Ethylenediammonium decafluorodineptunate(IV)
An organically templated neptunium(IV) fluoride compound, {(C2H10N2)[Np2F10]}n, has been synthesized under mild hydrothermal conditions. The compound crystallizes in the monoclinic space group C2/c (No. 15). The structure consists of NpF9 tricapped trigonal prisms connected through edge‐ and corner...
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| Veröffentlicht in: | Acta crystallographica. Section E, Structure reports online Structure reports online, 2004-07, Vol.60 (7), p.m973-m975 |
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| container_title | Acta crystallographica. Section E, Structure reports online |
| container_volume | 60 |
| creator | Sullens, Tyler A. Almond, Philip M. Albrecht‐Schmitt, T. E. |
| description | An organically templated neptunium(IV) fluoride compound, {(C2H10N2)[Np2F10]}n, has been synthesized under mild hydrothermal conditions. The compound crystallizes in the monoclinic space group C2/c (No. 15). The structure consists of NpF9 tricapped trigonal prisms connected through edge‐ and corner‐sharing to form infinite two‐dimensional [Np2F10]2− sheets, that are separated by the ethylenediammonium dications. The C2H10N22+ cations form hydrogen‐bonding interactions with the [Np2F10]2− layers. |
| doi_str_mv | 10.1107/S1600536804014217 |
| format | Article |
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| title | Ethylenediammonium decafluorodineptunate(IV) |
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