Aldehydes, -photometric analysis 5 Formaldehyde precursors

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Hauptverfasser: Sawicki, Eugene (VerfasserIn), Sawicki, Carole R. (VerfasserIn)
Format: Buch
Sprache:English
Veröffentlicht: London u.a. Acad. Pr. 1978
Schriftenreihe:The analysis of organic materials 9
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adam_text Titel: Bd. 5. Aldehydes, photometric analysis. Formaldehyde precursors Autor: Sawicki, Eugene Jahr: 1978 CONTENTS Preface v 62. FORMALDEHYDE PRECURSORS 1 I. Introduction 1 II. R 2 C = CH 2 Compounds 21 A. Introduction 21 B. 1-Alkenes 23 1. Photochemical smog 23 2. Oxidative MBTH test 28 3. Spectrophotofluorimetric assay 29 C. Polar R 2 C=CH 2 compounds 30 1. Colorimetric methods 30 2. Fluorimetric methods 31 D. Miscellaneous hydrocarbons 32 III. Alcohols 32 A. Miscellaneous alcohols 32 B. 2-Nitro-l-alkanols 33 IV. Aldosterone 47 V. Amines 47 A. 1,2-Aminoalkanols 48 B. Ethylenediamines 48 C. Hexosamines 48 D. Glycine 48 E. Aminomethyl ketones 50 F. Aminopyrinë 50 VI. Azomethane Derivatives 51 A. Azoalkanes 53 B. Azoxymethanes 53 C. Cycasin 54 VII. Bilirubin 55 VIII. a-Chloromethyl Ethers 56 IX. Lignin Products 58 X. Cellulose and Derivatives 58 A. Carboxymethylcellulose 58 B. Cellulose 59 XI. Chloroacetates 60 XII. 3-(4-Chlorophenyl)-l-methylurea 60 XIII. Cholesterol 61 XIV. 2-Deoxyribose 61 XV. 1,1-Dichloroethylene 62 vii CONTENTS viii XVI. Dimethylnitrosamine 63 A. Introduction 63 B. Source and environmental concentrations 63 C. Carcinogenic activity 67 D. Formaldehyde formation and biological activity 69 1. Introduction 69 2. Méthylation of DNA 70 3. Toxicity 70 4. Mutagenesis 73 5. Mutagenesis and carcinogenesis 74 E. Human health effects 76 F. Enzymatic reactions and formaldehyde formation 77 G. Other nitrosamine reactions 78 XVII. Epoxides 79 XVIII. Ethanolamine and Ethylenimine 82 XIX. Ethylene 83 XX. Ethylenediamines, N-Phenothiazinyl 83 XXI. Ethylene Glycol 84 XXII. Eugenol 86 XXIII. Formals 86 XXIV. Formates 87 XXV. Formyl and Isonitrile Groups 89 XXVI. Glucaric Acid 89 XXVII. Glucose and Derivatives 90 A. Glucose 90 B. Glucose phenylosazone 90 XXVIII. Glycerol Derivatives 91 A. Glycerides 91 B. a-Glycerophosphates 93 C. Glycerophosphatides 93 XXIX. Glycidyl Stearate 94 XXX. Glycine 94 XXXI. Glycolic Acids 99 A. Introduction 99 B. Glycolic acid 99 1. 2.7-Dihydroxynaphthalene 99 2. Chromotropic acid 100 3. ß-Naphthol 10! C. Phenoxyacetic acids 101 D. Alkoxyacetic acids 102 XXXII. 1.2-Glycols IO3 A. Introduction 03 B. Atmospheric a-glycols IO7 C. Miscellaneous reagents 107 D. Chromatographic localization 108 E. Sialoglycoproteins HI XXXIII. Glycoproteins and Polysaccharides HI XXXIV. Glyoxylic Acids H3 XXXV. Heptitols. Hexitols. Tetritols and Other Sugar Alcohols H4 XXXVI. Hexahydro-1.3.5-trinitro-s-triazíne H8 CONTENTS IX XXXVII. Hexamethylenetetramine 119 XXXVIII. Hexamethylmelamine 120 XXXIX. HFSH and HCG 121 XL. Hydrazines, Triazenes and Tetrazenes 121 A. Introduction 121 B. Methylhydrazines 121 C. Alar 124 D. Triazenes 124 E. Hydrazones of formaldehyde 126 XLI. Hydrocarbons, Unsaturated 128 XLII. p-Hydroxybenzyl Alcohols 129 XLIII. Hydroxylysine 131 XLIV. Hydroxymethylketones or Acetols 131 XLV. 4-Hydroxystyrenes 132 XLVI. Lactose and Maltose 134 XLVII. Mannitol 135 XLVIII. Methanol and Methyl Esters 136 A. Methanol—chemical oxidation 136 B. Methanol—enzymatic oxidation 138 C. Methyl esters 138 D. Indirect reactions 139 XLIX. Methionine Sulphoxide 140 L. Methoxone 141 LI. Methoxyflurane 142 LII. Methoxymethyl Methanesulphonate 142 LIII. N-Methyl Compounds 142 A. Introduction 142 B. Aliphatic amines 155 C. Aromatic amines 163 D. Heterocyclic amines 166 E. Azo dye amines 168 F. Heterocyclic 172 G. Nitrosamines 179 H. Hydroxylamines 186 LIV. O-Methyl Compounds 187 LV. S-Methyl Compounds 192 LVI. Methylene, Hydrolyzable 193 A. Introduction 193 1. Compound types 193 2. Formaldehyde standards 193 3. Physiological activity 195 4. Atmospheric formaldehyde 196 5. Methods 198 6. Formation of formaldehyde precursors 204 B. —O—CH 2 —O— compounds 212 C. —O—CH 2 —compounds 217 D. —O—CH 2 —S— compounds 222 / E. —CH 2 —compounds 223 A* x CONTENTS F. ^N—CH 2 —S— compounds G. -S-CH 2 H S— compounds —O—CH 2 —(Jľ— compounds I. Methylene halides J. Formaldehyde and the genotoxic methylene group LVII. 5-Methyltetrahydrofolic Acid LVIII. Nitrites, Alkyl LIX. Olefins LX. Oxalic acid LXI. Oxetanes LXII. Ozonides LXIII. Pilocarpine LXIV. Polymethylene Oxides LXV. Polyols LXVI. P-Propiolactone LXVII. Sophorose and Sophoritol LXVIII. Thiol-bound Formaldehyde LXIX. Triglycerides A. Introduction B. Chromotropic acid C. MBTH D. 2,4-Pentanedione 1. Colorimetric manual 2. Colorimetric automated 3. Fluorimetrie manual 4. Fluorimetrie semiautomated 5. Fluorimetrie automated LXX. Uric Acid LXXI. Vinyl Chloride A. Introduction Atmospheric and metabolic reactions 1. Atmospheric oxidation 2. Metabolism Physiological activity 1. Toxicity 2. Clastogenicity 3. Mutagenicity 4. Carcinogenicity 5. Teratogenicity D. Analysis Vinyl Compounds A. Vinyl butyl ether and acrolein B. 2-Vinylpyridine and 5-vinyl-2-picoline Xylonic, Cellobionic and Gluconic Acids Basic Precursor Structures Reagents and Reactions in Formaldehyde Formation Chromogen-Forming Reagents Fluorogen-Forming Reagents B. C. LXXII. LXXIII. LXXIV. LXXV. LXXV1 LXXV11 227 228 230 231 232 234 242 243 244 246 247 248 249 251 251 253 254 255 255 256 260 260 260 264 266 267 267 268 269 269 269 269 271 273 273 273 273 273 274 274 274 275 275 275 276 277 283 283 CONTENTS XI LXXVIII. Application 283 References 284 Subject Index 323
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publishDate 1978
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series The analysis of organic materials
series2 The analysis of organic materials
The analysis of organic materials.
spelling Sawicki, Eugene Verfasser aut
Aldehydes, -photometric analysis 5 Formaldehyde precursors Eugene Sawicki ; Carole R. Sawicki*
London u.a. Acad. Pr. 1978
XI, 408 S. graph. Darst.
txt rdacontent
n rdamedia
nc rdacarrier
The analysis of organic materials 9
The analysis of organic materials. ...
Sawicki, Carole R. Verfasser aut
(DE-604)BV002383749 5
The analysis of organic materials 9 (DE-604)BV019940446 9
HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=004328461&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis
spellingShingle Sawicki, Eugene
Sawicki, Carole R.
Aldehydes, -photometric analysis
The analysis of organic materials
title Aldehydes, -photometric analysis
title_auth Aldehydes, -photometric analysis
title_exact_search Aldehydes, -photometric analysis
title_full Aldehydes, -photometric analysis 5 Formaldehyde precursors Eugene Sawicki ; Carole R. Sawicki*
title_fullStr Aldehydes, -photometric analysis 5 Formaldehyde precursors Eugene Sawicki ; Carole R. Sawicki*
title_full_unstemmed Aldehydes, -photometric analysis 5 Formaldehyde precursors Eugene Sawicki ; Carole R. Sawicki*
title_short Aldehydes, -photometric analysis
title_sort aldehydes photometric analysis formaldehyde precursors
url http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=004328461&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA
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