Clusters of atoms and molecules 2 Solvation and chemistry of free clusters, and embedded, supported and compressed clusters : with 15 tables
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| Format: | Buch |
|---|---|
| Sprache: | English |
| Veröffentlicht: |
Berlin u.a.
Springer
1994
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| Schriftenreihe: | Springer series in chemical physics
56 |
| Online-Zugang: | Inhaltsverzeichnis |
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| 245 | 1 | 0 | |a Clusters of atoms and molecules |n 2 |p Solvation and chemistry of free clusters, and embedded, supported and compressed clusters : with 15 tables |c Hellmut Haberland (ed.) |
| 264 | 1 | |a Berlin u.a. |b Springer |c 1994 | |
| 300 | |a XVIII, 412 S. |b graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 490 | 1 | |a Springer series in chemical physics |v 56 | |
| 490 | 0 | |a Springer series in chemical physics |v ... | |
| 700 | 1 | |a Haberland, Hellmut |e Sonstige |4 oth | |
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| 830 | 0 | |a Springer series in chemical physics |v 56 |w (DE-604)BV000000670 |9 56 | |
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Datensatz im Suchindex
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| adam_text | CONTENTS 1 INTRODUCTION H. HABERLAND 1 1.1 HISTORICAL APPLICATION OF
METAL CLUSTERS 2 1.2 OUTLOOK 3 REFERENCE 3 2 SOLVATION, CHEMISTRY, AND
CHARGING OF FREE CLUSTERS 2.1 SOLVATED ATOMS IN POLAR SOLVENTS C.P.
SCHULZ AND I.V. HERTEL (WITH 8 FIGURES) 7 2.1.1 INTRODUCTION 7 2.1.2
EXPERIMENTAL 8 2.1.3 IONISATION POTENTIALS 10 2.1.4 FURTHER
SPECTROSCOPIC STUDIES 16 REFERENCES 18 2.2 IR SPECTROSCOPY OF SOLVATED
MOLECULES F.G. AMAR, S. GOYAL, D.J. LEVANDIER, L. PERERA, AND G. SCOLES
(WITH 12 FIGURES) 19 2.2.1 INTRODUCTION 19 2.2.2 SOLVATION STUDIES 21
2.2.3 COMPUTER SIMULATIONS 28 2.2.4 COMPLEX FORMING REACTIONS ON THE
SURFACE AND IN THE INTERIOR OF A CLUSTER 37 2.2.5 RECENT EXPERIMENTAL
RESULTS 40 REFERENCES 42 2.3 IR SPECTROSCOPY OF HYDROGEN BONDED CHARGED
CLUSTERS M.W. CROFTON, J.M. PRICE, AND Y.T. LEE (WITH 10 FIGURES) ... 44
2.3.1 GENERAL BACKGROUND AND MOTIVATION 44 2.3.2 SOME PREVIOUS STUDIES
47 2.3.3 CONSEQUENCE SPECTROSCOPY OF CHARGED CLUSTERS 49 2.3.4 BASIC
PRINCIPLES OF THE EXPERIMENT 49 2.3.5 TYPICAL RESULTS AND
INTERPRETATIONS 54 2.3.6 CONCLUDING REMARKS 69 REFERENCES 74 2.4
SOLVATED CLUSTER IONS A.W. CASTLEMAN, JR. (WITH 17 FIGURES) 77 2.4.1
INTRODUCTION 77 2.4.2 EXPERIMENTAL TECHNIQUES 79 2.4.3 REACTIONS
INFLUENCED BY SOLVATION 87 2.4.4 SOLVATION PHENOMENA ILL 2.4.5
PHOTODISSOCIATION EXPERIMENTS OF SOLVATED CLUSTER IONS 122 2.4.6 RECENT
DEVELOPMENTS 127 REFERENCES 127 2.5 SOLVATED ELECTRON CLUSTERS H.
HABERLAND AND K.H. BOWEN (WITH 12 FIGURES) 134 2.5.1 INTRODUCTION 134
2.5.2 CASE STUDIES 137 2.5.3 OUTLOOK 152 2.5.4 RECENT DEVELOPMENTS 152
REFERENCES 152 2.6 INTERNAL REACTIONS AND METASTABLE DISSOCIATIONS AFTER
IONIZATION OF VAN DER WAALS CLUSTERS T.D. MAERK AND O. ECHT (WITH 17
FIGURES) 154 2.6.1 INTRODUCTION 154 2.6.2 IONIZATION MECHANISMS AND
PROCESSES 155 2.6.3 IONIZATION EFFICIENCY 157 2.6.4 POST COLLISION
INTERNAL REACTIONS 159 2.6.5 METASTABLE DISSOCIATIONS 161 2.6.6 RECENT
DEVELOPMENTS 178 REFERENCES 178 2.7 MULTIPLY CHARGED CLUSTERS O. ECHT
AND T.D. MAERK (WITH 17 FIGURES) 183 2.7.1 INTRODUCTION 183 2.7.2
FORMATION OF MULTIPLY CHARGED CLUSTERS 185 2.7.3 STABILITY AND
FRAGMENTATION OF MULTIPLY CHARGED CLUSTERS 201 2.7.4 OUTLOOK 216 2.7.5
RECENT DEVELOPMENTS 216 REFERENCES 217 2.8 CHEMISTRY WITH NEUTRAL METAL
CLUSTERS S.J. RILEY (WITH 7 FIGURES) 221 2.8.1 INTRODUCTION - CLUSTERS
AND HETEROGENEOUS CATALYSIS . . 221 2.8.2 EXPERIMENTAL 222 2.8.3
ADSORBATE UPTAKE - THE PATH TO COVERAGE 223 2.8.4 KINETICS - STRONG
CLUSTER SIZE DEPENDENCE AND THE APPROACH TO BULK 225 2.8.5 EQUILIBRIUM -
THE THERMODYNAMICS OF ADSORBATE BINDING 227 2.8.6 SATURATED COMPOSITIONS
- THE NUMBER AND NATURE OF ADSORPTION SITES 229 2.8.7 CHEMICAL PROBES OF
METAL CLUSTER STRUCTURE 231 2.8.8 CHEMISTRY ON CLUSTERS - ADSORBATE
DECOMPOSITION . . . 235 2.8.9 FUTURE PROSPECTS 238 2.8.10 RECENT
DEVELOPMENTS 239 REFERENCES 239 2.9 CHEMISTRY WITH CLUSTER IONS S.L.
ANDERSON (WITH 7 FIGURES) 241 2.9.1 INTRODUCTION 241 2.9.2 EXPERIMENTAL
METHODS 243 2.9.3 COMPARISON OF ION AND NEUTRAL CLUSTER REACTIVITY . . .
247 2.9.4 BORON CLUSTER IONS: A CASE STUDY WITH ION BEAMS . . . 248
2.9.5 CHEMISTRY STUDIES WITH ICR METHODS 254 2.9.6 CHEMICAL
IDENTIFICATION OF ISOMERS 255 2.9.7 FUTURE DIRECTIONS 257 2.9.8 RECENT
DEVELOPMENTS 258 REFERENCES 258 3 EMBEDDED, SUPPORTED, AND COMPRESSED
CLUSTERS 3.1 OPTICAL PROPERTIES OF SILVER CLUSTERS IN DIELECTRIC
MATRICES K.-P. CHARLE AND W. SCHULZE (WITH 3 FIGURES) 263 3.1.1
INTRODUCTION 263 3.1.2 OPTICAL ABSORPTION OF COLLOIDS 263 3.1.3 SIZE
EFFECT AND THE INFLUENCE OF THE MATRIX 266 REFERENCES 271 3.2 AEROSOLS,
LARGE CLUSTERS IN GAS SUSPENSIONS H. BURTSCHER AND H.C. SIEGMANN (WITH
11 FIGURES) 272 3.2.1 INTRODUCTION 272 3.2.2 SOME TOOLS OF AEROSOL
SCIENCE 273 3.2.3 DIFFUSION CHARGING OF PARTICLES 274 3.2.4
PHOTOELECTRIC CHARGING OF PARTICLES 275 3.2.5 THE PHOTOELECTRIC YIELD OF
SMALL METALS PARTICLES .... 277 3.2.6 ADSORPTION OF GAS MOLECULES AT THE
SURFACE OF PARTICLES 281 3.2.7 APPLICATIONS OF PHOTOELECTRON EMISSION
FROM PARTICLES . 284 3.2.8 X-RAY ABSORPTION OF PARTICLES 286 3.2.9
CONCLUSIONS 287 3.2.10 RECENT DEVELOPMENTS 288 REFERENCES 288 3.3 METAL
CLUSTERS IN A LIQUID ENVIRONMENT PHOTOGRAPHIC DEVELOPMENT J. BELLONI, J.
AMBLARD, J.L. MARIGNIER AND M. MOSTAFAVI (WITH 4 FIGURES) 290 3.3.1
INTRODUCTION 290 3.3.2 SYNTHESIS 291 3.3.3 PHYSICAL PROPERTIES 295 3.3.4
CHEMICAL PROPERTIES 298 3.3.5 PHOTOGRAPHIC DEVELOPMENT 306 3.3.6
CONCLUSION 308 3.3.7 RECENT DEVELOPMENTS 309 REFERENCES 309 3.4 LARGER
SEMICONDUCTOR CLUSTERS ( QUANTUM DOTS ) L. BRUS (WITH 4 FIGURES) 312
3.4.1 INTRODUCTION 312 3.4.2 ELEMENTARY THEORY 313 3.4.3 SUMMARY 319
REFERENCES 320 3.5 ELECTROMAGNETIC EXCITATIONS OF LARGE CLUSTERS U.
KREIBIG AND M. QUINTEN (WITH 19 FIGURES) 321 3.5.1 INTRODUCTION 321
3.5.2 EXTINCTION OF RADIATION BY SINGLE PARTICLES 327 3.5.3 DISCUSSION
OF OPTICAL PROPERTIES OF ISOLATED CLUSTERS . . 330 3.5.4 INTRINSIC
OPTICAL CLUSTER SIZE EFFECTS 338 3.5.5 OPTICAL PROPERTIES OF CLUSTER
MATTER 342 3.5.6 APPENDIX: COMPUTER PROGRAM OF THE MIE THEORY .... 348
REFERENCES 358 3.6 SUPPORTED CLUSTERS S.B. DICENZO AND G.K. WERTHEIM
(WITH 10 FIGURES) 361 3.6.1 INTRODUCTION 361 3.6.2 PREPARATION OF
SUPPORTED CLUSTERS 362 3.6.3 CLUSTER GROWTH 364 3.6.4 BAND STRUCTURE OF
CLUSTERS 365 3.6.5 CORE ELECTRON SPECTRA 367 3.6.6 OTHER TYPES OF
MEASUREMENT 376 3.6.7 METAL-INSULATOR TRANSITION 378 3.6.8 PROSPECTS FOR
THE FUTURE 380 3.6.9 CONCLUSION 382 REFERENCES 382 3.7 NANOCRYSTALLINE
MATERIALS R. BIRRINGER AND H. GLEITER (WITH 16 FIGURES) 384 3.7.1
INTRODUCTION 384 3.7.2 BASIC IDEAS 384 3.7.3 PREPARATION AND
CHARACTERIZATION 387 3.7.4 STRUCTURAL STUDIES 390 3.7.5 PROPERTIES 395
3.7.6 MULTIPHASE NANOCRYSTALLINE MATERIALS 401 3.7.7 PROSPECTS 402
REFERENCES 403 SUBJECT INDEX 405 SUBJECT INDEX OF VOLUME 52 409
|
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| indexdate | 2024-12-23T13:37:37Z |
| institution | BVB |
| isbn | 3540569588 0387569588 |
| language | English |
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| physical | XVIII, 412 S. graph. Darst. |
| publishDate | 1994 |
| publishDateSearch | 1994 |
| publishDateSort | 1994 |
| publisher | Springer |
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| series | Springer series in chemical physics |
| series2 | Springer series in chemical physics |
| spellingShingle | Clusters of atoms and molecules Springer series in chemical physics |
| title | Clusters of atoms and molecules |
| title_auth | Clusters of atoms and molecules |
| title_exact_search | Clusters of atoms and molecules |
| title_full | Clusters of atoms and molecules 2 Solvation and chemistry of free clusters, and embedded, supported and compressed clusters : with 15 tables Hellmut Haberland (ed.) |
| title_fullStr | Clusters of atoms and molecules 2 Solvation and chemistry of free clusters, and embedded, supported and compressed clusters : with 15 tables Hellmut Haberland (ed.) |
| title_full_unstemmed | Clusters of atoms and molecules 2 Solvation and chemistry of free clusters, and embedded, supported and compressed clusters : with 15 tables Hellmut Haberland (ed.) |
| title_short | Clusters of atoms and molecules |
| title_sort | clusters of atoms and molecules solvation and chemistry of free clusters and embedded supported and compressed clusters with 15 tables |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=006485767&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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| work_keys_str_mv | AT haberlandhellmut clustersofatomsandmolecules2 |