHEIM ISBN: 3-527-31369-9 VLLL CONTENTS I ENTROPICALLY DRIVEN MICROPHASE SEPARATION IN ROD-SPHERE MIXTURES 46 LAMELLAR PHASE IN ROD-POLYMER AND ROD-SPHERE MIXTURES 48 COLUMNAR PHASE AND CHAIN-LIKE STRUCTURES IN MIXTURES OF FD VIRUS AND HARD SPHERES 51 SELF-ASSEMBLED COLLOIDAL MEMBRANES AND TWISTED RIBBONS 55 MONTE CARLO SIMULATION OF COLLOIDAL MEMBRANES 61 CRYSTALLINE MEMBRANES 63 SURFACE-INDUCED SMECTIC ORDERING IN ROD-POLYMER MIXTURES 64 KINETICS OF LIQUID-CRYSTALLINE PHASE TRANSITIONS 67 KINETICS OF THE ISOTROPIE-NEMATIC AND NEMATIC-SMECTIC PHASE TRANSITIONS IN HARD-ROD SUSPENSIONS 68 KINETICS OF THE ISOTROPIC-SMECTIC PHASE TRANSITION 69 FILAMENTOUS STMCTURES ASSOCIATED WITH NEMATIC-SMECTIC PHASE TRANSITIONS 72 MULTIPLE PATHWAYS OBSEMED IN MELTING OFTHE LAMELLAR PHASE 74 CONCLUSIONS AND OPEN QUESTIONS 78 FIELD THEORY OF POLYMER-COLLOID LNTERACTIONS 87 ERICH EISENRIEGLER INTRODUCTION 87 POLYMERS AND FIELD THEORY 90 POLYMERS INTERACTING WITH BOUNDARIES 96 POLYMERS INTERACTING WITH A PLANAR WALL 100 IDEAL POLYMERS 100 BEHAVIOR NEAR THE WALL: DENSITY-PRESSURE RELATION AND BOUNDARY OPERATOR EXPANSION 101 SLIGHTLY DEFORMED PLANAR WALL 105 SURFACE TENSION I 06 SPHERICAL PARTICLE IN A POLYMER SOLUTION 108 IDEAL POLYMERS 108 END DENSITY 108 FREE ENERGY OF IMMERSION 108 MONOMER DENSITY PROFILE AND THE DENSITY-PRESSURE RELATION 11 I SMALL-SPHERE EXPANSION I 12 POLYMER SOLUTION OF ARBITRARY OVERLAP 115 PARALLEL PLATES AND PLATE-WALL LNTERACTION 117 CHAIN TRAPPED BETWEEN TWO PARALLEL PLATES 11 7 FORCE ON THE PLATES 11 7 LDEAL CHAIN I 18 MONOMER DENSITY PROFILE AND DENSITY-FORCE RELATION 118 PLATE-WALL LNTERACTION 11 9 SPHERE-WALL LNTERACTION 121 DERJAGUIN APPROXIMATION FOR A LARGE SPHERE 122 SMALL-PARTICLE EXPANSION FOR A SMALL SPHERE 123 ARBITRARY SIZE RATIOS 124 INTERACTION BETWEEN TWO OR MORE SPHERES 127 DERJAGUIN APPROXIMATION FOR LARGE SPHERES 127 TWO SMALL SPHERES 128 THREE SMALL SPHERES 130 ARBITRARY SIZE RATIOS 130 SMALL ANISOTROPIC PARTICLES 13 1 OPERATOR EXPANSIONS FOR SMALL ANISOTROPIC PARTICLES 132 DUMBBELLS 133 ELLIPSOIDS 137 INTERACTION BETWEEN AN ANISOTROPIC PARTICLE AND A WALL 139 SUMMARY AND CONCLUDING REMARKS 142 ROD-LIKE BROWNIAN PARTICLES IN SHEAR FLOW 147 ]AN K. G. DHONT AND WIM]. BRIELS INTRODUCTION 148 THE VELOCITY-GRADIENT TENSOR 151 HYDRODYNAMICS 153 THE CONTINUITY EQUATION 154 THE NAVIER-STOKES EQUATION 155 THE CREEPING FLOW EQUATIONS 159 THE OSEEN TENSOR 161 HYDRODYNAMIC FRICTION OF A SINGLE ROD 163 TRANSLATIONAL FRICTION 165 ROTATIONAL FRICTION 169 MOTION OF NON-BROWNIAN RODS IN SHEAR FLOW: JEFFERY ORBITS 173 JEFFERY ORBITS IN ELONGATIONAL FLOW 174 JEFFERY ORBITS IN SIMPLE SHEAR FLOW 176 AN EXPERIMENT 179 BROWNIAN MOTION OF A FREE ROD (WITHOUT SHEAR FLOW) 181 NEWTON'S EQUATIONS OF MOTION FOR A RIGID BODY 181 THE LANGEVIN EQUATION FOR A LONG AND THIN ROD 184 BROWNIAN TIME SCALE: RELAXATION RATES OF TRANSLATIONAL AND ROTATIONAL VELOCITY 186 BROWNIAN LENGTH SCALE AND BROWNIAN ANGLE 187 CALCULATION OF FLUCTUATION STRENGTHS 189 X CONTENTS I 3.6.6 TRANSLATIONAL BROWNIAN MOTION OF A ROD 192 3.6.7 ORIENTATIONAL CORRELATIONS 194 3.7 EQUATIONS OF MOTION FOR INTERACTING RODS 198 3.7.1 THE N-PARTICLE SMOLUCHOWSKI EQUATION 199 3.7.2 TRANSLATIONAL AND ROTATIONAL DIFFUSION OF NON-INTERACTING RODS WITHOUT SHEAR FLOW 206 3.8 THE ORIENTATIONAL ORDER PARAMETER 208 3.9 NON-INTERACTING BROWNIAN RODS IN SHEAR FLOW 210 3.9.1 ELONGATIONAL FLOW 212 3.9.2 SIMPLE SHEAR FLOW 213 3.10 THE DOI-EDWARDS EQUATION OF MOTION AND THE MAIER-SAUPE POTENTIAL 21 6 3.10.1 EQUATION OF MOTION FOR P(&, T) 216 3.10.2 EQUATION OF MOTION FOR S(T) 219 3.10.3 DENSITY EXPANSION OF THE PAIR CORRELATION FUNCTION 221 3.10.4 ORIENTATIONAL CLOSURE RELATION 222 3.11 PARANEMATIC-NEMATIC SPINODALS AND THE BINODAL UNDER SHEAR FLOW 224 3.11.1 SPINODALS 225 3.11.2 THE BINODAL 229 3.11.3 A REMARK ON PATTERN FORMATION AND TIME-PERIODIC STATES 230 3.12 HOW IMPORTANT ARE DYNAMIC CORRELATIONS? 231 3.13 THE STRESS TENSOR FOR ROD SUSPENSIONS 233 3.13.1 THE BASIC IDEA 233 3.1 3.1.1 PARTICLE-PARTICLE STRESS TENSOR CI'P 235 3.13.1.2 PARTICLE-SOLVENT STRESS TENSOR CPS 236 3.13.1.3 SOLVENT-SOLVENT STRESS TENSOR C"" 239 3.13.2 TOTAL STRESS TENSOR 242 3.13.3 STRESS TENSOR FOR HOMOGENEOUS SUSPENSIONS 243 3.13.4 EXPLICIT EVALUATION OF STRESS TENSOR FOR VERY LONG AND THIN RODS 244 3.13.5 STRESS TENSOR FOR A HOMOGENEOUS SYSTEM EXPRESSED IN TERMS OF ORDER PARAMETER 248 3.14 VISCOELASTIC RESPONSE FUNCTIONS 249 3.14.1 SHEAR VISCOSITY AND NORMAL STRESSES FOR LOW SHEAR RATES 250 3.14.2 VISCOELASTIC RESPONSE AT HIGH SHEAR RATES 253 3.14.3 NONLINEAR VISCOELASTIC RESPONSE 255 3.14.4 COMPARISON WITH OTHER THEORIES, SIMULATIONS, AND EXPERIMENTS 257 3.15 CURRENT RESEARCH TOPICS 266 3.15.1 SHEAR-BANDING TRANSITIONS 266 3.15.1.1 VORTICITY BANDING 267 GRADIENT BANDING 268 NON-EQUILIBRIUM PHASE DIAGRAM UNDER SHEAR FLOW 270 PHASE SEPARATION KINETICS UNDER FLOW CONDITIONS 271 APPENDIX 271 BEAD INDEX SUMMATIONS 271 USEFUL MATHEMATICAL IDENTITIES 273 ON THE ACCURACY OF THE CLOSURE RELATION (3.227) 273 EVALUATION OF SUMS OVER BEAD LNDEX NUMBERS 274 DERIVATION OF EQ. (3.279) 278 LNDEX 285
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spellingShingle Soft matter
Kolloid (DE-588)4164695-2 gnd
Lösung Chemie (DE-588)4036159-7 gnd
subject_GND (DE-588)4164695-2
(DE-588)4036159-7
title Soft matter
title_auth Soft matter
title_exact_search Soft matter
title_exact_search_txtP Soft matter
title_full Soft matter 2 Complex colloidal suspensions ed. by Gerhard Gompper ...
title_fullStr Soft matter 2 Complex colloidal suspensions ed. by Gerhard Gompper ...
title_full_unstemmed Soft matter 2 Complex colloidal suspensions ed. by Gerhard Gompper ...
title_short Soft matter
title_sort soft matter complex colloidal suspensions
topic Kolloid (DE-588)4164695-2 gnd
Lösung Chemie (DE-588)4036159-7 gnd
topic_facet Kolloid
Lösung Chemie
url http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=014646943&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA
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