Biosynthesis of tetrapyrroles
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| Format: | Buch |
|---|---|
| Sprache: | English |
| Veröffentlicht: |
Amsterdam [u.a.]
Elsevier
1991
|
| Schriftenreihe: | New comprehensive biochemistry
19 |
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| Online-Zugang: | Inhaltsverzeichnis |
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| 245 | 1 | 0 | |a Biosynthesis of tetrapyrroles |c ed. P. M. Jordan |
| 264 | 1 | |a Amsterdam [u.a.] |b Elsevier |c 1991 | |
| 300 | |a XII, 309 S. |b graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 490 | 1 | |a New comprehensive biochemistry |v 19 | |
| 650 | 4 | |a Pyrroles |x metabolism | |
| 650 | 4 | |a Tetrapyrroles |x Synthesis | |
| 650 | 0 | 7 | |a Pflanzen |0 (DE-588)4045539-7 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Stoffwechsel |0 (DE-588)4057699-1 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Tetrapyrrole |0 (DE-588)4140190-6 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Chemische Synthese |0 (DE-588)4133806-6 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Biosynthese |0 (DE-588)4006902-3 |2 gnd |9 rswk-swf |
| 655 | 7 | |0 (DE-588)4143413-4 |a Aufsatzsammlung |2 gnd-content | |
| 689 | 0 | 0 | |a Tetrapyrrole |0 (DE-588)4140190-6 |D s |
| 689 | 0 | 1 | |a Biosynthese |0 (DE-588)4006902-3 |D s |
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| 689 | 1 | 1 | |a Stoffwechsel |0 (DE-588)4057699-1 |D s |
| 689 | 1 | 2 | |a Tetrapyrrole |0 (DE-588)4140190-6 |D s |
| 689 | 1 | |5 DE-604 | |
| 689 | 2 | 0 | |a Tetrapyrrole |0 (DE-588)4140190-6 |D s |
| 689 | 2 | 1 | |a Chemische Synthese |0 (DE-588)4133806-6 |D s |
| 689 | 2 | |5 DE-604 | |
| 700 | 1 | |a Jordan, Peter M. |e Sonstige |4 oth | |
| 830 | 0 | |a New comprehensive biochemistry |v 19 |w (DE-604)BV000003914 |9 19 | |
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Datensatz im Suchindex
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| adam_text | IMAGE 1
VLL
CONTENTS
FOREWORD V
CHAPTER 1 THE BIOSYNTHESIS OF 5-AMINOLAEVULNIC ACID AND ITS
TRANSFORMATION INTO UROPORPHY- RINOGEN III P.M. JORDAN (LONDON, UK) 1
1. INTRODUCTION 1
2. EARLY ISOTOPIC STUDIES ON THE ORIGIN OF THE TETRAPYRROLE RING 2
3. THE BIOSYNTHESIS OF 5-AMINOLAEVULINIC ACID FROM GLYCINE 4
3.1. OCCURRENCE AND PROPERTIES OF 5-AMINOLAEVULINIC ACID SYNTHASE 4
3.2. REGULATION OF 5-AMINOLAEVULINIC ACID SYNTHASE IN BACTERIA 5
3.3. REGULATION OF 5-AMINOLAEVULINIC ACID SYNTHASE IN EUKARYOTES 6
3.4. SUBSTRATE SPECIFICITY AND KINETICS 9
3.5. MECHANISM OF 5-AMINOLAEVULINIC ACID SYNTHASE 11
3.6. STRUCTURE OF THE ENZYME AND MOLECULAR BIOLOGY 14
4 THE BIOSYNTHESIS OF 5-AMINOLAEVULINIC ACID FROM GLUTAMATE 15
4.1. DISCOVERY OF THE C-5 PATHWAY 15
4.2. THE ENZYMES OF THE C-5 PATHWAY 16
5. THE BIOSYNTHESIS OF PORPHOBILINOGCN 19
5.1. INTRODUCTION 19
5.2. GENERAL PROPERTIES OF 5-AMINOLAEVULINIC ACID DEHYDRATASES 20
5.3. IMPORTANCE OF SULFHYDRYL GROUPS 21
5.4. REQUIREMENT FOR METALS 22
5.5. INHIBITION BY LEAD 23
5.6. NATURE OF THE ACTIVE SITE GROUPS 24
5.7. ORDER OF BINDING THE TWO SUBSTRATES AND THE ENZYME MECHANISM 26
5.8. CATALYTIC GROUPS AND THE NATURE OF THE ACTIVE SITE 28
6. THE BIOSYNTHESIS OF UROPORPHYRINOGEN III 30
6.1. INTRODUCTION 30
6.2. PROPERTIES OF PORPHOBILINOGEN AND UROPORPHYRINOGENS 32
6.3. PORPHOBILINOGEN DEAMINASE 33
6.4. UROPORPHYRINOGEN III SYNTHASE (COSYNTHASE) 34
6.5. EARLY INVESTIGATIONS ON THE MECHANISM OF UROPORPHYRINOGEN
BIOSYNTHESIS 34 6.6. EXPERIMENTS WITH AMINOMETHYLDIPYRROMETHANES,
AMINOMETHYLTRIPYRRANES AND AMINO- METHYLBILANES 35
6.7. THE DISCOVERY OF PREUROPORPHYRINOGEN, THE SUBSTRATE FOR
UROPORPHYRINOGEN III SYNTHASE 38 6.8. ORDER OF ASSEMBLY OF THE FOUR
PYRROLE RINGS OF THE TETRAPYRROLE 41
6.9. ENZYME INTERMEDIATE COMPLEXES BETWEEN THE DEAMINASE AND
PORPHOBILINOGEN 42 6.10. PRELIMINARY STUDIES ON THE NATURE OF THE
ENZYMIC GROUP INVOLVED IN SUBSTRATE COVALCNT BINDING 43
6.11. DISCOVERY OF A COFACTOR IN ALL PORPHOBILINOGEN DEAMINASES -THE
DIPYRROMETHANE COFACTOR 43 6.12. FURTHER EVIDENCE FOR THE ROLE OF THE
DIPYRROMETHANE COFACTOR FROM EXPERIMENTS WITH THE CHAIN TERMINATION
SUICIDE INHIBITOR A-BROMOPORPHOBILINOGEN 46
6.13. ATTACHMENT SITE AND MECHANISM OF ASSEMBLY OF THE DIPYRROMETHANE
COFACTOR 47
IMAGE 2
VLLL
6.14. MECHANISM OF ACTION OF PORPHOBILINOGEN DEAMINASE 49
6.15. REACTION OF PORPHOBILINOGEN DEAMINASE WITH 1-AMINOMETHYLBILANES 53
6.16. STERIC COURSE OF THE PORPHOBILINOGEN DEAMINASE AND
UROPORPHYRINOGEN III SYNTHASE REACTIONS 53
6.17. USE OF SYNTHETIC ANALOGUES TO INVESTIGATE THE UROPORPHYRINOGEN III
SYNTHASE REACTION . 55 6.18. MECHANISM OF ACTION OF UROPORPHYRINOGEN III
SYNTHASE 56
6.19. MOLECULAR BIOLOGY AND PROTEIN STRUCTURE OF PORPHOBILINOGEN
DEAMINASE 57
6.20. MOLECULAR BIOLOGY OF UROPORPHYRINOGEN SYNTHASE 58
ACKNOWLEDGEMENTS 59
REFERENCES 59
CHAPTER 2
MECHANISM AND STEROCHEMISTRY OF THE ENZYMES INVOLVED IN THE CONVERSION
OF URO- PORPHYRINOGEN III INTO HAEM M. AKHTAR (SOUTHAMPTON, HANTS., UK)
67
1. INTRODUCTION 67
2. UROPORPHYRINOGEN DECARBOXYLASE (UROPORPHYRINOGEN CARBOXYLYASE) 67
2.1. INTRODUCTION 67
2.2. INTERMEDIATES IN THE DECARBOXYLATION 68
2.3. THE INTERACTION BETWEEN THE DECARBOXYLASE AND THE SUBSTRATES 70
2.4. ISOLATION AND STRUCTURAL STUDIES ON UROPORPHYRINOGEN DECARBOXYLASE
72
2.5. THE NUMBER OF ACTIVE SITES 73
2.6. MECHANISTIC AND STEREOCHEMICAL STUDIES 74
2.7. THE MECHANISM 75
3. COPROPORPHYRINOGEN III OXIDASE 77
3.1. INTRODUCTION 77
3.2. ISOLATION OF, AND STRUCTURAL STUDIES ON, COPROPORPHYRINOGEN OXIDASE
78
3.3. THE ORDER IN WHICH THE PROPIONIC SIDE-CHAINS ARE DECARBOXYLATED 79
3.4. STEREOCHEMICAL AND MECHANISTIC STUDIES ON COPROPORPHYRINOGEN III
OXIDASE 79 3.5. THE MECHANISM OF THE AEROBIC COPROPORPHYRINOGEN III
OXIDASE CATALYSED REACTION . . .. 81 3.6. CONCERNING THE STEREOCHEMISTRY
AND MECHANISM OF THE ANAEROBIC COPROPORPHYRINOGEN III OXIDASE 83
4. PROTOPORPHYRINOGEN IX OXIDASE 84
4.1. INTRODUCTION 84
4.2. ISOLATION OF, AND STRUCTURAL STUDIES ON, PROTOPORPHYRINOGEN IX
OXIDASE 85
4.3. STEREOCHEMICAL AND MECHANISTIC STUDIES ON PROTOPORPHYRINOGEN IX
OXIDASE 86 4.4. THE MECHANISM OF THE PROTOPORPHYRINOGEN IX OXIDASE
CATALYSED REACTION 90
5. FERROCHELATASE 92
5.1. OCCURRENCE AND ISOLATION OF FERROCHELATASES 92
5.2. PROPERTIES OF FERROCHELATASES 92
5.3. SUBSTRATE SPECIFICITY 93
5.4. METAL REQUIREMENTS 94
5.5. INHIBITION OF FERROCHELATASES BY N-ALKYLPORPHYRINS 94
5.6. KINETICS, ACTIVE SITE AND MECHANISM OF ACTION OF FERROCHELATASES 95
ACKNOWLEDGEMENTS 96
REFERENCES 96
IMAGE 3
IX
CHAPTER 3
THE BIOSYNTHESIS OF VITAMIN B, 2 A.I. SCOTT AND P.J. SANTANDER (COLLEGE
STATION, TX, USA) 101
1. INTRODUCTION 101
2. THE CARBON BALANCE 104
3. STEREOCHEMISTRY OF METHYL GROUP INSERTION IN CORRINOID BIOSYNTHESIS
104
4. CONCERNING THE FATE OF THE METHYL GROUP PROTONS 106
5. URO GEN III IS A PRECURSOR OF VITAMIN B 12 106
6. CHARACTERIZATION AND INTERMEDIACY OF THE ISOBACTERIOCHLORINS OF P.
SHERMANII 107
7. THE METHYLATION SEQUENCE: PULSE EXPERIMENTS 112
8. TIMING OF THE DECARBOXYLATION STEP 116
9. THE PROTEIN BALANCE OF VITAMIN B 12 BIOSYNTHESIS 120
10. FACTORS S,-S 4, ISOMERIC, TETRAMETHYLATED CORPHINOIDS DERIVED FROM
URO GEN I 123
11. THE METHYL TRANSFERASES 128
12. BIOSYNTHESIS OF THE NEUCLEOTIDE LOOP AND COENZYME B, 2 132
13. EVOLUTIONARY ASPECTS OF B, 2 BIOSYNTHESIS 133
13.1. THE C 5 PATHWAY 133
13.2. CHEMICAL METHODS 134
13.3. WHY TYPE III? 134
REFERENCES 135
CHAPTER 4
BIOCHEMISTRY OF COENZYME F430, A NICKEL PORPHINOID INVOLVED IN
METHANOGENESIS H.C. FRIEDMANN, A. KLEIN AND R.K. THAUER (MARBURG, FRG
AND CHICAGO, IL, USA) 139
1. INTRODUCTION 139
2. STRUCTURAL RELATIONS TO OTHER TETRAPYRROLES 140
3. BIOSYNTHESIS FROM GLUTAMATE VIA UROPORPHYRINOGEN III AND
DIHYDROSIROHYDROCHLORIN 143 4. PROPERTIES OF FREE COENZYME F430
INCLUDING ITS REDOX BEHAVIOUR 144
5. FUNCTION OF COENZYME F430 AS PROSTHETIC GROUP OF METHYL COENZYME M
REDUCTASE IN METHANO- GENESIS 147
6. COMPARATIVE ANALYSIS OF GENES ENCODING METHYL COENZYME M REDUCTASE
149
ACKNOWLEDGEMENTS 152
REFERENCES 152
CHAPTER 5
BIOCHEMISTRY AND REGULATION OF PHOTOSYNTHETIC PIGMENT FORMATION IN
PLANTS AND ALGAE S.I. BEALE AND J.D. WEINSTEIN (PROVIDENCE, RI AND
CLEMSON, SC, USA) . . 155
1. THE VARIETY AND FUNCTIONS OF PLANT AND ALGAL TETRAPYRROLES 155
1.1. INTRODUCTION TO THE BRANCHED TETRAPYRROLE BIOSYNTHETIC PATHWAY 155
1.2. CHLOROPHYLLS AND BACTERIOCHLOROPHYLLS 155
IMAGE 4
1.3. HEMES
1.4. PHYCOBILINS AND THE PHYTOCHROME CHROMOPHORE 1.5. OTHER
TETRAPYRROLES FOUND IN PHOTOTROPHIC ORGANISMS . THE BIOSYNTHETIC ROUTE
2.1. ALA FORMATION
IMAGE 5
XI
3. REGULATION 202
3.1. ENVIRONMENTAL AND PHYSIOLOGICAL MODULATION OF PIGMENT CONTENT 202
3.1.1. PHYSIOLOGY OF GREENING IN PLANTS AND ALGAE 202
3.1.2. EFFECTS OF FE CHELATORS AND ANAEROBIOSIS ON GREENING IN INTACT
TISSUE AND CHLOROPLASTS 205
3.1.3. CHLOROPHYLL AND HEME TURNOVER 206
3.1.4. NONPLASTID HEME SYNTHESIS AND TURNOVER 208
3.2. REGULATION OF BIOSYNTHETIC STEPS 209
3.2.1. SUBCELLULAR COMPARTMENTATION OF TETRAPYRROLE BIOSYNTHESIS 209
3.2.2. REGULATIONS OF METABOLIC ACTIVITY 210
3.2.2.1. EFFECTOR-MEDIATED REGULATION OF ALA-FORMING ACTIVITY 211
3.2.2.2. EXPRESSION AND TURNOVER OF ALA-FORMING ENZYMES 213
3.2.2.3. REGULATION OF ALA DEHYDRATASE ACTIVITY 215
3.2.2.4. BRANCH POINT REGULATION 215
3.2.2.5. REGULATION OF PROTOCHLOROPHYLLIDE PHOTOREDUCTION 216
3.3. REGULATION OF PHYCOBITIN CONTENT BY LIGHT AND NUTRITIONAL STATUS
218
3.3.1. LIGHT EFFECTS 218
3.3.2. RESPONSES TO NITROGEN STATUS 221
ACKNOWLEDGMENTS 222
REFERENCES 223
CHAPTER 6
THE STRUCTURE AND BIOSYNTHESIS OF BACTERIOCHLOROPHYLLS KEVIN M. SMITH
(DAVIS, CA, USA) 237
1. NOMENCLATURE 237
2. OCCURRENCE AND STRUCTURES 238
2.1. BACTERIOCHLOROPHYLLS A, B 238
2.2. BACTERIOCHLOROPHYLLS C, D, E,F 239
2.3. BACTERIOCHLOROPHYLL G 239
3. BIOSYNTHESIS 240
3.1. BACTERIOCHLOROPHYLLS A, B, G 240
3.2. BACTERIOCHLOROPHYLLS E, D, E,F 246
ACKNOWLEDGMENT 253
REFERENCES 253
CHAPTER 7
THE GENES OF TETRAPYRROLE BIOSYNTHESIS P.M. JORDAN AND B.I.A. MGBEJE
(LONDON, UK) 257
1. GENES OF HAEM BIOSYNTHESIS 257
1.1. MAPPING OF HAEM BIOSYNTHESIS GENES 257
1.1. THE HEM GENES IN ESCHERICHIA COLI 258
1.2. THE HEM GENES IN SALMONELLA TYPHIMURIUM 259
1.3. THE HEM GENES IN STAPHYLOCOCCUS AUREUS 260
1.4. THE HEM GENES IN BACILLUS SUBTILIS 260
1.5. THE HEM GENES IN RHODOBACTER SPHAEROIDES 261
1.6. THE HEM GENES IN YEAST 261
IMAGE 6
XLL
1.1.7. THE HEM GENES IN MAMMALIAN SPECIES 262
1.2. MOLECULAR BIOLOGY OF HAEM BIOSYNTHESIS GENES 263
1.2.1. 5-AMINOLAEVULINIC ACID SYNTHESIS 263
1.2.1.1. 5-AMINOLAEVULINIC ACID SYNTHASE (THE GLYCINE PATHWAY) 263
1.2.1.2. THE GENES OF THE GLUTAMATE (C 5) PATHWAY 266
1.2.2. 5-AMINOLAEVULINIC ACID DEHYDRATASE 268
1.2.3. PORPHOBILINOGEN DEAMINASE 269
1.2.4. UROPORPHYRINOGEN III SYNTHASE (COSYNTHASE) 272
1.2.5. UROPORPHYRINOGEN DECARBOXYLASE 273
1.2.6. COPROPORPHYRINOGEN OXIDASE 274
1.2.7. PROTOPORPHYRINOGEN OXIDASE 275
1.2.8. FERROCHELATASE 275
2. GENES OF COBALAMIN (VITAMIN B L2) BIOSYNTHESIS 276
3. GENES OF BACTERIOCHLOROPHYLL AND CHLOROPHYLL BIOSYNTHESIS 282
3.1. BACTERIOCHLOROPHYLL BIOSYNTHESIS GENES 282
3.2. CHLOROPHYLL BIOSYNTHESIS GENES 287
REFERENCES 288
SUBJECT INDEX 295
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| genre | (DE-588)4143413-4 Aufsatzsammlung gnd-content |
| genre_facet | Aufsatzsammlung |
| id | DE-604.BV004710270 |
| illustrated | Illustrated |
| indexdate | 2024-12-23T11:22:14Z |
| institution | BVB |
| isbn | 0444892850 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-002895174 |
| oclc_num | 24430050 |
| open_access_boolean | |
| owner | DE-12 DE-19 DE-BY-UBM DE-703 DE-29 DE-355 DE-BY-UBR DE-20 DE-83 DE-11 DE-188 |
| owner_facet | DE-12 DE-19 DE-BY-UBM DE-703 DE-29 DE-355 DE-BY-UBR DE-20 DE-83 DE-11 DE-188 |
| physical | XII, 309 S. graph. Darst. |
| publishDate | 1991 |
| publishDateSearch | 1991 |
| publishDateSort | 1991 |
| publisher | Elsevier |
| record_format | marc |
| series | New comprehensive biochemistry |
| series2 | New comprehensive biochemistry |
| spellingShingle | Biosynthesis of tetrapyrroles New comprehensive biochemistry Pyrroles metabolism Tetrapyrroles Synthesis Pflanzen (DE-588)4045539-7 gnd Stoffwechsel (DE-588)4057699-1 gnd Tetrapyrrole (DE-588)4140190-6 gnd Chemische Synthese (DE-588)4133806-6 gnd Biosynthese (DE-588)4006902-3 gnd |
| subject_GND | (DE-588)4045539-7 (DE-588)4057699-1 (DE-588)4140190-6 (DE-588)4133806-6 (DE-588)4006902-3 (DE-588)4143413-4 |
| title | Biosynthesis of tetrapyrroles |
| title_auth | Biosynthesis of tetrapyrroles |
| title_exact_search | Biosynthesis of tetrapyrroles |
| title_full | Biosynthesis of tetrapyrroles ed. P. M. Jordan |
| title_fullStr | Biosynthesis of tetrapyrroles ed. P. M. Jordan |
| title_full_unstemmed | Biosynthesis of tetrapyrroles ed. P. M. Jordan |
| title_short | Biosynthesis of tetrapyrroles |
| title_sort | biosynthesis of tetrapyrroles |
| topic | Pyrroles metabolism Tetrapyrroles Synthesis Pflanzen (DE-588)4045539-7 gnd Stoffwechsel (DE-588)4057699-1 gnd Tetrapyrrole (DE-588)4140190-6 gnd Chemische Synthese (DE-588)4133806-6 gnd Biosynthese (DE-588)4006902-3 gnd |
| topic_facet | Pyrroles metabolism Tetrapyrroles Synthesis Pflanzen Stoffwechsel Tetrapyrrole Chemische Synthese Biosynthese Aufsatzsammlung |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=002895174&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| volume_link | (DE-604)BV000003914 |
| work_keys_str_mv | AT jordanpeterm biosynthesisoftetrapyrroles |