Synthesis, Structure, and Spectroscopic and Electrochemical Properties of Heteroleptic Bis(phthalocyaninato) Rare Earth Complexes with a C4 Symmetry
A series of eleven heteroleptic bis(phthalocyaninato) rare earth double‐deckers [MIII(pc){pc(α‐OC5H11)4}] 1–11 (M=Y, SmLu; pc=phthalocyaninato; pc(α‐OC5H11)4=1,8,15,22‐tetrakis(1‐ethylpropoxy)phthalocyaninato) were prepared as racemic mixtures by [MIII(pc)(acac)]‐induced (acac=acetylacetonato) cycl...
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| Veröffentlicht in: | Helvetica chimica acta 2004-10, Vol.87 (10), p.2581-2596 |
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| creator | Bian, Yongzhong Wang, Rongming Wang, Daqi Zhu, Pehua Li, Renjie Dou, Jianmin Liu, Wei Choi, Chi-Fung Chan, Hoi-Shan Ma, Changqin Ng, Dennis K. P. Jiang, Jianzhuang |
| description | A series of eleven heteroleptic bis(phthalocyaninato) rare earth double‐deckers [MIII(pc){pc(α‐OC5H11)4}] 1–11 (M=Y, SmLu; pc=phthalocyaninato; pc(α‐OC5H11)4=1,8,15,22‐tetrakis(1‐ethylpropoxy)phthalocyaninato) were prepared as racemic mixtures by [MIII(pc)(acac)]‐induced (acac=acetylacetonato) cyclic tetramerization of 3‐(1‐ethylpropoxy)phthalonitrile in the presence of 1,8‐diazabicyclo[5.4.0]undec‐7‐ene (DBU) in refluxing pentanol. These compounds could also be prepared by treating [MIII(pc)(acac)] with the metal‐free phthalocyanine H2{pc(α‐OC5H11)4} in refluxing octanol. The whole series of double‐decker complexes 1–11 were characterized by elemental analysis and various spectroscopic methods. The molecular structures of the Sm, Eu, and Er complexes 1, 2, and 8, respectively, were also determined by single‐crystal X‐ray diffraction analysis. The effects of the rare earth ion size on the reaction yield, molecular structure, and spectroscopic and electrochemical properties of these complexes were systematically examined. |
| doi_str_mv | 10.1002/hlca.200490231 |
| format | Article |
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P. ; Jiang, Jianzhuang</creator><creatorcontrib>Bian, Yongzhong ; Wang, Rongming ; Wang, Daqi ; Zhu, Pehua ; Li, Renjie ; Dou, Jianmin ; Liu, Wei ; Choi, Chi-Fung ; Chan, Hoi-Shan ; Ma, Changqin ; Ng, Dennis K. P. ; Jiang, Jianzhuang</creatorcontrib><description>A series of eleven heteroleptic bis(phthalocyaninato) rare earth double‐deckers [MIII(pc){pc(α‐OC5H11)4}] 1–11 (M=Y, SmLu; pc=phthalocyaninato; pc(α‐OC5H11)4=1,8,15,22‐tetrakis(1‐ethylpropoxy)phthalocyaninato) were prepared as racemic mixtures by [MIII(pc)(acac)]‐induced (acac=acetylacetonato) cyclic tetramerization of 3‐(1‐ethylpropoxy)phthalonitrile in the presence of 1,8‐diazabicyclo[5.4.0]undec‐7‐ene (DBU) in refluxing pentanol. These compounds could also be prepared by treating [MIII(pc)(acac)] with the metal‐free phthalocyanine H2{pc(α‐OC5H11)4} in refluxing octanol. The whole series of double‐decker complexes 1–11 were characterized by elemental analysis and various spectroscopic methods. The molecular structures of the Sm, Eu, and Er complexes 1, 2, and 8, respectively, were also determined by single‐crystal X‐ray diffraction analysis. The effects of the rare earth ion size on the reaction yield, molecular structure, and spectroscopic and electrochemical properties of these complexes were systematically examined.</description><identifier>ISSN: 0018-019X</identifier><identifier>EISSN: 1522-2675</identifier><identifier>DOI: 10.1002/hlca.200490231</identifier><language>eng</language><publisher>Zürich: WILEY-VCH Verlag</publisher><ispartof>Helvetica chimica acta, 2004-10, Vol.87 (10), p.2581-2596</ispartof><rights>Copyright © 2004 Schweizerische Chemische Gesellschaft, Switzerland</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fhlca.200490231$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1416,27922,27923,45573</link.rule.ids></links><search><creatorcontrib>Bian, Yongzhong</creatorcontrib><creatorcontrib>Wang, Rongming</creatorcontrib><creatorcontrib>Wang, Daqi</creatorcontrib><creatorcontrib>Zhu, Pehua</creatorcontrib><creatorcontrib>Li, Renjie</creatorcontrib><creatorcontrib>Dou, Jianmin</creatorcontrib><creatorcontrib>Liu, Wei</creatorcontrib><creatorcontrib>Choi, Chi-Fung</creatorcontrib><creatorcontrib>Chan, Hoi-Shan</creatorcontrib><creatorcontrib>Ma, Changqin</creatorcontrib><creatorcontrib>Ng, Dennis K. P.</creatorcontrib><creatorcontrib>Jiang, Jianzhuang</creatorcontrib><title>Synthesis, Structure, and Spectroscopic and Electrochemical Properties of Heteroleptic Bis(phthalocyaninato) Rare Earth Complexes with a C4 Symmetry</title><title>Helvetica chimica acta</title><addtitle>HCA</addtitle><description>A series of eleven heteroleptic bis(phthalocyaninato) rare earth double‐deckers [MIII(pc){pc(α‐OC5H11)4}] 1–11 (M=Y, SmLu; pc=phthalocyaninato; pc(α‐OC5H11)4=1,8,15,22‐tetrakis(1‐ethylpropoxy)phthalocyaninato) were prepared as racemic mixtures by [MIII(pc)(acac)]‐induced (acac=acetylacetonato) cyclic tetramerization of 3‐(1‐ethylpropoxy)phthalonitrile in the presence of 1,8‐diazabicyclo[5.4.0]undec‐7‐ene (DBU) in refluxing pentanol. These compounds could also be prepared by treating [MIII(pc)(acac)] with the metal‐free phthalocyanine H2{pc(α‐OC5H11)4} in refluxing octanol. The whole series of double‐decker complexes 1–11 were characterized by elemental analysis and various spectroscopic methods. The molecular structures of the Sm, Eu, and Er complexes 1, 2, and 8, respectively, were also determined by single‐crystal X‐ray diffraction analysis. The effects of the rare earth ion size on the reaction yield, molecular structure, and spectroscopic and electrochemical properties of these complexes were systematically examined.</description><issn>0018-019X</issn><issn>1522-2675</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2004</creationdate><recordtype>article</recordtype><recordid>eNo9kMtO8zAQhS0EEuWyZe0lSATGSRPHS_5QKKjiVhDsrKk7UcyfNJFtBHkPHphwUVejczTfSPMxdiDgRADEp1Vt8CQGGCuIE7HBRiKN4yjOZLrJRgAij0Col2224_0rACgFcsQ-5_0qVOStP-bz4N5MeHN0zHG15POOTHCtN21nzU8zqX8aU1FjDdb8zrUduWDJ87bkUwrk2pq6MKz_s_6wq0KFdWt6XNkVhvaIP6AjPkEXKl60TVfTx4C-2yEiL8Z83jcNBdfvsa0Sa0_7f3OXPV1MHotpNLu9vCrOZpEVaSai4c8chSS1UGmSlbnKYjJGCCjVYqzKTJZS4XIJIkFVqlKKMapUprlZ5IhgKNll6vfuu62p152zDbpeC9DfQvW3UL0Wqqez4mydBjb6Za0P9LFm0f3XmUxkqp9vLvV9nF6f5_mFfk6-AHBqfq8</recordid><startdate>200410</startdate><enddate>200410</enddate><creator>Bian, Yongzhong</creator><creator>Wang, Rongming</creator><creator>Wang, Daqi</creator><creator>Zhu, Pehua</creator><creator>Li, Renjie</creator><creator>Dou, Jianmin</creator><creator>Liu, Wei</creator><creator>Choi, Chi-Fung</creator><creator>Chan, Hoi-Shan</creator><creator>Ma, Changqin</creator><creator>Ng, Dennis K. 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P. ; Jiang, Jianzhuang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-i1561-9028a17e9b9536f8962ecc110f9b49f67f79add013a9f9f714a95758cb8aa0ce3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2004</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Bian, Yongzhong</creatorcontrib><creatorcontrib>Wang, Rongming</creatorcontrib><creatorcontrib>Wang, Daqi</creatorcontrib><creatorcontrib>Zhu, Pehua</creatorcontrib><creatorcontrib>Li, Renjie</creatorcontrib><creatorcontrib>Dou, Jianmin</creatorcontrib><creatorcontrib>Liu, Wei</creatorcontrib><creatorcontrib>Choi, Chi-Fung</creatorcontrib><creatorcontrib>Chan, Hoi-Shan</creatorcontrib><creatorcontrib>Ma, Changqin</creatorcontrib><creatorcontrib>Ng, Dennis K. P.</creatorcontrib><creatorcontrib>Jiang, Jianzhuang</creatorcontrib><collection>Istex</collection><jtitle>Helvetica chimica acta</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Bian, Yongzhong</au><au>Wang, Rongming</au><au>Wang, Daqi</au><au>Zhu, Pehua</au><au>Li, Renjie</au><au>Dou, Jianmin</au><au>Liu, Wei</au><au>Choi, Chi-Fung</au><au>Chan, Hoi-Shan</au><au>Ma, Changqin</au><au>Ng, Dennis K. P.</au><au>Jiang, Jianzhuang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis, Structure, and Spectroscopic and Electrochemical Properties of Heteroleptic Bis(phthalocyaninato) Rare Earth Complexes with a C4 Symmetry</atitle><jtitle>Helvetica chimica acta</jtitle><addtitle>HCA</addtitle><date>2004-10</date><risdate>2004</risdate><volume>87</volume><issue>10</issue><spage>2581</spage><epage>2596</epage><pages>2581-2596</pages><issn>0018-019X</issn><eissn>1522-2675</eissn><abstract>A series of eleven heteroleptic bis(phthalocyaninato) rare earth double‐deckers [MIII(pc){pc(α‐OC5H11)4}] 1–11 (M=Y, SmLu; pc=phthalocyaninato; pc(α‐OC5H11)4=1,8,15,22‐tetrakis(1‐ethylpropoxy)phthalocyaninato) were prepared as racemic mixtures by [MIII(pc)(acac)]‐induced (acac=acetylacetonato) cyclic tetramerization of 3‐(1‐ethylpropoxy)phthalonitrile in the presence of 1,8‐diazabicyclo[5.4.0]undec‐7‐ene (DBU) in refluxing pentanol. These compounds could also be prepared by treating [MIII(pc)(acac)] with the metal‐free phthalocyanine H2{pc(α‐OC5H11)4} in refluxing octanol. The whole series of double‐decker complexes 1–11 were characterized by elemental analysis and various spectroscopic methods. The molecular structures of the Sm, Eu, and Er complexes 1, 2, and 8, respectively, were also determined by single‐crystal X‐ray diffraction analysis. The effects of the rare earth ion size on the reaction yield, molecular structure, and spectroscopic and electrochemical properties of these complexes were systematically examined.</abstract><cop>Zürich</cop><pub>WILEY-VCH Verlag</pub><doi>10.1002/hlca.200490231</doi><tpages>16</tpages></addata></record> |
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| title | Synthesis, Structure, and Spectroscopic and Electrochemical Properties of Heteroleptic Bis(phthalocyaninato) Rare Earth Complexes with a C4 Symmetry |
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