Oxidative Coupling Reactions Mediated by MoCl5 Leading to 2,2′-Cyclolignans: The Specific Role of HCl

The scope and performance of oxidative coupling reaction using MoCl5 can be significantly improved by employing Lewis‐acidic additives such as TiCl4, SnCl4, or SiCl4. Since the by‐product, HCl, plays a particular function as an inhibitor for MoCl5 by forming chloro complexes, exploiting typical chlo...

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Veröffentlicht in:	European journal of organic chemistry 2003-09, Vol.2003 (18), p.3549-3554
Hauptverfasser:	Kramer, Beate, Fröhlich, Roland, Waldvogel, Siegfried R.
Format:	Artikel
Sprache:	eng
Schlagworte:	Biaryls C-C coupling Cyclization Lewis acids Molybdenum
Online-Zugang:	Volltext
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