Growth, Magnetic, and Optoelectronic Properties of Fe Doped MAPbI3 Crystals

Organic–inorganic hybrid perovskite is a wide family in which CH3NH3PbI3 is investigated mostly due to its superior optoelectronic and photovoltaic properties in solar cells. The doping in CH3NH3PbI3 is an effective way to adjust their properties. Fe is chosen as a dopant and CH3NH3(Pb1−xFex)I3 (x =...

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Veröffentlicht in:Crystal research and technology (1979) 2022-04, Vol.57 (4), p.n/a
Hauptverfasser: Fu, Haoran, Shu, Huchen, Xu, Zhiwen, Tao, Hong, Fu, Qiuming, Zhao, Hongyang, Weng, Jun, Xiong, Liwei
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container_issue 4
container_start_page
container_title Crystal research and technology (1979)
container_volume 57
creator Fu, Haoran
Shu, Huchen
Xu, Zhiwen
Tao, Hong
Fu, Qiuming
Zhao, Hongyang
Weng, Jun
Xiong, Liwei
description Organic–inorganic hybrid perovskite is a wide family in which CH3NH3PbI3 is investigated mostly due to its superior optoelectronic and photovoltaic properties in solar cells. The doping in CH3NH3PbI3 is an effective way to adjust their properties. Fe is chosen as a dopant and CH3NH3(Pb1−xFex)I3 (x = 0, 0.2, 0.6) single crystals are grown successfully. Their optoelectronic and magnetic properties are investigated. It shows antiferromagnetic when x = 0.6 while others show paramagnetic. The photodetector when x = 0.6 also shows best behavior. It is meaningful to design such ferromagnetic photovoltaic halide perovskite and investigate the role of the doping magnetic elements. MAPbI3, MA(Pb0.8Fe0.2)I3, and MA(Pb0.4Fe0.6)I3 single crystals are grown by solution method. The Fe doping in perovskite MAPbI3 gives the crystal antiferromagnetic with Neel temperature at 23 K. And even small amount of doping Fe can improve the photodetector performance of MAPbI3.
doi_str_mv 10.1002/crat.202100260
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photodetector
title Growth, Magnetic, and Optoelectronic Properties of Fe Doped MAPbI3 Crystals
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