Electrical properties of polymers

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Hauptverfasser: Blythe, Anthony R. (VerfasserIn), Bloor, D. 1937- (VerfasserIn)
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Sprache:English
Veröffentlicht: Cambridge [u.a.] Cambridge Univ. Press 2005
Ausgabe:2. ed.
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Datensatz im Suchindex

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adam_text ELECTRICAL PROPERTIES OF POLYMERS SECOND EDITION TONY BLYTHE FORMER CHIEF SCIENTIST, BICC CABLES DAVID BLOOR UNIVERSITY OF DURHAM, VK B CAMBRIDGE QGPP UNIVERSITY PRESS CONTENTS PREFACE 1 INTRODUCTION 1.1 OVERVIEW 1.2 STRUCTURE OF POLYMERS 1.2.1 CHEMICAL STRUCTURE - SATURATED POLYMERS 1.2.2 CHEMICAL STRUCTURE - UNSATURATED POLYMERS 1.2.3 PREPARATION OF POLYMERS 1.2.4 CHEMICAL AND PHYSICAL VARIANTS 1.2.5 CONFORMATION AND HINDERED ROTATION 1.2.6 COPOLYMERS 1.2.7 CRYSTALLISATION AND ORIENTATION 1.3 POLYMERS AS NON-CONDUCTIVE MATERIALS 1.4 POLYMERS AS CONDUCTIVE MATERIALS 1.5 ELECTRICAL APPLICATIONS OF POLYMERS 1.6 FURTHER READING 2 DIELECTRICS IN STATIC FIELDS 2.1 ELECTROSTATIC RELATIONS 2.2 MOLECULAR POLARISABILITY 2.3 THE LOCAL FIELD 2.4 THE CLAUSIUS-MOSOTTI RELATION 2.5 POLAR MOLECULES 2.6 RELATIVE PERMITTIVITY OF POLYMERS 2.6.1 NON-POLAR POLYMERS 2.6.2 POLAR POLYMERS 2.6.3 MEAN-SQUARE MOMENT 2.7 LOW RELATIVE PERMITTIVITY POLYMERS 2.8 FURTHER READING 3 DIELECTRIC RELAXATION 3.1 GENERAL THEORY V CONTENTS 3.1.1 COMPLEX RELATIVE PERMITTIVITY AND DIELECTRIC LOSS 58 3.1.2 THE DIELECTRIC RELAXATION PROCESS 60 3.1.3 DEPARTURES FROM THE DEBYE MODEL 64 3.2 THERMAL ACTIVATION OF DIPOLAR RELAXATION 66 3.3 COOPERATIVE DIPOLAR RELAXATION IN POLYMERS 69 3.4 DIELECTRIC RELAXATION IN SOLID POLYMERS 72 3.5 POLYMER LIQUIDS 79 3.5.1 DILUTE SOLUTIONS 79 3.5.2 CONCENTRATED SOLUTIONS AND MELTS 84 3.6 INTERFACIAL POLARISATION 85 3.6.1 MAXWELL-WAGNER EFFECTS 85 3.6.2 ELECTRODE POLARISATION 87 3.7 ELECTRONIC EFFECTS 88 3.7.1 NON-LINEAR EFFECTS 94 3.7.2 MOLECULAR NON-LINEARITY 97 3.8 FURTHER READING 110 ELECTRONIC CONDUCTION IN POLYMERS 111 4.1 INTRODUCTION 111 4.2 THEORIES OF ELECTRONIC CONDUCTION 115 4.2.1 BAND THEORY OF CONDUCTION 115 4.2.2 PROPERTIES OF SEMICONDUCTORS 125 4.2.3 HOPPING CONDUCTION 132 4.2.4 THE METAL-INSULATOR TRANSITION 136 4.2.5 BAND THEORY APPLIED TO POLYMERS 140 4.2.6 SUPERCONDUCTION 149 4.3 FURTHER READING 152 MEASUREMENT OF ELECTRICAL PROPERTIES 154 5.1 INTRODUCTION 154 5.2 BRIDGE METHODS 161 5.3 RESONANCE METHODS 164 5.4 FREQUENCY RESPONSE ANALYSER METHODS 166 5.5 WAVE-TRANSMISSION METHODS 169 5.6 TIME-DOMAIN METHODS 173 5.7 MEASUREMENT OF RESISTIVITY 177 5.8 FURTHER READING 185 DIELECTRIC BREAKDOWN 186 6.1 INTRODUCTION 186 6.2 ELECTRONIC BREAKDOWN 187 6.3 ELECTROMECHANICAL BREAKDOWN 192 6.4 THERMAL BREAKDOWN 194 CONTENTS VN 6.5 BREAKDOWN CAUSED BY GAS DISCHARGES 195 6.5.1 INTERNAL DISCHARGES AND ELECTRIC TREEING 196 6.5.2 EXTERNAL DISCHARGES AND SURFACE TRACKING 199 6.6 LONG TERM ENDURANCE UNDER ELECTRICAL STRESS 201 6.6.1 ENDURANCE EXPERIMENTS 202 6.6.2 ELECTROKINETIC MODELLING OF DIELECTRIC ENDURANCE 203 6.6.3 ALTERNATING GELDS 208 6.6.4 WATER TREEING 209 6.6.5 EFFECT OF SPACE CHARGES 210 6.7 EXAMPLES OF HIGH-VOLTAGE DESIGN 211 6.7.1 POWER CABLES 211 6.7.2 THIN-GLM CAPACITORS 212 6.8 FURTHER READING 214 6.9 APPENDIX - BREAKDOWN STATISTICS 214 STATIC CHARGES 217 7.1 INTRODUCTION 217 7.2 MEASUREMENT OF STATIC CHARGES 220 7.2.1 MEASUREMENT OF SURFACE CHARGES 221 7.2.2 MEASUREMENT OF SPACE CHARGES 227 7.3 CONTACT CHARGING OF POLYMERS 232 7.3.1 CHARGE TRANSFER BY ELECTRONS 232 7.3.2 CHARGE TRANSFER BYIONS 242 7.4 ELECTRETS 245 7.5 FURTHER READING 249 LONIC CONDUCTION AND PARTICULATE AND MOLECULAR COMPOSITES 250 8.1 INTRODUCTION 250 8.2 LONIC CONDUCTION 251 8.2.1 LONIC IMPURITIES 251 8.2.2 ANTISTATIC AGENTS 257 8.2.3 POLYELECTROLYTES AND PROTONIC CONDUCTORS 258 8.2.4 SOLID POLYMER ELECTROLYTES 261 8.3 PARTICULATE COMPOSITES 266 8.3.1 CONDUCTIVE POWDER COMPOSITES 270 8.3.2 CONDUCTIVE GBRE COMPOSITES 284 8.4 MOLECULAR COMPOSITES 287 8.4.1 CARRIER MOBILITY 290 8.4.2 PHOTOCONDUCTIVITY 299 8.4.3 SPACE CHARGE EFFECTS 302 8.5 FURTHER READING 305 VLLL CONTENTS 9 INTRINSICALLY CONDUCTIVE POLYMERS 306 9.1 INTRODUCTION 306 9.2 CONJUGATED POLYMERS 307 9.2.1 PREPARATIVE METHODS 311 9.3 THEORIES OF ELECTRONIC PROPERTIES 322 9.3.1 DOPING OF CONJUGATED POLYMERS 327 9.3.2 DISORDERED CONJUGATED POLYMERS 333 9.4 PHYSICAL AND CHEMICAL PROPERTIES 340 9.4.1 MORPHOLOGY 341 9.4.2 INTRINSIC OPTICAL PROPERTIES 344 9.4.3 INTRINSIC ELECTRONIC PROPERTIES 359 9.4.4 DOPED AND METALLIC POLYMERS 379 9.5 FURTHER READING 393 10 APPLICATIONS OF ELECTRO-ACTIVE AND CONDUCTIVE POLYMERS 395 10.1 INTRODUCTION 395 10.2 ELECTRO-ACTIVE POLYMERS 395 10.2.1 XEROGRAPHY 395 10.2.2 ORGANIC LIGHT EMITTING DIODES AND SOLAR CELLS 401 10.2.3 NON-LINEAR OPTICS 404 10.3 INTRINSICALLY CONDUCTIVE POLYMERS 412 10.3.1 SOFT ELECTRONICS 414 10.3.2 LIGHT EMITTING DIODES 421 10.3.3 PHOTOVOLTAIC DEVICES 432 10.3.4 SENSORS 438 10.3.5 ELECTROCHEMICAL APPLICATIONS 441 10.3.6 CONDUCTIVE COATINGS AND COMPOSITES 447 10.3.7 OTHER APPLICATIONS 451 10.4 FURTHER READING 456 REFERENCES 458 INDEX 475
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record_format marc
spellingShingle Blythe, Anthony R.
Bloor, D. 1937-
Electrical properties of polymers
Polymers Electric properties
Elektrische Eigenschaft (DE-588)4193812-4 gnd
Polymere (DE-588)4046699-1 gnd
subject_GND (DE-588)4193812-4
(DE-588)4046699-1
title Electrical properties of polymers
title_auth Electrical properties of polymers
title_exact_search Electrical properties of polymers
title_full Electrical properties of polymers Tony Blythe ; David Bloor
title_fullStr Electrical properties of polymers Tony Blythe ; David Bloor
title_full_unstemmed Electrical properties of polymers Tony Blythe ; David Bloor
title_short Electrical properties of polymers
title_sort electrical properties of polymers
topic Polymers Electric properties
Elektrische Eigenschaft (DE-588)4193812-4 gnd
Polymere (DE-588)4046699-1 gnd
topic_facet Polymers Electric properties
Elektrische Eigenschaft
Polymere
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