15N Chemically Induced Dynamic Nuclear Polarization (15N-CIDNP) Investigations of the Peroxynitrite Decay and Nitration of N-Acetyl-L-tyrosine

During the decay of (15N)peroxynitrite (O15NOO−) in the presence of N‐acetyl‐L‐tyrosine (Tyrac) in neutral solution and at 268 K, the 15N‐NMR signals of 15NO$\rm{_2^ - }$ and 15NO$\rm{_3^ - }$ show emission (E) and enhanced absorption (A) as it has already been observed by Butler and co‐workers in...

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Veröffentlicht in:	Helvetica chimica acta 2006-10, Vol.89 (10), p.2144-2166
Hauptverfasser:	Lehnig, Manfred, Kirsch, Michael
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemically induced dynamic nuclear polarization (CIDNP) Nitrogen dioxide Nitrogen oxide Nitrotyrosine Peroxynitrite Radicals Reactive nitrogen spezies (RNS)
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