Soil pollution processes and dynamics

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Hauptverfasser: Yaron, Bruno 1929- (VerfasserIn), Calvet, Raoul (VerfasserIn), Prost, René 1938- (VerfasserIn)
Format: Buch
Sprache:German
Veröffentlicht: Berlin [u.a.] Springer 1996
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Datensatz im Suchindex

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DE-BY-TUM_call_number 1002/UMW 141f 10.1996 A 1097
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adam_text CONTENTS PART I THE INTERACTING MATERIALS CHAPTER I THE SOIL AS A POROUS MEDIUM 1.1 THE SOLID PHASE 4 . 1 CLAY MATERIALS 5 .2 MINERALS OTHER THA N CLAYS 7 .3 SOIL ORGANIC MATTE R 8 .4 INTERACTIONS BETWEEN COMPONENTS OF THE SOLID PHASE 10 .1.5 THE ELECTRIFIED SURFACE OF THE SOLID PHASE 12 .2 THE LIQUID PHASE 13 .2.1 WATER NEA R SOIL SOLID PHASE 13 .2.2 THE AQUEOUS SOLUTION 15 .3 THE SOIL GASEOUS PHASE 17 .4 THE SOIL AS BIOLOGICAL SYSTEM 18 .4.1 SOIL BIOTA: COMPONENTS AN D DISTRIBUTION 18 .4.2 MICROORGANISM BIOACTIVITY 19 .5 SOIL HETEROGENEITY 21 REFERENCES 22 CHAPTER 2 THE SOIL POLLUTANTS 25 2.1 INORGANIC AN D INORGANIC-ORGANICALLY COMBINED POLLUTANTS 25 2.1.1 NITROGEN FORM S 25 2.1.2 PHOSPHORUS FORM S 27 2.1.3 SALTS 29 2.1.4 POTENTIALLY TOXIC TRACE ELEMENTS 32 2.2 TOXIC ORGANIC RESIDUES 41 2.2.1 SMALL ORGANIC MOLECULES 42 2.2.2 ORGANIC MACROMOLECULES 49 REFERENCES 51 VI N CONTENTS PART II POLLUTANTS PARTITIONING AMONG SOIL PHASES CHAPTER 3 POLLUTANTS-SOIL SOLUTION INTERACTIONS 57 3.1 ACID-BASE EQUILIBRIA 58 3.2 PRECIPITATION-DISSOLUTION 59 3.3 LIGAND EFFECT 61 3.4 OXIDATION-REDUCTION EQUILIBRIUM 63 3.5 EFFECTS OF MIXED SOLVENTS AND SURFACTANTS ... . 64 3.6 TEMPERATURE EFFECT ON SOLUBILITY 66 3.7 EXAMPLES 66 3.7.1 ACID RAINS AND AL DISSOLUTION 66 3.7.2 ALKALINE SOILS AND GYPSUM DISSOLUTION 68 3.7.3 SLUDGE EFFECT ON POTENTIALLY TOXIC INORGANIC TRACE ELEMENT SOLUBILITY 69 3.7.4 REDOX PROCESSES AN D METAL SOLUBILITY 72 3.7.5 SOLUBILITY OF ORGANIC SOLVENTS UNDER A WASTE-DISPOSAL SITE 74 REFERENCES 77 CHAPTER 4 VOLATILIZATION INTO THE SOIL ATMOSPHERE 79 4.1 THE VOLATILIZATION PROCESS 80 4.2 VAPOR PRESSURE AN D VAPORIZATION RELATIONSHIP . 81 4.3 VOLATILIZATION OF MULTICOMPONENT POLLUTANTS . . 83 4.4 EXAMPLES 84 4.4.1 AMMONIA VOLATILIZATION 84 4.4.2 PESTICIDE VOLATILIZATION 87 4.4.3 PETROLEUM PRODUCTS VOLATILIZATION 92 REFERENCES 97 CHAPTER 5 RETENTION OF POLLUTANTS ON AND WITHIN THE SOIL SOLID PHASE 99 5.1 SURFACE ADSORPTION 99 5.1.1 ADSORPTION OF IONIC POLLUTANTS 100 5.1.2 ADSORPTION OF NONIONI C POLLUTANTS 107 5.1.3 ADSORPTION OF COMPLEX MIXTURES 109 5.1.4 ADSORPTION ISOTHERMS IL L 5.1.5 KINETICS OF ADSORPTION 114 5.1.6 FACTORS AFFECTING ADSORPTION 116 5.2 NONADSORPTIVE RETENTION 120 5.2.1 POLLUTANT PRECIPITATION 121 5.2.2 TRAPPING 122 5.3 EXAMPLES 125 CONTENTS IX 5.3.1 POLLUTANTS ADSORPTION 125 5.3.2 NONADSORPTIVE RETENTION 140 REFERENCES 144 PART III POLLUTANT BEHAVIOR IN SOILS CHAPTER 6 REVERSIBLE AND IRREVERSIBLE RETENTION - RELEASE AND BOUND RESIDUES 151 6.1 RETENTION HYSTERESIS 151 6.1.1 TRUE HYSTERESIS 152 6.1.2 APPAREN T HYSTERESIS 154 6.1.3 METHOD-CREATED HYSTERESIS 156 6.2 BOUND RESIDUES 158 6.2.1 EXPERIMENTAL DEFINITION 158 6.2.2 MECHANISMS 159 6.3 EXAMPLES 162 6.3.1 INORGANIC POLLUTANTS 162 6.3.2 ORGANIC POLLUTANTS 171 6.3.3 ORGANO-CLAYS 178 REFERENCES 179 CHAPTER 7 TRANSFORMATION AND METABOLITE FORMATION ... . 183 7.1 DECOMPOSITION RATE 183 7.2 ABIOTICALLY INDUCED TRANSFORMATION 185 7.2.1 TRANSFORMATION IN SOIL WATER 186 7.2.2 TRANSFORMATION A T THE SOLID-LIQUID INTERFACE . . 190 7.3 BIOLOGICALLY MEDIATED TRANSFORMATIONS 195 7.3.1 MICROBIAL REACTIONS 195 7.3.2 TRANSFORMATION OF INORGANIC COMPOUND S ... . 197 7.3.3 TRANSFORMATION OF ORGANIC TOXIC CHEMICALS . . 200 7.4 EXAMPLES 203 7.4.1 HYDROLYSIS 204 7.4.2 THE REDOX PROCESS 206 7.4.3 PHOTOLYTIC DEGRADATION 209 7.4.4 COORDINATIVE TRANSFORMATIONS 212 7.4.5 LIQUID MIXTURE TRANSFORMATIONS 215 REFERENCES 218 CHAPTER 8 POLLUTANTS TRANSPORT IN THE SOIL MEDIUM 223 8.1 SOLUTE TRANSPOR T 223 8.1.1 TRANSPOR T MECHANISMS 224 X CONTENTS 8.1.2 PREFERENTIAL FLOW OF SOLUTE 228 8.2 TRANSPOR T OF NONAQUEOUS-PHASE LIQUID 230 8.3 VAPOR FLUX 234 8.4 TRANSPOR T ON SUSPENDED PARTICLES 236 8.4.1 TRANSPOR T ON ERODED SEDIMENTS 236 8.4.2 TRANSPOR T IN ASSOCIATION WITH DISPERSED COLLOIDAL MATERIAL 237 8.5 FACTOR S AFFECTING TRANSPOR T PROCESSES 239 8.5.1 FIELD AND CLIMATE VARIABILITY 239 8.5.2 HETEROGENEITY OF THE POLLUTANT 241 8.6 EXAMPLES 241 8.6.1 DIFFUSION OF A DEGRADABLE PESTICIDE 241 8.6.2 MISCIBLE DISPLACEMENT 243 8.6.3 TRANSPOR T OF NONAQUEOU S POLLUTAN T LIQUIDS (NAPL) 246 8.6.4 VERTICAL TRANSPOR T OF PESTICIDES ADSORBED ON COLLOIDS 250 8.6.5 PREFERENTIAL FLOW 253 8.6.6 TRANSPOR T OF PATHOGENIC MICROORGANISMS ... . 258 REFERENCES 259 PAR T IV PREDICTION AND REMEDIATION CHAPTER 9 MODELING THE FAT E O F POLLUTANTS IN THE SOI L ... . 26 5 9.1 OVERVIE W O F MODEL S 26 5 9.2 DESCRIPTIO N O F MODEL S 26 7 9.2.1 DETERMINISTI C MODEL S 26 8 9.2.2 STOCHASTI C MODEL S 27 7 9.3 EXAMPLE S O F MODEL S DESCRIBIN G TH E FAT E O F PESTICIDE S IN SOILS 278 9.3.1 TRANSPOR T PHENOMEN A 27 9 9.3.2 SINK/SOURC E PHENOMEN A 28 0 9.4 SOM E PROBLEM S CONNECTE D WIT H MODELIN G ... . 28 3 9.4.1 TH E SCAL E O F MODELIN G 28 3 9.4.2 MODE L SENSITIVIT Y 28 5 9.4.3 MODE L VALIDATIO N 287 REFERENCE S 28 9 CHAPTER 10 RISK S AND REMEDIES 29 5 10.1 RIS K ASSESSMEN T 29 5 10.1.1 DIAGNOSI S 29 6 10.1.2 PROGNOSI S 29 7 CONTENTS XI 10.2 SELECTION OF REMEDIES 297 10.2.1 THERE IS N O POLLUTION RISK IN THE LAND UNDER CONSIDERATION 298 10.2.2 THERE IS N O RISK AROUN D THE CONTAMINATED SITE 298 10.2.3 THERE IS A RISK FOR THE ENVIRONMENT 299 10.3 REMEDIATION TECHNOLOGIES 301 10.3.1 HAR D TECHNIQUES WITH EXCAVATION (SURGICAL OPERATION) 301 10.3.2 SOFT TECHNIQUES WITHOU T EXCAVATION (CHEMOTHERAPY) 302 10.3.3 CONTRO L AND COST 308 REFERENCES 309 SUBJECT INDEX 311
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author Yaron, Bruno 1929-
Calvet, Raoul
Prost, René 1938-
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publishDate 1996
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spellingShingle Yaron, Bruno 1929-
Calvet, Raoul
Prost, René 1938-
Soil pollution processes and dynamics
Bodenverschmutzung (DE-588)4206275-5 gnd
subject_GND (DE-588)4206275-5
title Soil pollution processes and dynamics
title_auth Soil pollution processes and dynamics
title_exact_search Soil pollution processes and dynamics
title_full Soil pollution processes and dynamics B. Yaron ; R. Calvet ; R. Prost
title_fullStr Soil pollution processes and dynamics B. Yaron ; R. Calvet ; R. Prost
title_full_unstemmed Soil pollution processes and dynamics B. Yaron ; R. Calvet ; R. Prost
title_short Soil pollution
title_sort soil pollution processes and dynamics
title_sub processes and dynamics
topic Bodenverschmutzung (DE-588)4206275-5 gnd
topic_facet Bodenverschmutzung
url http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=007217803&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA
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