Modern aspects of solid state chemistry

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Veröffentlicht: New York u.a. Plenum Press [1970]
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adam_text Modern Aspects of Solid State Chemistry Edited by CNR Rao • Professor of Chemistry*- Indian Institute of Technology Kanpur, India 5? PLENUM PRESS • NEW YORK-LONDON • 1970 CONTENTS Page No I 1 LATTICE DYNAMICS by J» Mahanty 1 Introduction Theory of Small Oscillations Effect of Lattice Symmetry Density of Vibrational States: Vibrational Thermodynamic Properties of Crystals X-ray and Neutron Scattering 2 COHESIVE ENERGIES OF IONIC SOLIDS by CNR Rac 17 Born-Haber Cycle Born Treatment of Ionic Solids Some Related Aspects t 3 DEFECT CHEMISTRY AND NON-STOICHIOK ETRIC COMPOUNDS by J S Anderson 29 Point Defect Equilibria in Crystals The Systematics of Non-Stoichiometric Compounds Grossly Non-Stoichiometric Compounds Ferrous Oxides A Case History Strong Defect Orderingi Intermediate Superstructure Phases Elimination of Defectsj Crystallographic Shear Imperfections of Ordered Structures (Lattice Imaging) Conclusions and Outstanding Problems 4 THEORY OF POINT DEFECTS IN IONIC CRYSTALS by CNR Rao and S Ramdas 107 Introduction to Point Defects in Ionic Crjstals Experimental Studies of Point Defects Theoretical Calculations of the Formation Energies of Schottky Defects Defect Interaction Energies Migration Energies Interstitial Defects Concluding Remarks ix CONTENTS 5 DIELECTRIC PROPERTIES bv E C Subbarao 129 Definitions and Units Mechanisms of Polarization Alternating Current Phenomena Ferroelectries 6 MAGNETISM by N Menyuk 159 Non-Interacting Atoms Magnetic Interactions Long-Range Order Spiral Configurations Magnetic Atoms in a Crystal Superexchange Interactions Collective d-Electron Model 7 NEUTRON DIFFRACTION AND SOLID STATE PROPERTIES by D«C Khan 219 Introduction Thermal Neutrons Elastic Scattering Inelastic Scattering Conclusions 8 MAGNETIC RESONANCE by P T« Narasimhan 231 Introduc tion Nuclear Moments and Nuclear Magnetic Resonance Spin-Lattice Relaxation Bloch Equations and Transverse Relaxation Experimental Arrangements NMR in Non-metallic Solids w Quadrupolar Splittings in NMR NMR in Metals Chemical Shift and Spin Coupling in Solids Pure Quadrupole Resonance in Solids Electron Paramagnetic Resonance Concluding Remarks 9 NUCLEAR MAGNETIC RESONANCE IN SUPERCONDUCTORS AND DILUTE ALLOYS by R» Vl jayaraghavan 261 NMR in Superconductors NMR in Dilute Alloys CONTENTS xi 10 MAGNETOSTRICTION IN MATERIALS by R K Ray 273 Introduction Behaviour of Common Materials Conclusions 11 MOSSBAUER EFFECT AND DYNAMICS OF ATOMIC MOTIOF IN SOLIDS by V G Bhide 287 •a Resonance Fluorescence Mossbauer s Experiment Resonance Absorption of Gamma Rays and Dynamics of Atomic Motion Experimental Results Concluding Remarks 12 POSITRON ANNIHILATION IN SOLIDS bv R M Singri 329 Introduction Methods and Results 13 ELEMENTS OF ORDER-DISORDER THEORY AND DIVERSE APPLICATIONS by J M Honig 343 Statement of the Problem The Zero Order Approximation (Langmuir Isotherm) The Fermi-Dirac Distribution Function Decomposition of the Lattice into Subfigires The Fowler-Guggenheim Adsorption Isothern Thermodynamic Properties of Binary Mixtures in the Bragg-Williams Approximation 14 DIFFUSION IN SOLIDS by V Ramekrishna 359 The Diffusion Coefficient Intrinsic Diffusion Coefficients Self-Diffusion Coefficients Experimental Procedures 1 5 IONIC CONDUCTIVITY by C Ramasastry YVGS Murti and BSVSR Acharyulu 377 Conduction Mechanisms in Ionic Crystals Anisotropy of Conduction in Ionic Crystals xii CONTENTS 16 INORGANIC GLASSES by D Chakravorty 391 Constitution of Glass Glass Formation Inorganic Glass Forming Systems Transport Properties of Glasses 17 ^ ELECTRICAL PROPERTIES OF SOLID CATALYSTS by MVC Sastri,, V Srinivasan and B» Vis-w ana than 425 Historical Introduction Classification of Solid Catalysts based on Electronic Properties Inverse Mixed Catalysts Conclusions 18 DISLOCATIONS AND SOLID STATE REACTIONS by A S Paiasnls 447 Dislocations, Their Structure and Properties The Role of Dislocations in Chemical Reactior s 19 SOLID STATE REACTIONS by S R Yoganarasimhan 465 Role of Defects in the Reactivity of Solids Solid-Gas Reactions: Oxidation of Metals Solid-Solid Reactions Thermal Decomposition of Solids 20 BAND AND TRANSPORT THEORIES IN SOLIDS by J M Honjg 497 Introduction to Band Structure Concepts (P article-in-the-Box) Kronig-Penney Model v Bloch Functions for the Circular Chain Band Structure for a Circular Chain in the Tight Binding Approximation Pauli Exclusion Principle and Fermi-Dirac Statistics Heat Capacity of a Metal Classification of Materials Elementary Discussion of Various Transport Phenomena Fermi Levels and Conductivity in Intrinsic and Extrinsic Semiconductors Transport Effects in Materials Characterized by Hopping* Electrons Brief Survey of Experimental Results CONTENTS 21 SPECTROSCOPY OF METALS AND SEMICONDUCTORS by R Sharan Introduction Macroscopic Theory and Experimental Methods Microscopic Theory of Optical Properties Optical Properties of Metals Optical Properties of Semiconductors Conclusions a 22 PHASE TRANSFORMATIONS IN SOLIDS, by CNR Rao Introduction Thermodynamic Considerations Structural Changes in Transformations Kinetics of Transformations Order-Disorder Transitions Martensite Transformations Ferroelectric Transformations Magnetic Transitions Semiconductor-Metal Transitions High Pressure Transformations Born Treatment of Phase Transformations in Alkali Halides Comments on Experimental Techniques «
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spellingShingle Modern aspects of solid state chemistry
Chimie de l'état solide ram
Chimie physique et théorique - Congrès
Solides - Congrès
Solid state chemistry Congresses
Festkörperchemie (DE-588)4129288-1 gnd
Festkörperphysik (DE-588)4016921-2 gnd
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title Modern aspects of solid state chemistry
title_auth Modern aspects of solid state chemistry
title_exact_search Modern aspects of solid state chemistry
title_full Modern aspects of solid state chemistry edited by C. N. R. Rao, Professor of chemistry, Indian Institute of Technology, Kanpur, India
title_fullStr Modern aspects of solid state chemistry edited by C. N. R. Rao, Professor of chemistry, Indian Institute of Technology, Kanpur, India
title_full_unstemmed Modern aspects of solid state chemistry edited by C. N. R. Rao, Professor of chemistry, Indian Institute of Technology, Kanpur, India
title_short Modern aspects of solid state chemistry
title_sort modern aspects of solid state chemistry
topic Chimie de l'état solide ram
Chimie physique et théorique - Congrès
Solides - Congrès
Solid state chemistry Congresses
Festkörperchemie (DE-588)4129288-1 gnd
Festkörperphysik (DE-588)4016921-2 gnd
topic_facet Chimie de l'état solide
Chimie physique et théorique - Congrès
Solides - Congrès
Solid state chemistry Congresses
Festkörperchemie
Festkörperphysik
Konferenzschrift
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