Atom tunneling phenomena in physics, chemistry and biology with 24 tables
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Berlin [u.a.]
Springer
2004
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245 | 1 | 0 | |a Atom tunneling phenomena in physics, chemistry and biology |b with 24 tables |c Tetsuo Miyazaki (ed.) |
250 | |a 1. Aufl. | ||
264 | 1 | |a Berlin [u.a.] |b Springer |c 2004 | |
300 | |a XIV, 313 S. |b Ill., graph. Darst. : 24 cm | ||
336 | |b txt |2 rdacontent | ||
337 | |b n |2 rdamedia | ||
338 | |b nc |2 rdacarrier | ||
490 | 1 | |a Springer series on atomic, optical, and plasma physics |v 36 | |
490 | 0 | |a Physics and astronomy online library | |
650 | 4 | |a Tunneleffekt - Atom | |
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Datensatz im Suchindex
DE-BY-TUM_call_number | 0202 PHY 022f 2004 A 30 |
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DE-BY-TUM_katkey | 1466212 |
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adam_text | TABLE OF CONTENTS 1. INTRODUCTION (T. MIYAZAKI)
..............................................................................
1 1.1 ATOM TUNNELING PHENOMENA
...................................................................1
1.2 AIM OF THE BOOK
......................................................................................4
1.3 OUTLINE OF
REFERENCES....................................................................
....................................11 PART 1 ATOM TUNNELING IN
PHYSICS 2 THEORY OF ATOM TUNNELING REACTIONS IN THE GAS
PHASE.............................15 (T. TAKAYANAGI) 2.1 INTRODUCTION
...........................................................................................15
2.2 WHAT IS TUNNELING IN CHEMICAL
REACTIONS?...........................................16 2.3 QUANTUM
MECHANICAL METHODS FOR CALCULATING RATE CONSTANTS............18 2.4
LOW TEMPERATURE BEHAVIOR OF RATE CONSTANTS: WIGNER THRESHOLD
LAW..........................................................................20
2.5 EFFECT OF VAN DER WAALS INTERACTIONS ON TUNNELING
REACTIONS...............21 2.6 H + H2 TUNNELING REACTION IN SOLID
PHASE: APPLICATION OF GAS-PHASE MODELS
.........................................................24 2.7
TUNNELING IN THE F + H2, D2, AND HD
REACTIONS....................................26 2.8 CONCLUSION AND
FUTURE DEVELOPMENT
....................................................28
REFERENCES........................................................................................................29
3 THEORY OF ATOM TUNNELING REACTIONS IN THE SOLID
PHASE...........................33 (L. I. TRAKHTENBERG) 3.1
INTRODUCTION
...........................................................................................33
3.2 DESCRIPTION OF LOW TEMPERATURE CHEMICAL
REACTIONS..........................36 3.3 EXPERIMENTAL DATA ON
H-ATOM TUNNELING AND FITTING BY ONE DIMENSIONAL
MODEL...................................................................42
3.4 EFFECT OF PROMOTIVE MODES ON THE RATE CONSTANT OF ATOM
TUNNELING..43 3.4.1 RELAXATION PROCESSES
.................................................................44
3.4.2 TIME OF TUNNELING
TRANSITION....................................................44 3.4.3
DOUBLE ADIABATIC APPROXIMATION
.............................................45 3.4.4 MODIFIED THEORY
OF RADIATIONLESS TRANSITIONS ..........................46 3.4.5
COMPARISON OF THEORY WITH EXPERIMENTAL DATA........................48
3.5 MECHANISMS OF TEMPERATURE AND PRESSURE DEPENDENCIES OF THE RATE
CONSTANT
..............................................................................49
VIII TABLE OF CONTENTS 3.5.1 ROLE OF MEDIUM REORGANIZATION IN
D-TRANSFER IN AN IRRADIATED HD CRYSTAL
....................................................... 50 3.5.2
H-ATOM TUNNELING IN THE FLUORENE*ACRIDINE SYSTEM................ 52
3.6 CONCLUSION AND FUTURE DEVELOPMENT
.................................................... 54 REFERENCES
.......................................................................................................
55 4 ATOM TUNNELING REACTIONS IN QUANTUM SOLID HYDROGEN
.......................... 59 (T. MIYAZAKI) 4.1 INTRODUCTION. CLASSICAL
REACTIONS AND TUNNELING REACTIONS.................. 59 4.1.1
TEMPERATURE
DEPENDENCE.......................................................... 60
4.1.2 ISOTOPE EFFECT
............................................................................
62 4.2 ESR MEASUREMENT AT VERY LOW
TEMPERATURE....................................... 63 4.3 CONCLUSIVE
EVIDENCE FOR ATOM TUNNELING REACTIONS............................ 64
4.3.1 TEMPERATURE INDEPENDENCE
....................................................... 65 4.3.2 LARGE
ISOTOPE EFFECT
.................................................................. 66
4.3.3 COMPARISON OF EXPERIMENTAL RATE CONSTANTS WITH THEORETICAL
VALUES............................................................. 68
4.4 CONTROLLING FACTORS OF CLASSICAL
REACTIONS............................................ 70 4.5
CONTROLLING FACTORS OF TUNNELING
REACTIONS.......................................... 70 4.5.1 EFFECT OF
DEFORMATION OF CRYSTALLINE STRUCTURE ......................... 70
4.5.2 ANOMALOUS TEMPERATURE EFFECT ON THE DECAY OF H2 * ANIONS ... 74
4.5.3 EFFECT OF DISORDER AND ENERGY
DISSIPATION................................ 77 4.5.4 INVERSE SECONDARY
ISOTOPE EFFECT OF METHYL RADICAL REACTIONS
..................................................... 85 4.6
FASCINATING QUANTUM PROPERTIES OF SOLID HYDROGEN
............................. 86 4.7 CONCLUSION AND FUTURE DEVELOPMENT
.................................................... 87 REFERENCES
.......................................................................................................
88 5 ATOM TUNNELING PHENOMENA IN QUANTUM SOLID AND LIQUID HELIUM
....... 91 (Y. MIURA) 5.1 INTRODUCTION. QUANTUM NATURE OF HELIUM
ATOMS.................................. 91 5.2 NUCLEAR MAGNETIC
ORDERING OF SOLID 3 HE ARISING FROM TUNNELING OF
ATOMS......................................................................
92 5.3 QUANTUM NUCLEATION IN SUPERFLUID HELIUM BY
TUNNELING..................... 98 5.4 TUNNELING MOTION OF
DISLOCATION LINES IN SOLID 3 HE.......................... 103 5.5
CONCLUSION AND FUTURE DEVELOPMENT
.................................................. 108 REFERENCES
.....................................................................................................
109 6 QUANTUM TUNNELING DIFFUSION (R. KADONO)
.............................................. 111 6.1 INTRODUCTION
.........................................................................................
111 6.2 QUANTUM TUNNELING DIFFUSION OF POSITIVE MUONS AND
MUONIUM....... 112 6.3 EFFECT OF DISORDER AND SUPERCONDUCTIVITY
........................................... 115 6.4 MUONIUM IN A BLOCH
STATE...................................................................
117 6.5 CONCLUSION AND FUTURE DEVELOPMENT
.................................................. 123 REFERENCES
.....................................................................................................
123 TABLE OF CONTENTS IX PART 2 ATOM TUNNELING IN CHEMISTRY 7
FASCINATING ASPECTS OF TUNNELING REACTIONS IN ORGANIC SUBSTANCES
......127 (T. MIYAZAKI) 7.1 INTRODUCTION
.........................................................................................127
7.2 SELECTIVE TUNNELING REACTION IN ALKANE MIXTURES BY H
ATOMS..........128 7.2.1 FORMATION OF H ATOMS IN RADIOLYSIS OF ALKANE
......................128 7.2.2 EVIDENCE FOR TUNNELING REACTION
............................................131 7.2.3 SELECTIVITY IN
TUNNELING REACTION............................................132
7.2.4 LOCAL MOTION AND SELECTIVE TUNNELING
REACTION.....................135 7.3 SELECTIVE TUNNELING REACTION IN
THE SAME ALKANE BY H ATOMS .........138 7.4 INSTABILITY OF
MOLECULES. TUNNELING ELIMINATION OF H2 MOLECULE FROM ALKANE CATION
.............................................................................140
7.5 INSTABILITY OF MOLECULES. TUNNELING CIS*TRANS ISOMERIZATION OF
FORMIC ACID
....................................................................................144
7.6 CONCLUSION AND FUTURE DEVELOPMENT
..................................................145
REFERENCES......................................................................................................145
8 TUNNELING INSERTION REACTION OF CARBENES (H. TOMIOKA)
.........................147 8.1 INTRODUCTION
.........................................................................................147
8.1.1 DICOORDINATE CARBON
INTERMEDIATE*CARBENES..........................147 8.1.2 CARBENES HAVE
TWO-ELECTRONIC STATES SINGLET AND TRIPLET MULTIPLICITIES
.........................................................148 8.1.3
SINGLET AND TRIPLET STATES SHOW DIFFERENT REACTION PATTERNS ..149
8.1.4 HOW TO GENERATE A
CARBENE.....................................................151 8.2
REACTIONS OF ARYLCARBENES WITH ALKENES AT 77 K
................................152 8.3 REACTIONS OF ARYLCARBENES
WITH ALCOHOLS AT 77 K...............................155 8.4
TUNNELING C*H INSERTION FROM TRIPLET CARBENES AT LOW
TEMPERATURE.............................................................................157
8.5 WHY CAN ONLY TRIPLETS FIND A TUNNELING
PATHWAY?...........................160 8.6 TUNNELING REACTIONS OF
CARBENE HAVING INTRAMOLECULAR REACTION CHANNELS
.......................161 8.7 TUNNELING IN INTRAMOLECULAR
REACTIONS................................................164 8.8
TUNNELING REACTION AT ELEVATED
TEMPERATURES....................................166 8.9 CONCLUSION
AND FUTURE DEVELOPMENT
..................................................170
REFERENCES......................................................................................................171
9 PRODUCTION OF INTERSTELLAR MOLECULES AND AMORPHOUS SEMICONDUCTORS BY
ATOM TUNNELING REACTION (K. HIRAOKA)
.................................................173 9.1 INTRODUCTION
.........................................................................................173
9.2
METHOD.................................................................................................175
9.3 LABORATORY SIMULATION OF H-ATOM TUNNELING REACTIONS IN
INTERSTELLAR ICES
................................................................................177
9.3.1 GAS*GRAIN PROCESSES FOR THE FORMATION OF NH3, CH4, AND H2O
...................................................................................178
X TABLE OF CONTENTS 9.3.2 FORMATION OF FORMALDEHYDE BY THE TUNNELING
REACTION OF H WITH SOLID CO AT 10 K
..................................................... 182 9.3.3
TUNNELING REACTIONS OF H ATOMS WITH SOLID C2H2, C2H4, AND C2H6
..................................................................................
184 9.3.4 TUNNELING REACTIONS OF D ATOMS WITH C2H2, C2H4 AND C2H6:
ISOTOPE EFFECT
..........................................................................
189 9.3.5 NEGATIVE TEMPERATURE DEPENDENCE OF H-ATOM TUNNELING
REACTIONS ............................................. 190 9.4
FORMATION OF AMORPHOUS SEMICONDUCTOR BY H-ATOM TUNNELING
REACTIONS......................................................... 193
9.5 CONCLUSION AND FUTURE DEVELOPMENT
.................................................. 197 REFERENCES
.....................................................................................................
198 10 ATOM TUNNELING AND MOLECULAR STRUCTURE (H. SEKIYA)
............................ 201 10.1 INTRODUCTION
.........................................................................................
201 10.2 EXPERIMENTAL
METHODS.........................................................................
201 10.3 PROTON TUNNELING IN MOLECULES AND
COMPLEXES.................................. 206 10.3.1 PROTON
TUNNELING IN MOLECULES ............................................. 206
10.3.2 PROTON TUNNELING IN
COMPLEXES............................................ 219 10.4
CONCLUSION AND FUTURE DEVELOPMENT
.................................................. 227 REFERENCES
.....................................................................................................
228 11 ATOM TUNNELING AND CRYSTALLINE STRUCTURE (T. MATSUO)
.......................... 233 11.1 INTRODUCTION
.........................................................................................
233 11.2 GENERAL CONSIDERATIONS ON X-RAY AND NEUTRON DIFFRACTION,
CRYSTAL STRUCTURE AND PHASE
TRANSITIONS.............................................. 234 11.3
PROTON TUNNELING IN HYDROGEN-BONDED CRYSTALS
................................ 237 11.4 TUNNELING ENERGY LEVELS OF
AMMONIUM IONS IN AMMONIUM HEXACHLOROMETALLATES: GLOBAL AND LOCAL
ROTATION AND TUNNELING...... 245 11.5 DELOCALIZATION OF H (D) ATOMS.
STRUCTURE OF (NH4)2PTCL6, (NH4)2SNCL6 AND (ND4)2SNCL6 BY NEUTRON
DIFFRACTION ....................... 251 11.6 OTHER COMPOUNDS
POSSESSING STRONG ISOTOPE-DEPENDENT PROPERTIES.. 257 11.7 CONCLUSION
AND FUTURE DEVELOPMENT
.................................................. 258 REFERENCES
.....................................................................................................
258 PART 3 ATOM TUNNELING IN BIOLOGY 12 ATOM TUNNELING REACTION OF
VITAMIN C IN SUPPRESSION OF MUTATION..... 263 (T. MIYAZAKI AND J.
KUMAGAI) 12.1 INTRODUCTION
.........................................................................................
263 12.1.1 TUNNELING REACTION AT ROOM TEMPERATURE
........................... 263 12.1.2 HOW TO STUDY TUNNELING
REACTIONS IN BIOLOGICAL SYSTEMS... 265 12.2 LONG-LIVED RADICALS IN *
-IRRADIATED CELLS .......................................... 267
TABLE OF CONTENTS XI 12.2.1 DISCOVERY OF LONG-LIVED RADICALS AND
REACTIONS WITH VITAMIN C
......................................................................267
12.2.2 WHY DO REACTIVE RADICALS SURVIVE FOR A LONG TIME?..........269
12.2.3 ASSIGNMENT OF LONG-LIVED RADICALS
.....................................272 12.3 REACTION OF LONG-LIVED
RADICALS WITH VITAMIN C ..............................275 12.4
BIOLOGICAL EFFECTS OF TUNNELING REACTION OF LONG-LIVED RADICALS WITH
VITAMIN C
....................................................................................277
12.5 TUNNELING REACTION OF LONG-LIVED RADICALS WITH VITAMIN
C.............280 12.6 CONCLUSION AND FUTURE DEVELOPMENT
..................................................282
REFERENCES......................................................................................................283
13 ATOM TUNNELING REACTION OF VITAMIN E IN ANTIOXIDANT, PROOXIDANT AND
REGENERATION REACTIONS (S. NAGAOKA)
.................................................285 13.1 INTRODUCTION
.........................................................................................285
13.2 TUNNELING ANTIOXIDANT REACTION OF VITAMIN
E....................................289 13.3 PROOXIDANT REACTION OF
VITAMIN E.......................................................295
13.4 TUNNELING REGENERATION REACTION OF VITAMIN
E..................................298 13.5 CONCLUSION AND FUTURE
DEVELOPMENT ..................................................301 R
EFERENCES......................................................................................................302
INDEX***************************** 305
|
any_adam_object | 1 |
author_GND | (DE-588)128721774 |
building | Verbundindex |
bvnumber | BV017304552 |
classification_rvk | UK 7500 UL 1000 UP 1400 UR 1100 |
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dewey-full | 530.416 |
dewey-hundreds | 500 - Natural sciences and mathematics |
dewey-ones | 530 - Physics |
dewey-raw | 530.416 |
dewey-search | 530.416 |
dewey-sort | 3530.416 |
dewey-tens | 530 - Physics |
discipline | Physik |
edition | 1. Aufl. |
format | Book |
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id | DE-604.BV017304552 |
illustrated | Illustrated |
indexdate | 2024-12-23T16:19:36Z |
institution | BVB |
isbn | 3540015264 |
language | English |
oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-010430181 |
oclc_num | 249222038 |
open_access_boolean | |
owner | DE-91G DE-BY-TUM DE-703 DE-11 |
owner_facet | DE-91G DE-BY-TUM DE-703 DE-11 |
physical | XIV, 313 S. Ill., graph. Darst. : 24 cm |
publishDate | 2004 |
publishDateSearch | 2004 |
publishDateSort | 2004 |
publisher | Springer |
record_format | marc |
series | Springer series on atomic, optical, and plasma physics |
series2 | Springer series on atomic, optical, and plasma physics Physics and astronomy online library |
spellingShingle | Atom tunneling phenomena in physics, chemistry and biology with 24 tables Springer series on atomic, optical, and plasma physics Tunneleffekt - Atom Tunneleffekt (DE-588)4136216-0 gnd Atom (DE-588)4003412-4 gnd |
subject_GND | (DE-588)4136216-0 (DE-588)4003412-4 |
title | Atom tunneling phenomena in physics, chemistry and biology with 24 tables |
title_auth | Atom tunneling phenomena in physics, chemistry and biology with 24 tables |
title_exact_search | Atom tunneling phenomena in physics, chemistry and biology with 24 tables |
title_full | Atom tunneling phenomena in physics, chemistry and biology with 24 tables Tetsuo Miyazaki (ed.) |
title_fullStr | Atom tunneling phenomena in physics, chemistry and biology with 24 tables Tetsuo Miyazaki (ed.) |
title_full_unstemmed | Atom tunneling phenomena in physics, chemistry and biology with 24 tables Tetsuo Miyazaki (ed.) |
title_short | Atom tunneling phenomena in physics, chemistry and biology |
title_sort | atom tunneling phenomena in physics chemistry and biology with 24 tables |
title_sub | with 24 tables |
topic | Tunneleffekt - Atom Tunneleffekt (DE-588)4136216-0 gnd Atom (DE-588)4003412-4 gnd |
topic_facet | Tunneleffekt - Atom Tunneleffekt Atom |
url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=010430181&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
volume_link | (DE-604)BV013270105 |
work_keys_str_mv | AT miyazakitetsuo atomtunnelingphenomenainphysicschemistryandbiologywith24tables |