catena-Poly[[tetrakis(μ-3,3-dimethylbutyrato-O:O′)dicopper(II)]-μ-3,3-dimethylbutyrato-O:O′-[bis(2,6-dimethylpyridine-N)copper(II)]-μ-3,3-dimethylbutyrato-O:O′] and tetrakis(μ-2,2-dimethylpropanoato-O:O′)bis[(2,6-dimethylpyridine-N)copper(II)]
The two title compounds, [Cu3(C6H11O2)6(C7H9N)2]n, (I), and [Cu2(C5H9O2)4(C7H9N)2], (II), have chain and finite‐molecular structures, respectively. In (I), binuclear cage units and mononuclear 2,6‐dimethylpyridine complexes, both of which have inversion centres, are arranged alternately and are li...
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| Veröffentlicht in: | Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2000-08, Vol.56 (8), p.923-925 |
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| container_title | Acta crystallographica. Section C, Crystal structure communications |
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| creator | Kani, Yoshiyuki Tsuchimoto, Masanobu Ohba, Shigeru Matsushima, Hideaki Tokii, Tadashi |
| description | The two title compounds, [Cu3(C6H11O2)6(C7H9N)2]n, (I), and [Cu2(C5H9O2)4(C7H9N)2], (II), have chain and finite‐molecular structures, respectively. In (I), binuclear cage units and mononuclear 2,6‐dimethylpyridine complexes, both of which have inversion centres, are arranged alternately and are linked by the carboxylate ions to form one‐dimensional chains along the a axis. In (II), the binuclear cage unit has an inversion centre and the coordination geometry around the Cu atom is typical square pyramidal, with 2,6‐dimethylpyridine at the apical position. |
| doi_str_mv | 10.1107/S0108270100006697 |
| format | Article |
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In (I), binuclear cage units and mononuclear 2,6‐dimethylpyridine complexes, both of which have inversion centres, are arranged alternately and are linked by the carboxylate ions to form one‐dimensional chains along the a axis. In (II), the binuclear cage unit has an inversion centre and the coordination geometry around the Cu atom is typical square pyramidal, with 2,6‐dimethylpyridine at the apical position.</description><identifier>ISSN: 0108-2701</identifier><identifier>EISSN: 1600-5759</identifier><identifier>DOI: 10.1107/S0108270100006697</identifier><language>eng</language><publisher>5 Abbey Square, Chester, Cheshire CH1 2HU, England: Munksgaard International Publishers</publisher><ispartof>Acta crystallographica. 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In (II), the binuclear cage unit has an inversion centre and the coordination geometry around the Cu atom is typical square pyramidal, with 2,6‐dimethylpyridine at the apical position.</description><issn>0108-2701</issn><issn>1600-5759</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2000</creationdate><recordtype>article</recordtype><recordid>eNqVUU1Kw0AUjmLBWj2Auy5b6Oj8dGYy7mq1tVBaxYJKKMMkM8GxPwlJRLPzQm5cu_IAHsKTmNJSCorgW7y3-H7hOc4hgkcIQX58DRF0MS92MYwJvu2UEYMQUE7FjlNewGCB7zp7afpQkDDGpLxVClRm5gpcRtPc8zKTJWpi09rnOyANArSdmew-n_qPWZ6oLALDk-HXy1td2yCKY5PUer36GKzJH6-_0oHnF5a4wTYocZ5YbecGDOr_sRpX1VxXN2viBl7XjJMoVvNoo2gR7K2S_8rdd0qhmqbmYHUrzqhzPmpfgP6w22u3-sC63AVBiIlhCCFOkGEaMcyMCCmlRGlfayOawgijmiLQAWeYUoiFj5soZJpqFFJScdyl7ZOdmlzGiZ2pJJcIysUP5Y8fytZdu3uGoHALKVhKbZqZ57VUJRPJOOFU3gy6snN167Zh51SOyDfizatv</recordid><startdate>200008</startdate><enddate>200008</enddate><creator>Kani, Yoshiyuki</creator><creator>Tsuchimoto, Masanobu</creator><creator>Ohba, Shigeru</creator><creator>Matsushima, Hideaki</creator><creator>Tokii, Tadashi</creator><general>Munksgaard International Publishers</general><scope>BSCLL</scope></search><sort><creationdate>200008</creationdate><title>catena-Poly[[tetrakis(μ-3,3-dimethylbutyrato-O:O′)dicopper(II)]-μ-3,3-dimethylbutyrato-O:O′-[bis(2,6-dimethylpyridine-N)copper(II)]-μ-3,3-dimethylbutyrato-O:O′] and tetrakis(μ-2,2-dimethylpropanoato-O:O′)bis[(2,6-dimethylpyridine-N)copper(II)]</title><author>Kani, Yoshiyuki ; Tsuchimoto, Masanobu ; Ohba, Shigeru ; Matsushima, Hideaki ; Tokii, Tadashi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-i878-cf23e6111731e6d1626e9f5553adbdde949e9ea49cdc76255029b241f6d5d1f53</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2000</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kani, Yoshiyuki</creatorcontrib><creatorcontrib>Tsuchimoto, Masanobu</creatorcontrib><creatorcontrib>Ohba, Shigeru</creatorcontrib><creatorcontrib>Matsushima, Hideaki</creatorcontrib><creatorcontrib>Tokii, Tadashi</creatorcontrib><collection>Istex</collection><jtitle>Acta crystallographica. 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C</addtitle><date>2000-08</date><risdate>2000</risdate><volume>56</volume><issue>8</issue><spage>923</spage><epage>925</epage><pages>923-925</pages><issn>0108-2701</issn><eissn>1600-5759</eissn><abstract>The two title compounds, [Cu3(C6H11O2)6(C7H9N)2]n, (I), and [Cu2(C5H9O2)4(C7H9N)2], (II), have chain and finite‐molecular structures, respectively. In (I), binuclear cage units and mononuclear 2,6‐dimethylpyridine complexes, both of which have inversion centres, are arranged alternately and are linked by the carboxylate ions to form one‐dimensional chains along the a axis. In (II), the binuclear cage unit has an inversion centre and the coordination geometry around the Cu atom is typical square pyramidal, with 2,6‐dimethylpyridine at the apical position.</abstract><cop>5 Abbey Square, Chester, Cheshire CH1 2HU, England</cop><pub>Munksgaard International Publishers</pub><doi>10.1107/S0108270100006697</doi><tpages>3</tpages></addata></record> |
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| identifier | ISSN: 0108-2701 |
| ispartof | Acta crystallographica. Section C, Crystal structure communications, 2000-08, Vol.56 (8), p.923-925 |
| issn | 0108-2701 1600-5759 |
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| source | Wiley Journals; Crystallography Journals Online |
| title | catena-Poly[[tetrakis(μ-3,3-dimethylbutyrato-O:O′)dicopper(II)]-μ-3,3-dimethylbutyrato-O:O′-[bis(2,6-dimethylpyridine-N)copper(II)]-μ-3,3-dimethylbutyrato-O:O′] and tetrakis(μ-2,2-dimethylpropanoato-O:O′)bis[(2,6-dimethylpyridine-N)copper(II)] |
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