Ba3V2O4F8: [V4(O,F)20]8− tetrameric groups of octahedra inserted a tridimensional network of (FBa4) tetrahedra
Ba3V2O4F8 is prepared by hydrothermal synthesis. The crystal structure is established from single crystal X‐ray diffraction data: Space group Pnnm, Z = 4, a = 9.945(4) Å, b = 10.277(1) Å and c = 9.673(1) Å R = 0.0331, Rw = 0.0315 for 892 independent reflections and 86 parameters. The structure is re...
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| Veröffentlicht in: | Zeitschrift für anorganische und allgemeine Chemie (1950) 1993-09, Vol.619 (9), p.1597-1602 |
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| container_title | Zeitschrift für anorganische und allgemeine Chemie (1950) |
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| creator | Crosnier-Lopez, M. P. Duroy, H. Fourquet, J. L. |
| description | Ba3V2O4F8 is prepared by hydrothermal synthesis. The crystal structure is established from single crystal X‐ray diffraction data: Space group Pnnm, Z = 4, a = 9.945(4) Å, b = 10.277(1) Å and c = 9.673(1) Å R = 0.0331, Rw = 0.0315 for 892 independent reflections and 86 parameters. The structure is related to that Ba3Al2F12 and is described in terms of isolated [V4(O,F)20]8− tetrameric groups of octahedra inserted in a tridimensional network of (FBa4) tetrahedra. Location of oxygen and fluorine atoms is discussed with the help of bond valence calculations.
Ba3V2O4F8: [V4(O,F)20]8− tetramere Gruppen von Oktaedern in einem dreidimensionalen Netz von (FBa4)‐Tetraedern
Ba3V2O4F8 wird durch hydrothermale synthese dargestellt und die Kristallstruktur aus Einkristalldaten bestimmt: Raumgruppe: Pnnm, Z = 4, a = 9,945(4), b = 10,277(1), c = 9,673(1) Å; R = 0,0331, Rw = 0,0315 für 892 unabhängige Reflexe und 86 freie Parameter. Die Struktur ist verwandt mit der von Ba3Al2F12 und kann durch isolierte, tetramere [V4(O,F)20]8−‐Gruppen von Oktaedern in einem dreidimensionalen Netz von (FBa4)‐Tetraedern beschrieben werden. Die Anordnung der Sauerstoff‐ und Fluoratome wird mit Hilfe von Valenzband‐Rechnungen diskutiert. |
| doi_str_mv | 10.1002/zaac.19936190915 |
| format | Article |
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Ba3V2O4F8: [V4(O,F)20]8− tetramere Gruppen von Oktaedern in einem dreidimensionalen Netz von (FBa4)‐Tetraedern
Ba3V2O4F8 wird durch hydrothermale synthese dargestellt und die Kristallstruktur aus Einkristalldaten bestimmt: Raumgruppe: Pnnm, Z = 4, a = 9,945(4), b = 10,277(1), c = 9,673(1) Å; R = 0,0331, Rw = 0,0315 für 892 unabhängige Reflexe und 86 freie Parameter. Die Struktur ist verwandt mit der von Ba3Al2F12 und kann durch isolierte, tetramere [V4(O,F)20]8−‐Gruppen von Oktaedern in einem dreidimensionalen Netz von (FBa4)‐Tetraedern beschrieben werden. Die Anordnung der Sauerstoff‐ und Fluoratome wird mit Hilfe von Valenzband‐Rechnungen diskutiert.</description><identifier>ISSN: 0044-2313</identifier><identifier>EISSN: 1521-3749</identifier><identifier>DOI: 10.1002/zaac.19936190915</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>Barium vanadium oxide fluorides ; bond valence calculations ; crystal structures</subject><ispartof>Zeitschrift für anorganische und allgemeine Chemie (1950), 1993-09, Vol.619 (9), p.1597-1602</ispartof><rights>Copyright © 1993 Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fzaac.19936190915$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fzaac.19936190915$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids></links><search><creatorcontrib>Crosnier-Lopez, M. P.</creatorcontrib><creatorcontrib>Duroy, H.</creatorcontrib><creatorcontrib>Fourquet, J. L.</creatorcontrib><title>Ba3V2O4F8: [V4(O,F)20]8− tetrameric groups of octahedra inserted a tridimensional network of (FBa4) tetrahedra</title><title>Zeitschrift für anorganische und allgemeine Chemie (1950)</title><addtitle>Z. anorg. allg. Chem</addtitle><description>Ba3V2O4F8 is prepared by hydrothermal synthesis. The crystal structure is established from single crystal X‐ray diffraction data: Space group Pnnm, Z = 4, a = 9.945(4) Å, b = 10.277(1) Å and c = 9.673(1) Å R = 0.0331, Rw = 0.0315 for 892 independent reflections and 86 parameters. The structure is related to that Ba3Al2F12 and is described in terms of isolated [V4(O,F)20]8− tetrameric groups of octahedra inserted in a tridimensional network of (FBa4) tetrahedra. Location of oxygen and fluorine atoms is discussed with the help of bond valence calculations.
Ba3V2O4F8: [V4(O,F)20]8− tetramere Gruppen von Oktaedern in einem dreidimensionalen Netz von (FBa4)‐Tetraedern
Ba3V2O4F8 wird durch hydrothermale synthese dargestellt und die Kristallstruktur aus Einkristalldaten bestimmt: Raumgruppe: Pnnm, Z = 4, a = 9,945(4), b = 10,277(1), c = 9,673(1) Å; R = 0,0331, Rw = 0,0315 für 892 unabhängige Reflexe und 86 freie Parameter. Die Struktur ist verwandt mit der von Ba3Al2F12 und kann durch isolierte, tetramere [V4(O,F)20]8−‐Gruppen von Oktaedern in einem dreidimensionalen Netz von (FBa4)‐Tetraedern beschrieben werden. Die Anordnung der Sauerstoff‐ und Fluoratome wird mit Hilfe von Valenzband‐Rechnungen diskutiert.</description><subject>Barium vanadium oxide fluorides</subject><subject>bond valence calculations</subject><subject>crystal structures</subject><issn>0044-2313</issn><issn>1521-3749</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1993</creationdate><recordtype>article</recordtype><recordid>eNpNkM1Kw0AYRQdRsFb3LmfZgqnzzU8mI7hoi6lCbTdaRZFhkkx0tE3KJFLrE7j2EX0SrRXp6nLhnrs4CB0C6QAh9PjdmLQDSrEQFFEgtlADBIWASa62UYMQzgPKgO2ivap6JoQAEaKB5j3DJnTM4-gE3094a3wUtyl5iL4-PnFta29m1rsUP_rydV7hMsdlWpsnm3mDXVFZX9sMG1x7l7mZLSpXFmaKC1svSv-ymrfinuHt9dUvto92cjOt7MFfNtF1fHbVPw-G48FFvzsMHEgpggSMUBkzMlMq5NQKISmNFE9TIvNcRSBCJkyShBFR1kKW5xlNjQCZ5DQXKWFNdLr-XbipXeq5dzPjlxqIXunSK116Q5e-63b7G_2HD9a8q2r79s8b_6JDyaTQN6OB7sHo9nIyHGjJvgE4PXC0</recordid><startdate>199309</startdate><enddate>199309</enddate><creator>Crosnier-Lopez, M. P.</creator><creator>Duroy, H.</creator><creator>Fourquet, J. L.</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><scope>BSCLL</scope></search><sort><creationdate>199309</creationdate><title>Ba3V2O4F8: [V4(O,F)20]8− tetrameric groups of octahedra inserted a tridimensional network of (FBa4) tetrahedra</title><author>Crosnier-Lopez, M. P. ; Duroy, H. ; Fourquet, J. L.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-i1775-b1a59d3a7d99642e55722894cc07ff9815635abb6809ee1dffd2ca517bf2f5c03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1993</creationdate><topic>Barium vanadium oxide fluorides</topic><topic>bond valence calculations</topic><topic>crystal structures</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Crosnier-Lopez, M. P.</creatorcontrib><creatorcontrib>Duroy, H.</creatorcontrib><creatorcontrib>Fourquet, J. L.</creatorcontrib><collection>Istex</collection><jtitle>Zeitschrift für anorganische und allgemeine Chemie (1950)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Crosnier-Lopez, M. P.</au><au>Duroy, H.</au><au>Fourquet, J. L.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Ba3V2O4F8: [V4(O,F)20]8− tetrameric groups of octahedra inserted a tridimensional network of (FBa4) tetrahedra</atitle><jtitle>Zeitschrift für anorganische und allgemeine Chemie (1950)</jtitle><addtitle>Z. anorg. allg. Chem</addtitle><date>1993-09</date><risdate>1993</risdate><volume>619</volume><issue>9</issue><spage>1597</spage><epage>1602</epage><pages>1597-1602</pages><issn>0044-2313</issn><eissn>1521-3749</eissn><abstract>Ba3V2O4F8 is prepared by hydrothermal synthesis. The crystal structure is established from single crystal X‐ray diffraction data: Space group Pnnm, Z = 4, a = 9.945(4) Å, b = 10.277(1) Å and c = 9.673(1) Å R = 0.0331, Rw = 0.0315 for 892 independent reflections and 86 parameters. The structure is related to that Ba3Al2F12 and is described in terms of isolated [V4(O,F)20]8− tetrameric groups of octahedra inserted in a tridimensional network of (FBa4) tetrahedra. Location of oxygen and fluorine atoms is discussed with the help of bond valence calculations.
Ba3V2O4F8: [V4(O,F)20]8− tetramere Gruppen von Oktaedern in einem dreidimensionalen Netz von (FBa4)‐Tetraedern
Ba3V2O4F8 wird durch hydrothermale synthese dargestellt und die Kristallstruktur aus Einkristalldaten bestimmt: Raumgruppe: Pnnm, Z = 4, a = 9,945(4), b = 10,277(1), c = 9,673(1) Å; R = 0,0331, Rw = 0,0315 für 892 unabhängige Reflexe und 86 freie Parameter. Die Struktur ist verwandt mit der von Ba3Al2F12 und kann durch isolierte, tetramere [V4(O,F)20]8−‐Gruppen von Oktaedern in einem dreidimensionalen Netz von (FBa4)‐Tetraedern beschrieben werden. Die Anordnung der Sauerstoff‐ und Fluoratome wird mit Hilfe von Valenzband‐Rechnungen diskutiert.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><doi>10.1002/zaac.19936190915</doi><tpages>6</tpages></addata></record> |
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| ispartof | Zeitschrift für anorganische und allgemeine Chemie (1950), 1993-09, Vol.619 (9), p.1597-1602 |
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| language | eng |
| recordid | cdi_wiley_primary_10_1002_zaac_19936190915_ZAAC19936190915 |
| source | Wiley Online Library - AutoHoldings Journals |
| subjects | Barium vanadium oxide fluorides bond valence calculations crystal structures |
| title | Ba3V2O4F8: [V4(O,F)20]8− tetrameric groups of octahedra inserted a tridimensional network of (FBa4) tetrahedra |
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