Structural and Piezoelectric Properties of (1−x)Pb(Zr1−yTiy)O3-xPb(Zn0.4Ni0.6)1/3Nb2/3O3 Ceramics Near Triple Point

Structural and Piezoelectric Properties of (1−x)Pb(Zr1−yTiy)O3-xPb(Zn0.4Ni0.6)1/3Nb2/3O3 Ceramics Near Triple Point

The crystal structure and piezoelectric properties of (1−x)Pb(Zr1−yTiy)O3‐xPb(Zn0.4Ni0.6)1/3Nb2/3O3 [(1−x)PZ1−yTy‐xPZNN] ceramics were investigated. The 0.665PZ0.45T0.55‐0.335PZNN ceramic has the triple point composition, where the rhombohedral, pseudocubic, and tetragonal structures coexist. Maximu...

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Veröffentlicht in:Journal of the American Ceramic Society 2015-09, Vol.98 (9), p.2887-2893
Hauptverfasser: Hur, Joon, Kim, Jong-Hyun, Lee, Tae-Gon, Seo, In-Tae, Kim, Dae-Hyeon, Nahm, Sahn, Kang, Chong-Yun
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container_end_page 2893
container_issue 9
container_start_page 2887
container_title Journal of the American Ceramic Society
container_volume 98
creator Hur, Joon
Kim, Jong-Hyun
Lee, Tae-Gon
Seo, In-Tae
Kim, Dae-Hyeon
Nahm, Sahn
Kang, Chong-Yun
description The crystal structure and piezoelectric properties of (1−x)Pb(Zr1−yTiy)O3‐xPb(Zn0.4Ni0.6)1/3Nb2/3O3 [(1−x)PZ1−yTy‐xPZNN] ceramics were investigated. The 0.665PZ0.45T0.55‐0.335PZNN ceramic has the triple point composition, where the rhombohedral, pseudocubic, and tetragonal structures coexist. Maximum d33 and kp values of 770 pC/N and 0.69, respectively, were observed from this specimen; it also exhibited a large εT33/εo value of 3250. Although the maximum d33 value was obtained from the triple point composition specimen, its g33 and d33 × g33 values were relatively small because of its large εT33/εo value. However, the 0.665PZ0.46T0.54‐0.335PZNN ceramic, which has a rhombohedral structure, exhibited a large g33 value of 43 × 10−3 Vm/N and a d33 × g33 value of 27 000 × 10−15 m2/N. Therefore, this ceramic is a good candidate for multilayer actuators and piezoelectric energy harvesters.
doi_str_mv 10.1111/jace.13687
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The 0.665PZ0.45T0.55‐0.335PZNN ceramic has the triple point composition, where the rhombohedral, pseudocubic, and tetragonal structures coexist. Maximum d33 and kp values of 770 pC/N and 0.69, respectively, were observed from this specimen; it also exhibited a large εT33/εo value of 3250. Although the maximum d33 value was obtained from the triple point composition specimen, its g33 and d33 × g33 values were relatively small because of its large εT33/εo value. However, the 0.665PZ0.46T0.54‐0.335PZNN ceramic, which has a rhombohedral structure, exhibited a large g33 value of 43 × 10−3 Vm/N and a d33 × g33 value of 27 000 × 10−15 m2/N. 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Am. Ceram. Soc</addtitle><description>The crystal structure and piezoelectric properties of (1−x)Pb(Zr1−yTiy)O3‐xPb(Zn0.4Ni0.6)1/3Nb2/3O3 [(1−x)PZ1−yTy‐xPZNN] ceramics were investigated. The 0.665PZ0.45T0.55‐0.335PZNN ceramic has the triple point composition, where the rhombohedral, pseudocubic, and tetragonal structures coexist. Maximum d33 and kp values of 770 pC/N and 0.69, respectively, were observed from this specimen; it also exhibited a large εT33/εo value of 3250. Although the maximum d33 value was obtained from the triple point composition specimen, its g33 and d33 × g33 values were relatively small because of its large εT33/εo value. However, the 0.665PZ0.46T0.54‐0.335PZNN ceramic, which has a rhombohedral structure, exhibited a large g33 value of 43 × 10−3 Vm/N and a d33 × g33 value of 27 000 × 10−15 m2/N. 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Am. Ceram. Soc</addtitle><date>2015-09</date><risdate>2015</risdate><volume>98</volume><issue>9</issue><spage>2887</spage><epage>2893</epage><pages>2887-2893</pages><issn>0002-7820</issn><eissn>1551-2916</eissn><abstract>The crystal structure and piezoelectric properties of (1−x)Pb(Zr1−yTiy)O3‐xPb(Zn0.4Ni0.6)1/3Nb2/3O3 [(1−x)PZ1−yTy‐xPZNN] ceramics were investigated. The 0.665PZ0.45T0.55‐0.335PZNN ceramic has the triple point composition, where the rhombohedral, pseudocubic, and tetragonal structures coexist. Maximum d33 and kp values of 770 pC/N and 0.69, respectively, were observed from this specimen; it also exhibited a large εT33/εo value of 3250. Although the maximum d33 value was obtained from the triple point composition specimen, its g33 and d33 × g33 values were relatively small because of its large εT33/εo value. However, the 0.665PZ0.46T0.54‐0.335PZNN ceramic, which has a rhombohedral structure, exhibited a large g33 value of 43 × 10−3 Vm/N and a d33 × g33 value of 27 000 × 10−15 m2/N. Therefore, this ceramic is a good candidate for multilayer actuators and piezoelectric energy harvesters.</abstract><pub>Blackwell Publishing Ltd</pub><doi>10.1111/jace.13687</doi><tpages>7</tpages></addata></record>
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title Structural and Piezoelectric Properties of (1−x)Pb(Zr1−yTiy)O3-xPb(Zn0.4Ni0.6)1/3Nb2/3O3 Ceramics Near Triple Point
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