Hydrothermal Synthesis and Symmetrical Supercapacitor Study of 1D Ln‐H2PDA (Ln=La and Sm) Metal‐Organic Frameworks

Rare earth based metal‐organic frameworks (RE‐MOFs) are gaining importance in energy storage applications. Herein, we report the synthesis of two new RE‐MOFs (Ln‐H2PDA, Ln=La and Sm) under hydrothermal conditions using pyridine‐2,6‐dicarboxylic acid (H2PDA) linker. The single‐crystal analysis reveal...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:ChemistrySelect (Weinheim) 2022-07, Vol.7 (26), p.n/a
Hauptverfasser: Lata Singh, Deep, Mishra, Vineet, Kumar Ghosh, Tapan, Ranga Rao, G.
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page n/a
container_issue 26
container_start_page
container_title ChemistrySelect (Weinheim)
container_volume 7
creator Lata Singh, Deep
Mishra, Vineet
Kumar Ghosh, Tapan
Ranga Rao, G.
description Rare earth based metal‐organic frameworks (RE‐MOFs) are gaining importance in energy storage applications. Herein, we report the synthesis of two new RE‐MOFs (Ln‐H2PDA, Ln=La and Sm) under hydrothermal conditions using pyridine‐2,6‐dicarboxylic acid (H2PDA) linker. The single‐crystal analysis revealed that La‐H2PDA MOF crystallizes into monoclinic system with P 21/c space group. Sm‐H2PDA MOF also has the same crystal system, which is confirmed by powder X‐ray diffraction pattern. These MOFs are evaluated for their charge storage behaviour using conventional 3‐electrode system. Both La‐H2PDA and Sm‐H2PDA delivered high specific capacity of 220 C g−1 (488 F g−1) and 711 C g−1 (1580 F g−1) at a current density of 1 A g−1, respectively. Furthermore, a symmetric Swagelok device (Sm‐H2PDA∥Sm‐H2PDA) has been fabricated using Sm‐H2PDA MOF as working electrodes. The maximum energy density and power density delivered by this device are 18 Wh kg−1 and 3744 W kg−1. New Sm and La‐based based 1D‐MOFs are synthesized using water as a solvent in a Pyrex tube immersed in an oil bath at 100 °C. MOF sythesis is carried out using H2PDA ligand under mild hydrothermal conditions. Among the two Ln‐MOFs, Sm‐H2PDA shows higher charge storage capacity (1580 F g−1) in a 3‐elecrode sytem and delivers power density of 3744 W kg−1 from the fabicated symmetric supercapacitor device, Sm-H2PDASm-H2PDA .
doi_str_mv 10.1002/slct.202202076
format Article
fullrecord <record><control><sourceid>wiley</sourceid><recordid>TN_cdi_wiley_primary_10_1002_slct_202202076_SLCT202202076</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>SLCT202202076</sourcerecordid><originalsourceid>FETCH-LOGICAL-s1206-8e925e0dfdeb02ec19667300f1eb30b6c5c35207727b8fa0935e1b9449e58b3e3</originalsourceid><addsrcrecordid>eNpNkE9Lw0AQxRdRsGivnveoh9TZ3e4me_BQWmuFSIXWc9hsJhrNn7KbWnLzI_gZ_SSmVIowMO_xmIH3I-SKwYgB8Ftf2nbEgfcDoTohAy6UDJQc69N_-pwMvX8HAKYixWU4IJ-LLnNN-4auMiVddXUvfeGpqbPeVRW2rrD7ZLtBZ83G2KJtHF2126yjTU7ZjMb1z9f3gj_PJvQ6ru9icziubugTtqbsw6V7NXVh6dyZCneN-_CX5Cw3pcfh374gL_P79XQRxMuHx-kkDjzjoIIINZcIWZ5hChwt00qFAiBnmApIlZVWyL5wyMM0yg1oIZGlejzWKKNUoLgg-vB3V5TYJRtXVMZ1CYNkTy3ZU0uO1JJVPF0fnfgFdjJlMg</addsrcrecordid><sourcetype>Publisher</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Hydrothermal Synthesis and Symmetrical Supercapacitor Study of 1D Ln‐H2PDA (Ln=La and Sm) Metal‐Organic Frameworks</title><source>Wiley Journals</source><creator>Lata Singh, Deep ; Mishra, Vineet ; Kumar Ghosh, Tapan ; Ranga Rao, G.</creator><creatorcontrib>Lata Singh, Deep ; Mishra, Vineet ; Kumar Ghosh, Tapan ; Ranga Rao, G.</creatorcontrib><description>Rare earth based metal‐organic frameworks (RE‐MOFs) are gaining importance in energy storage applications. Herein, we report the synthesis of two new RE‐MOFs (Ln‐H2PDA, Ln=La and Sm) under hydrothermal conditions using pyridine‐2,6‐dicarboxylic acid (H2PDA) linker. The single‐crystal analysis revealed that La‐H2PDA MOF crystallizes into monoclinic system with P 21/c space group. Sm‐H2PDA MOF also has the same crystal system, which is confirmed by powder X‐ray diffraction pattern. These MOFs are evaluated for their charge storage behaviour using conventional 3‐electrode system. Both La‐H2PDA and Sm‐H2PDA delivered high specific capacity of 220 C g−1 (488 F g−1) and 711 C g−1 (1580 F g−1) at a current density of 1 A g−1, respectively. Furthermore, a symmetric Swagelok device (Sm‐H2PDA∥Sm‐H2PDA) has been fabricated using Sm‐H2PDA MOF as working electrodes. The maximum energy density and power density delivered by this device are 18 Wh kg−1 and 3744 W kg−1. New Sm and La‐based based 1D‐MOFs are synthesized using water as a solvent in a Pyrex tube immersed in an oil bath at 100 °C. MOF sythesis is carried out using H2PDA ligand under mild hydrothermal conditions. Among the two Ln‐MOFs, Sm‐H2PDA shows higher charge storage capacity (1580 F g−1) in a 3‐elecrode sytem and delivers power density of 3744 W kg−1 from the fabicated symmetric supercapacitor device, Sm-H2PDASm-H2PDA .</description><identifier>ISSN: 2365-6549</identifier><identifier>EISSN: 2365-6549</identifier><identifier>DOI: 10.1002/slct.202202076</identifier><language>eng</language><subject>energy storage ; lanthanides ; MOF ; pyridine-2,6-dicarboxylic acid ; symmetric supercapacitor</subject><ispartof>ChemistrySelect (Weinheim), 2022-07, Vol.7 (26), p.n/a</ispartof><rights>2022 Wiley‐VCH GmbH</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><orcidid>0000-0001-7389-9887 ; 0000-0002-1724-2255 ; 0000-0001-6576-1909 ; 0000-0002-2930-3756</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fslct.202202076$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fslct.202202076$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids></links><search><creatorcontrib>Lata Singh, Deep</creatorcontrib><creatorcontrib>Mishra, Vineet</creatorcontrib><creatorcontrib>Kumar Ghosh, Tapan</creatorcontrib><creatorcontrib>Ranga Rao, G.</creatorcontrib><title>Hydrothermal Synthesis and Symmetrical Supercapacitor Study of 1D Ln‐H2PDA (Ln=La and Sm) Metal‐Organic Frameworks</title><title>ChemistrySelect (Weinheim)</title><description>Rare earth based metal‐organic frameworks (RE‐MOFs) are gaining importance in energy storage applications. Herein, we report the synthesis of two new RE‐MOFs (Ln‐H2PDA, Ln=La and Sm) under hydrothermal conditions using pyridine‐2,6‐dicarboxylic acid (H2PDA) linker. The single‐crystal analysis revealed that La‐H2PDA MOF crystallizes into monoclinic system with P 21/c space group. Sm‐H2PDA MOF also has the same crystal system, which is confirmed by powder X‐ray diffraction pattern. These MOFs are evaluated for their charge storage behaviour using conventional 3‐electrode system. Both La‐H2PDA and Sm‐H2PDA delivered high specific capacity of 220 C g−1 (488 F g−1) and 711 C g−1 (1580 F g−1) at a current density of 1 A g−1, respectively. Furthermore, a symmetric Swagelok device (Sm‐H2PDA∥Sm‐H2PDA) has been fabricated using Sm‐H2PDA MOF as working electrodes. The maximum energy density and power density delivered by this device are 18 Wh kg−1 and 3744 W kg−1. New Sm and La‐based based 1D‐MOFs are synthesized using water as a solvent in a Pyrex tube immersed in an oil bath at 100 °C. MOF sythesis is carried out using H2PDA ligand under mild hydrothermal conditions. Among the two Ln‐MOFs, Sm‐H2PDA shows higher charge storage capacity (1580 F g−1) in a 3‐elecrode sytem and delivers power density of 3744 W kg−1 from the fabicated symmetric supercapacitor device, Sm-H2PDASm-H2PDA .</description><subject>energy storage</subject><subject>lanthanides</subject><subject>MOF</subject><subject>pyridine-2,6-dicarboxylic acid</subject><subject>symmetric supercapacitor</subject><issn>2365-6549</issn><issn>2365-6549</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNpNkE9Lw0AQxRdRsGivnveoh9TZ3e4me_BQWmuFSIXWc9hsJhrNn7KbWnLzI_gZ_SSmVIowMO_xmIH3I-SKwYgB8Ftf2nbEgfcDoTohAy6UDJQc69N_-pwMvX8HAKYixWU4IJ-LLnNN-4auMiVddXUvfeGpqbPeVRW2rrD7ZLtBZ83G2KJtHF2126yjTU7ZjMb1z9f3gj_PJvQ6ru9icziubugTtqbsw6V7NXVh6dyZCneN-_CX5Cw3pcfh374gL_P79XQRxMuHx-kkDjzjoIIINZcIWZ5hChwt00qFAiBnmApIlZVWyL5wyMM0yg1oIZGlejzWKKNUoLgg-vB3V5TYJRtXVMZ1CYNkTy3ZU0uO1JJVPF0fnfgFdjJlMg</recordid><startdate>20220714</startdate><enddate>20220714</enddate><creator>Lata Singh, Deep</creator><creator>Mishra, Vineet</creator><creator>Kumar Ghosh, Tapan</creator><creator>Ranga Rao, G.</creator><scope/><orcidid>https://orcid.org/0000-0001-7389-9887</orcidid><orcidid>https://orcid.org/0000-0002-1724-2255</orcidid><orcidid>https://orcid.org/0000-0001-6576-1909</orcidid><orcidid>https://orcid.org/0000-0002-2930-3756</orcidid></search><sort><creationdate>20220714</creationdate><title>Hydrothermal Synthesis and Symmetrical Supercapacitor Study of 1D Ln‐H2PDA (Ln=La and Sm) Metal‐Organic Frameworks</title><author>Lata Singh, Deep ; Mishra, Vineet ; Kumar Ghosh, Tapan ; Ranga Rao, G.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-s1206-8e925e0dfdeb02ec19667300f1eb30b6c5c35207727b8fa0935e1b9449e58b3e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>energy storage</topic><topic>lanthanides</topic><topic>MOF</topic><topic>pyridine-2,6-dicarboxylic acid</topic><topic>symmetric supercapacitor</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lata Singh, Deep</creatorcontrib><creatorcontrib>Mishra, Vineet</creatorcontrib><creatorcontrib>Kumar Ghosh, Tapan</creatorcontrib><creatorcontrib>Ranga Rao, G.</creatorcontrib><jtitle>ChemistrySelect (Weinheim)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lata Singh, Deep</au><au>Mishra, Vineet</au><au>Kumar Ghosh, Tapan</au><au>Ranga Rao, G.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Hydrothermal Synthesis and Symmetrical Supercapacitor Study of 1D Ln‐H2PDA (Ln=La and Sm) Metal‐Organic Frameworks</atitle><jtitle>ChemistrySelect (Weinheim)</jtitle><date>2022-07-14</date><risdate>2022</risdate><volume>7</volume><issue>26</issue><epage>n/a</epage><issn>2365-6549</issn><eissn>2365-6549</eissn><abstract>Rare earth based metal‐organic frameworks (RE‐MOFs) are gaining importance in energy storage applications. Herein, we report the synthesis of two new RE‐MOFs (Ln‐H2PDA, Ln=La and Sm) under hydrothermal conditions using pyridine‐2,6‐dicarboxylic acid (H2PDA) linker. The single‐crystal analysis revealed that La‐H2PDA MOF crystallizes into monoclinic system with P 21/c space group. Sm‐H2PDA MOF also has the same crystal system, which is confirmed by powder X‐ray diffraction pattern. These MOFs are evaluated for their charge storage behaviour using conventional 3‐electrode system. Both La‐H2PDA and Sm‐H2PDA delivered high specific capacity of 220 C g−1 (488 F g−1) and 711 C g−1 (1580 F g−1) at a current density of 1 A g−1, respectively. Furthermore, a symmetric Swagelok device (Sm‐H2PDA∥Sm‐H2PDA) has been fabricated using Sm‐H2PDA MOF as working electrodes. The maximum energy density and power density delivered by this device are 18 Wh kg−1 and 3744 W kg−1. New Sm and La‐based based 1D‐MOFs are synthesized using water as a solvent in a Pyrex tube immersed in an oil bath at 100 °C. MOF sythesis is carried out using H2PDA ligand under mild hydrothermal conditions. Among the two Ln‐MOFs, Sm‐H2PDA shows higher charge storage capacity (1580 F g−1) in a 3‐elecrode sytem and delivers power density of 3744 W kg−1 from the fabicated symmetric supercapacitor device, Sm-H2PDASm-H2PDA .</abstract><doi>10.1002/slct.202202076</doi><tpages>9</tpages><orcidid>https://orcid.org/0000-0001-7389-9887</orcidid><orcidid>https://orcid.org/0000-0002-1724-2255</orcidid><orcidid>https://orcid.org/0000-0001-6576-1909</orcidid><orcidid>https://orcid.org/0000-0002-2930-3756</orcidid></addata></record>
fulltext fulltext
identifier ISSN: 2365-6549
ispartof ChemistrySelect (Weinheim), 2022-07, Vol.7 (26), p.n/a
issn 2365-6549
2365-6549
language eng
recordid cdi_wiley_primary_10_1002_slct_202202076_SLCT202202076
source Wiley Journals
subjects energy storage
lanthanides
MOF
pyridine-2,6-dicarboxylic acid
symmetric supercapacitor
title Hydrothermal Synthesis and Symmetrical Supercapacitor Study of 1D Ln‐H2PDA (Ln=La and Sm) Metal‐Organic Frameworks
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-01T00%3A52%3A46IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-wiley&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Hydrothermal%20Synthesis%20and%20Symmetrical%20Supercapacitor%20Study%20of%201D%20Ln%E2%80%90H2PDA%20(Ln=La%20and%20Sm)%20Metal%E2%80%90Organic%20Frameworks&rft.jtitle=ChemistrySelect%20(Weinheim)&rft.au=Lata%20Singh,%20Deep&rft.date=2022-07-14&rft.volume=7&rft.issue=26&rft.epage=n/a&rft.issn=2365-6549&rft.eissn=2365-6549&rft_id=info:doi/10.1002/slct.202202076&rft_dat=%3Cwiley%3ESLCT202202076%3C/wiley%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true