All‐solid‐state Fluoride Ion‐selective Electrode using LaF3 Single Crystal with Poly(3,4‐ethylenedioxythiophene) as Solid Contact Layer
An all‐solid‐state fluoride ion‐selective electrode (ISE) was prepared using LaF3 single crystal with poly(3,4‐ethylenedioxythiophene (PEDOT) as the solid contact layer. In contrast to polymer‐based ISEs, crystalline membrane‐based ISEs have not been used for all‐solid‐state device, thereby prohibit...
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| Veröffentlicht in: | Electroanalysis (New York, N.Y.) N.Y.), 2023-04, Vol.35 (4), p.n/a |
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| container_title | Electroanalysis (New York, N.Y.) |
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| creator | Yamada, Tetsuya Kanda, Kaito Yanagida, Yasuko Mayanagi, Gen Washio, Jumpei Takahashi, Nobuhiro |
| description | An all‐solid‐state fluoride ion‐selective electrode (ISE) was prepared using LaF3 single crystal with poly(3,4‐ethylenedioxythiophene (PEDOT) as the solid contact layer. In contrast to polymer‐based ISEs, crystalline membrane‐based ISEs have not been used for all‐solid‐state device, thereby prohibiting the integration of ISEs on a chip. The all‐solid‐state fluoride ISE developed in this study exhibited superior sensitivity (−56.0±0.9 mV/dec) and selectivity compared to those of conventional inner filling solution ISE. The effects of PEDOT as a solid contact layer were analyzed using chronopotentiometry and electrochemical impedance spectroscopy, which revealed that PEDOT promoted electrode stability. The all‐solid‐state device can miniaturize the fluoride ISE and facilitate environmental, industrial, agricultural, and physiological monitoring. |
| doi_str_mv | 10.1002/elan.202200103 |
| format | Article |
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In contrast to polymer‐based ISEs, crystalline membrane‐based ISEs have not been used for all‐solid‐state device, thereby prohibiting the integration of ISEs on a chip. The all‐solid‐state fluoride ISE developed in this study exhibited superior sensitivity (−56.0±0.9 mV/dec) and selectivity compared to those of conventional inner filling solution ISE. The effects of PEDOT as a solid contact layer were analyzed using chronopotentiometry and electrochemical impedance spectroscopy, which revealed that PEDOT promoted electrode stability. The all‐solid‐state device can miniaturize the fluoride ISE and facilitate environmental, industrial, agricultural, and physiological monitoring.</description><identifier>ISSN: 1040-0397</identifier><identifier>EISSN: 1521-4109</identifier><identifier>DOI: 10.1002/elan.202200103</identifier><language>eng</language><subject>Electrochemistry ; fluoride ion-selective electrode ; poly(3,4-ethylenedioxythiophene) ; sensors ; solid contact ion-selective electrode</subject><ispartof>Electroanalysis (New York, N.Y.), 2023-04, Vol.35 (4), p.n/a</ispartof><rights>2022 The Authors. 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The all‐solid‐state device can miniaturize the fluoride ISE and facilitate environmental, industrial, agricultural, and physiological monitoring.</description><subject>Electrochemistry</subject><subject>fluoride ion-selective electrode</subject><subject>poly(3,4-ethylenedioxythiophene)</subject><subject>sensors</subject><subject>solid contact ion-selective electrode</subject><issn>1040-0397</issn><issn>1521-4109</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><sourceid>24P</sourceid><sourceid>WIN</sourceid><recordid>eNo9UMFKw0AUXETBWr163qOCqW93kyZ7LKXVQlCheg67zVuzsmZLsrXm5h_oN_olJiieZuY9ZgaGkHMGEwbAr9GpesKBcwAG4oCMWMJZFDOQhz2HGCIQMj0mJ237AgByGssR-Zw59_3x1XpnywGDCkiXbucbWyJd-Xo4osNNsG9IFwNpfP_ZtbZ-prlaCrrumUM6b7re7ejehoo-eNddiKu4d2OoOoc1lta_d6Gyflv16pKqlq6HVjr3dVCb0Id12JySI6Nci2d_OCZPy8Xj_DbK729W81ketTxORGTSOJMq0ToTpQZpMmNwKjTjCc8My1DHcak2AkQpUBhulNRMC2CpllOdGi7GRP7m7q3Drtg29lU1XcGgGLYshi2L_y2LRT67-1fiB9XgcTg</recordid><startdate>202304</startdate><enddate>202304</enddate><creator>Yamada, Tetsuya</creator><creator>Kanda, Kaito</creator><creator>Yanagida, Yasuko</creator><creator>Mayanagi, Gen</creator><creator>Washio, Jumpei</creator><creator>Takahashi, Nobuhiro</creator><scope>24P</scope><scope>WIN</scope><orcidid>https://orcid.org/0000-0002-1712-6027</orcidid></search><sort><creationdate>202304</creationdate><title>All‐solid‐state Fluoride Ion‐selective Electrode using LaF3 Single Crystal with Poly(3,4‐ethylenedioxythiophene) as Solid Contact Layer</title><author>Yamada, Tetsuya ; Kanda, Kaito ; Yanagida, Yasuko ; Mayanagi, Gen ; Washio, Jumpei ; Takahashi, Nobuhiro</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-s2453-f7489a5bb83db09f8ffe63b12528f18eb44dac303d3e3f2fa9b1b3017b96b7f23</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Electrochemistry</topic><topic>fluoride ion-selective electrode</topic><topic>poly(3,4-ethylenedioxythiophene)</topic><topic>sensors</topic><topic>solid contact ion-selective electrode</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yamada, Tetsuya</creatorcontrib><creatorcontrib>Kanda, Kaito</creatorcontrib><creatorcontrib>Yanagida, Yasuko</creatorcontrib><creatorcontrib>Mayanagi, Gen</creatorcontrib><creatorcontrib>Washio, Jumpei</creatorcontrib><creatorcontrib>Takahashi, Nobuhiro</creatorcontrib><collection>Wiley Online Library Open Access</collection><collection>Wiley Online Library Free Content</collection><jtitle>Electroanalysis (New York, N.Y.)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yamada, Tetsuya</au><au>Kanda, Kaito</au><au>Yanagida, Yasuko</au><au>Mayanagi, Gen</au><au>Washio, Jumpei</au><au>Takahashi, Nobuhiro</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>All‐solid‐state Fluoride Ion‐selective Electrode using LaF3 Single Crystal with Poly(3,4‐ethylenedioxythiophene) as Solid Contact Layer</atitle><jtitle>Electroanalysis (New York, N.Y.)</jtitle><date>2023-04</date><risdate>2023</risdate><volume>35</volume><issue>4</issue><epage>n/a</epage><issn>1040-0397</issn><eissn>1521-4109</eissn><abstract>An all‐solid‐state fluoride ion‐selective electrode (ISE) was prepared using LaF3 single crystal with poly(3,4‐ethylenedioxythiophene (PEDOT) as the solid contact layer. 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| ispartof | Electroanalysis (New York, N.Y.), 2023-04, Vol.35 (4), p.n/a |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Electrochemistry fluoride ion-selective electrode poly(3,4-ethylenedioxythiophene) sensors solid contact ion-selective electrode |
| title | All‐solid‐state Fluoride Ion‐selective Electrode using LaF3 Single Crystal with Poly(3,4‐ethylenedioxythiophene) as Solid Contact Layer |
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