Discrete versus 1D Compounds based on Pentagonal Bipyramid Coordination Geometries: A Matter of Solubility?

A series of heterometallic compounds based on the association of trans‐dicyanido Cr(III) complex [Cr(L)(CN)2]K ⋅ 2H2O and several divalent [MnII(H2Ln)Cl2] heptacoordinated complexes, where Ln stands for pentadentate ligands featuring a planar N3O2 coordination pocket and various substituents (NH2, c...

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Veröffentlicht in:	European journal of inorganic chemistry 2021-12, Vol.2021 (48), p.5112-5118
Hauptverfasser:	Pichon, Céline, Duhayon, Carine, Delahaye, Emilie, Sutter, Jean‐Pascal
Format:	Artikel
Sprache:	eng
Schlagworte:	Chain compounds Chemical Sciences Coordination chemistry Coordination polymers Crystal structure Crystallization Cyanidometallates Heptacoordination Heterometallic complexes Inorganic chemistry Magnetic properties Stoichiometry
Online-Zugang:	Volltext
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