13C Chemical shifts and 13C15N coupling constants of some 15N-labelled bridgehead nitro compounds

Measurement of the 13C NMR spectra of the bridgehead nitro compounds 1a–5a has been performed. It is found that one‐bond 13C15N coupling is not necessarily a reflection of the degree of s character of the bridgehead carbon exocyclic bonding orbital. Although the magnitude of vicinal coupling to the...

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Veröffentlicht in:	Heteroatom chemistry 1992-02, Vol.3 (1), p.33-36
Hauptverfasser:	Della, Ernest W., Janowski, Wit K., Kasum, Bruno, Kirkbride, K. Paul, Shirley, Neil J.
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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