Principles of defect chemistry of crystalline solids

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1. Verfasser: Gool, W. van (VerfasserIn)
Format: Buch
Sprache:English
Veröffentlicht: New York Acad.Pr. 1966
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adam_text Principles of Defect Chemistry of Crystalline Solids WVANGOOL SCIENTIFIC LABORATORY FORD MOTOR COMPANY ACADEMIC PRESS New York and London 1966 Contents PREFACE V CHAPTER 1 Introduction 1 1 Scope of the Subject 1 1 2 Some Chemical Aspects (Experimental) 3 1 3 Physical Aspects (Theory) 6 1 4 Some Physical Aspects (Properties) 8 General References 11 Problems 12 CHAPTER 2 Introduction to the Thermodynamics of Lattice Defects 2 1 Introduction 13 2 2 Types of Defects 14 2 3 Formulation of Reaction Equations 15 2 4 Laws of Mass Action 19 Appendix Other Symbols Describing Defects 21 References 24 Problems 25 vii viii CONTENTS CHAPTER 3 Thermodynamics of Lattice Defects 3 1 Definition of Thermodynamic Potentials of Lattice Defects 3 2 Concentration Dependence 3 3 Impurities and Associated Centers 3 4 Charged Defects and the Fermi Level References Problems CHAPTER 4 High Temperature Equilibria (Pure Compounds) 4 1 Introduction 4 2 Interaction between Pure MX and Its Vapor (Elementary Treatment) 4 3 Interaction between Pure MX and Its Vapor (Extended Treatment) 4 4 Some Special Defect Situations 4 5 Summary References Problems CHAPTER 5 High Temperature Equilibria (Impure Compounds) 5 1 Introduction 5 2 Gas Phase Equilibria 5 3 General Aspects of the Impure Defective State 5 4 The Impure Defective State 5 5 Solubility of the Impurity and Deviation from Stoichiometry 5 6 Summary References Problems CONTENTS ix CHAPTER 6 High Temperature Equilibria (Considerations about Equilibrium Constants) 6 1 Introduction 81 6 2 Formation of Vacancies and Interstitials (Single Defects) 82 6 3 Schottky Constants 86 164 Other Defect Situations 88 6 5 Bandgap 90 References 91 CHAPTER 7 High Temperature Equilibria (General Aspects) 7 1 Introduction 92 7 2 Calculation of Defect Concentrations 92 7 3 Anomalous Behavior 99 7 4 Representations and Phase Diagrams 101 7 5 Fermi Level 107 7 6 Relation between Solubility of an Impurity and Defect Chemistry 108 7 7 Relation between the Density of Crystals and Defect Chemistry _ 114 7 8 Deviation from Stoichiometry 117 References 118 Problems 118 CHAPTER 8 Defective State after Quenching of High Temperature Equilibria 8 1 Introduction 121 8 2 Some Simplified Situations 121 83A More Complicated Example 127 8 4 Intermediate Temperatures 129 Reference 130 X CONTENTS CHAPTER 9 Some Topics Related to the Defect Chemistry of Binary Compounds 9 1 Introduction 131 9 2 Defect Chemistry of Elements 131 9 3 Defect Chemistry of Ternary Compounds 132 9 4 The Relation between Defect Chemistry and Heterogeneous Catalysis 133 9 5 Physical Properties and Defect Chemistry 135 References 136 CHAPTER 10 Trends in the Development of Defect Chemistry 10 1 Introduction 138 10 2 Investigation of Defect Chemistry of New Compounds 139 10 3 Investigations Related to the Selection of Materials 141 Reference 144 SUBJECT INDEX 145
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spelling Gool, W. van Verfasser aut
Principles of defect chemistry of crystalline solids
New York Acad.Pr. 1966
X,148 S.m.Abb.u.Tab.
txt rdacontent
n rdamedia
nc rdacarrier
Cristallochimie ram
Cristaux - Défauts ram
Evenwichten gtt
Kristalstructuur gtt
Roosterfouten gtt
Solides ram
Thermodynamica gtt
Vaste stoffen gtt
Crystals Defects
Solids
Kristalliner Festkörper (DE-588)4165761-5 gnd rswk-swf
Gitterbaufehler (DE-588)4125030-8 gnd rswk-swf
Gitterbaufehler (DE-588)4125030-8 s
Kristalliner Festkörper (DE-588)4165761-5 s
DE-604
HEBIS Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=004580991&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis
spellingShingle Gool, W. van
Principles of defect chemistry of crystalline solids
Cristallochimie ram
Cristaux - Défauts ram
Evenwichten gtt
Kristalstructuur gtt
Roosterfouten gtt
Solides ram
Thermodynamica gtt
Vaste stoffen gtt
Crystals Defects
Solids
Kristalliner Festkörper (DE-588)4165761-5 gnd
Gitterbaufehler (DE-588)4125030-8 gnd
subject_GND (DE-588)4165761-5
(DE-588)4125030-8
title Principles of defect chemistry of crystalline solids
title_auth Principles of defect chemistry of crystalline solids
title_exact_search Principles of defect chemistry of crystalline solids
title_full Principles of defect chemistry of crystalline solids
title_fullStr Principles of defect chemistry of crystalline solids
title_full_unstemmed Principles of defect chemistry of crystalline solids
title_short Principles of defect chemistry of crystalline solids
title_sort principles of defect chemistry of crystalline solids
topic Cristallochimie ram
Cristaux - Défauts ram
Evenwichten gtt
Kristalstructuur gtt
Roosterfouten gtt
Solides ram
Thermodynamica gtt
Vaste stoffen gtt
Crystals Defects
Solids
Kristalliner Festkörper (DE-588)4165761-5 gnd
Gitterbaufehler (DE-588)4125030-8 gnd
topic_facet Cristallochimie
Cristaux - Défauts
Evenwichten
Kristalstructuur
Roosterfouten
Solides
Thermodynamica
Vaste stoffen
Crystals Defects
Solids
Kristalliner Festkörper
Gitterbaufehler
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