The Crucial Role of S‐oxidation State on the Selectivity and Reaction Rate of the 1,3‐Dipolar Cycloaddition of Azomethine Ylides and Homochiral Thiazolines

The novel enantiopure synthesis of protected proline‐cysteine analogs by means of 1,3‐dipolar cycloaddition of homochiral thiazolines and azomethine ylides is described. The important role of the oxidation state of the sulfur atom of the dipolarophile in such reaction is demonstrated affecting stron...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	European journal of organic chemistry 2021-05, Vol.2021 (20), p.2843-2854
Hauptverfasser:	Gracia‐Vitoria, Jaime, Osante, Iñaki, Cativiela, Carlos
Format:	Artikel
Sprache:	eng
Schlagworte:	Analogs Azomethine ylides Chemistry Chemistry, Organic Cycloaddition Cysteine Heterocycles Oxidation Physical Sciences Proline Regioselectivity Rings (mathematics) Science & Technology Selectivity Sulfur Synthetic methods Valence
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

Schreiben Sie den ersten Kommentar!