4,4,6,6-Tetra­chloro-2,2-(propyl­ene­dioxy­di-o-phenyl­enedi­imino)-2λ5,4λ5,6λ5-cyclotriphosphazene

The title compound, C15H16Cl4N5O2P3, is a cyclo­phosphazenic lariat (PNP‐pivot) ether with a spiro‐cyclic 12‐membered macrocyclic ligand containing two ether O and two N atoms; the phosphazene ring is nearly planar. In the macrocyclic ring, there is a four‐center (trifurcate) N—H⋯O/N—H⋯N hydrogen bo...

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Veröffentlicht in:Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2004-06, Vol.60 (6), p.o381-o383
Hauptverfasser: Tercan, Barış, Hökelek, Tuncer, Bilge, Selen, Özgüç, Bilgehan, Kılıç, Zeynel
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container_issue 6
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container_title Acta crystallographica. Section C, Crystal structure communications
container_volume 60
creator Tercan, Barış
Hökelek, Tuncer
Bilge, Selen
Özgüç, Bilgehan
Kılıç, Zeynel
description The title compound, C15H16Cl4N5O2P3, is a cyclo­phosphazenic lariat (PNP‐pivot) ether with a spiro‐cyclic 12‐membered macrocyclic ligand containing two ether O and two N atoms; the phosphazene ring is nearly planar. In the macrocyclic ring, there is a four‐center (trifurcate) N—H⋯O/N—H⋯N hydrogen bond. The relative inner‐hole size of the macrocycle is estimated as approximately 0.95 Å.
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title 4,4,6,6-Tetra­chloro-2,2-(propyl­ene­dioxy­di-o-phenyl­enedi­imino)-2λ5,4λ5,6λ5-cyclotriphosphazene
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