Activation of CO2, CS2, and Dehydrogenation of Formic Acid Catalyzed by Iron(II) Hydride Complexes

Fluoroarylimine‐stabilized iron(II) hydrides were used for the activation of CO2. The resulting iron(II) formate complex 6, which was obtained by formal CO2 insertion into the Fe–H bond, turned out to be unstable in solution. CO was suitable for the formation of stable analogues of complex 6. From t...

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Veröffentlicht in:	European journal of inorganic chemistry 2016-11, Vol.2016 (33), p.5205-5214
Hauptverfasser:	Wang, Lin, Sun, Hongjian, Zuo, Zhenyu, Li, Xiaoyan, Xu, Weiqin, Langer, Robert, Fuhr, Olaf, Fenske, Dieter
Format:	Artikel
Sprache:	eng
Schlagworte:	Carbon dioxide Carbon disulfide Dehydrogenation Hydrides Iron
Online-Zugang:	Volltext
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