Investigations of a highly crowded phosphino-substituted biphenyl: A precursor for a λ3, λ5-diphosphaphenanthrene
The synthesis of 2,2′‐bis(bis(dimethylamino)‐phosphino)‐3,3′5,5′‐tetra‐tert‐butylbiphennyl (5) is described. It was extensively studied by 1H, 13C, and 31P NMR spectroscopy. Furthermore, the X‐ray analysis of 5 is reported. Crystals of 5 are tetragonal, space group P¯421c, a = b = 24.770 (3) Å, c =...
Gespeichert in:
| Veröffentlicht in: | Heteroatom chemistry 1991-02, Vol.2 (1), p.17-28 |
|---|---|
| Hauptverfasser: | , , , , , , |
| Format: | Artikel |
| Sprache: | eng ; jpn |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 28 |
|---|---|
| container_issue | 1 |
| container_start_page | 17 |
| container_title | Heteroatom chemistry |
| container_volume | 2 |
| creator | Van Den Winkel, Yvar Van Der Laarse, Jeroen De Kanter, Frans J. J. Van Der Does, Thomas Bickelhaupt, Friedrich Smeets, Wilberth J. J. Spek, Anthony L. |
| description | The synthesis of 2,2′‐bis(bis(dimethylamino)‐phosphino)‐3,3′5,5′‐tetra‐tert‐butylbiphennyl (5) is described. It was extensively studied by 1H, 13C, and 31P NMR spectroscopy. Furthermore, the X‐ray analysis of 5 is reported. Crystals of 5 are tetragonal, space group P¯421c, a = b = 24.770 (3) Å, c = 12.658 (4) Å, Z = 8. The surprising reaction of 5 with proton acids leading to the formation of various phosphorus containing five‐ and six‐membered ring compounds is discussed. On reaction of one of the six‐membered ring compounds (9) with magnesium in THF, a λ3, λ5‐diphosphaphenanthrene (19) was obtained. |
| doi_str_mv | 10.1002/hc.520020104 |
| format | Article |
| fullrecord | <record><control><sourceid>wiley_istex</sourceid><recordid>TN_cdi_wiley_primary_10_1002_hc_520020104_HC520020104</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>HC520020104</sourcerecordid><originalsourceid>FETCH-LOGICAL-i1504-aeb1b6d82d117161c20b4effff113652a3347d68653b437cbafea3939351a64c3</originalsourceid><addsrcrecordid>eNo9UEtOwzAQtRBIlMKOA_gAuHhiO0nZVRX9qcAGVMTGchKnNpQkslNKzsYdOBOuijqjmXkavTcaPYSugQ6A0ujW5AMRBUCB8hPUAzpMCdAETveYRySBmJ2jC-_fKQXgw7SH_Lz60r61a9XauvK4LrHCxq7NpsO5q3eFLnBjat8YW9XEb7PAbbdt2Ga2MbrqNnd4hBun863ztcNlKIV_f9hNaIIU9iBWe66qWuN0pS_RWak2Xl_9zz56mdw_j2dk-TSdj0dLYkFQTpTOIIuLNCoAwueQRzTjugwBwGIRKcZ4UsRpLFjGWZJnqtSKDUMKUDHPWR-Jw92d3ehONs5-KtdJoHLvljS5PLolZ-MjDjpy0Fnf6u-jTrkPGScsEXL1OJWrh9Xi7fVxISfsD69Zcig</addsrcrecordid><sourcetype>Publisher</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Investigations of a highly crowded phosphino-substituted biphenyl: A precursor for a λ3, λ5-diphosphaphenanthrene</title><source>Alma/SFX Local Collection</source><creator>Van Den Winkel, Yvar ; Van Der Laarse, Jeroen ; De Kanter, Frans J. J. ; Van Der Does, Thomas ; Bickelhaupt, Friedrich ; Smeets, Wilberth J. J. ; Spek, Anthony L.</creator><creatorcontrib>Van Den Winkel, Yvar ; Van Der Laarse, Jeroen ; De Kanter, Frans J. J. ; Van Der Does, Thomas ; Bickelhaupt, Friedrich ; Smeets, Wilberth J. J. ; Spek, Anthony L.</creatorcontrib><description>The synthesis of 2,2′‐bis(bis(dimethylamino)‐phosphino)‐3,3′5,5′‐tetra‐tert‐butylbiphennyl (5) is described. It was extensively studied by 1H, 13C, and 31P NMR spectroscopy. Furthermore, the X‐ray analysis of 5 is reported. Crystals of 5 are tetragonal, space group P¯421c, a = b = 24.770 (3) Å, c = 12.658 (4) Å, Z = 8. The surprising reaction of 5 with proton acids leading to the formation of various phosphorus containing five‐ and six‐membered ring compounds is discussed. On reaction of one of the six‐membered ring compounds (9) with magnesium in THF, a λ3, λ5‐diphosphaphenanthrene (19) was obtained.</description><identifier>ISSN: 1042-7163</identifier><identifier>EISSN: 1098-1071</identifier><identifier>DOI: 10.1002/hc.520020104</identifier><language>eng ; jpn</language><publisher>Florida: VCH Publishers, Inc</publisher><ispartof>Heteroatom chemistry, 1991-02, Vol.2 (1), p.17-28</ispartof><rights>Copyright © 1991 VCH Publishers, Inc.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Van Den Winkel, Yvar</creatorcontrib><creatorcontrib>Van Der Laarse, Jeroen</creatorcontrib><creatorcontrib>De Kanter, Frans J. J.</creatorcontrib><creatorcontrib>Van Der Does, Thomas</creatorcontrib><creatorcontrib>Bickelhaupt, Friedrich</creatorcontrib><creatorcontrib>Smeets, Wilberth J. J.</creatorcontrib><creatorcontrib>Spek, Anthony L.</creatorcontrib><title>Investigations of a highly crowded phosphino-substituted biphenyl: A precursor for a λ3, λ5-diphosphaphenanthrene</title><title>Heteroatom chemistry</title><addtitle>Heteroatom Chem</addtitle><description>The synthesis of 2,2′‐bis(bis(dimethylamino)‐phosphino)‐3,3′5,5′‐tetra‐tert‐butylbiphennyl (5) is described. It was extensively studied by 1H, 13C, and 31P NMR spectroscopy. Furthermore, the X‐ray analysis of 5 is reported. Crystals of 5 are tetragonal, space group P¯421c, a = b = 24.770 (3) Å, c = 12.658 (4) Å, Z = 8. The surprising reaction of 5 with proton acids leading to the formation of various phosphorus containing five‐ and six‐membered ring compounds is discussed. On reaction of one of the six‐membered ring compounds (9) with magnesium in THF, a λ3, λ5‐diphosphaphenanthrene (19) was obtained.</description><issn>1042-7163</issn><issn>1098-1071</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1991</creationdate><recordtype>article</recordtype><recordid>eNo9UEtOwzAQtRBIlMKOA_gAuHhiO0nZVRX9qcAGVMTGchKnNpQkslNKzsYdOBOuijqjmXkavTcaPYSugQ6A0ujW5AMRBUCB8hPUAzpMCdAETveYRySBmJ2jC-_fKQXgw7SH_Lz60r61a9XauvK4LrHCxq7NpsO5q3eFLnBjat8YW9XEb7PAbbdt2Ga2MbrqNnd4hBun863ztcNlKIV_f9hNaIIU9iBWe66qWuN0pS_RWak2Xl_9zz56mdw_j2dk-TSdj0dLYkFQTpTOIIuLNCoAwueQRzTjugwBwGIRKcZ4UsRpLFjGWZJnqtSKDUMKUDHPWR-Jw92d3ehONs5-KtdJoHLvljS5PLolZ-MjDjpy0Fnf6u-jTrkPGScsEXL1OJWrh9Xi7fVxISfsD69Zcig</recordid><startdate>199102</startdate><enddate>199102</enddate><creator>Van Den Winkel, Yvar</creator><creator>Van Der Laarse, Jeroen</creator><creator>De Kanter, Frans J. J.</creator><creator>Van Der Does, Thomas</creator><creator>Bickelhaupt, Friedrich</creator><creator>Smeets, Wilberth J. J.</creator><creator>Spek, Anthony L.</creator><general>VCH Publishers, Inc</general><scope>BSCLL</scope></search><sort><creationdate>199102</creationdate><title>Investigations of a highly crowded phosphino-substituted biphenyl: A precursor for a λ3, λ5-diphosphaphenanthrene</title><author>Van Den Winkel, Yvar ; Van Der Laarse, Jeroen ; De Kanter, Frans J. J. ; Van Der Does, Thomas ; Bickelhaupt, Friedrich ; Smeets, Wilberth J. J. ; Spek, Anthony L.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-i1504-aeb1b6d82d117161c20b4effff113652a3347d68653b437cbafea3939351a64c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng ; jpn</language><creationdate>1991</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Van Den Winkel, Yvar</creatorcontrib><creatorcontrib>Van Der Laarse, Jeroen</creatorcontrib><creatorcontrib>De Kanter, Frans J. J.</creatorcontrib><creatorcontrib>Van Der Does, Thomas</creatorcontrib><creatorcontrib>Bickelhaupt, Friedrich</creatorcontrib><creatorcontrib>Smeets, Wilberth J. J.</creatorcontrib><creatorcontrib>Spek, Anthony L.</creatorcontrib><collection>Istex</collection><jtitle>Heteroatom chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Van Den Winkel, Yvar</au><au>Van Der Laarse, Jeroen</au><au>De Kanter, Frans J. J.</au><au>Van Der Does, Thomas</au><au>Bickelhaupt, Friedrich</au><au>Smeets, Wilberth J. J.</au><au>Spek, Anthony L.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Investigations of a highly crowded phosphino-substituted biphenyl: A precursor for a λ3, λ5-diphosphaphenanthrene</atitle><jtitle>Heteroatom chemistry</jtitle><addtitle>Heteroatom Chem</addtitle><date>1991-02</date><risdate>1991</risdate><volume>2</volume><issue>1</issue><spage>17</spage><epage>28</epage><pages>17-28</pages><issn>1042-7163</issn><eissn>1098-1071</eissn><abstract>The synthesis of 2,2′‐bis(bis(dimethylamino)‐phosphino)‐3,3′5,5′‐tetra‐tert‐butylbiphennyl (5) is described. It was extensively studied by 1H, 13C, and 31P NMR spectroscopy. Furthermore, the X‐ray analysis of 5 is reported. Crystals of 5 are tetragonal, space group P¯421c, a = b = 24.770 (3) Å, c = 12.658 (4) Å, Z = 8. The surprising reaction of 5 with proton acids leading to the formation of various phosphorus containing five‐ and six‐membered ring compounds is discussed. On reaction of one of the six‐membered ring compounds (9) with magnesium in THF, a λ3, λ5‐diphosphaphenanthrene (19) was obtained.</abstract><cop>Florida</cop><pub>VCH Publishers, Inc</pub><doi>10.1002/hc.520020104</doi><tpages>12</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1042-7163 |
| ispartof | Heteroatom chemistry, 1991-02, Vol.2 (1), p.17-28 |
| issn | 1042-7163 1098-1071 |
| language | eng ; jpn |
| recordid | cdi_wiley_primary_10_1002_hc_520020104_HC520020104 |
| source | Alma/SFX Local Collection |
| title | Investigations of a highly crowded phosphino-substituted biphenyl: A precursor for a λ3, λ5-diphosphaphenanthrene |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-22T13%3A57%3A28IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-wiley_istex&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Investigations%20of%20a%20highly%20crowded%20phosphino-substituted%20biphenyl:%20A%20precursor%20for%20a%20%CE%BB3,%20%CE%BB5-diphosphaphenanthrene&rft.jtitle=Heteroatom%20chemistry&rft.au=Van%20Den%20Winkel,%20Yvar&rft.date=1991-02&rft.volume=2&rft.issue=1&rft.spage=17&rft.epage=28&rft.pages=17-28&rft.issn=1042-7163&rft.eissn=1098-1071&rft_id=info:doi/10.1002/hc.520020104&rft_dat=%3Cwiley_istex%3EHC520020104%3C/wiley_istex%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |