4,4,6,6-Tetra­chloro-2,2-(propyl­ene­dioxy­di-o-phenyl­enedi­imino)-2λ5,4λ5,6λ5-cyclotriphosphazene

4,4,6,6-Tetra­chloro-2,2-(propyl­ene­dioxy­di-o-phenyl­enedi­imino)-2λ5,4λ5,6λ5-cyclotriphosphazene

The title compound, C15H16Cl4N5O2P3, is a cyclo­phosphazenic lariat (PNP‐pivot) ether with a spiro‐cyclic 12‐membered macrocyclic ligand containing two ether O and two N atoms; the phosphazene ring is nearly planar. In the macrocyclic ring, there is a four‐center (trifurcate) N—H⋯O/N—H⋯N hydrogen bo...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2004-06, Vol.60 (6), p.o381-o383
Hauptverfasser: Tercan, Barış, Hökelek, Tuncer, Bilge, Selen, Özgüç, Bilgehan, Kılıç, Zeynel
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:The title compound, C15H16Cl4N5O2P3, is a cyclo­phosphazenic lariat (PNP‐pivot) ether with a spiro‐cyclic 12‐membered macrocyclic ligand containing two ether O and two N atoms; the phosphazene ring is nearly planar. In the macrocyclic ring, there is a four‐center (trifurcate) N—H⋯O/N—H⋯N hydrogen bond. The relative inner‐hole size of the macrocycle is estimated as approximately 0.95 Å.
ISSN:0108-2701
1600-5759
DOI:10.1107/S0108270104006894