C1-Symmetric Heterocyclic Zirconocenes as Catalysts for Propylene Polymerization, 1

The synthesis of C1‐symmetric zirconocene complexes bearing the 2,5‐dimethyl‐7H‐cyclopenta[1,2‐b:4,3‐b′]dithiophene ligand (S2‐3) linked to substituted cyclopentadienes is described. Different syntheses of S2‐3, the common intermediate for the preparation of these complexes, are discussed. Many of t...

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Veröffentlicht in:Macromolecular chemistry and physics 2004-11, Vol.205 (17), p.2275-2291
Hauptverfasser: Nifant'ev, Ilya E., Laishevtsev, Ilya, Ivchenko, Pavel V., Kashulin, Igor A., Guidotti, Simona, Piemontesi, Fabrizio, Camurati, Isabella, Resconi, Luigi, Klusener, Peter A. A., Rijsemus, Jos J. H., de Kloe, Kees P., Korndorffer, Frans M.
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Sprache:eng
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